The global ocean currently absorbs over a third of anthropogenic carbon dioxide (CO₂) emissions, slowing down the growth of atmospheric CO₂, and thus moderating climate change. However, there is significant variability in the strength of the ocean carbon sink on interannual to decadal timescales. There are also uncertainties in the ocean carbon sink, a source of which lies in the coastal ocean. Coastal carbon fluxes are globally relevant and highly variable, but due to the paucity of observations, the coastal ocean remains largely unconstrained. Quantifying and understanding the variability of the ocean carbon sink, and constraining its uncertainties, is essential for supporting climate policy and predicting how the ocean will continue to moderate climate change in the future. This is challenging due to the complex physical and biogeochemical processes in the ocean, as well as the limited observations of ocean carbon. The goal of this thesis is to contribute to the understanding of the ocean carbon cycle and its variability with observations of CO₂ fluxes in the coastal ocean (Chapter 2), a multi-model study of surface carbon interannual variability (Chapter 3), and a mechanistic investigation of decadal variability of air-sea CO₂ fluxes in the global ocean (Chapter 4). (Chapter 2) Jamaica Bay is a hypereutrophic coastal urban estuary within the land-ocean aquatic continuum. Anthropogenic perturbations to the carbon cycle of the continuum are often excluded from global carbon budgets. Studies have shown that not accounting for the lateral transport of anthropogenic carbon through the continuum can lead to an overestimation of land carbon sinks and an underestimation of ocean carbon sinks. In this study, we used the direct covariance method to make direct estimates of CO₂ fluxes in Jamaica Bay. Over a 587-day observational study, Jamaica Bay emitted CO₂ to the atmosphere at an average rate of 130 gC/m2/yr. However, we find that the waters within the estuary are a strong CO₂ sink (-170 gC/m2/yr). Thus, on average, air-water CO₂ fluxes damp estuary emissions. We find that the water CO₂ sink is strongest in the summer due to the growth of intense algal blooms which likely drawdown CO₂ via photosynthesis. Although the direction of air-water CO₂ flux is ultimately a function of surface carbon concentrations, we find that in the summer, sea-breeze is a near-daily forcing agent for air-water CO₂ fluxes, contributing up to 43% of the mean summer water CO₂ sink rate. (Chapter 3) The El Nino-Southern Oscillation (ENSO) in the equatorial Pacific is the dominant mode of global air-sea CO₂ flux interannual variability (IAV). Air-sea CO2 fluxes are driven by the difference between atmospheric and surface ocean pCO₂, with variability of the latter driving flux variability. Previous studies found that models in Coupled Model Intercomparison Project Phase 5 (CMIP5) failed to reproduce the observed ENSO-related pattern of CO₂ fluxes and had weak pCO₂ IAV, which were explained by both weak upwelling IAV and weak mean vertical DIC gradients. We assess whether the latest generation of CMIP6 models can reproduce equatorial Pacific pCO₂ IAV by validating models against observations-based data products. We decompose pCO₂ IAV into thermally and non-thermally driven anomalies to examine the balance between these competing anomalies, which explain the total pCO₂ IAV. The majority of CMIP6 models underestimate pCO₂ IAV, while they overestimate SST IAV. Insufficient compensation of non-thermal pCO₂ to thermal pCO₂ IAV in models results in weak total pCO₂ IAV. We compare the relative strengths of the vertical transport of temperature and DIC and evaluate their contributions to thermal and non-thermal pCO₂ anomalies. Model-to-observations-based product comparisons reveal that modeled mean vertical DIC gradients are biased weak relative to their mean vertical temperature gradients, but upwelling acting on these gradients is insufficient to explain the relative magnitudes of thermal and non-thermal pCO₂ anomalies. (Chapter 4) The ocean carbon sink has absorbed about 25% of anthropogenic emissions, thus mitigating the effects of climate change. Over time, the ocean carbon sink has grown almost proportionally with the growth of atmospheric CO₂ concentrations. However, natural variability in the ocean carbon sink combined with large uncertainties, makes it hard to distinguish changes in the ocean sink due to natural variability versus the forced-trend. Thus, there is a need to understand and quantify the variability in the ocean carbon sink. Using the LDEO-Hybrid Physics Data product (1959-2020), we assess the decadal variability of global air-sea CO₂ fluxes. Here, we compare regional contributions to the decadal variability of the global ocean carbon sink and evaluate global patterns of decadal changes to elucidate the mechanisms that drive the dominant mode of global air-sea CO₂ flux decadal variability. We find that the dominant mode of decadal air-sea CO₂ flux variability exhibits strong synchronous signals over the tropical Pacific and Southern Ocean. We suggest that the synchronicity between the tropical Pacific and the Southern Ocean is modulated by the Pacific Decadal Oscillation (PDO) index, which is connected to the Multivariate ENSO Index (MEI). The composite patterns over the tropical Pacific can be explained by ENSO-like mechanisms operating on the decadal timescale, while the composite patterns over the Southern Ocean show a different regime where the westerly winds weakened over the composite period, the mixed layer shoaled, and the Southern Ocean sink weakened. Using a box model, we show that this reduction in mixed layer entrainment drives an accumulation of DIC in the mixed layer, which, when amplified by the high Revelle factor in the Southern Ocean, results in a 14-fold amplification in the surface pCO₂, reducing the ocean's capacity to uptake CO₂.

Exponential growth of heat flux densities in commercial and industrial electronics, and compact heat exchangers demand surfaces and heat sinks with high dissipation rate capabilities. Among different technologies proposed to meet these demands, high-porosity metal foams have attracted the attention of many investigators due to their higher surface area densities as well as higher thermal performance due to the turbulence and tortuosity generated in the flow due to their structure. One of the disadvantages of such metal foams, however, is the attendant higher pressure drop or pumping power penalty. This thesis was undertaken to investigate whether channels partially filled with metal foams can reduce the required pumping power with a minimal loss in thermal performance. The thermo-hydraulic (T-H) performance factor J/F<sup>1/3, where J is the Colburn-J factor and F is the friction factor, was used to compare the relative performance of foams for various values of blocking fractions (B), where B is defined as the ratio of the height of the foam to the height of the channel. The metal foam samples considered were 10 PPI (pores per inch) 6101-T6 Aluminum, with porosity of ∼ 94 − 96%, and B of 1/6, 1/3, 2/3, 5/6, and 1. Each of these samples was attached to an aluminum slab embedded in one of the walls, which had a patch heater that acted as a heat source. A modification was made to all B < 1 configurations by attaching an aluminum plate on top, which then separated the foam-free and the foam-filled flows completely. These configurations are denoted by a 'P' in their names (e.g. B = 1/3P is the plated modification of B = 1/3). Experiments were conducted in an in-house designed wind tunnel, with a test section of 45" in length and a cross-section of 3"X3". Reynolds number (based on channel hydraulic diameter and inlet velocity) was varied from 1,000 to 15,000 to capture the flow domains from laminar to turbulent. The data obtained for the three scenarios namely - 1. Controlled-Flow Scenario 2. Pumping Power Variation with Temperature Difference, and 3. Fan-Based System were analyzed for their thermo-hydraulic performance. The extreme low blocking fractions are evaluated and compared against the dimpled/protruded surfaces, and were found to give superior performance, hence displaying potential as good turbulators. The plated configurations were found to perform better in almost all scenarios when compared to their non-plated counterparts. Furthermore, a new simplified analytical model is introduced that considers the flow in the partially-blocked region as two separate 'parallel' flows, one in the foam-free region and the other in the foam-filled region. The comparison between this novel approach and the analytical solution from the literature shows good agreement, suggesting that this simplified model may be appropriate. This model is then used for determining the foam-filled region flow ratios for the performed experiments, and a correlation is presented. / Master of Science / Portable devices, such as laptops, and mobile phones are trending towards miniaturization and simultaneously becoming more power-hungry, leading to ever-increasing heat flux densities. Growing energy and technology demands require high thermal dissipation rates to be achieved in equipment such as industrial and commercial electronics, data centers, heat exchangers in automobiles, and power plants - both renewable and non-renewable. One of the best ways to enhance convective heat transfer is by increasing the heat transfer surface area. This is traditionally done using fins. A much higher surface area can be achieved using a metal foam instead, along with improving the turbulent mixing of the fluid. The flow through the metal foam, however, faces a higher pressure drop penalty which is one of the major reasons for a continued preference for fins. In this experimental study, we aim at minimizing this pressure drop penalty of a metal-foam heat-sink along with maintaining a respectable heat transfer performance through 'partial-blocking' (filling) of the channel, where the height of the foam is lower than the total channel height. The ratio of metal foam height to the channel height is named as blocking fraction B. A general comparison of the hydraulic, thermal, and thermo-hydraulic (T-H) performance reveals that the ∼ 83.3% plated configuration is capable of superseding the baseline of full blockage. The 'plating' here denotes a slight modification - a solid plate rests on top of the metal foam, separating the foam-free and foam-filled flow. For applications with Re > 10000, ∼ 33.3% plated configuration is highly recommended. For fan-based systems, ∼ 83.3% plated, ∼ 33.3% plated, and 33.3% non-plated configurations emerge as possible alternatives to the fully-blocked case. Furthermore, while considering partial configurations, it is shown that one should go for lower PPI metal foams to improve the flow ratio inside the metal foam. For pressure-drop critical equipment, ∼ 16.7% configuration is found to perform better than the conventional double-protruded walls and other turbulence-enhancing surface treatments. Finally, this thesis presents a novel and simplified approach for estimating the flow ratios for partially-blocked channels using scaling analysis.

The continuous miniaturization of electronic devices and the corresponding increase in computing powers have led to a significant growth in the density of heat dissipation within these devices. This increase in heat generation has challenged conventional air fan cooling and alternative solutions for heat removal are required to avoid overheating and part damage. Micro/Mini channel heat sinks (M/MCHS) that use liquids for heat removal appear as an attractive solution to this problem as they provide large heat transfer area per volume. Mini/microchannels traditionally have suffered from geometrical and material restrictions due to fabrication constraints. An emerging new additive manufacturing technique called binder jetting has the potential to overcome some of those restrictions. In this study, a straight minichannel heat sink is manufactured from stainless steel using binder jetting, and it is experimentally evaluated. The hydraulic performance of the heat sink is tested over a range of Reynolds numbers (150-1200). The comparison between the hydraulic results and standard correlations confirms that the targeted geometry was produced, although the high surface roughness created an early transition from laminar-to-turbulent flow. The heat transfer performance was also experimentally characterized at different heat flux conditions ($3000W/m^2$, $5000W/m^2$, $6500W/m^2$), and a range of Reynolds numbers (150-800). These results indicated that convection heat transfer coefficients on the order of $1000 W/m^2-K$ can be obtained with a simple heat sink design. Finally, the effects of the contact resistance on the results are studied, and contact resistance is shown to have critical importance on the thermal measurements. / Master of Science / The continuous miniaturization of electronic devices and the corresponding increase in computing powers have led to a significant growth in the density of heat dissipation within these devices. This increase in heat generation has challenged conventional air fan cooling and alternative solutions for heat removal are required to avoid overheating and part damage. Micro/Mini channel heat sinks (M/MCHS) that use water instead of air for heat removal appear as an attractive solution to this problem as they provide large heat transfer area per volume due to the small channels. Mini/microchannels are distinguished from conventional channels by the hydraulic diameter, where they range from $10mu m$ to $2mm$. M/MCHS are typically manufactured from a highly conductive metals with the channels fabricated on the surface. However, mini/microchannels traditionally have suffered from geometrical and material restrictions due to fabrication constraints. Complex features like curves or internall channels are difficult or even impossible to manufacture. An emerging new additive manufacturing technique called binder jetting has the potential to overcome some of those restrictions. Binder jetting possess unique advantageous as it uses precise control of a liquid binder applied to a bed of fine powder to create complex geometries Furthermore, it does not require extreme heating during the fabrication process. The advantages of binder jetting include that it is low cost, high speed, can be applied to a variety of materials, and the ability to scale easily in size. In this study, a straight minichannel heat sink is manufactured from stainless steel using binder jetting, and this heat sink is experimentally evaluated. The hydraulic performance of the heat sink is tested over different water flow rates (Reynolds numbers between 150-1200). The comparison between the hydraulic results and standard correlations confirms that the targeted geometry was produced, although the high surface roughness created an early transition from laminar-to-turbulent flow. The surface roughness effect should be considered in future designs of additively manufactured minichannels. The heat transfer performance was also experimentally characterized at different heat flux conditions ($3000W/m^2$, $5000W/m^2$, $6500W/m^2$), and different water flow conditions (Reynolds numbers 150-800). These results indicated that convection heat transfer coefficients on the order of $1000 W/m^2-K$ can be obtained with a simple heat sink design. However, a mismatch between the experimental data and the correlation requires further investigation. Finally, the effects of the contact resistance on the results are studied, and contact resistance is shown to have critical importance on the thermal measurements.

Digital elevation models (DEMs) and their derivatives such as slope, flow direction and flow accumulation maps, are used frequently as inputs to hydrologic and nonpoint source modeling. The depressions which are frequently present in DEMs may represent the actual topography, but are often the result of errors. Creating a depression-free surface is commonly required prior to deriving flow direction, flow accumulation, flow network, and watershed boundary maps. The objectives of this study were: 1) characterize the occurrence of depressions in 30m USGS DEMs and assess correlations to watershed topographic characteristics, and 2) compare the performance of two algorithms used to remove depressions and delineate flow networks from DEMs. Sixty-six watersheds were selected to represent a range of topographic conditions characteristic of the Piedmont and Mountain and Valley regions of Virginia. Analysis was based on USGS 30m DEMs with elevations in integer meters. With few exceptions watersheds fell on single 7.5minute USGS quadrangle sheets, ranged in size from 450 to 3000 hectares, and had average slopes ranging from 3 to 20 percent. ArcView (3.1) with the Spatial Analyst (1.1) extension was used to summarize characteristics of each watershed including slope, elevation range, elevation standard deviation, curvature, channel slope, and drainage density. TOPAZ (ver 1.2) and ArcView were each used to generate a depression-free surface, flow network and watershed area. Characteristics of the areas 'cut' and 'filled' by the algorithms were compared to topographic characteristics of the watersheds. Blue line streams were digitized from scanned USGS 7.5minute topographic maps (DRGs) then rasterized at 30 m for analysis of distance from the derived flow networks. The removal of depressions resulted in changes in elevation values in 0 - 11% of the cells in the watersheds. The percentage of area changed was higher in flatter watersheds. Changed elevation cells resulted in changes in two to three times as many cells in derivative flow direction, flow accumulation and slope grids. Mean fill depth by watershed ranged from 0 to 10 m, with maximum fill depths up to 40 m. In comparison with ArcView, TOPAZ, on average affected 30% fewer cells with less change in elevation. The significance of the difference between ArcView and TOPAZ decreased as watershed slope increased. A spatial assessment of the modified elevation and slope cells showed that depressions in the DEMs occur predominantly on or along the flow network. Flow networks derived by ArcView and TOPAZ were not significantly different from blue line streams digitized from the USGS quadrangles as indicated by a paired t test. Watershed area delineated by ArcView and TOPAZ was different for almost all watersheds, but was generally within 1%. Conclusions from this study are: 1) The depressions in 30 m DEMs can make up a significant portion of the area especially for flatter watersheds; 2) The TOPAZ algorithm performed better than ArcView in minimizing the area modified in the process of creating a depressionless surface, particularly in flatter topography; 3) Areas affected by removing depressions are predominantly adjacent to the stream network; 4) For every elevation cell changed, slopes are changed for two to three cells, on average; and 5) ArcView and TOPAZ derived flow networks closely matched the blue line streams. / Master of Science

Yes / Sensing coverage and network connectivity are two of the most fundamental issues to ensure that there are effective environmental sensing and robust data communication in a WSN application. Random positioning of nodes in a WSN may result in random connectivity, which can cause a large variety of key parameters within the WSN. For example, data latency and battery lifetime can lead to the isolation of nodes, which causes a disconnection between nodes within the network. These problems can be avoided by using mobile data sinks, which travel between nodes that have connection problems. This research aims to design, test and optimise a data collection system that addresses the isolated node problem, as well as to improve the connectivity between sensor nodes and base station, and to reduce the energy consumption simultaneously. In addition, this system will help to solve several problems such as the imbalance of delay and hotspot problems. The effort in this paper is focussed on the feasibility of using the proposed methodology in different applications. More ongoing experimental work will aim to provide a detailed study for advanced applications e.g. transport systems for civil purposes. / European Union’s Horizon 2020 research and innovation programme under grant agreement H2020-MSCA-ITN-2016 SECRET-722424.

During the last decade, the academic interest for Earth’s natural carbon sinks and their role concerning climate change has increased. Today, many scientists around the world are trying to calculate different ecosystem’s potential to sequester and store carbon dioxide from the atmosphere. As a newcomer to the scientific arena, the term ‘blue carbon’ has been well received by scientists in the field. ‘Blue carbon’ highlights the carbon captured and stored by productive ecosystems along the world’s coasts. The term refers to coastal wetlands – such as mangrove forests, salt marshes and seagrass meadows – and it came to life as the scientific community recognized these ecosystems’ significant potential as effective carbon sinks. New research indicates that these ecosystems’ complex and vertical root systems can store much larger amounts of carbon in the soil than any other terrestrial ecosystem. By studying this subject, scientists are trying to understand how these ecosystems can help us in the quest of removing excessive carbon dioxide from the atmosphere. The goal of this thesis is to conduct a literature review, aiming to analyse and compile the new research on ‘blue carbon’ that has been published during the last 10 years. The paper aims to investigate whether the ecosystem’s potential as carbon sinks differ from each other, and what threats they will face in the future. It will additionally review if scientists have been able to unite around any predictions about what the future for ‘blue carbon’ – and its role in mitigating climate change – will look like. / Under det senaste decenniet har intresset kring naturliga kolsänkors potential och roll i att mildra klimatförändringar ökat. Idag är det många forskare som arbetar med att beräkna mängden kol som olika ekosystem runt om världen kan lagra i sin biomassa och i jorden under dess rötter. Som en nykomling på den vetenskapliga arenan, har termen ’blue carbon’ blivit väl mottaget av forskare inom området. ’Blue carbon’ syftar på det kol som fixeras och lagras av de produktiva ekosystemen längs världens kuster. Termen refererar till kustbelägna våtmarker – så som mangroveskogar, saltträsk och sjögräsbäddar – och introducerades efter att den vetenskapliga världen erkänt deras imponerande potential som kolsänkor. Ny forskning tyder på att deras avancerade och vertikala rotsystem kan lagra mer koldioxid i marken än vad vanliga terrestra skogar kan. Genom att studera detta ämne försöker forskare att förstå hur dessa ekosystem kan hjälpa oss att avlägsna överskottet av koldioxid från atmosfären. Målet med denna uppsats är att utföra en litteraturstudie och analysera, samt sammanställa den nya forskningen om ’blue carbon’ som publicerats de senaste 10 åren. Uppsatsen kommer undersöka hur stor skillnad det är mellan de olika ekosystemen och vilka hot de står inför i framtiden. Dessutom kommer den undersöka ifall forskare kommit närmre i att enas kring förutsägelser om framtiden för ’blue carbon’, och hur dess roll i att mildra klimatförändringarna kommer se ut.

The use of gas chromatography isotope ratio mass spectrometry (GC-IRMS) for compound specific stable isotope analysis is an underutilized technique because of the complexity of the instrumentation and high analytical costs. However stable isotopic data, when coupled with concentration measurements, can provide additional information on a compounds production, transformation, loss, and cycling within the biosphere and atmosphere. A GC-IRMS system was developed to accurately and precisely measure δ13C values for numerous oxygenated volatile organic compounds (OVOCs) having natural and anthropogenic sources. The OVOCs include methanol, ethanol, acetone, methyl ethyl ketone, 2-pentanone, and 3-pentanone. Guided by the requirements for analysis of trace components in air, the GC-IRMS system was developed with the goals of increasing sensitivity, reducing dead-volume and peak band broadening, optimizing combustion and water removal, and decreasing the split ratio to the IRMS. The technique relied on a two-stage preconcentration system, a low-volume capillary reactor and water trap, and a balanced reference gas delivery system. Measurements were performed on samples collected from two distinct sources (i.e. biogenic and vehicle emissions) and ambient air collected from downtown Miami and Everglades National Park. However, the instrumentation and the method have the capability to analyze a variety of source and ambient samples. The measured isotopic signatures that were obtained from source and ambient samples provide a new isotopic constraint for atmospheric chemists and can serve as a new way to evaluate their models and budgets for many OVOCs. In almost all cases, OVOCs emitted from fuel combustion were enriched in 13C when compared to the natural emissions of plants. This was particularly true for ethanol gas emitted in vehicle exhaust, which was observed to have a uniquely enriched isotopic signature that was attributed to ethanol’s corn origin and use as an alternative fuel or fuel additive. Results from this effort show that ethanol’s unique isotopic signature can be incorporated into air chemistry models for fingerprinting and source apportionment purposes and can be used as a stable isotopic tracer for biofuel inputs to the atmosphere on local to regional scales.

Finned heat sink use for electronics cooling via natural convection is numerically investigated. An experimental study from the literature that is for vertical surfaces is taken as the base case and the experimental setup is numerically modeled using commercial CFD software. The flow and temperature fields are resolved. A scale analysis is applied to produce an order-of-magnitude estimate for maximum convection heat transfer corresponding to the optimum fin spacing. By showing a good agreement of the results with the experimental data, the model is verified. Then the model is used for heat transfer from inclined surfaces. After a large number of simulations for various forward and backward angles between 0-90 degrees, the dependence of heat transfer to the angle and Rayleigh number is investigated. It is observed that the contributions of radiation and natural convection changes with the angle considerably. Results are also verified by comparing them with experimental results available in literature.

Wireless Sensor Networks (WSNs) continue to evolve as new applications emerge. In the recent past, WSNs were mostly single sink networks with a few number of homogeneous and static sensor nodes. Now, several applications require networks with multiple and moving sinks and targets as well as thousands of heterogeneous devices. However, the same constraints remain: sensor nodes continue to be very limited in resources, posing new challenges in the design of scalable and energy-efficient algorithms and communication protocols to support these new applications. This dissertation first addresses the problem of sink localization in large scale WSNs. A scalable and energy-efficient sink localization mechanism, called the Anchor Location Service (ALS), is introduced to support the use of location-based routing protocols. ALS avoids frequent and costly flooding procedures derived from the mobility of the sinks and targets, and utilizes face routing to guarantee the success of localization. The problem of topology control in heterogeneous environments is addressed next. A new topology control mechanism, the Residual Energy-Aware Dynamic (READ) algorithm, is devised to extend the lifetime of the network while maintaining connectivity. READ extends the lifetime of the network by assigning a more prominent role to more powerful devices. ALS and READ are evaluated and compared with other well-known protocols using analytical means and simulations. Results show that ALS provides a scalable sink location service and reduces the communication overhead in scenarios with multiple and moving sinks and targets. Results also show that READ increases both the network lifetime and the packet delivery rate.

Free radicals play a critical role in the formation of tropospheric air pollution, but current condensed chemical mechanisms used in gridded photochemical models under-predict total radical concentrations. This dissertation evaluates three hypotheses regarding radical sources and sinks using environmental chamber data and ambient data from southeast Texas. The first hypothesis, that aromatics chemistry is under-represented as a radical source in condensed chemical mechanisms, was evaluated mainly by using environmental chamber simulations and in part by using ambient simulations. Results indicate that improved characterization of aromatics chemistry in condensed chemical mechanisms will lead to more rapid and extensive free radical formation. The second hypothesis, that alkene reactions are under-represented as a radical source in condensed chemical mechanisms, was also evaluated using chamber data and TexAQS-2000 data. Results indicate that the methods used in mechanism condensation lead to lower estimates of free radical production than detailed, compound specific models. The third hypothesis, chlorine emissions and chemistry as a radical source, was also evaluated in a series of sensitivity analyses with various levels of molecular chlorine emissions. Results imply that incorporating chlorine chemistry in condensed chemical mechanisms is expected to lead to more accurate modeling of OH, HO₂ and O₃, particularly for the southeast Texas region where relatively large chlorine emissions occur from various anthropogenic sources of molecular chlorine. The relative magnitudes of these radical sources (aromatics, alkenes, and molecular chlorine) in southeast Texas were also compared using box modeling with TexAQS-2000 data. Results indicate that the relative importance of these three types of radical sources depends on the strengths of their corresponding emissions. / text