Magíster en Análisis Sistémico Aplicado a la Sociedad / Se presenta en este informe de Tesis un análisis de las perspectivas de desarrollo de la Energía Solar observadas en el Solar Energy Research Center (SERC), en específico aquellas relacionadas con los ámbitos de Ciencia y Tecnología, Mercado y Políticas Públicas. Para ello, y a partir de metodologías cualitativas, se desarrollaron redes semánticas asociadas a cada ámbito señalado, indagando en las formas de procesamiento usadas por miembros del SERC para tratarlos. A partir de ello, se muestra el surgimiento de distintos niveles de complejidad en las formas de abordar el fenómeno y su incidencia en el proceso de estabilización de la Energía Solar en nuestro país, relevando el papel que el concepto de perspectiva tiene en la configuración del emergente campo solar en nuestro país

Tendo por base o conceito de Energia Renovável e Armazenada, este trabalho realiza a comparação entre a eficiência de conversão da irradiação solar fotovoltaica e a fotossintética em Energia Elétrica através da análise do ciclo de vida energético (ACVE) e de sua expressão em empreendimentos implantados. Esta análise envolveu um exame aprofundado dos recursos (tecnologia, implantação, estrutura financeira e operativa, utilização de recursos hídricos e alocação de resíduos, além de aspectos da produção de alimentos e aquecimento global) envolvidos em todas as etapas do ciclo de vida dos empreendimentos. Isso se fazia necessário porque as eficiências propaladas em proposições acadêmicas ou comerciais tendiam a ser parciais, não dando conta da efetiva energia líquida gerada. A apuração da energia líquida gerada enfatiza a necessidade de fomento às cadeias de suprimento, incentivando conteúdo local por meio de intervenção regulatória sugerida. Tal intervenção busca identificar e favorecer uma tecnologia de conversão de irradiação solar e , assim procedendo, agregar segurança à matriz energética do Brasil, aumentando sua capacidade de armazenamento sustentável de energia. / Based on the concept of Renewable and Stored Energy, this paper performs a comparison between the efficiency of photovoltaic and photosynthetic solar electricity conversion by examining the life cycle energy analysis (ACVE) and its expression in projects deployed. This analysis involved a detailed examination of the resources (technology, deployment, operational and financial structure, water use and allocation of waste, as well as aspects of food production and global warming) involved in all stages of the life cycle of the projects. This was necessary because the efficiencies verified in academic and/or business propositions tended to be partial, not realizing the effective net energy generated. The calculation of net energy generated emphasizes the need for fostering supply chains by encouraging local content through regulatory intervention suggested. This intervention seeks to identify and promote a technology of converting solar radiation and, in so doing, add security to Brazil\'s energy matrix, increasing its storage capacity in terms of sustainable energy.

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A series of 28 square-planar dithiol(diimine)platinum(II) chromophoric complexes have been synthesized, characterized, and evaluated for potential efficacy in sensitization of solid state photovoltaic devices to the near-infrared regions of the electromagnetic spectrum. The effect of molecular stacking in the solid state and self-association in solution are shown to influence spectral, electronic, and magnetic properties of the chromophores. Such properties are investigated in the pure form and as partners in donor-acceptor charge transfer adducts. Finally, selected chromophores have been incorporated into single layer schottky diodes as neat films and as dopants in multi-layer organic photovoltaic devices. Evaluation of the devices internal quantum efficiency and voltage-current was measured as proof of concept.

abstract: Water desalination has become one of the viable solutions to provide drinking water in regions with limited natural resources. This is particularly true in small communities in arid regions, which suffer from low rainfall, declining surface water and increasing salinity of groundwater. Yet, current desalination methods are difficult to be implemented in these areas due to their centralized large-scale design. In addition, these methods require intensive maintenance, and sometimes do not operate in high salinity feedwater. Membrane distillation (MD) is one technology that can potentially overcome these challenges and has received increasing attention in the last 15 years. The driving force of MD is the difference in vapor pressure across a microporous hydrophobic membrane. Compared to conventional membrane-based technologies, MD can treat high concentration feedwater, does not need intensive pretreatment, and has better fouling resistance. More importantly, MD operates at low feed temperatures and so it can utilize low–grade heat sources such as solar energy for its operation. While the integration of solar energy and MD was conventionally indirect (i.e. by having two separate systems: a solar collector and an MD module), recent efforts were focused on direct integration where the membrane itself is integrated within a solar collector aiming to have a more compact, standalone design suitable for small-scale applications. In this dissertation, a comprehensive review of these efforts is discussed in Chapter ‎2. Two novel direct solar-powered MD systems were proposed and investigated experimentally: firstly, a direct contact MD (DCMD) system was designed by placing capillary membranes within an evacuated tube solar collector (ETC) (Chapter ‎3), and secondly, a submerged vacuum MD (S-VMD) system that uses circulation and aeration as agitation techniques was investigated (Chapter ‎4). A maximum water production per absorbing area of 0.96 kg·m–2·h–1 and a thermal efficiency of 0.51 were achieved. A final study was conducted to investigate the effect of ultrasound in an S-VMD unit (Chapter ‎5), which significantly enhanced the permeate flux (up to 24%) and reduced the specific energy consumption (up to 14%). The results add substantially to the understanding of integrating ultrasound with different MD processes. / Dissertation/Thesis / Doctoral Dissertation Mechanical Engineering 2020

This work addresses the design and real-time implementation of adaptive control strategies on the parabolic solar collector to enhance the production efficiency under varying working conditions. For example, the unpredictable variations of the solar irradiance and thermal losses, these factors can be a major problem in the control design. The control objective is to force the outlet temperature of the collector fluid, to track a predefined reference temperature regardless of the environmental changes. In this work, two control strategies have been designed and analyzed. First, an intelligent proportional-integral feedback control, which combines the proportionalintegral feedback control with an ultra-local model is proposed. This strategy uses a transfer function model that has been derived and identified from real-time data and used to test the controller performance. Second, an adaptive nonlinear control using Lyapunov stability theory combined with the phenomenological representation of the system is introduced. This strategy uses a bilinear model derived from the heat transfer equation. Both control strategies showed good performance in the simulations with respect to the convergence time and tracking accuracy. Besides, the conventional proportional-integral controller has been successfully implemented in the real system.

There has been significant growth in both utility-scale and residential-scale solar installa- tions in recent years, driven by rapid technology improvements and falling prices. Unlike utility-scale solar farms that are professionally managed and maintained, smaller residential- scale installations often lack sensing and instrumentation for performance monitoring and fault detection. As a result, faults may go undetected for long periods of time, resulting in generation and revenue losses for the homeowner. In this thesis, we present SunDown, a sensorless approach designed to detect per-panel faults in residential solar arrays. SunDown does not require any new sensors for its fault detection and instead uses a model-driven ap- proach that leverages correlations between the power produced by adjacent panels to de- tect deviations from expected behavior. SunDown can handle concurrent faults in multiple panels and perform anomaly classification to determine probable causes. Using two years of solar generation data from a real home and a manually generated dataset of multiple solar faults, we show that our approach has a MAPE of 2.98% when predicting per-panel output. Our results also show that SunDown is able to detect and classify faults, including from snow cover, leaves and debris, and electrical failures with 99.13% accuracy, and can detect multi- ple concurrent faults with 97.2% accuracy.

Jellyfish have inhabited this planet for millions of years and are the oldest known metazoans that swim using muscles. They are found in freshwater sources and in oceans all over the world. Over millions of years of evolution, they have adapted to survive in a given environment. They are considered as one of the most energy efficient swimmers. Owing to these characteristics, jellyfish has attracted a lot of attention for developing energy efficient unmanned undersea vehicles (UUVs). The goal of this thesis is to provide understanding of the different physical mechanisms that jellyfish employs to achieve efficient swimming by using analytical and computational models. The models were validated by using the experimental data from literature. Based upon these models refinements and changes to engineering vehicles was proposed that could lead to significant enhancement in propulsion efficiency. In addition to the propulsion, the thesis addresses the practical aspects of deploying a jellyfish-inspired robotic vehicle by providing insights into buoyancy control and energy generation. The thesis is structured in a manner such that propulsive and structural models inspired from the natural animal were systematically combined with the practical aspects related to ionic diffusion driven buoyancy control system and thermal -- magnetic energy harvesting system. Jellyfish morphology, swimming mechanism and muscle architecture were critically reviewed to accurately describe the natural behavior and material properties. We provide full understanding of mesoglea, which plays most significant role towards swimming performance, in terms of composition, mechanical properties and nonlinear dynamics. Different jellyfish species exhibit different microstructure of mesoglea and thus there is a wide variety of soft materials. Mechanical properties of collagen fibers that form the main constituent toward imparting elasticity to mesoglea were reviewed and analyzed. The thesis discusses the theoretical models describing the role of structure of mesoglea towards its mechanical properties and explains the variation occurring in stiffness under given experimental environment. Muscle architecture found in jellyfish, nerve nets and its interconnection with the muscles were investigated to develop comprehensive understanding of jellyfish propulsion and its reaction to external stimuli. Different muscle arrangements were studied including radial, coronal muscle, and coronal-muscles-with-breaks in-between them as observed in Cyanea capillata. We modeled these muscle arrangements through finite element modeling (FEM) to determine their deformation and stroke characteristics and their overall role in bell contraction. We found that location and arrangement of coronal muscle rings plays an important role in determining their efficient utilization. Once the understanding of natural jellyfish was achieved, we translated the findings onto artificial jellyfish vehicle designed using Bio-inspired Shape Memory Alloy Composite (BISMAC) actuators. Detailed structural modeling was conducted to demonstrate deformation similar to that of jellyfish bell. FEM model incorporated hyperelastic behavior of artificial mesoglea (Ecoflex-0010 RTV, room temperature vulcanizing silicone with shore hardness (0010)), experimentally measured SMA temperature transformation, gravity and buoyancy forces. The model uses the actual control cycle that was optimized for driving the artificial jellyfish vehicle "robojelly". Using a comparative analysis approach, fundamental understanding of the jellyfish bell deformation, thrust generation, and mechanical efficiency were provided. Meeting energy needs of artificial vehicle is of prime importance for the UUVs. Some jellyfish species are known to use photosynthesis process indirectly by growing algae on their exumbrella and thereby utilizing the sunlight to generate energy. Inspired by this concept, an extensive model was developed for harvesting solar energy in underwater environment from the jellyfish bell structure. Three different species were modeled for solar energy harvesting, namely A.aurita, C.capillata and Mastigia sp., using the amorphous silicon solar cell and taking into account effect of fineness ratio, bell diameter, turbidity, depth in water and incidence angle. The models shows that in shallow water with low turbidity a large diameter vehicle may actually generate enough energy as required for meeting the demand of low duty cycle propulsion. In future, when the solar energy harvesting technology based upon artificial photosynthesis, referred to as "dye-sensitized solar cells", matures the model presented here can be easily extended to determine its performance in underwater conditions. In order to supplement the energy demand, a novel concept of thermal -- magnetic energy harvesting was developed and extensively modeled. The proposed harvester design allows capturing of even small temperature differences which are difficult for the thermoelectrics.  A systematic step-by-step model of thermo-magnetic energy harvester was presented and validated against the experimental data available in literature. The multi-physics model incorporates heat transfer, magnetostatic forces, mechanical vibrations, interface contact behavior, and piezoelectric based energy converter. We estimated natural frequency of the harvester, operating temperature regimes, and electromechanical efficiency as a function of dimensional and physical variables. The model provided limit cycle operation regimes which can be tuned using physical variables to meet the specific environment. Buoyancy control is used in aquatic animals in order to maintain their vertical trajectory and travel in water column with minimum energy expense. Some crustaceans employ selective ion replacement of heavy or lighter ions in their dorsal carapace. A model of a buoyancy chamber was developed to achieve similar buoyancy control using electro-osmosis. The model captures all the essential ionic transport and electrochemistry to provide practical operating cycle for the buoyancy engine in the ocean environment. / Ph. D.

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Possible modern application of piston steam engine is electricity production using steam made by solar energy. This diploma thesis focuses on designing such piston steam engine Described solution would be effective as an off grid electricity generator, because alternative source of steam could be added for occasions, when sunlight is not powerfull enough for steam production.