<p>Many hydrocarbon reservoirs are situated in barren sequences that display poor stratigraphic control. Correlation between the wells can become extremely difficult and traditional correlation techniques can prove to be inadequate. Past studies have shown that trace and major element concentrations can be used as a correlation tool. This practice of using geochemical fingerprints to characterize between wells is called Chemostratigraphic analysis. (Pearce et al, 1999) Chemostratigraphy has been recognized as a very important correlation technique as it can be used for rocks of any age, in any geological setting as well as sequences that are traditionally defined as barren. Chemostratigraphic analyses can be used as a means of getting rid of ambiguities within data produced by traditional correlation methods such as Biostratigraphy, Lithostratigraphy and Geophysical Logging. In areas where stratigraphic data is not available it can be used to construct correlation frameworks for the sequences found in the area. The motivation behind this study is that the research is not only worthy of academic investigation, but can also provide the industry with new insights into areas that were previously misunderstood because traditional correlation methods were not adequate. The study area, the Orange basin, is located offshore South Africa and is largely underexplored. The basin, that hosts two gas field namely the Ibhubesi and the Kudu gas fields, has large potential but in the past has not been given due attention with only 34 wells being drilled in the area. The Orange basin has recently been the topic of investigation because of the belief that it may be hosts to more hydrocarbons. This study will utilise Chemostratigraphy to attempt to provide geological information on this relatively under-explored basin. The aim of this research study is to produce a chemostratigraphic framework -scheme for the Orange Basin in order to facilitate reservoir scale interwell correlation. The Objectives of this research study will be to identify chemostratigraphic units or indices, to prove the adequate use of chemostratigraphy as an independent correlation technique and to integrate the chemostratigraphy and petrophysical characteristics of the four wells to facilitate lithological identification.</p>

<p>Many hydrocarbon reservoirs are situated in barren sequences that display poor stratigraphic control. Correlation between the wells can become extremely difficult and traditional correlation techniques can prove to be inadequate. Past studies have shown that trace and major element concentrations can be used as a correlation tool. This practice of using geochemical fingerprints to characterize between wells is called Chemostratigraphic analysis. (Pearce et al, 1999) Chemostratigraphy has been recognized as a very important correlation technique as it can be used for rocks of any age, in any geological setting as well as sequences that are traditionally defined as barren. Chemostratigraphic analyses can be used as a means of getting rid of ambiguities within data produced by traditional correlation methods such as Biostratigraphy, Lithostratigraphy and Geophysical Logging. In areas where stratigraphic data is not available it can be used to construct correlation frameworks for the sequences found in the area. The motivation behind this study is that the research is not only worthy of academic investigation, but can also provide the industry with new insights into areas that were previously misunderstood because traditional correlation methods were not adequate. The study area, the Orange basin, is located offshore South Africa and is largely underexplored. The basin, that hosts two gas field namely the Ibhubesi and the Kudu gas fields, has large potential but in the past has not been given due attention with only 34 wells being drilled in the area. The Orange basin has recently been the topic of investigation because of the belief that it may be hosts to more hydrocarbons. This study will utilise Chemostratigraphy to attempt to provide geological information on this relatively under-explored basin. The aim of this research study is to produce a chemostratigraphic framework -scheme for the Orange Basin in order to facilitate reservoir scale interwell correlation. The Objectives of this research study will be to identify chemostratigraphic units or indices, to prove the adequate use of chemostratigraphy as an independent correlation technique and to integrate the chemostratigraphy and petrophysical characteristics of the four wells to facilitate lithological identification.</p>

Magister Scientiae - MSc / Many hydrocarbon reservoirs are situated in barren sequences that display poor stratigraphic control. Correlation between the wells can become extremely difficult and traditional correlation techniques can prove to be inadequate. Past studies have shown that trace and major element concentrations can be used as a correlation tool. This practice of using geochemical fingerprints to characterize between wells is called Chemostratigraphic analysis. (Pearce et al, 1999) Chemostratigraphy has been recognized as a very important correlation technique as it can be used for rocks of any age, in any geological setting as well as sequences that are traditionally defined as barren. Chemostratigraphic analyses can be used as a means of getting rid of ambiguities within data produced by traditional correlation methods such as Biostratigraphy, Lithostratigraphy and Geophysical Logging. In areas where stratigraphic data is not available it can be used to construct correlation frameworks for the sequences found in the area. The motivation behind this study is that the research is not only worthy of academic investigation, but can also provide the industry with new insights into areas that were previously misunderstood because traditional correlation methods were not adequate. The study area, the Orange basin, is located offshore South Africa and is largely underexplored. The basin, that hosts two gas field namely the Ibhubesi and the Kudu gas fields, has large potential but in the past has not been given due attention with only 34 wells being drilled in the area. The Orange basin has recently been the topic of investigation because of the belief that it may be hosts to more hydrocarbons. This study will utilise Chemostratigraphy to attempt to provide geological information on this relatively under-explored basin. The aim of this research study is to produce a chemostratigraphic framework -scheme for the Orange Basin in order to facilitate reservoir scale interwell correlation. The Objectives of this research study will be to identify chemostratigraphic units or indices, to prove the adequate use of chemostratigraphy as an independent correlation technique and to integrate the chemostratigraphy and petrophysical characteristics of the four wells to facilitate lithological identification. / South Africa

>Magister Scientiae - MSc / Many hydrocarbon reservoirs are situated in barren sequences that display poor stratigraphic control. Correlation between the wells can become extremely difficult and traditional correlation techniques can prove to be inadequate. Past studies have shown that trace and major element concentrations can be used as a correlation tool. This practice of using geochemical fingerprints to characterize between wells is called Chemostratigraphic analysis. (Pearce et al, 1999) Chemostratigraphy has been recognized as a very important correlation technique as it can be used for rocks of any age, in any geological setting as well as sequences that are traditionally defined as barren. Chemostratigraphic analyses can be used as a means of getting rid of ambiguities within data produced by traditional correlation methods such as Biostratigraphy, Lithostratigraphy and Geophysical Logging. In areas where stratigraphic data is not available it can be used to construct correlation frameworks for the sequences found in the area. The motivation behind this study is that the research is not only worthy of academic investigation, but can also provide the industry with new insights into areas that were previously misunderstood because traditional correlation methods were not adequate. The study area, the Orange basin, is located offshore South Africa and is largely underexplored. The basin, that hosts two gas field namely the Ibhubesi and the Kudu gas fields, has large potential but in the past has not been given due attention with only 34 wells being drilled in the area. The Orange basin has recently been the topic of investigation because of the belief that it may be hosts to more hydrocarbons. This study will utilise Chemostratigraphy to attempt to provide geological information on this relatively under-explored basin. The aim of this research study is to produce a chemostratigraphic framework -scheme for the Orange Basin in order to facilitate reservoir scale interwell correlation. The Objectives of this research study will be to identify chemostratigraphic units or indices, to prove the adequate use of chemostratigraphy as an independent correlation technique and to integrate the chemostratigraphy and petrophysical characteristics of the four wells to facilitate lithological identification. Element distribution Analysis was done on the data. This brought to the fore. the dominance of Si02 across the samples for the four wells. Ah03 concentrations were relatively high across the wells and were indicative of the clay rich nature of the samples. This also indicated that the samples were relatively immature. Principal Component Analysis (PCA) plots were constructed for the purpose of identifying diametrical relationships between the elements or element clusters. These diametric relationships were in turn used to calculate the geochemical indices. The relative positions of the elements on the PCA plot highlighted the presence of alternating units of sandstone, feldspathic sandstone, calcareous clays and non calcareous clays within the samples. The PCA plots displayed diametric relationships between Si02 and the carbonate mineral clusters, Si02 and the clay mineral clusters, Nd and V, Nb nad Ni, Zr and Co, Nb and Zn. Si02 and Co, Y and Pb, Zr and Sr, and lastly Nb and Ra / Downhole plots were constructed to illustrate recognizable trends in the PCA plot and to relate this to the occurrence of various lithologies in the wells. Based on the element distribution patterns, PCA plots and Major and Trace element downhole profiles geochemical indices were calculated. They are grouped into three clusters, ratios indicative of the presence of clean sandstones (High Si02/Ah03, Si02/Co, Zr/Co, Zr/Sr, YlPb and low Nd/V values); ratios indicative of the presence of clays (Low Si02/Ah03, Fe203/Ah03, Si02/Co, Zr/Co, YlPb and high Rb/Zn values); thirdly those indicative of the presence of feldspathic sandstones (High Na201K20) and lastly those indicative of the presence of carbonates (low Zr/Sr). Using the geochemical Indices six units were identified in Well A_AI, nine in A-II and 8 iin Well A-UI and A-LI. Four units (A-D) were found to correlate across the wells. I Well log interpretation for the Wells A-AI, A-II, A-Lland A-UI started with a general overview of the log responses. The log responses for the four wells highlighted the presence of sandstones, argillaceous sandstones, shales and shale components. Geophysical units were identified using the logs responses. Six units were identified in Well A-AI, nine in Well A-II and eight in Wells A-LI and A-UI. These units coincide with the units identified using Chemostratigraphic analysis. Neutron - Density cross plots were constructed for each unit across the four wells. The plotting of the points on the Neutron - Density cross plots for the wells A-AI, A-II, A-LI and A-UI indicated the presence of sandstones, shales or greywackes and either limestones and dolomites but from the geochemistry it is known that neither limestone nor dolomite is present in the wells and it was thus inferred that the points plotting between the limestone and dolomite lithology curves indicated the presence of calcareous shales. M-N plots were constructed for each unit. The patterns exhibited by the points on the M-N plots for the wells was indicative of the presence calcareous clays, sandstones, greywacke and shales. The Chemostratigraphic and Petrophysical results produced accurate and comparable results, however, the Chemostratigraphic analysis provided finer details regarding the lithology of the units. Based on the well log responses no distinction could be made between highly feldspathic sandstone, arkosic and argillaceous sandstone, while these distinctions were possible when analyzing the samples using Chemostratigraphy. The geochemistry was capable of providing signatures in areas where the wireline tools malfunctioned. The logs, on the other hand, sheds light on properties such as porosity and permeability of the rocks which cannot be obtained accurately from the geochemistry. When comparing the correlation capabilities of these two techniques, the one based on geochemical signatures and the other based on the responses obtained from wireline tools, it is important to acknowledge that both these techniques has strengths and weaknesses. The best of both these techniques can only be fully utilised when either technique is used in conjunction with other techniques. With respect to the Orange Basin, located offshore South Africa, it can be concluded that the dominant lithologies in the basin are sandstones, argillaceous sandstones, shales, feldspathic and arkosic sandstones and clays. In terms of petroleum prospectivity the sandstones in Wells A-AI, A-II, A-UI and A-LI could possibly be considered to be reservoirs and the shales could be considered to be seals or source rocks, depending on the organic matter content. On the down side, the sandstones display relatively poor permeabilities and the porosities are variable. The density logs indicate that the sandstones are highly compacted and that could be an indication of poor porosities but more research needs to be done. Another factor highlighted from the research is the presence of alternating lithologies. This means that the reservoirs are compartmentalised and that the area has a high degree of heterogeneity.

O objetivo do presente estudo é avaliar o uso associado dos proxies ?18O e Mg/Ca obtidos em testas de foraminíferos. Para alcançar tal objetivo foram realizadas análises de ?18O e Elemento/Ca em amostras de foraminíferos planctônicos (G. ruber e G. sacculifer) e bentônicos (Cibicidoides spp., C. corpulentus, Uvigerina spp. e H. elegans) de dois testemunhos do Atlântico Sul. Os resultados demonstraram que apesar dos proxies ?18O e Mg/Ca apresentarem perfis distintos em relação às espécies os mesmos se correlacionam de forma apropriada, sendo possível estimar a temperatura e os sinais de ?18OSW e ?18OLocal a partir dos mesmos. A partir dos dados de temperatura estimados com base em Mg/Ca foi possível identificar uma anomalia negativa das águas superficias entre o LGM e o HL de -1,5 ± 0,2 °C, enquanto que nas águas profundas observou-se uma anomali positiva de 1,7 ± 0,4 °C para o mesmo período. Os dados de ?18OSW estimados com base nos dados de temperatura e ?18O indicaram uma oscilação de 1,0 ± 0,1 ? e 2,0 ± 0,2 ? para as espécies planctônicas e bentônicas durante o LGM e o HL. Segundo o valor esperado para a variação do volume de gelo (~1,2 ?) há uma oscilação muito baixa da salinidade nas águas superficias da região de estudo, em contraste com uma oscilação bem marcada da salinidade nas águas de fundo. As estimativas de ?18OLocal indicaram uma oscilação entre o LGM e o HL muito pequena da salinidade (~0,1 ?) nas águas superficiais, com uma oscilação maior nas águas de fundo (1,0 ± 0,3 ?). O aumento da salinidade das águas de fundo durante o LGM corrobora a anomalia positiva da temperatura observada neste estudo, visto que, para a ocorrência da mesma, é necessário que a densidade das águas de fundo seja suficiente para manter a estratificação da coluna de água. / The goal of this study is to evaluate the associated use of the proxies ?18O and Mg/Ca, both analyzed in foraminifera tests. ?18O and trace metals analyses were performed in order to achieve this purpose on samples of planktonic (G. ruber and G. sacculifer) and benthic (Cibicidoides spp., C. corpulentus, Uvigerina spp. and H. elegans) species of foraminifera from two cores from South Atlantic. Despite of the fact that the proxies used on this study present distinct fits within the species they correlate very well, being possible to estimate the values of temperature, ?18OSW and ?18OLocal. Based on the temperature estimated by Mg/Ca it was possible to identify a negative anomaly of -1,5 ± 0,2 °C between the LGM and HL, meanwhile a positive anomaly of 1,7 ± 0,4 °C was observed in the deep waters for the same period. The ?18OSW data estimated by temperature and ?18O indicate an oscilation of 1,0 ± 0,1 ? and 2,0 ± 0,2 ? for planktonic and benthic species between the LGM and the HL. Based on the literature value for the ice volume signal (~1,2 ?) the superficial waters of the study area indicated a very low salinity oscilation, opposite to the high salinity oscillation in the deep waters. The ?18OLocal estimatives exhibited a very weak salinity oscillation between LGM and HL in the superficial waters (~0,1 ?), providing a much more strong oscilation in the deep waters (1,0 ± 0,3 ?). The salinity increase during the LGM in the deep waters establish the validity of the positive temperature anomaly observed in this study, since the density of the deep water needs to be adequate to maintain the water column stratification.

O objetivo do presente estudo é avaliar o uso associado dos proxies ?18O e Mg/Ca obtidos em testas de foraminíferos. Para alcançar tal objetivo foram realizadas análises de ?18O e Elemento/Ca em amostras de foraminíferos planctônicos (G. ruber e G. sacculifer) e bentônicos (Cibicidoides spp., C. corpulentus, Uvigerina spp. e H. elegans) de dois testemunhos do Atlântico Sul. Os resultados demonstraram que apesar dos proxies ?18O e Mg/Ca apresentarem perfis distintos em relação às espécies os mesmos se correlacionam de forma apropriada, sendo possível estimar a temperatura e os sinais de ?18OSW e ?18OLocal a partir dos mesmos. A partir dos dados de temperatura estimados com base em Mg/Ca foi possível identificar uma anomalia negativa das águas superficias entre o LGM e o HL de -1,5 ± 0,2 °C, enquanto que nas águas profundas observou-se uma anomali positiva de 1,7 ± 0,4 °C para o mesmo período. Os dados de ?18OSW estimados com base nos dados de temperatura e ?18O indicaram uma oscilação de 1,0 ± 0,1 ? e 2,0 ± 0,2 ? para as espécies planctônicas e bentônicas durante o LGM e o HL. Segundo o valor esperado para a variação do volume de gelo (~1,2 ?) há uma oscilação muito baixa da salinidade nas águas superficias da região de estudo, em contraste com uma oscilação bem marcada da salinidade nas águas de fundo. As estimativas de ?18OLocal indicaram uma oscilação entre o LGM e o HL muito pequena da salinidade (~0,1 ?) nas águas superficiais, com uma oscilação maior nas águas de fundo (1,0 ± 0,3 ?). O aumento da salinidade das águas de fundo durante o LGM corrobora a anomalia positiva da temperatura observada neste estudo, visto que, para a ocorrência da mesma, é necessário que a densidade das águas de fundo seja suficiente para manter a estratificação da coluna de água. / The goal of this study is to evaluate the associated use of the proxies ?18O and Mg/Ca, both analyzed in foraminifera tests. ?18O and trace metals analyses were performed in order to achieve this purpose on samples of planktonic (G. ruber and G. sacculifer) and benthic (Cibicidoides spp., C. corpulentus, Uvigerina spp. and H. elegans) species of foraminifera from two cores from South Atlantic. Despite of the fact that the proxies used on this study present distinct fits within the species they correlate very well, being possible to estimate the values of temperature, ?18OSW and ?18OLocal. Based on the temperature estimated by Mg/Ca it was possible to identify a negative anomaly of -1,5 ± 0,2 °C between the LGM and HL, meanwhile a positive anomaly of 1,7 ± 0,4 °C was observed in the deep waters for the same period. The ?18OSW data estimated by temperature and ?18O indicate an oscilation of 1,0 ± 0,1 ? and 2,0 ± 0,2 ? for planktonic and benthic species between the LGM and the HL. Based on the literature value for the ice volume signal (~1,2 ?) the superficial waters of the study area indicated a very low salinity oscilation, opposite to the high salinity oscillation in the deep waters. The ?18OLocal estimatives exhibited a very weak salinity oscillation between LGM and HL in the superficial waters (~0,1 ?), providing a much more strong oscilation in the deep waters (1,0 ± 0,3 ?). The salinity increase during the LGM in the deep waters establish the validity of the positive temperature anomaly observed in this study, since the density of the deep water needs to be adequate to maintain the water column stratification.