Inaug.-diss.--Halle. / Vita. "Cap. III (Die 'consuetudines Hirsauzienses') und IV (Hirschauer anonymus) werden in einer besonderen abhandlung erscheinen." "Quellen und litteraturangabe": p. [9]-13.

High arsenic concentrations (>100 ppb) have been measured in wells completed in the Ordovician St. Peter sandstone aquifer of eastern Wisconsin. The primary source of arsenic is As-bearing sulfide minerals within the aquifer. There is concern that periodic disinfection of wells by chlorination may facilitate arsenic release to groundwater by increasing the rate of sulfide mineral oxidation. Current guidance from the Wisconsin Department of Natural Resources recommends a "low-dose" treatment of 20% of the chlorine strength and 10% of the of the contact time of chlorine treatments used in non-arsenic impacted wells for well disinfection and biofilm removal. In order to provide information pertaining to WDNR's recommendations, St. Peter sulfide minerals were reacted with a range of chlorine "shock-treatments" similar to those occurring in wells. This study focuses on abiotic processes that mobilize arsenic from the solid phase during controlled exposure to chlorinated solutions. Thin sections were made from aquifer material collected at Leonard's Michael quarry, located in Winnebago County, Wisconsin. Bulk arsenic content of this material was measured as 674 ppm. Quantitative EPMA analysis shows As zoning in pyrite grains with concentrations up to 1 wt. % As. After mineral characterization, the thin sections were exposed to solutions of 60 mg/L "free chlorine," 1200 mg/L "free chlorine," and nanopure water (control) at pH 7.0 and pH 8.5 for 24 hours. Thin sections were then analyzed to measure changes in the pyrite surfaces. For solution experiments, aquifer material was crushed to between 250 μm and 355 μm mesh sizes (S.A. ~ 50 cm2/g – 60 cm2/g, Foust et al. 1980) and reacted under the same conditions as the thin sections in a batch reactor. Solution samples were collected periodically during the 24 hour exposure and analyzed for arsenic, iron, and sulfate ion. Pyrite oxidation is shown to dramatically increase with increasing chlorine concentrations as shown by measurements of released sulfate ion, used here as the reaction progress variable. EPMA maps also reveal complete oxidation of pyrite cements to Fe-oxyhydroxides at 1200 mg/L "free chlorine" and pH 7.0. This behavior does not occur at lower concentrations or higher pH. Arsenic release to solution does not appear to be directly correlated to increasing chlorine concentrations, but is governed by Fe-oxyhydroxide nucleation, which inhibits the release of dissolved arsenic at higher concentrations of chlorine. / Master of Science

A investigação da Terra através da gravimetria implica um grande número de informações sobre o seu interior em diferentes escalas de observação. O presente estudo considerou pesquisas anteriormente realizadas na área da Zona de Fratura São Paulo (ZFSP) e Arquipélago São Pedro e São Paulo (ASPSP), no Oceano Atlântico Equatorial, cujos dados geoquímicos e petrológicos apontam a presença de uma anomalia térmica. Nesta área alguns levantamentos geofísicos já foram realizados, mas nada que contribuísse de forma significativa através de dados gravimétricos. O objetivo principal deste trabalho é a caracterização gravimétrica da Zona de Fratura São Paulo através de dados de gravidade, anomalia ar livre, anomalia bouguer, tensor gradiente da gravidade e altura geoidal residual. Como objetivo secundário, procurou-se a expressão desta anomalia térmica no campo geopotencial. Entretanto, os resultados obtidos indicam que o efeito da batimetria sobre este dados deve ser levado em consideração. Uma vez que área de estudo está localizada na porção equatorial da dorsal mesoatlântica e o processo de compensação isostática nesta área está influenciando os valores da gravidade no local. Sendo, portanto, necessária a confluência de outros métodos geofísicos para detectar a expressão desta anomalia térmica. / The investigation of the Earth by gravity implies a lot of information about the interior at different scales of observation. This study considered research previously conducted in the area of St. Paul Fracture Zone (ZFSP) Archipelago and St Peter and St Paul (ASPSP), the Equatorial Atlantic Ocean, whose petrological and geochemical data indicate the presence of a thermal anomaly. In this area some geophysical surveys have been conducted, but nothing that would contribute significantly by gravity data. The main objective of this work is the characterization of gravimetric St. Paul Fracture Zone by gravity data, free air anomaly, Bouguer anomaly, the gravity gradient tensor and residual geoid height. As a secondary objective, have sought the expression of this thermal anomaly in the field geopotential. However, the results indicate that the effect of bathymetry on this data should be taken into consideration. Since the study area is located in the equatorial portion of the mid-ridge atlantic and the process of isostatic compensation in this area is influencing the gravity values at the site. Therefore required the confluence of other geophysical methods to detect the expression of this thermal anomaly.

Middle Ordovician (Whiterockian) sandstone units within the Oil Creek, McLish, and Tulip Creek formations of the Simpson Group of Oklahoma, and the Everton (Calico Rock Member) and St. Peter formations of Arkansas were deposited on the southern margin of Laurentia. They represent the first major siliciclastic input to the southern U.S. Midcontinent above the post-Sauk unconformity. Samples were collected from outcrops of the major sandstone units to determine their U-Pb detrital zircon age distributions for provenance. Samples were prepared and analyzed using laser ablation - inductively coupled plasma - mass spectrometry (LA-ICP-MS). Probability-density plots were created to determine likely source areas for sediment, based on comparing detrital zircon ages to known ages of basement terranes. Detrital zircon grains from the Early Whiterockian Calico Rock sandstone indicate a majority of its zircon population was ultimately derived from the 900-1300 Ma Grenville orogenic province, with secondary input ultimately derived from the 1300-1550 Ma Granite-Rhyolite/Anorogenic Province and the Archean Superior province along the Transcontinental Arch. It is likely, at this time, that zircons were also sourced from reworked sediments from more proximal secondary sources. With sea level rise and transgression, the depositional shoreline and the sediment source areas moved to the north and west. The basal Oil Creek Sandstone of the Simpson Group was deposited unconformably above the Arbuckle Group in southern Oklahoma, and its zircon population is dominated by grains from Archean source terranes along the Transcontinental Arch. The basal sandstone unit of the McLish Formation indicates renewed sediment input containing zircons from 1300-1550 Ma Granite-Rhyolite/Anorogenic and 1600-1700 Ma Yavapai-Mazatzal terranes along the Transcontinental Arch. The Nemaha Ridge in northeastern Kansas likely acted as a source of first-cycle sediment in the southern midcontinent during this time. Small populations of detrital zircon grains between 1800 Ma and 2000 Ma occur in the majority of the samples. Their probability density peaks are generally centered at roughly 1850 Ma, suggesting an ultimate source in the Penokean orogenic province along the Transcontinental Arch.

Thesis (M.A.P.S.)--Catholic Theological Union at Chicago, 2001. / Vita. Includes bibliographical references (leaves [62]-64).

Thesis (M.A.P.S.)--Catholic Theological Union at Chicago, 2001. / Vita. Includes bibliographical references (leaves [62]-64).

Thesis (M.A.P.S.)--Catholic Theological Union at Chicago, 2001. / Vita. Includes bibliographical references (leaves [62]-64).

A investigação da Terra através da gravimetria implica um grande número de informações sobre o seu interior em diferentes escalas de observação. O presente estudo considerou pesquisas anteriormente realizadas na área da Zona de Fratura São Paulo (ZFSP) e Arquipélago São Pedro e São Paulo (ASPSP), no Oceano Atlântico Equatorial, cujos dados geoquímicos e petrológicos apontam a presença de uma anomalia térmica. Nesta área alguns levantamentos geofísicos já foram realizados, mas nada que contribuísse de forma significativa através de dados gravimétricos. O objetivo principal deste trabalho é a caracterização gravimétrica da Zona de Fratura São Paulo através de dados de gravidade, anomalia ar livre, anomalia bouguer, tensor gradiente da gravidade e altura geoidal residual. Como objetivo secundário, procurou-se a expressão desta anomalia térmica no campo geopotencial. Entretanto, os resultados obtidos indicam que o efeito da batimetria sobre este dados deve ser levado em consideração. Uma vez que área de estudo está localizada na porção equatorial da dorsal mesoatlântica e o processo de compensação isostática nesta área está influenciando os valores da gravidade no local. Sendo, portanto, necessária a confluência de outros métodos geofísicos para detectar a expressão desta anomalia térmica. / The investigation of the Earth by gravity implies a lot of information about the interior at different scales of observation. This study considered research previously conducted in the area of St. Paul Fracture Zone (ZFSP) Archipelago and St Peter and St Paul (ASPSP), the Equatorial Atlantic Ocean, whose petrological and geochemical data indicate the presence of a thermal anomaly. In this area some geophysical surveys have been conducted, but nothing that would contribute significantly by gravity data. The main objective of this work is the characterization of gravimetric St. Paul Fracture Zone by gravity data, free air anomaly, Bouguer anomaly, the gravity gradient tensor and residual geoid height. As a secondary objective, have sought the expression of this thermal anomaly in the field geopotential. However, the results indicate that the effect of bathymetry on this data should be taken into consideration. Since the study area is located in the equatorial portion of the mid-ridge atlantic and the process of isostatic compensation in this area is influencing the gravity values at the site. Therefore required the confluence of other geophysical methods to detect the expression of this thermal anomaly.

1 Summary The thesis, Imago gratiosa - Crowned Madonnas in Central Europe in the Baroque Period presents original research results primarily focused on the Madonne Coronate collection in the Archivio Capitolo di San Pietro at the Vatican Library, which was realised as part of Charles University grant project no. 356911 Coronation of Merciful Marian Imagos in Central Europe in the 17th and 18th Century. To become merciful (imago gratiosa) or miraculous (imago miraculosa) a Marian imago must demonstrate divine mercy (save lives during a disaster, cause miraculous recovery from illness, conception, etc.). The greatest expression of veneration and devotion to a merciful or miraculous imago or statue of the Virgin Mary is its coronation. The theological basis of this liturgical ceremony is the coronation of the Virgin Mary on her assumption to heaven. On earth, the Virgin Mary was crowned with imitations of the crowns of worldly monarchs and her crowned imago placed on a royal throne or altar, usually made especially for this occasion for greater honour and glory. This was always the exquisite work of goldsmiths and silversmiths, which if not preserved until today, we can see in numerous manuscripts, prints and engravings specially published to mark the coronation. The nature of the coronation ceremony developed...

Diagnosing a contemporary societal lack in regards to the foundational virtue of patience, this comparative study of Søren Kierkegaard’s three upbuilding discourses To Gain One’s Soul in Patience, To Preserve One’s Soul in Patience and Patience in Expectancy (1844) is studied in relation to the work of St Peter of Damascus in the eastern orthodox writings of the Philokalia (12th century A.D.). The author seeks to trace differences and similarities in between the two authors, in order to explore the possible occurrence of a shared virtue ethic on the subject of patience, bridging east end west across history and church tradition. The thesis makes a brief historical presentation of the Philokalia, wherein it treats the practise of virtuous patience in the eastern orthodox tradition and lays out an outline of the thematic treatment of patience in the writings of St Peter of Damascus. It further presents a basic overview of Kierkegaardian theology in relation to patience before it explores the three discourses through a comparative analysis, followed by a discussion where similarities and differences are traced. Similarities are treated in a schematic manner under general themes of hesychia, man and God, patience and the virtues, discrimination, kenosis, the fragmentation of impatience, impatience and society and the ontological status of patience. Differences are traced to general historical and traditional contexts. The Philokalia, being as it is, intertwined within the orthodox ecclesiastical and traditional understanding, and Kierkegaard as a critical protestant searching for Christian roots. The thesis finishes with the conclusion that the main themes emerging in Kierkegaard’s three discourses on patience are broadly congruent with the writings of St Peter of Damascus in The Philokalia. The main differences found in between the two being those of historical, ecclesiastical and traditional nature.