Many lithographic methods to pattern surfaces both by a mechanical manipulation of the surface or by printing functionalities in the form of particles or molecules have been developed and used in research. Examples for contact-lithographic methods are soft lithography and polymer-pen lithography. One of the main drawbacks of the these methods is the lateral dimension of the obtained pattern. Due to limitations of stamps, materials and the methods themselves, feature sizes of arrays consisting of discrete spots in the sub-micrometer range remain challenging. Another factor in the state-of-the-art contact-lithographic methods is the ex situ adsorption of ink prior to the stamping procedure and thus, an uninterrupted flow of ink cannot be guaranteed. As the variety of imaginable inks is wide and the appropriate solvent often appears to be of organic nature, state-of-the-art contact-lithographic methods are unable to print these inks. The elastomeric polymer stamps used within contact-lithographic methods swell or dissolve in contact with organic solvents. Often, contact-lithographic methods require expensive equipment or defined conditions, e.g. high vacuum or a solvent-enriched humidity, and cannot be carried out in a simple and efficient way under ambient conditions. In this work, a new approach to generate patterned structures with feature sizes in the sub-micrometer range and spot-to-spot distances in the one-micron range is presented. Stamps with an integrated, continuous pore system generate the patterns while the ink is supplied through the capillaries of the stamp. The method of capillary nanostamping provides a simple and low-cost stamping procedure by the synthesis of spongy mesoporous silica stamps. Due to a continuous pore system within the stamp, the ink can be supplied continuously and even without a refilling system, the stamp itself serves as ink reservoir. This provides a continuous or intermittently ink supply for a stamping process with several stamping cycles without the need to refill the stamp. A new stamp or re-inking after one stamping cycle is not necessary. The stamping process is carried out manually by hand under ambient conditions. Due to the silica network, the stamps can be infiltrated with organic solvents. The development of spongy mesoporous silica stamps for capillary nanostamping is presented in this work by demonstrating the progress from pure silica stamps in a typical well-known sol-gel synthesis to spongy and flexible silica stamps with a reduced network bonding and hydrophobic internal residues. For the proof of concept of capillary nanostamping with spongy mesoporous silica stamps, several different inks are stamped. All inks are chosen with respect to a potential application and consist of a volatile organic solvent to proof the stability of the stamps against these solvents, and a non-volatile component, which remains on the substrate surface after precipitation and drying of the solvent. As ink, a dispersion of C60 fullerenes in toluene is stamped onto perfluorinated glass slides. A solution of 1-dodecanethiol in ethanol is stamped onto a gold-coated glass with the outcome of a heterogeneous surface. As a model for nanoparticles, nanodiamonds dispersed in isopropanol are stamped and subsequently functionalized with a fluorescent dye in a click-reaction. A polymer and two different block copolymers dissolved in toluene/chloroform are stamped onto differently functionalized substrate surfaces to analyze the dependency of the nature of the substrate on the stamping results. In a final experiment, a solution of 17α-ethinylestradiol in acetonitrile is stamped as a model for an active pharmaceutical ingredient and subsequently detached from the substrate surface to obtain a defined nanodispersion.

This thesis focuses on the surface patterning by using nanoporous block copolymer (BCP) stamps. Polystyrene‐block‐poly(2‐vinylpyridine) (PS‐b‐P2VP) was used as model BCP. Nanoporous BCP stamps were fabricated by replication of lithographically patterned silicon molds. Nanopores inside of BCP stamps were generated by swelling‐induced pore formation. A method for scanner-based capillary stamping (SCS) with spongy nanoporous BCP stamps was developed. First, in the course of stamps design using replication molding of PS-b-P2VP against surface-modified macroporous silicon molds, PS-b-P2VP fiber rings remaining on the macroporous silicon molds were obtained that allow immobilization of water drops on the hydrophobically modified surfaces of the macroporous silicon molds. Water drops immobilized by these rings can be prevented from dewetting within the PS‐b‐P2VP fiber rings. Second, after spongy nanoporous PS-b-P2VP stamps had been obtained, preliminary experiments with non-inked PS-b-P2VP stamps revealed that parts of the stamps’ contact elements can be lithographically transferred onto counterpart surfaces. As a result, arrays of nanostructured submicron PS‐b‐P2VP dots with heights of ∼100 nm onto silicon wafers and glass slides were produced. Lastly, the SCS technique was developed, which overcomes the limitation of time-consuming re-inking procedures associated with classical soft lithography including microcontact printing (µCP) and polymer pen lithography (PPL) with solid stamps, as well as the limitations regarding throughput of scanning probe‐based serial writing approaches such as nanoscale dispensing (NADIS) and other micropipetting techniques. In addition, sizes of stamped droplets can be controlled by adjusting surface wettability and dwell time.

Chemical and topographic surface patterning for the preparation of functional surfaces and particle arrays has been intensively investigated and widely applied in sensor technology, engineering of adhesion and wetting, catalysis, as well as nanobioanalytics. However, the parallel high-throughput functionalization of surfaces with microparticle arrays under ambient conditions by state-of-the-art surface patterning methods has remained challenging. The aim of this thesis is the parallel generation of microparticle arrays on surfaces to tailor the surface properties. Two strategies are studied for this purpose. The first strategy, inspired by the functional principles of adhesive secretion of insect feet’s hairy contact elements yielding tiny droplets as footprints onto contact substrates, involves the formation of microdot arrays by capillary submicron stamping using spongy continuous nanoporous block copolymer stamps with regular hexagonal arrays of contact elements. After infiltration of AgNO3 solution from the stamps’ backside, arrays of discrete two-dimensional AgNO3 microdots with an average diameter ~ 730 nm on silicon wafers extending several square millimetres were generated, while under higher pressure holey AgNO3 films were obtained. Subsequently, the patterns were transferred into Si wafers by surface-limited metal-assisted chemical etching (MACE). Topographically patterned silicon (tpSi) characterized by hexagonal arrays of wells resulted from MACE of Si wafers patterned with AgNO3 microdots, while MACE of Si wafers patterned with holey AgNO3 films yielded ordered Si pillar arrays. H2PtCl6, PdCl2 and HAuCl4 aqueous solutions were also employed as inks for preparation of tpSi by insect-inspired capillary sub-microstamping and MACE. Exploratory experiments suggest that inkjet printing of polymeric inks onto tpSi could yield persistent and scratch-resistant polymer blot patterns without coffee ring-like features for potential utilization as permanent identity labels or quick response codes. Hexagonal arrays of Au microparticles were rationally positioned by solid-state dewetting of thin gold films on tpSi at an elevated temperature under Ar atmosphere. The rationally positioned Au microparticles subsequently acted as seeds for the growth of dense, homogeneous layers of overlapping three-dimensional (3D) gold nanodendrites by templated galvanic displacement reactions. The obtained 3D gold nanodendrite layers on tpSi featuring high specific surfaces as well as abundance of sharp edges and vertices showed promising performances in SERS-based sensing and the heterocatalytic reduction of 4-nitrophenol to 4-aminophenol. The second example involves the functionalization of polymer surfaces with arrays of inorganic lubricant microparticles for friction management and the tailoring of tribological properties based on an imprint lithographic approach. For example, the tailoring of the interfacial shear behavior of a movable polymer part might be customized in this way by functionalizing the polymeric parts’ surfaces with MoS2 microparticle arrays. Monodomain monolayers of MoS2 microparticles were prepared on SiO2-coated Si wafers via thermal sulfurization arrays of ammonium tetrathiomolybdate microparticles obtained by imprint lithography. After transfer of the MoS2 microparticle arrays to poly(methyl methacrylate) (PMMA) monoliths (PMMA_MoS2) under conservation of the array order in such a way that the MoS2 microparticles were partially embedded into the PMMA and partially exposed, the obtained PMMA_MoS2 exhibited modified mechanical properties characterized by low friction coefficients half as that of non-modified PMMA monoliths. Therefore, the functionalization of surfaces with microparticle arrays is a viable and promising strategy to generate unprecedented surface functionalities.

In recent years, the automotive industry has turned to press hardened steels (PHS) to improve passenger safety while enabling vehicle weight reduction. To form the complex shapes required for this purpose, they are often direct hot press formed. It is possible to provide corrosion resistance to these parts by galvanizing the PHS sheets prior to direct hot press forming (DHPF). However, the austenitization of the galvanized steel causes the Zn-based coating to transform into two intermetallic phases. These are iron-rich α-Fe(Zn) and zinc-rich Г-Fe3Zn10. The Г-Fe3Zn10 is liquid during traditional DHPF, and the applied stress can result in liquid metal embrittlement (LME). Recently, two new grades of PHS have been developed, which allow for DHPF at 600-700°C, below the Fe-Zn peritectic temperature at 782°C, thus avoiding LME. These prototype PHS grades are designated 2%Mn (0.2C-2Mn-0.25Si-0.005B (wt%)) and 2.5%Mn (0.2C-2.5Mn-0.25Si-0.005B (wt%)). The objective of this work is to determine the effect of DHPF on the ability of a Zn-based coating to provide robust cathodic protection to the two prototype PHS. Galvanized panels of both the 2%Mn and 2.5%Mn steel were DHPF with a U-shape die at 700°C. The surface and cross-section of the coating were examined to determine the effects of DHPF on the coating surface. Die friction during DHPF resulted in die wiping on the wall of the part, leading to removal of surface Г-Fe3Zn10. In cross-section, coating cracks were present at the wall and corner of the U-shape part due to the deformation during DHPF. Potentiodynamic polarization scans were used to determine the corrosion potential of the coating, and this was used to calculate the driving force for cathodic protection using the difference in corrosion potential between the coating phases and the substrate. It was found that only Γ-Fe3Zn10 provided robust cathodic protection to both steel substrates, and the driving force for cathodic protection was lower for the coated DHPF 2.5%Mn steel. Galvanostatic scans were used to evaluate dissolution kinetics of coating phases. Robust cathodic protection was provided by the galvanized coating for austenitization times of 30 - 120 s for the 2%Mn substrate and 30 - 60 s for the 2.5%Mn substrate. The duration that robust cathodic protection was provided was shortest at the wall of the U-shape part. This result was attributed to die wiping caused by DHPF, where the surface is smoothed by die friction. When there is less Г-Fe3Zn10 in the coating, such as at longer austenization times, surface Г-Fe3Zn10 was removed and an increased amount of α-Fe(Zn) is exposed, which does not provide robust cathodic protection. In addition, coating cracks form along α-Fe(Zn) grain boundaries after austenitization for 180 s on all examined regions of the U-shape part, allowing a greater surface area of the coating exposed to electrolyte, further increasing dissolution of the coating. / Thesis / Master of Applied Science (MASc)

This qualitative study consists of eight interviews. The selection of respondents is individuals who have a background as a former addict, who currently lives a drug-free life.  The respondents are members of NA (anonymous drug addicts) in Skåne. In our study, we have chosen to examine how women and men are treated by society and the surroundings, given the background as a former addict. Furthermore, the study will deepen on whether the gender aspect has played an influential role in being considered a socially accepted citizen. We also want to inform the feelings, thoughts and experiences of the respondents about stamping and gender.  We used the hermeneutic perspective to interpret our results and get an overall picture. The results show that all respondents feel that they are treated differently based on gender aspects of what is male and female. The results also show that the majority of the male respondents have been denied treatment for their addiction, and have been sent home with a few words such as "you are a man you can do it on your own". Furthermore, the results show that it is more shameful to be an addict as a woman than a man. The majority of the results that emerged based on our interpretations of the empirical material agree with our pre-understanding that we had before we began this study. Keywords: Substance abuse, gender differences, gender, deviators, stamping, stigma / Denna kvalitativa studien består av åtta intervjuer. Urvalet består av individer som har enbakgrund som före detta missbrukare, som lever ett drogfritt liv. Respondenterna ärmedlemmar i NA (anonyma narkomaner) i Skåne. I vår studie har vi valt att undersöka hurkvinnor respektive män bemöts av samhället och omgivningen, med tanke på bakgrundensom före detta missbrukare. Vidare kommer studien fördjupa i hur könsaspekten har varit enpåverkande roll för att anses som en socialt accepterad samhällsmedborgare. Vi vill ävenupplysa känslor, tankar och upplevelser respondenterna har kring stämpling och genus.Vi använde oss av det hermeneutistiska perspektivet för att tolka vårt resultat och få enhelhetsbild. I resultatet framgår det att alla respondenter upplever att de blir behandlade olikautifrån genusaspekter vad som är manligt och kvinnligt. Där majoriteten av manligarespondenterna blivit nekade till behandling för sitt missbruk, och blivit hemskickade mednågra ord som “du är en man du klarar det på egen hand”. Vidare framgår det i resultatet attdet är mer skamligt att vara en missbrukare som kvinna än en man. Resultatet av detempiriska materialet stämmer i stort sätt överens med vår förförståelse.

In stamping operations, sheet metal is formed into a desired shape by pressing it in a hydraulic or mechanical press between suitably shaped dies. As a predominant manufacturing process, sheet metal forming has been widely used for the production of automobiles, aircraft, home appliances, beverage cans and many other industrial and commercial products. A major effort till date on stamping processes monitoring has been focused on investigating variations in the press force. Given that the press force itself is an integral of the contact pressure distribution over the die and binder contact interfaces, it is conceivable that defects may be better identified by analyzing the contact pressure distribution directly at the tooling-workpiece interface, instead of measuring the press force, which is less reflective of the localized forming process due to its nature as a secondary effect. It is thus desirable that a new, integrated sensing method capable of directly assimilating forming pressure distribution in the tooling structure be devised for improved stamping process monitoring. Designing such a distributed sensing scheme and analyzing the feasibility of its structural integration into a stamping tooling structure is the objective of this reported work. In this context, four research tasks have been identified and examined during the course of this work: 1) Devising a New, Embedded Sensing Method The new sensing method monitors stamping processes by means of an array of force sensors structurally integrated into the stamping tooling. The ability to directly measure local forming events by means of such an integrated and distributed sensing provides a new means of performing defect detection and process monitoring. Such a distributed sensing system overcomes the limitations of traditional tonnage and acceleration sensing systems which are focused on the measurement of indirect, global parameters. The new method is based on the evaluation of spatially continuous pressure surfaces from spatially discrete sensor measurements that are directly related to the local events at the stamping interface. To evaluate the effectiveness of this method, a panel stamping test bed equipped with an array of embedded force sensors has been designed, modeled and fabricated. Data obtained from experiments conducted on the test bed indicates that the new sensing method can be highly effective in process monitoring of stamping operations. 2) Reconstruction of Spatio-Temporal Distribution of Contact Pressure Structurally integrating sensors under tooling surfaces reduces the surface rigidity of the tool, thus limiting the number of sensors and the locations at which they can be embedded. This in turn affects the reconstruction of contact pressure distribution on the tooling surface. Numeric surface generation methods, such as Bezier surfaces and Thin Plate Spline surfaces offer a method for estimating the contact pressure distributions on the tooling surfaces from a sparse distribution of sensors. The concept of interpolating force distributions using surfaces has been investigated by researchers previously. However, selection of the surface generation method has remained largely an ad hoc process. The work presented here addresses this issue by using tooling interface contact pressure distribution information obtained from FE simulations as the basis for evaluating the accuracy of two commonly employed surface methods mentioned above. In order to reach a generic conclusion, the mathematical background of these schemes has been examined in light of the purpose at hand. The results indicate that an interpolative scheme such as the Thin Plate Spline surfaces (TPS), which can estimate the contact pressure distributions more accurately in a multi-sensor environment. The local and global accuracies of the Thin Plate Spline surface modeling technique have been experimentally evaluated using a sensor embedded stamping test bed designed for the purpose. 3) Modeling of Contact Pressure Distribution at the Sheet Metal-Tooling Interface Information about the contact pressure distribution at the tooling interface is critical to identifying the accuracy of numeric schemes that estimate by interpolation or approximation the contact pressure at any point on the tooling surface, based on a limited number of spatially distributed sensors. Furthermore, such knowledge is valuable in identifying operational parameters for the sensors to be integrated into the stamping tooling structure. In the absence of a tractable analytic method of determining the contact pressure distribution on stamping tooling surfaces, Finite Element models of a stamping operation have been created. Furthermore the drilling of sensor cavities under the working surfaces of the dies adversely affects the working life of stamping dies and their strength. The accuracy of analytic fatigue failure mechanics in evaluating the effect of parameters, such as embedding depth and sensor rigidity, on the operational life of the die, suffers from uncertainty in the estimation of stress concentrations around sharp geometric features of the sensor cavity. This shortcoming has been circumvented by the creation of FE models of the sensor cavity for more accurate estimation of stress concentrations around sharp geometries. The effect of different embedding materials on the sensitivity of embedded sensors has also been evaluated based on these models. 4) Defect Detection in Stamping Operation The ultimate goal of this thesis research was to study the feasibility of identifying defects in a stamping process based on the contact pressure distribution surfaces. This was achieved in this reported work by spatio-temporal decomposition of ‘parameters’ derived from the contact pressure distribution surfaces. Here ‘parameters’ refers to quantities such as the minimum, maximum, and mean contact pressures. These parameters have a time-varying spatial location as well as magnitude value associated with them. The feasibility of defect detection in stamping operations based on such parameters has been investigated. In addition to these focal areas, the design and implementation of a stamping test bed equipped for distributed contact pressure sensing has also been researched. This test bed was utilized for experimental verification of the developed theories and numerical models. Design of the proposed test bed required research into additional topics like the design of a protective package for embedded sensors and the effect of sensor embedding depth on contact pressure measurements. These issues have been addressed in this work, culminating in the experimental demonstration of the embedded pressure sensing system for process monitoring in the sheet metal stamping processes.

This thesis is based on a research project to evaluate a quality control system for car component stamping lines. The quality control system measures the abrasion of the stamping tools by measuring the surface of the products. A 3D vision system is developed for the real time online measurement of the product surface. In this thesis, there are three main research themes. First is to produce an industrial application. All the components of this vision system are selected from industrial products and user application software is developed. A rich human machine interface for interaction with the vision system is developed along with a link between the vision system and a control unit which is established for interaction with a production line. The second research theme is to enhance the robustness of the 3D measurement. As an industrial product, this system will be deployed in different factories. It should be robust against environmental uncertainties. For this purpose, a high signal to noise ratio is required with the light pattern being produced by a laser projector. Additionally, multiple height calculation methods and a spatial Kalman filter are proposed for optimal height estimation. The final research theme is to achieve real time 3D measurement. The vision system is expected to be installed on production lines for online quality inspection. A new 3D measurement method is developed. It combines the spatial binary coded method with phase shift methods with a single image needs to be captured. / SHRIS (Shanghai Ro-Intelligent System,co.,Ltd.)

No description available.

No description available.

No description available.