Thermal barrier coatings (TBC) are used for reduction of component temperatures in gas turbines. The service temperature for turbines can be as high as 1100ºC and the components are exposed to thermal cycling and gases that will cause the component to oxidize and corrode. The coatings are designed to protect the substrate material from this, but eventually it will lead to failure of the TBC. It is important to have knowledge about when this failure is expected, since it is detrimental for the gas turbine. The scope of this thesis has been to see if an existing life model for thin TBC also is valid for thick TBC. In order to do so, a thermal cycling fatigue test, a tensile test and finite element calculation have been performed. The thermal cycling fatigue test and finite element calculation were done to find correlations between the damage due to thermal cycling, the number of thermal cycles and the energy release rate. The tensile test was preformed to find the amount accumulated strain until damage. The thermal cycling lead to failure of the TBC at the bond coat/top coat interface. The measurment of damage, porosity and thickness of thermally grown oxide were unsatisfying due to problems with the specimen preparation. However, a tendency for the damage development were seen. The finite element calculations gave values for the energy release rate the stress intensity factors in mode~I and mode~II that can be used in the life model. The tensile test showed that the failure mechanism is dependent of the coating thickness and it gave a rough value of the maximum strain acceptable.

L'objectif de ce travail de thèse est d'étudier le comportement de l'endommagement des matériaux composites sous chargement statique et fatigue par contrôle non destructif (C.N.D) thermographie et soutenu par émission acoustique et la tomographie (CT scan). Pour cela, ce unidirectionnels composite à fibres de verre (GFRP) et discontinue composite à fibres de carbone (DCFC) ont été utilisés comme les éprouvettes qui ont fourni par PSA peugeot citröen, France. Une série d'essais mécaniques a été réalisée pour déterminer le comportement de l'endommagement sous chargement statique et fatigue. Pendant tout des essais mécanique, la thermographie a été utilisé pour l'observation en temps réel pour suivre l'évolution des températures sur la surface de l'éprouvette et supporté par émission acoustique dans certaines conditions. Cette étude a utilisé une forme rectangulaire et se compose d'éprouvettes trouées et non trouées au centre de l'éprouvette. La vitesse de déplacement constante est appliquée pour observer l'effet sur le comportement de l'endommagement sous chargement de traction statique. Sous les essais de fatigue, le paramètre constant de la fréquence et de l'amplitude de stress a été étudiée pour chaque niveau de charge pour avoir les propriétés de fatigue et l'évolution de l'endommagement de l'éprouvette. La tomographie a été utilisée pour confirmer l'apparition de l'endommagement et l'etat du matériau après l'essai de fatigue. L'analyse des résultats de l'expérimentation et de l'observation NDT montré le bon accord entre les résultats mechnical et NDT thermographie avec prise en charge par l'observation de l'émission acoustique en détecter l'apparition et la propagation de l'endommagement de GFRP PRV et DCFC sous chargement de statique en traction. Les essais en fatigue montrent que la dissipation thermique est liée à l'évolution de l'endommagement et également thermographie et peut être utilisé avec succès pour déterminer la limite d'endurance (HCFS) et la courbe de Wöhler du matériau composite. Les résultats par CT scan ont mesurée avec succès les endommagements et l'état du matériau après essai de fatigue du matériau composite. / The aim of this study is to investigate the damage behaviour of composite material in static and fatigue condition with non destructive testing (NDT) thermography method and supported by acoustic emission and also computed tomography (CT) scan. Thermography and acoustic emission are used in real-time monitoring techniques during the test. On the other hand, NDT observation of tomography is used for a post-failure analysis. In order to achive this, continuous glass fiber composite (GFRP) and discontinuous carbon fiber composite (DCFC) have been used as the test specimens which supplied by PSA Company, France. A series of mechanical testing was carried out to determine the damage behaviour under static and fatigue loading. During all the mechanical testing, thermography was used in real-time observation to follow the temperature change on specimen surface and supported by acoustic emission in certain condition. This study used rectangular shape and consist of specimen with and without circular notches (hole) at the center. The constant displacement rate is applied to observe the effect on damage behaviour under tensile static loading. Under fatigue testing, the constant parameter of frequency and amplitude of stress was explored for each load level to have the fatigue properties and damage evolution of specimen. The tomography was used to confirm the appearance of damage and material condition after fatigue testing. The analysis from the experiment results and NDT observation shown the good agreement between mechnical results and NDT thermography with supported by acoustic emission observation in detect the appearance and propagation of damage for GFRP and DCFC under static loading. Fatigue testing shows that thermal dissipation is related to the damage evolution and also thermography and can be successfully used to determine high cycle fatigue strength (HCFS) and S-N curve of fiber composite material. From post failure analysis, CT scan analysis successfully measured and evaluated damage and material condition after fatigue test for fiber composite material. v

A aplicação de aços de alta resistência está fortemente difundida na indústria mecânica, principalmente em aplicações onde a redução de peso é importante, como por exemplo, a indústria de implementos rodoviários e maquinários agrícolas. Esta dissertação visa analisar a influência de diferentes aportes térmicos no comportamento microestrutural e mecânico de juntas soldadas através do processo MAG de modo a obter juntas com propriedades otimizadas. Para este estudo foram utilizadas chapas metálicas com espessura de 3 mm do aço de alta resistência e baixa liga USI LNE700. Os parâmetros nominais de energia de soldagem foram variados de acordo com os valores descritos pelo fornecedor SSAB. O processo de soldagem foi realizado com o auxílio de um sistema robotizado para manter a homogeneidade ao longo da junta, distância e posicionamento correto no comprimento total da junta soldada. Os ensaios para verificação do comportamento microestrutural e mecânico foram realizados com auxílio de microscopia ótica, perfis de microdureza e ensaios de tração. Buscaram-se utilizar aportes térmicos reduzidos para minimizar os efeitos de revenimento da martensita presente no metal de base, um dos principais responsáveis pela redução das propriedades mecânicas da junta soldada. Os resultados não mostraram significativa variações na microestrutura e propriedades de tração do material, porém o preenchimento da junta soldada formada apresenta um comportamento diretamente proporcional à energia de soldagem. / The application of high strength steels is strongly diffused in the engineering industry, especially in applications where weight reduction is important, such as the industry of agricultural machines and trailers industry. This investigation aims to analyze the influence of different heat inputs on microstructural and mechanical behavior of joint welded by GMAW in order to obtain joints with optimized properties. Sheet metal with a thickness of 3 mm high strength low alloy steel LNE700 (supplier Usiminas) were used. The welding energy was varied around the nominal value informed by the steel supplier SSAB for this study. The welding process was made using robotic system to maintain homogeneity along the joint, right distance and position during the total weld joint length. The microstructural and mechanical behaviors were performed with the optical microscope, microhardness profile and traction test. We attempted to use lower heat inputs to minimize the effects of tempering of martensite present in the base metal, a major contributor to the reduction of the mechanical properties of the welded joint. The results did not show significant microestructural and tensile properties variation, however, when the welding energy is increased, the welded joint penetration formed was increased as well.

A aplicação de aços de alta resistência está fortemente difundida na indústria mecânica, principalmente em aplicações onde a redução de peso é importante, como por exemplo, a indústria de implementos rodoviários e maquinários agrícolas. Esta dissertação visa analisar a influência de diferentes aportes térmicos no comportamento microestrutural e mecânico de juntas soldadas através do processo MAG de modo a obter juntas com propriedades otimizadas. Para este estudo foram utilizadas chapas metálicas com espessura de 3 mm do aço de alta resistência e baixa liga USI LNE700. Os parâmetros nominais de energia de soldagem foram variados de acordo com os valores descritos pelo fornecedor SSAB. O processo de soldagem foi realizado com o auxílio de um sistema robotizado para manter a homogeneidade ao longo da junta, distância e posicionamento correto no comprimento total da junta soldada. Os ensaios para verificação do comportamento microestrutural e mecânico foram realizados com auxílio de microscopia ótica, perfis de microdureza e ensaios de tração. Buscaram-se utilizar aportes térmicos reduzidos para minimizar os efeitos de revenimento da martensita presente no metal de base, um dos principais responsáveis pela redução das propriedades mecânicas da junta soldada. Os resultados não mostraram significativa variações na microestrutura e propriedades de tração do material, porém o preenchimento da junta soldada formada apresenta um comportamento diretamente proporcional à energia de soldagem. / The application of high strength steels is strongly diffused in the engineering industry, especially in applications where weight reduction is important, such as the industry of agricultural machines and trailers industry. This investigation aims to analyze the influence of different heat inputs on microstructural and mechanical behavior of joint welded by GMAW in order to obtain joints with optimized properties. Sheet metal with a thickness of 3 mm high strength low alloy steel LNE700 (supplier Usiminas) were used. The welding energy was varied around the nominal value informed by the steel supplier SSAB for this study. The welding process was made using robotic system to maintain homogeneity along the joint, right distance and position during the total weld joint length. The microstructural and mechanical behaviors were performed with the optical microscope, microhardness profile and traction test. We attempted to use lower heat inputs to minimize the effects of tempering of martensite present in the base metal, a major contributor to the reduction of the mechanical properties of the welded joint. The results did not show significant microestructural and tensile properties variation, however, when the welding energy is increased, the welded joint penetration formed was increased as well.

CoordenaÃÃo de AperfeiÃoamento de Pessoal de NÃvel Superior / A adequaÃÃo de um trator agrÃcola, visando utilizaÃÃo de pressÃes de inflaÃÃo dos pneus adequadas, para diferentes condiÃÃes superficiais de solo, resulta em melhor desempenho geral, com consequente aumento da capacidade operacional e melhor qualidade de operaÃÃo. Assim este trabalho teve como objetivo avaliar o desempenho energÃtico de um trator agrÃcola 4x2 - TDA trabalhando com diferentes forÃas na barra de traÃÃo, pressÃo de inflaÃÃo dos pneus em superfÃcie de concreto e em solo mobilizado, utilizando como norma de ensaio a OECD â âCÃdigo 2â (2012). Os ensaios foram realizados, no NÃcleo de Ensaios de MÃquinas e Pneus Agroflorestais â NEMPA, com delineamento experimental em faixas e esquema fatorial 2x3x2 com cinco repetiÃÃes, sendo duas pressÃes de inflaÃÃo dos pneus do trator 165,4 kPa (24 psi) nos rodados traseiro e 220,6 kPa (32 psi) nos rodados dianteiro do trator, correspondente a mÃxima pressÃo de inflaÃÃo recomendada pelo fabricante dos pneus e 110,3 kPa (16 psi) nos rodados traseiro e 110,3 kPa (16 psi) nos rodados dianteiro do trator, correspondente a mÃnima pressÃo de inflaÃÃo recomendada pelo fabricante dos pneus, trÃs forÃas aplicadas na barra de traÃÃo 100%, 75% e 50% da forÃa mÃxima de traÃÃo na potÃncia mÃxima e velocidade nominal do motor e dois tipos de superfÃcies de rolamento. Esses fatores foram arranjados para permitir a avaliaÃÃo dos efeitos das variÃveis de desempenho individualmente ou em grupos, sendo todos os dados que apresentaram normalidade foram submetidos à anÃlise de variÃncia, aplicando o teste DMS a 5% de significÃncia, para a comparaÃÃo das mÃdias, os dados que nÃo apresentaram distribuiÃÃo normal foram arranjados para analise estatÃstica atravÃs da MÃdia MÃvel Exponencialmente Ponderada - MMEP. O trator avaliado no ensaio foi o New Holland TM 7040 com potÃncia mÃxima no motor indicada pelo fabricante de 132 kW a 2200 rpm, tracionando a Unidade MÃvel de Ensaio na Barra de TraÃÃo - UMEB. Nos ensaios de campo observou-se que a mÃnima pressÃo de inflaÃÃo dos pneus recomendada pelo fabricante dos pneus melhorou o desempenho energÃtico do trator, reduzindo o consumo especifico de combustÃvel e aumentando o rendimento na barra de traÃÃo do trator. Em superfÃcie de concreto o trator obteve forÃa mÃxima de traÃÃo 32,6% superior à forÃa mÃxima de traÃÃo obtida em superfÃcie de solo mobilizado. Os critÃrios de ensaio empregados da norma OECD - âCÃdigo 2â proporcionaram uma padronizaÃÃo no ensaio facilitando a comparaÃÃo entre os fatores avaliados. / Agricult tractor adequation aiming the use of appropriated tire inflation pressures for different surface conditions results in better overall performance with consequent increase in operational capacity and better quality of service. Thus this study aimed to assess the energy performance of a farm tractor 4x2 - TDA working with different forces in the drawbar, inflation pressure of tires on concrete surface and tilled soil, using as a testing standard OECD â âCode 2" (2012). The tests were conducted at the Center for Testing Machines and Tires Agroforestry - NEMPA, a randomized 2x3x2 factorial and tracks with five repetitions, two tire inflation pressures Tractor 165.4 kPa (24 psi) in rear axles and 220.6 kPa (32 psi) front axles on the tractor, corresponding to maximum inflation pressure recommended by the tire manufacturer and 110.3 kPa (16 psi) in rear axles and 110.3 kPa (16 psi) in front wheelsets Tractor, corresponding to minimal inflation pressure recommended by the tire manufacturer, three forces applied to the drawbar 100%, 75% and 50% of the maximum force of traction at maximum power and rated speed of the engine and two types of bearing surfaces . These factors were arranged to allow evaluation of the effects of performance variables individually or in groups, with all data presented normality were subjected to analysis of variance, using the DMS test at 5% significance for the comparison of means, the data not normally distributed were arranged for statistical analysis by Exponentially Weighted Moving Average - MMEP. The tractor test was evaluated in the 7040 New Holland TM engine with maximum power specified by the manufacturer of 132 kW at 2200 rpm, pulling the Mobile Unit Testing in Drawbar - UMEB generated. In field trials showed that the minimum tire inflation pressure recommended by the tire manufacturer has improved the energy performance of the tractor, reducing specific consumption of fuel and increasing the yield on the tractor drawbar. In concrete surface the tractor got maximum tensile strength 32.6% higher than the maximum tensile strength obtained in surface soil mobilized. The test criteria employed the standard OECD - "Code 2" provided a standardized test in facilitating the comparison between the factors evaluated.

Os colares das sondas de prospecção petrolíferas são fabricadas de aço inoxidável austenítico devido as suas características eletromagnéticas e de corrosão. Normalmente, a temperatura de serviço é de aproximadamente 300ºC, meio aquoso e a sonda é submetida a carregamentos cíclicos. Várias foram as tentativas de desenvolvimento de um aço que atendesse as necessidades de serviço destes colares. Neste trabalho foram determinadas as propriedades mecânicas de tração e de fadiga de baixo ciclo de um aço inoxidável austenítico do sistema Fe-Mn-Cr-N, quando ensaiado mecanicamente nas temperaturas ambiente e à 300ºC. Foi observado que os valores dos limites de escoamento e de resistência e o alongamento diminuem significativamente quando a temperatura é elevada para 300ºC. Como conseqüência destas alterações, ocorreu uma diminuição da vida em fadiga. A comparação entre as curvas tensão-deformação monotônica e cíclica mostrou que este material, ensaiado à 300ºC e nas amplitudes de deformações estudadas, apresenta amolecimento cíclico. A expressão encontrada para a relação deformação-vida é dada por &#916&#949t/2=0,0054 (2Nf)-0,064 + 0,438 (2Nf)-0,595 com ponto de transição em 2Nt = 9,5 x 103. Quanto aos métodos estimativos das propriedades mecânicas de fadiga, obtidos a partir das propriedades mecânicas de tração, foi verificado que o Método da Inclinação Universal Modificado se aproxima mais da curva experimental obtida neste trabalho. A análise fratográfica mostrou a presença de estrias no estágio II de propagação de trinca. / In this work the monotonic and low cycle fatigue mechanical properties of an Cr-Mn-N austenitic stainless steel, used to produce drill collars used for deep drilling in offshore industry, were evaluated. The low cycle fatigue testing was carried out according to the ASTM E606 standard, under strain control and R = - 1, at temperature of 300°C, which is the temperature that the drill collar reaches in service. It was observed that the yield and the ultimate tensile strength and the elongation decreased sharply with increasing temperature. As a consequence, in both high and low cycle regions, the fatigue life decreased with increasing temperature. The comparison between the stress - strain monotonic and cyclic curves, showed that this material exhibited cyclic softening for the applied strain amplitudes. The correlation between strain and number of cycles to failure was can be given by &#916&#949t/2 = 0,0054 (2Nf)-0,064 + 0,438 (2Nf)-0,595 with transition in 2Nt = 9,5x103 reverses. The experimental results were compared with some models used to predict the fatigue life based on the tensile monotonic properties. The Modified Universal Shopes a better fitting with the experimental data. The fractographic analysis showed the presence of stage II striations.

The ductile fracture process, which consists of the nucleation, growth and coalescence of microvoids, was extensively studied for materials deforming homogeneously. For materials with a non-homogeneous deformation behavior, such as those having hexagonal closed packed (HCP) crystal structure, experimental and numerical data is lacking. Therefore, the fracture properties of materials with such HCP structure, like titanium (used in aerospace and biomedical applications), zirconium (nuclear industry) and magnesium (manufacturing industry) are not well understood. The main research objective of this Ph.D. thesis is to better understand the mechanisms governing fracture in commercially pure (CP) titanium. In particular, the effect of grain orientation on void growth is investigated. The fracture process of CP titanium was visualized in model materials containing artificial holes. These model materials were fabricated using a femtosecond laser coupled with a diffusion bonding technique to obtain voids in the interior of titanium samples. Diffusion bonding was carried out either above or below the phase transformation temperature resulting in different microstructures. Changes in void dimensions during in-situ straining were recorded in three dimensions using x-ray computed tomography. Void growth obtained experimentally was compared with the Rice and Tracey model which predicted well the average void growth. However, a large scatter in void growth was observed experimentally and was explained in terms of differences in grain orientation which was confirmed by crystal plasticity simulations. It was also shown that grain orientation has a stronger effect on void growth than intervoid spacing and material strength. Intervoid spacing, however, appears to control whether the intervoid ligament failure is ductile or brittle. While this study showed a good agreement between experiments and simulations on average, there is no direct void growth comparison for particular grain orientations. In a follow-up study, an experimental approach was developed to directly relate the growth of a void to its underlying grain orientation. This is achieved by first annealing CP titanium samples below the α-β phase transformation temperature, then performing electron backscatter diffraction iii (EBSD) and finally diffusion bonding the samples together. Samples were then tested in x-ray tomography. This study showed the importance of the local state of strain on void growth. Crystal plasticity simulations that take into account the particular grain orientation and the local state of strain were found to predict well experimental void growth. Crystal plasticity simulations confirmed that the orientation of the voidcontaining grain is more important than the orientation of surrounding grains and more important than the volume fraction of voids, in order to determine void growth. This thesis on the growth and coalescence of voids is important to validate and improve the predictions of ductile fracture models and to design new materials with improved fracture properties.

The thesis deals with the determination of mechanical properties of materials used for 3D printing (ABS, nylon and PLA). Standardized samples produced using a 3D printer using the Fused Deposition Modeling method were subsequently used for mechanical testing. The work is also extended to determine the mechanical properties of samples made by Soft Tooling. For the production of Soft Tooling samples, polyurethane resins SG 2000 and SG 145 were used. Individual materials were analyzed by mechanical tests (tensile test and hardness test). Surface integrity parameters have also been determined for 3D-printed materials. Parameters were selected from the individual tests (tensile strength, modulus of elasticity) ductility and hardness), which were subsequently statistically processed. The work is concluded by evaluating the results obtained, which were compared with the values given in material sheets.

The aim of this thesis is the construction of a diagram of fracture strain for high strength steel OCHN3MFA and its application for the estimation of fracture toughness of this material. The first part of the thesis contains the necessary theoretical framework for numerical modelling of tensile tests of various specimens - smooth specimen, specimen with a notch and specimen with a circumferential crack, it describes the influence of triaxiality on the fracture of bodies and the possibilities of construction of the diagram of fracture strain. Subsequently, a numerical model of these specimens is created using the finite element method (FEM). A non-linear, elastoplastic calculation is performed. Fracture is identified by means of comparing the true stress versus the strain obtained from tests with the finite element analysis results. Stress–strain states of specimens at the moment of fracture are obtained from a numerical model. A diagram of fracture strain is constructed, and it is used to estimate the fracture toughness of a cracked body. Finally, a local approach, which uses the diagram of fracture strain, and a classical approach of fracture mechanics, especially the stress intensity factor, are compared.

The master's thesis deals with the determination of mechanical properties of materials used for 3D printing (PLA, PETG, ABS, ASA). The theoretical part contains characteristics of polymer materials and describes testing of mechanical properties and additive technologies. In the experimental part, the standardized samples produced by the technology Fused Filament Fabrication were analysed using mechanical tests (tensile test and hardness test). Some of the examples were exposed to the selected factors of degradation. Selected parameters from mechanical testing (tensile strength, modulus of elasticity in tension, elongation and Shore hardness) were statistically processed. The conclusion of the thesis evaluates the impact of the factors of degradation on particular materials and compares them subsequently.