The Bay of Islands Ophiolitic Complex (BOIC) is one of most well preserved and well-exposed ophiolites in the world. The BOIC consist of four massifs; these are the Table Mountain (TBL), North Arm Mountain (NAM), Blow-Me-Down Mountain (BMD) and Lewis Hills massifs. Proposed geological environments of the BOIC in Newfoundland are diverse; ranging from oceanic spreading ridge to supra-subduction setting. The BOIC has a complete ophiolite sequence as defined at the Penrose Conference (Anonymous, 1972) including ultramafic mantle rocks, ultramafic to gabbroic cumulate rocks, sheeted dikes, pillowed basaltic rocks and capping sedimentary rocks in structurally ascending order. We studied harzburgite and overlying massive dunite in the BOIC. Harzburgite is generally medium-grained, and contains olivine, orthopyroxene, Cr-spinel, clinopyroxene and rare sulfide minerals. Harzburgite is massive to strongly deformed, with local development of mylonitic shear zones. A foliation and lineation are defined by elongated and fragmented grains of orthopyroxene and Cr-spinel. Dikes, sills, veins, and irregularly-shaped bodies of dunite and pyroxenite are present throughout the harzburgite unit. Dunite is the predominant lithology of the Blow-Me-Down Mountain. It is typically fine- to medium-grained, massive, and contains minor Cr-spinel and rare sulfide minerals. Dunite contains olivine, Cr-spinel and minor pyroxenes in some samples. Olivine crystals are commonly partly replaced by serpentine along fractures and in outer rims. Bulk rock and mineral composition data suggest that harzburgites are mild to highly refractory mantle residues after partial melting. In contrast all dunite samples show a cumulate geochemical signature from a mafic melt that originated from highly refractory mantle peridotites. Our study suggest that the harzburgite in the BOIC originally formed as oceanic lithosphere at a slow spreading ridge, possibly in the vicinity of active arc systems, whereas the parental melt for dunites formed in subduction setting. The second part of this study measured trace element compositions for olivine, Cr-spinel and bulk rock of dunite. The measured bulk rock compositions are compared to those of calculated based on mineral chemistry and their abundance. This comparison suggests that the trapped melt fraction was negligible during the crystallization of the dunites. The calculated melt compositions for the dunites confirm that the melt formed in subduction setting.

Magister Philosophiae - MPhil / Groundwater is an important water resource to be used to supplement the water demand for the City of Cape Town for present and future generations. Understanding the groundwater occurrence of the Table Mountain area is very important for future groundwater exploitation and management. Apart from the sea in the west, Table Mountain is mostly surrounded by the unconsolidated sediments including the Kirstenbosch, Newlands, and Oranjezicht areas. These areas are rich in groundwater resources, like springs; some of them were utilized, others not. However, there are few studies that focused on spring resource in this area. No up to date information is available for spring resources research and relative data is lacking from local research institutions. In fact, some of the spring resources in the Table Mountain area had been extracted and been utilized for local community for many years. Data and information newly obtained from this study about such groundwater resources will help future groundwater development and management. There are at least 13 springs in the selected study area. Those springs were investigated for groundwater occurrence, because spring is an important manifestation of the underlying aquifer through which groundwater dynamics can be detected. The main objective of the study was to sketch a clear picture of groundwater occurrence and to obtain an improved understanding of how geomorphology affects groundwater flow, its manifestation and quality. Water resources management is also important because this kind of water resource can be used to help meet the water demand of this local area in the future. There is relationship between the topographical features of the Table Mountain and spring occurrence. The research area delineated is used to interpret the relationship. Hydro-geochemical analysis is carried out to indicate the chemical components of the groundwater and to understand the groundwater type and water quality of this particular area. Based on the completed analysis and interpretation of factors influencing discharge and recharge, some good results were obtained and useful information is made available for first time. / South Africa

Philosophiae Doctor - PhD / The Table Mountain Group (TMG) Aquifer is a huge aquifer system which may provide large bulk water supplies for local municipalities and irrigation water for agriculture in the Western Cape and Eastern Cape Provinces in South Africa. In many locations, water pressure in an aquifer may force groundwater out of ground surface so that the borehole drilled into the aquifer would produce overflow without a pump. Appropriate testing and evaluation of such artesian aquifers is very critical for sound evaluation and sustainable utilization of groundwater resources in the TMG area. However, study on this aspect of hydrogeology in TMG is limited. Although the flow and storage of TMG aquifer was conceptualised in previous studies, no specific study on artesian aquifer in TMG was made available. There are dozens of flowing artesian boreholes in TMG in which the pressure heads in the boreholes are above ground surface locally. A common approach to estimate hydraulic properties of the aquifers underneath is to make use of free-flowing and recovery tests conducted on a flowing artesian borehole. However, such testing approach was seldom carried out in TMG due to lack of an appropriate device readily available for data collection. A special hydraulic test device was developed for data collection in this context. The test device was successfully tested at a flowing artesian borehole in TMG. The device can not only be used to measure simultaneous flow rate and pressure head at the test borehole, but also be portable and flexible for capturing the data during aquifer tests in similar conditions like artesian holes in Karoo, dolomite or other sites in which pressure head is above ground surface. The straight-line method proposed by Jacob-Lohman is often adopted for data interpretation. However, the approach may not be able to analyse the test data from flowing artesian holes in TMG. The reason is that the TMG aquifers are often bounded by impermeable faults or folds at local or intermediate scale, which implies that some assumptions of infinite aquifer required for the straight-line method cannot be fulfilled. Boundary conditions based on the Jacob-Lohman method need to be considered during the simulation. In addition, the diagnostic plot analysis method using reciprocal rate derivative is adapted to cross-check the results from the straight-line method. The approach could help identify the flow regimes and discern the boundary conditions, of which results further provide useful information to conceptualize the aquifer and facilitate an appropriate analytical method to evaluate the aquifer properties. Two case studies in TMG were selected to evaluate the hydraulic properties of artesian aquifers using the above methods. The transmissivities of the artesian aquifer in TMG range from 0.6 to 46.7 m2/d based on calculations with recovery test data. Storativities range from 10-4 to 10-3 derived from free-flowing test data analysis. For the aquifer at each specific site, the transmissivity value of the artesian aquifer in Rawsonville is estimated to be 7.5–23 m2/d, with storativity value ranging from 2.0×10-4 to 5.5×10-4. The transmissivity value of the artesian aquifer in Oudtshoorn is approximately 37 m2/d, with S value of 1.16×10-3. The simulation results by straight-line and diagnostic plot analysis methods, not only imply the existence of negative skin zone in the vicinity of the test boreholes, but also highlight the fact that the TMG aquifers are often bounded by impermeable faults or folds at local or intermediate scale. With the storativity values of artesian aquifers derived from data interpretation, total groundwater storage capacity of aquifers at two case studies was calculated. The figures will provide valuable information for decision-makers to plan and develop sustainable groundwater utilization of artesian aquifers in local or intermediate scales. With the hydraulic test device readily available for data collection, more aquifer tests can be carried out in other overflow artesian boreholes in TMG. It becomes feasible to determine the hydraulic properties of artesian aquifers for the entire TMG. Thereof quantification of groundwater resources of artesian aquifers in TMG at a mega-scale becomes achievable. This would also contribute towards global research initiative for quantification of groundwater resources at a mega-scale.

The Bay of Islands Ophiolitic Complex (BOIC) is one of most well preserved and well-exposed ophiolites in the world. The BOIC consist of four massifs; these are the Table Mountain (TBL), North Arm Mountain (NAM), Blow-Me-Down Mountain (BMD) and Lewis Hills massifs. Proposed geological environments of the BOIC in Newfoundland are diverse; ranging from oceanic spreading ridge to supra-subduction setting. The BOIC has a complete ophiolite sequence as defined at the Penrose Conference (Anonymous, 1972) including ultramafic mantle rocks, ultramafic to gabbroic cumulate rocks, sheeted dikes, pillowed basaltic rocks and capping sedimentary rocks in structurally ascending order. We studied harzburgite and overlying massive dunite in the BOIC. Harzburgite is generally medium-grained, and contains olivine, orthopyroxene, Cr-spinel, clinopyroxene and rare sulfide minerals. Harzburgite is massive to strongly deformed, with local development of mylonitic shear zones. A foliation and lineation are defined by elongated and fragmented grains of orthopyroxene and Cr-spinel. Dikes, sills, veins, and irregularly-shaped bodies of dunite and pyroxenite are present throughout the harzburgite unit. Dunite is the predominant lithology of the Blow-Me-Down Mountain. It is typically fine- to medium-grained, massive, and contains minor Cr-spinel and rare sulfide minerals. Dunite contains olivine, Cr-spinel and minor pyroxenes in some samples. Olivine crystals are commonly partly replaced by serpentine along fractures and in outer rims. Bulk rock and mineral composition data suggest that harzburgites are mild to highly refractory mantle residues after partial melting. In contrast all dunite samples show a cumulate geochemical signature from a mafic melt that originated from highly refractory mantle peridotites. Our study suggest that the harzburgite in the BOIC originally formed as oceanic lithosphere at a slow spreading ridge, possibly in the vicinity of active arc systems, whereas the parental melt for dunites formed in subduction setting. The second part of this study measured trace element compositions for olivine, Cr-spinel and bulk rock of dunite. The measured bulk rock compositions are compared to those of calculated based on mineral chemistry and their abundance. This comparison suggests that the trapped melt fraction was negligible during the crystallization of the dunites. The calculated melt compositions for the dunites confirm that the melt formed in subduction setting.

Basalt flows occur in the Snowville area of north-central Utah and the Table Mountain and Holbrook areas of south-central Idaho. All basalt flows are aphanitic in groundmass, and contain olivine, plagioclase, augite, and opaque oxides. They can be distinguished by texture. Snowville basalt has predominantly subophitic to intergranular textures. Table Mountain basalt is fine grained, with stumpy groundmass plagioclase and equant ilmenite crystals. Holbrook basalt has pilotaxitic to intergranular textures, with the presence of plagioclase phenocrysts and characteristic exsolution lamellae in Fe-Ti oxides. The olivine grains in Holbrook area are intensely oxidized to Fe-Ti oxides. Snowville basalt contains olivine phenocrysts (Fo88 -Fo44 ) in a groundmass of olivine (Fo63 -Fo47), augite (Wo42 -Wo36), and plagioclase (An77-An52). The lower flow unit of Table Mountain basalt contains olivine phenocrysts (Fo88-?) in a groundmass of augite (Wo44 En44 Fs17), and plagioclase (An58-An48). The upper flow unit of Table Mountain basalt has olivine phenocrysts (Fo82-Fo65), plagioclase phenocrysts (An73-An67), and plagioclase groundmass (An64-An55). The Holbrook basalt is composed of olivine phenocrysts (Fo67-Fo57)and plagioclase phenocrysts (An68-An43 ) in a groundmass of olivine (Fo59Fos53) augite (Wo39 En44 Fs17), and plagioclase (An67-An35). The basalts of the Snowville and Holbrook areas, represent petrographic, mineralogical, and chemical characteristics of both olivine-tholeiitic basalt and alkali-olivine basalt, whereas Table Mountain upper and lower flow units show their affinity with alkali-olivine basalt. Chemically, basalts from these three areas are consistently high in silica, magnesium, and alkali content. The Snowville basalt has a high Ba content and high strontium isotope ratio. Fractional crystallization models indicate that the basalt flows from the three different areas are genetically unrelated. The testing also suggests that the upper and lower flow units of the Table Mountain area are not genetically related. The basalts of the three areas also can not be evolved from the basalts found at Kelton, the Rozel Hills or Black Mountain. Basalts of the Snowville area have consistently higher magnesium and silica contents than Snake River basalt, Kelton area basalt, and Rozel Hills and Black Mountain basalt, indicating that they may represent what was initially a very primitive basaltic lava. High Ba content and strontium isotope ratio indicate that the Snowville basalt was contaminated by crustal material. Table Mountain and Holbrook basalt may have formed as a result of partial melting from a pyrolite or garnet peridotite mantle.

<p><font face="TimesNewRoman"> <p align="left">Research findings in current study provide a new insight into the fractured rock aquifers in the TMG area. Some of the results will have wide implications on the groundwater management and forms a solid basis the further study of the TMG aquifers.</p> </font></p>

<p><font face="TimesNewRoman"> <p align="left">Research findings in current study provide a new insight into the fractured rock aquifers in the TMG area. Some of the results will have wide implications on the groundwater management and forms a solid basis the further study of the TMG aquifers.</p> </font></p>

Philosophiae Doctor - PhD / Research findings in current study provide a new insight into the fractured rock aquifers in the TMG area. Some of the results will have wide implications on the groundwater management and forms a solid basis the further study of the TMG aquifers.

Philosophiae Doctor - PhD / Research findings in current study provide a new insight into the fractured rock aquifers in the TMG area. Some of the results will have wide implications on the groundwater management and forms a solid basis the further study of the TMG aquifers.

>Magister Scientiae - MSc / Deformation of the western part of the Table Mountain Group rocks during the Cape Orogeny created a series of folds and associated fractures. The subsequent continental break-up of Gondwana led to the development of large fault systems. These exert a major influence on deep and shallow groundwater flow. There are 3 main types of structures that are investigated. The geological contacts between hydraulically different lithologies, the primary characteristics of the sediments comprising the main geological units and the secondary structures developed from the tectonic events. These inter-alia include lithological boundaries, bedding and conjugate joints and large faults. Compartmentalisation of the aquifers by lithological and fault boundaries are the main regional level controls on flow in the study area. Joints are important for local control of flow, but cumulatively exert a regional effect as well. These controls exert a strong 3 dimensional impact on flow patterns within the area. Geological cross sections and detailed fieldwork combined with the conceptual models proposed are used to determine groundwater flow and the extent of the flow constraints. There is heterogeneity in the fault characteristics whilst there is consistence in the impermeable aquitards. These effect boundaries at the base of the aquifer, divide the aquifer into upper and lower units and cap the top of the aquifer. Using water level data, EC and pH an attempt is made to establish patterns created by structures, mainly faults. There appears to be some control of these shown by patterns seen on contour plots of the data. Understanding of the structures can significantly alter the way the available data could be interpreted. The integration of all available data into the conceptual model provides an effective research tool, which opens up further avenues for new approaches and methods for continued research in this area.