M.A. (Geography and Environmental Management) / Water can be regarded as a scarce commodity in South Africa and one cannot rely solely on the discovery of new water resources to meet the ever increasing demands. Water is arguably the most precious resource in South Africa and its proper management in all spheres of activity is imperative ( Middleton and Stern,1987 ). This is no different in the mining industry where a primary consumptive use of water is in the tailings dams and associated return water. Restricted implementation of Government water plans and a series of droughts has forced users of water to optimise their use of water. A key to correct water management of a tailings disposal system on a gold mine lies in accurate and meaningful water balance. To provide an accurate water balance, quantifying the water loss is necessary. The water loss in a tailings system is mainly due to evaporation and interstitial flow. For the purpose of this study, evaporation is dealt with in more detail.

La presente investigación tiene como finalidad mejorar la productividad en las partidas de mayor incidencia (Relleno de cuerpo de Presa material tipo 3, Colocación de material de filtros tipo 1 y tipo 2, Colocación de concreto curb en pantalla impermeabilizante y Limpieza de estribos) de la construcción de una Presa de Relaves de un Proyecto Minero aplicando herramientas de lean Construction. La poca productividad mostrada en las partidas identificadas de incidencia desde el punto de vista de costos, conlleva directamente a incumplimientos de Plazo, Costo y Calidad por ende afecta la rentabilidad de la Compañía y la satisfacción del cliente considerablemente. El resultado del presente trabajo de investigación es la mejora de la productividad e incremento significativo de los rendimientos reales superando a los ofertados, todo ello con la implementación, aplicación y seguimiento constante a las herramientas que proporciona la filosofía lean Construction aplicadas en las partidas más incidentes del proyecto. Con esta experiencia podemos afirmar que la filosofía Lean Construction aplicado a Proyectos de gran envergadura como son los proyectos mineros es una herramienta potente para el cumplimiento contractual. / The purpose of this research is to improve productivity in the items with the highest incidence (Filling of body of Dam material type 3, Placement of filter material type 1 and type 2, Placement of concrete curb in waterproofing screen and Cleaning of abutments) of the construction of a tailings dam for a mining project applying lean construction tools. The low productivity shown in the items identified of incidence from the point of view of costs, directly leads to non-compliance with Term, Cost and Quality, therefore it affects the profitability of the Company and the satisfaction of the client considerably. The result of this research work is the improvement of productivity and a significant increase in real yields, surpassing those offered, all with the implementation, application and constant monitoring of the tools provided by the lean Construction philosophy applied in the most incident items. of the project. With this experience we can affirm that the Lean Construction philosophy applied to large projects such as mining projects is a powerful tool for contractual compliance. / Trabajo de investigación

Tailings storage facilities (TSFs) serve as structures for storing tailings, i.e., waste materials generated by the mining industry. In recent years, tailings dam failures and collapse of these constructions have been reduced due to the establishment of regulations to control these structures, nevertheless, the consequences are catastrophic when tailings dam failures occur. There are some different construction methods for tailings dams. One common construction method is the upstream method; where the dam is raised by constructing embankments on top of the tailings stored in the impoundment. Thus, it is essential to understand the mechanical and geochemical behavior of deposited tailings to be able to perform safety assessments of tailings dams.  Material properties must be assessed for the present time as well as over a longer time since aging and continuous deposition might change the mechanical behavior over time. Continuous deposition leads to continuous increased vertical stress on particles, and there is a need to study if increased vertical stress can lead to a possible change of the mechanical properties of tailings. Therefore, this study has investigated the characteristics of tailings particles after being subjected to vertical stepwise loading. This study focuses on investigating the impact of particle breakage (or crushing) on tailings by analyzing material recovered from a tailings dam in Sweden. The research was performed on disturbed tailings material from a borehole of approximately 40 m depth. The study was conducted on four samples recovered 10 m apart, developing a characterization of the material and laboratory tests on each of them. The characterization consisted of the determination of intrinsic properties such as particle size distribution, particle shape, and mineralogy before and after testing; while the laboratory tests were conducted by means of the odometer test. The laboratory tests employed the oedometer test, which applies a vertical load in slow increments under K0 conditions to simulate the behavior of tailings consolidated in the impoundment. The results obtained from the oedometer tests showed interesting observations regarding changes in particle size distribution (PSD) before and after testing. Based on this study it is hard to conclude if the change in PSD solely is caused by crushing. Three samples show a PSD after oedometer which have slightly more fines than before oedometer, while the last sample has neglectable change in PSD. Theoretically, this small change in PSD indicates that larger tailings particles exhibited a higher susceptibility to some degree of crushing, but since the change is so small it cannot be excluded that the changes origins from the accuracy of determining the PSD.  The samples taken at different depths were prepared using the tamping method, and the oedometer testing indicated minimal differences in their compression characteristics, and since the soil fabric was destroyed under sampling and then reconstituted through tamping this is expected. To investigate the influence of particle arrangement on the compression and potential crushing, one of the samples was tested in a slurry configuration. This test demonstrated that particle arrangement appears to be a contributing factor to crushing, as it showed less deviation in particle size distribution compared to the tamped sample. To contextualize and validate the findings, the results were correlated, evaluated, and compared with previous studies conducted on tailings from the same tailings storage facility (TSF). Although future research on crushing in correlation of mineralogy respectively and changes in particle shape are needed, this comparative analysis has provided input that can contribute to enhanced understanding of tailings behavior under increased vertical load.

Thesis (MScIng)--University of Stellenbosch, 2007. / ENGLISH ABSTRACT: Due to economic and environmental constraints mining operations are placed under increasing pressure to effectively manage and operate tailings disposal operations. Restrictions imposed on water usage and tailings operations footprint have led to higher density and wider particle size distribution slurries conveyed to tailings areas. One means of efficiently disposing the tailings is co-disposal. In this method a concentrated fine vehicle slurry is used to convey a coarser fraction. This produces a higher density of tailings, with a number of advantages both upstream and downstream of the tailings process. Limited research has been conducted on the effect of coarse particles on the non-Newtonian rheological properties of these slurries. This lack of information complicates the design and reliable operation of these systems. This project aims at gaining a clearer understanding as to the mechanisms involved in the addition of coarse particles to a fine clay slurry vehicle; and to provide a means of estimating the measured slurry rheological properties. A number of experiments were designed to test the slurry (both Kaolin only, and Kaolin-coarse particle mixtures) rheological properties using a Couette viscometer (for the dynamic flow properties of yield stress and plastic viscosity) and a vane instrument (for the static yield stress measurements). The slurries were prepared in varying Kaolin clay solids concentrations with reverse osmosis water. Glass beads and two types of industrial sand were used as the coarse fractions. All of the coarse particles had a similar size but varied significantly in shape. Slurry pH and temperature readings were monitored throughout the tests. Tests were done initially on clay only slurries. The rheological properties of these slurries were repeatable, and no noticeable variations of properties with time were observed. The yield stress (both static and dynamic) and plastic viscosity data were well correlated with established relationships. Coarse particles were added to the clay only slurries, and then removed. The remaining clay only slurry exhibited the same rheological properties as the initial clay only slurry. The presence of coarse particles increased all the measured rheological properties (i.e. dynamic yield stress, Bingham viscosity, and static vane yield stress) in a fashion resembling the effect of adding clay to a clay only slurry. In addition, the change in measured rheological property by addition of coarse particle was independent of the clay fraction in the clay slurry. Furthermore, with both the clay only slurries and clay and coarse sand slurries, a constant linear relationship existed between the static and dynamic yield stress. Several correlations from the literature were found to provide reasonable prediction of the rheological property variations observed. These empirical and semi-empirical models however did little to explain the mechanisms involved in coarse particle addition. A new correlation has been proposed, Residual Clay Concentration, which predicts the change in rheological property based on an additional clay concentration, which in turn is a linear function of the coarse particle concentration. The accuracy of this model further strengthens the belief that the coarse particle acts in a similar fashion to a floc. By means of a case study example the importance of selecting an appropriate model for design was illustrated. The Residual Clay Concentration method provided the most conservative results. This combined with its theoretical basis strengthens the models recommendation for use in design. / AFRIKAANSE OPSOMMING: As gevolg van ekonomiese en omgewings beperkinge word mynwese nywerhede onder toenemende druk geplaas om doeltreffende afvalstroom bestuur en operasie toe te pas. Beperkinge geplaas op water gebruik en afvalstroom area-groote ly tot hoër digthede en wyer partikel-grooteverspreidings van flodders vervoer na afval areas. Een manier om van die afval doeltreffend ontslae te raak en te berg is deur medeberging. In die metode word ‘n gekonsentreerde fyn flodder gebruik as draer van ‘n growwer partikel-fraksie. Dit ly tot ‘n hoër digtheid flodder, met verskeie voordele in beide die op – en afstroom prosesse. Beperkte navorsing is gedoen op die effek van growwe partikels op die nie-Newoniese rheolgiese eienskappe van hierdie flodders. Hierdie tekort aan informasie maak die effektiewe, betroubare bedryf en operasie van die sisteme meer ingewikkeld. Hierdie projek is daarheen gemik om ‘n beter begrip te ontwikkel met betrekking tot die meganismes betrokke in die byvoeging van growwe partikels aan ‘n fyn klei-agtige flodder draer; en om ‘n manier te voorsien wat die rheologiese eienskappe kan beraam. Verskeie eksperimente was ontwerp om die flodders (beide slegs Kaolien, en Kaoliengrowwe partikel mengsels) se rheologiese eienskappe te toets deur die gebruik van ‘n Couette-viskometer. Die Couette viskometer was gebruik om die dinamiese eienskappe (van grens-spanning, en plastiese viskositet) te meet. ‘n Vaan apparaat is gebruik om die eienskap van statiese grens-spanning te meet. Die flodders was voorberei in verskeie Kaolien konsentrasies met tru-osmosis water. Glas krale en twee tipes industriële sand is gebruik as die growwe fraksies. Al die growwe partikels het soortgelyke groottes gehad, maar het grootliks verskil in vorm. Die flodder pH en temperatuur lesings is deurentyd nagegaan. Toetse was aanvanklik gedoen op die klei-alleenlike flodders. Die gemete reologiese eienskappe van die flodders was herhaalbaar, en geen opmerkbare veranderinge van die eienskappe met betrekking tot tyd is gemeet nie. Die grens-spanning (beide statiese en dinamiese) en plastiese viskositeit is goed gekorrelleer met gevestigde verhoudinge. Growwe partikels is aan die klei-alleenlike flodders bygevoeg, en daarnae verwyder. Die oorblywende klei-alleenlike flodder het dieselfde gemete rheologiese eienskappe getoon as die oorspronklike klei-allenlike flodder. Die teenwoordigheid van growwe partikels het na ‘n toename van al die gamete rheologiese eienskappe gelei wat fisies baie soortgelyk is aan die byvoeging van klei tot ‘n klei-alleenlike flodder. Verder, met beide die klei-alleenlike en klei-growwe partikel flodders het ‘n konstante liniëre funksie tussen die statiese en dinamiese grens-spannings bestaan. Verskeie verhoudings uit die literatuur het goeie korrelasie bewerkstellig met die waargenome rheologie veranderinge. Hierdie empiriese en semi-empiriese modelle doen egter min om die megansimes betrokke in die toevoeging van growwe partikels te verduidelik. ‘n Nuwe korrelasie is voorgestel, naamlik die Residu Klei Konsentrasie. Hierdie model voorspel die verandering in reologiese eienskappe gebaseer op ‘n addisionele klei konsentrasie, wat ‘n liniëre funkise is van die growwe partikel konsentrasie. Die goeie korrelasie gesien met die model versterk die idée dat die growwe partikel in ‘n soortgelyke manier as ‘n flok gedra in die teenwoordigheid van ander flokke. Deur middel van ‘n tipiese industriële voorbeeld is die belangrikheid in die keuse van die regte korrelasie geillustreer. Die Residu Klei Konsentrasie metode het die mees konservatiewe resultate gelewer. Hierdie feit gekombineerd met die model se soliede teoreitiese beginsels versterk dit as voorgestelde korrelasie vir ontwerp.

Numerical analyses are presented in this thesis to address potential stability problems that may occur during gradual raisings and under seismic loading conditions of Aitik tailings dam in northern Sweden. The dam is mainly raised using upstream construction method. It is planned to raise the dam gradually in several stages. Two dam parts were studied. The first dam part is a straight dam portion, and the second dam part is a corner. The main concerns associated with future raisings of the straight dam part were: (i) the stability of the dam could be affected by an increase in excess pore pressures during sequential raisings, (ii) how to gradually strengthen the dam by using rockfill berms as supports in such a way that required slope stability can be achieved with a minimum volume of rockfill berms, and (iii) if the dam is subjected to seismic loading, whether or not an increase in excess pore pressures could lead to extensive liquefaction which may cause a failure. The problems related to the dam corner were that tension zones and/or low compression zones could develop because of the horizontal pressure of the stored tailings on the inside of the curvature of the dam corner.Numerical analyses were conducted on both the dam parts using finite element method. Two dimensional (2D) plane strain finite element model was utilized to analyse the straight dam. The dam corner was analysed with both the three dimensional (3D) finite element model, and the 2D axisymmetric finite element model. Coupled deformation and consolidation analyses, and slope stability analyses were performed on both the dam parts to simulate gradual raisings, and to compute safety factors. In addition to this, dynamic analyses were carried out on the straight dam part to evaluate the potential for liquefaction, and seismic stability of the dam. The seismic behaviour of the dam was analysed for two cases: (i) a normal case (earthquake of 3.6 Swedish local magnitude), and (ii) an extreme case (earthquake of 5.8 moment magnitude).The results of the straight dam part, with only previously existing rockfill berms, indicate that stability of the dam was reduced due to an increase in excess pore pressures during raisings. Rockfill berms were utilized as supports to raise the dam with enough safety. An optimization technique was utilized to minimize the volume of rockfill berms. This technique could result in significant saving of cost of rockfill berms.The results of the dam corner show that tension zones and/or low compression zones were located on the surface of the dam corner, mainly above the phreatic level. It is interpreted that there is no risk of internal erosion through the embankments because no seepage path occurs above the phreatic level, and a filter zone exists along the slope of the dam. It is suggested to gradually strengthen the dam corner with rockfill berms. The results of the 2D axisymmetric analyses of the dam corner were in a fairly good agreement with those of the 3D analyses. This implies that the 2D axisymmetric analyses are valid for this dam corner. This is an important finding as 2D axisymmetric analyses require much less computational time compared to 3D analyses.The results of the dynamic analyses performed on the straight dam (including additional rockfill berms) suggest that, for the extreme case, liquefaction could occur in a limited zone that is located below the surface near the embankments. For both the normal and the extreme case, (i) seismically induced displacements seem to be tolerable, and (ii) the post seismic stability of the dam is considered to be sufficient.The findings of this study have been practically applied to the Aitik tailings dam. In general, the modelling procedure and the optimization technique to minimize volume of rockfill berms, presented in this study, could be applied to other tailings dams. / Godkänd; 2013; 20130513 (muhauc); Tillkännagivande disputation 2013-05-20 Nedanstående person kommer att disputera för avläggande av teknologie doktorsexamen. Namn: Muhammad Auchar Zardari Ämne: Geoteknik/Soil Mechanics and Foundation Engineering Avhandling: Numerical Analyses of Stability of a Gradually Raised Tailings Dam Opponent: Professor Daichao Sheng, School of Engineering, The University of Newcastle, New South Wales, Australia Ordförande: Professor Sven Knutsson, Institutionen för samhällsbyggnad och naturresurser, Luleå tekniska universitet Tid: Torsdag den 13 juni 2013, kl 10.00 Plats: F1031, Luleå tekniska universitet

Msc. / This study focuses on the functional evaluation of a gold Tailings Storage Facility (TSF), the Fleurhof TSF (designated slimes dam 2L3), which is representative of gold slimes (tailings) dams in the Witwatersrand. The aim is to evaluate the rehabilitation status (in terms of species composition and landscape function) of TSF surfaces that were planted ~20 to ~40 years ago using the most common rehabilitation practice, namely pasture grassing. Pasture grassing aims to obtain rapid dust control. Mine closure was not considered at the time, and the vegetation was hence not designed with ecological processes or long-term objectives in mind. However, over time, grassing practices became routine in the TSF vegetation industry, and the contribution that they have made towards surface rehabilitation needs to be assessed against the current site closure objectives. On the selected site, evaluations of vegetation cover, species composition, and substrate physical and chemical properties were conducted in 1975 (Thatcher, 1979). The aim of the current mid-summer study in 2009 was addressed by assessing the same parameters of vegetation cover, species composition, and soil physical and chemical properties, and comparing these to the results of the previous assessment in 1975. Landscape Function Analysis (LFA – an index-based method of evaluating the retention of resources by surfaces and soil condition), was applied to determine the landscape function (stability, infiltration and nutrient cycling that are derived from the eleven soil surface assessment indicators), and compared with the landscape function of natural analogues in the same locality. Landscape organisation (also an indicator of LFA) was used to investigate the contribution of vegetation overall, and of discrete plant functional groups to landscape functionality. A total of 35 plant species were observed in the quadrats (56 species on the TSF overall), with 51% of species overall being alien. Perennial vegetation and cryptogam covers contributed the most to stabilising the TSF slopes and flat (top) surfaces. The percentage of vegetation basal cover on the TSF (30% – 70%) was lower than for analogue grassland sites on a nearby hill (80% – 100%). Lower basal vegetation cover on the TSF than on the analogue site, were associated with lower LFA indices of stability on all TSF slope aspects (P = 8.19 x 10-13 for all aspects), iii lower nutrient cycling for the northern and southern TSF slopes (south aspect P = 4.20 x 10-6; top aspect P = 0.03), and lower infiltration on the southern slope of the TSF (P = 2.68 x 10-6). However, a higher infiltration on the northern TSF aspect (P = 0.02) than on the analogue site, was attained. Perennial tussock grass patch types (which included perennial forbs) made the largest contribution to the soil surface assessment (SSA) indicators on the TSF and analogue sites, and therefore to the LFA indices that were derived from these SSA indicators. The contribution of woody patches to function was not evaluated.

MESMEG / Department of Mining and Environmental Geology / The increase in the demand and market price of gold has led to reprocessing of gold tailings in many parts of the world. Mines are recently closing down due to depletion of resources and increasing mining costs leading to the reprocessing of old tailings dams. The cost of rehabilitation is high, and therefore a more convenient way of rehabilitation is required. The most convenient strategy identified here was to reprocess tailings for gold and use waste rocks as construction materials. The tailings residues (waste remaining after reprocessing) will be relocated to a more convenient place to avoid pollution. Gold reprocessing from tailings dams has gained momentum in South Africa especially in the Witwatersrand Basin where there are large volumes of tailings. Gold is being reprocessed from tailings in this area using hydraulic monitors. This study focused on the evaluation of gold and heavy metals within the tailings at Consolidated Murchison Mine tailings in Gravelotte, Limpopo province. Augering was conducted over the tailings up to a depth of 8 m along four sampling Profiles. The first profile had two sampling points, the second profile with three sampling points, the third and fourth profiles consisted of four and five sampling points respectively. Samples were collected at 1 m interval, therefore a total of 112 samples were collected and analysed for heavy metals using X-Ray Fluorescence spectrometry and 84 samples were analysed for gold using fire assaying. Tailings sampling was accompanied with tailings logging, taking note of colour, texture and moisture content. Based on this, the oxidation status of the tailings dam was determined. Oxidation zone of this tailings dam was mainly from top down to a depth of 3 m. The transitional zone was not identified, hence after the oxidation zone, the rest was unoxidized zone. This study established that gold was erratically distributed within the tailings dam with the lowest and highest values of 200 mg/kg and 1880 mg/kg respectively and the average was 670 mg/kg. The tonnage of tailings within the dam was found to be 13 280 310 tons with a total gold amount of 8 897. 81 kg. At the current world market, this interprets to US$ 306 932 396.00 (R 4 281 706 924.20). It was concluded that this tailings dam is economically viable for reprocessing, although previous studies have indicated that it is not possible to extract gold from tailings dams completely. The heavy metal content of Pb, Ni and Cr were found to be high with average values of (ppm); 5631.5, 2062.6 and 1345 v respectively. The metals with the lowest values were Cd, Co and Cu, averaging (ppm); 0.01 ppm, 19.8 ppm and 42.1 ppm respectively. Heavy metal content in soil around the tailings dam was gradually decreasing with distance from the tailings dam. Waste rocks have been used in some parts of the world as sub-base material for engineering construction, hence in this study, a total of 6 waste rock samples were collected using grab sampling method for geostatistical investigation. Such samples were subjected to various geotechnical tests which included particle size distribution analysis (sieve analysis), Atterberg limit tests and laboratory compaction test to determine their suitability for construction. The waste rock material was found to be suitable for road construction as it was classified under Group A-1-a using the AASHTO classification system. The material consisted mainly of rock fragments, gravel and sand material with minor silt/clay. In general, Consolidated Murchison mine waste was found to be suitable for road construction. / NRF

MESMEG / Department of Mining and Environmental Geology / This study entails geochemical and mineralogical characterization of gold tailings of Nestor Mine and Glynn’s Lydenberg Mine of the Sabie-Pilgrim’s Rest goldfields. A total of 35 samples were collected and were analysed for chemical composition (XRF and ICP-MS), mineralogical composition (XRD). In addition, acid-base accounting (ABA) techniques had been conducted to predict the potential for acid mine drainage. Seepage from Nestor tailings dump and water samples from the adjacent Sabie River were also collected and analysed by means of inductively coupled plasma mass spectrometry (ICP-MS) and immediate constituent (IC) -analytical techniques. The study revealed that Sabie-pilgrim’s rest goldfield is characterized by both acid generating and non-acid producing tailings, and this is attributed to variations in the mineralogy of source rocks. Gold occurred within the Black Reef Quartzite Formation in the Nestor Mine and within the Malmani Dolomite in the case of Glynn’s Lydenburg Mine. Mineralogy and bulk geochemical analyses performed in this study showed a clear variation in the chemistry of Nestor Mine and Glynn’s Lydenburg Mine tailings. Predominant oxides in Nestor mine tailings samples are SiO2 (ranging from 66.7-91.25 wt. %; followed by Fe2O3 and Al2O3 (in range of 0.82-15.63 wt. %; 3.21-12.50 wt. % respectively); TiO2 (0.18-10.18 wt. %) and CaO (0.005-3.2 wt. %). Also occurring in small amounts is CaO (0.005-3.2 wt. %), K2O (0.51-2.27 wt. %), MgO (0.005-1.46 wt. %), P2O5 (0.029-0.248), Cr2O3 (0.013-0.042 wt. %) and Na2O (0.005-0.05 wt. %). The samples also contain significant concentrations of As (137-1599 ppm), Cu (34-571 ppm), Cr (43-273 ppm), Pb (12-276 ppm), Ni (16-157 ppm), V (29-255 ppm), and Zn 7-485 ppm). In the Glynn’s Lydenburg Mine tailings SiO2 is also the most dominant oxide ranging between 47.95 and 65.89 w%; followed by Al2O3 (4.31 to 16.19 wt. %), Fe2O3 (8.48 to 11.70 wt %), CaO (2.18 to 7.10 wt. %), MgO (2.74 to 4.7 wt. %). Occurring in small amounts is K2O (1.12-1.70 wt. %), MnO (0.089-0.175 wt. %), P2O5 (0.058-0.144 wt. %) and Cr2O3 (0.015-0.027 wt. %). Arsenic (As), is also occurring in significant amounts (807-2502 ppm), followed by Cr (117-238 ppm), Cu (10-104 ppm), V (56-235 ppm), Ni (45-132 ppm), Pb (13-63 ppm) and Zn (90-240 ppm). Nestor Mine tailings associated with Black Reef Formation mineralization have net neutralizing potential (NPR) <2, hence more likely to generate acid; and their acid potential (AP) ranges 1.56 to 140.31 CaCO3/ton and neutralizing potential (NP) range from -57.75 to -0.3 CaCO3/ton. Glynn’s Lydenburg Mine tailings dump which is vi associated with dolomite mineralization, however, was not leaching acid. Based on acid-base accounting results, these tailings have more neutralizing potential (ranging between 57.6 and 207.88 CaCO3/ton) than acid potential (ranging between 7.5 and 72.1 CaCO3/ton); and their NPR>2, hence unlikely to produce acid. This is confirmed by paste pH which was in the ranges between 7.35 and 8.17. Tailings eroded from Nestor Mine tailings dump were also found to be characterized by high content of metals and oxides, namely, As, Cu, Ni, Pb, V, and Zn with SiO2, Fe2O3 and TiO2. The tailings were observed eroded into the Sabie River where AMD related precipitate (yellow boy) was also observed, indicating further oxidation downstream. Field observations, onsite analyses of water samples and laboratory results revealed that Nestor Mine tailings storage facility discharges acid mine drainage with considerable amounts of Al, As, Cu, Fe, Mn, Zn and SO4 and very low pH exceeding the limit as per South African water quality standards. High concentrations of these metals have toxicity potential on plants, animals and humans. Upon exposure to oxygen and water, tailings from Nestor Mine are more likely to generate acid mine drainage that can cause detrimental effect to the environment and the surrounding communities. Potential pollutants are Fe, Mn, Al, As, Cr, Cu, Ni and Pb. Tailings from Glynn’s Lydenberg showed no potential for acid mine drainage formation. / NRF

MENVSC / Department of Ecology and Resource Management / Mine tailings (MT) have been a global problem due to the environmental impacts the waste generates such as air, soil and water pollution. The detrimental impacts include a global problem such as acid mine drainage (AMD) which has been difficult to cleanup. Several studies have been conducted to find alternative measures in reducing or mitigating impacts such as AMD and air pollution. Several studies have revealed how alumino-silicate mineral waste can be used as raw material to produce construction materials. This study aimed at evaluating the potential of synthesizing a geopolymer material from Musina copper mine tailings. Tailings were characterized for their physicochemical and mineralogical compositions using standard laboratory techniques in order to evaluate suitability in geopolymerization. First section of the results presented physicochemical and mineralogical characterization of the Musina copper tailings together with the bioavailability of the chemical species. It was observed that the tailings are mainly composed of SiO2 and Al2O3 as the major oxides indicating that they are aluminosilicate material. Mineralogical analysis revealed dominance of quartz, epidote and chlorite as the major minerals. The bioavailability assessment showed that largely Cu and Ca are bioavailable and highly soluble in an aqueous solution while Al, Mg, Ni, Co, Cr and Fe have a high proportion in non-labile phase. Second section presented the preliminary results wherein the potential application of Musina copper tailings in geopolymerization was evaluated. The results showed that Musina copper tailings can be used to synthesize a geopolymer material. However, it was recommended that several parameters influencing geopolymerization need to be evaluated. The third section presented the evaluation of optimum parameters that influence the geopolymerization process, which include type of alkali activators, alkali activator concentration, curing temperature, liquid-solid (L/S) ratio and curing regime. It was observed that a mixture of NaOH:Na2SiO3.5H20 at a ratio of 70:30 yields a better geopolymer material. The concentration of 10 M NaOH:Na2SiO3.5H20 at a ratio of 70:30 was observed to be the best that yielded the UCS that is acceptable according to SANS1215 standards. When evaluating curing regime, it was found that the material cured using greenhouse has lower UCS as compared to the material cured using oven. The v effect of temperature showed that the UCS decreases with increasing curing temperature. An admixture of river sand and cement was introduced which resulted in a high UCS of 21.16 MPa when using an admixture of cement. The mineralogical composition of the geopolymer bricks showed formation of secondary minerals such as phlogopite, fluorapatite, diopside and actinolite. Batch leaching conducted on the geopolymer bricks detected high leaching of Na from the bricks. Based on the findings of the study of the raw MT potential to produce geopolymer bricks, it was concluded that the material can be used to produce bricks that are within the SANS 1215 requirements. The study further recommended that the study a focus on using cylindrical moulds, other alkali activators and a mechanical mixer. It was also recommended that the greenhouse be restructured to contain heat within the greenhouse during the evening so as to allow constant temperature within / NRF