This study describes the tectono-stratigraphic and climatic record of the NE Arabian Sea during the Cenozoic.  Compilation of regional knowledge and subsurface observations has in this thesis provided new interpretations and insights into the records present along this passive margin.  The first is the rifting period (80-65 Ma) and the identification of a syn-rift volcanic sequence, comparable to other volcanic rifted margins.  This is followed by the record of a drift sequence (~65 Ma to present day), composed of extensive carbonate platforms and an infill sequence of siliciclastic deposits.  The analysed drift sequence (sink) is partly the result of the erosion of the hinterland (source) characterised by the India-Eurasia continent-continent collision.  Influence of regional climate and/or tectonic forces on the accumulation rate in the sink was tested, but not conclusive as the study area (Upper Indus Fan) covers only a limited part of the sedimentary record of the Indus Fan.  The thermal regime of the western margin of India is sparsely sampled, but once analysed, allows the definition of first order constraints on multiple rifting events.  The post-rift subsidence of the margin is slow and anomalous for >28 m.y. after break-up, potentially in relation with vigorous asthenospheric convection and a sharp ocean-continent boundary.  Past and present fluid flow is recorded in the sedimentary sequence of the Upper Indus Fan.  The first is related to gas hydrate occurrence and is the result of the migration of fluids by a plumbing system to the shallow subsurface, expressed by bottom-simulating reflections crosscutting stratal reflections.  A longer term fluid migration is recorded in this basin by the longest lived (~22 m.y.) mud volcano field recorded to date.

In northern British Columbia, the Sylvester Allochthon of the Slide Mountain terrane is the most inboard of Cordilleran suspect terranes, resting as a vast klippe upon miogeoclinal strata of the Cassiar Platform. The Sylvester is oceanic; it comprises gabbro, pillowed and massive basalt, banded chert, carbonate, argillite, ultramafics and minor arenite, which range in age from Late Devonian to Late Triassic. Internal structure in the Sylvester Allochthon is characterized as a stack of innumerable interleaved tectonic slices, bounded by subhorizontal, layer-parallel faults. These lithotectonic units are an order of magnitude smaller than the terrane itself and may consist of only a single or a few repeated rock types. The internal structure of the Sylvester is complex but not chaotic; small numbers of slices occur together in larger second-order packages which are also fault-bounded and lensoidal. However, tectonic juxtaposition of unrelated lithologies and older-over-younger faults are common. The "stratigraphy" of the Sylvester assemblage is thus tectonic. Sliver-bounding faulting within the Sylvester is known to have, at least in part, predated its post-Triassic, pre-mid Cretaceous emplacement. The Sylvester was emplaced onto North America as the roof thrust to a foreland-style duplex within underlying North American strata. vii viii The Sylvester Allochthon is the most inboard of accreted terranes, however it does not represent a simple marginal basin. New microfossil dating demonstrates that most rock types occur through the complete range of Sylvester ages. Coeval but depositionally incompatable lithologies must have accumulated in separate ocean floor paleoenvironments. Lithologies of the allochthon derive almost exclusively from layer 1, only the surface of oceanic crust. Thus, Sylvester slices are telescoped remnants detached from a vast area of ocean crust which ranged in age and width through the upper Paleozoic but which is now otherwise entirely consumed. Similarities of rock type, internal structure, age range, and regional tectonic setting have identified the Sylvester Allochthon as broadly correlative with a discontinuous series of terranes extending the length of the Cordillera. Together, these terranes may represent the remnants of what was once the late Paleozoic proto-Pacific ocean floor.

A lingering question in Cordilleran tectonics is how high plateaus form in the absence of continental collision. The type example of an active Cordilleran high plateau is found in the Central Andes of Peru, Bolivia, Argentina, and Chile. Along this section of the South American Cordillera, tectonics are primarily driven by subduction of the oceanic Nazca Plate beneath the continental South American Plate. Extending over 1,800 km along the active continental margin, the Central Andean Plateau (CAP) reaches a maximum width of around 400 km with several peaks in excess of 6 km. Numerous morphotectonic subdivisions of the CAP highlight the complex along-strike variability of the Plateau providing a natural laboratory for investigating the relative contribution of tectonic processes involved in building and maintaining Cordilleran high plateaus. The scale of this problem extends far beyond the scope of any one geoscientific discipline requiring a multidisciplinary approach. Our contribution to this scientific problem and the focus of the work presented in this dissertation is to better understand the current lithospheric and uppermost mantle structure along the CAP. This is achieved by integrating recent advances in seismic imaging techniques with a growing availability of high-quality seismic data into three distinct studies across the South American continent. In the first study, we present a shear-wave velocity model for the crust below the Altiplano-Puna Volcanic Complex (APVC). The target of this study is to constrain the crustal volume of a large magma reservoir inferred to exist below the APVC. When combined with geological and petrological constraints, the large-volume magma reservoir imaged in this study suggests a significant magmatic contribution to the growth of the Plateau in excess of one kilometer over the last ten million years. In addition to the tectonic contributions of this work, we introduce a new method of jointly inverting surface-wave dispersion data and receiver functions to generate a three-dimensional velocity model. In the second study, we combine Rayleigh-wave dispersion data from ambient noise and earthquake-generated surface waves to invert for a shear-wave velocity model of the lithosphere and uppermost mantle below the Bolivian Orocline. The target of this study is to identify any possible mantle contributions to the uplift history along the northern CAP. The highlight of this study is a high-velocity feature that extends from the base of the crust to ~120 km depth below the Altiplano basin. We interpret this feature using a simple isostatic model and suggest it is responsible for the relatively low topography of the Altiplano basin. In the third and final study, we extend the seismic model of the APVC crust to cover the entire Puna Plateau (southern CAP). The target of this study is to assess the uniqueness of the APMB and to look for additional magma reservoirs in the crust. A highlight of this work is the nearly one-to-one spatial correlation between the long-wavelength topography, ignimbrite deposits, long-wavelength Bouguer gravity anomalies, and four additional mid-crustal low-velocity zones imaged in the southern Puna Plateau. When placed in the context of existing geological and petrological constraints, we suggest the contribution of magmatic addition as an uplift mechanism in Cordilleran systems is much larger than is currently accepted.

Abstract Three dimensional finite strain and kinematic data from the Resolution Island Shear Zone, Fiordland, New Zealand record the progressive evolution of a lower crustal metamorphic core complex. The Resolution Island Shear Zone is a mid-Cretaceous (~114-90 Ma) extensional shear zone that juxtaposes high-pressure (P~17-19 kbar) garnet-granulite and eclogite facies orthogneiss from the lower crust against mid-crustal (P~6-8 kbar) orthogneiss and paragneiss along a low-angle upper amphibolite facies ductile normal fault. In the lower plate of the Resolution Island Shear Zone the high-pressure garnetgranulite and eclogite facies gneissic foliations (S1) are attenuated by granulite facies extensional shear zone foliations (S2). Retrograde metamorphism marked by the breakdown of omphacite and garnet to amphibole and feldspar in S2 foliation records the unloading of the lower plate during extension. Continued extension localized strain into weaker amphibole and feldspar-bearing lithologies. Upper amphibolite facies shear zones anastomose around rigid lenses that preserve the S1 and S2 fabric. Upper amphibolite facies shear zone fabrics (S3/L3) that envelop these pods display a regional-scale domeand- basin pattern. These shear zones coalesce and form the Resolution Island Shear Zone. Coeval with the formation of the Resolution Island Shear Zone, a conjugate, southwest dipping, and lesser magnitude shear zone termed the Wet Jacket Shear Zone developed in the upper plate of the Resolution Island Shear Zone. Three-dimensional strain analyses from S3/L3 fabric in the Resolution Island Shear Zone show prolate-shaped strain ellipsoids. Stretching axes (X) from measured finite strain ellipsoids trend northeast and southwest and are subparallel to L3 mineral stretching lineations. Shortening axes (Y, Z) are subhorizontal and subvertical, respectively, and rotate through the YZ plane of the finite strain ellipsoid. This pattern reflects the dome-and-basin geometry displayed by anastomosing S3 foliations and indicates the Resolution Island Shear Zone developed in the field of constriction. Threedimensional kinematic results indicate a coaxial-dominated rotation of stretching lineations toward the X-axis in both the XZ and XY planes of the finite strain ellipsoid. Results suggest that a lower crustal metamorphic core complex developed in a constrictional strain field with components of coaxial-dominated subvertical and subhorizontal shortening. Mid-Cretaceous (~114-90 Ma) extensional structures exposed in Fiordland, including the Resolution Island, Wet Jacket, Mount Irene and Doubtful Sound shear zones and the Paparoa metamorphic core complex allows the reconstruction of a crustal column that describes the geometry of mid-Cretaceous continental rifting of Gondwana. The overall symmetry of crustal-scale structures during continental extension suggests kinematic links between flow in the lower crust and the geometry and mode of continental extension. This result is consistent with numerical models of lithospheric rifting that predict the lower crust has a primary control on the style of continental extension.

The Silurian-Devonian metasedimentary rocks of the Connecticut Valley-Gaspé trough (CVGT) were subjected to multiple deformational and metamorphic events during the Acadian orogeny in the Middle-Late Devonian. Plutons intruding the Devonian Waits River and Gile Mountain Formations have been considered post-tectonic, but microstructural studies of the intrusions and their metamorphic aureoles indicate some of these plutons intruded syntectonically. This study investigates the relationship between Acadian deformation and intrusion of the Knox Mountain pluton (KMP) of central Vermont. Structural and geochronological data were collected along a c. 15 km transect from the western limit of the CVGT, where the unconformable Richardson Memorial Contact coincides with the Dog River Fault Zone, into the margin of the KMP in the east. Field and microstructural observations indicate the KMP intruded syntectonically. Evidence for Acadian deformation post-dating intrusion includes folded and boudinaged granitic dikes at the margin of the KMP, and microstructures such as flame perthite, myrmekite, deformation twins, and textures associated with grain-boundary migration recrystallization in the granite. In the metamorphic aureole, biotite porphyroblasts overgrow S3, the earliest Acadian secondary foliation, and were deformed during S4 crenulation cleavage development. The KMP intruded at 377±5.2 Ma based on a U-Th-total Pb monazite crystallization age, which is concordant with the published age of the nearby Barre granite. The timing of S4 foliation development in the CVGT is constrained locally by 40Ar/39Ar geochronology at ~365 Ma, consistent with the microstructurally-inferred relative-age relationships. Plateau/weighted mean 40Ar/39Ar ages from across the transect and minimum ages from argon-loss profiles show a general trend of younging towards the east, suggesting these rocks have been affected by Alleghanian and Mesozoic deformation and exhumation.

This study combines structural field data with microstructural observations in an analysis of a mid-crustal shear zone related to the emplacement of the Misty pluton during a high-flux magmatic event in Northern Fiordland, New Zealand. These high-flux magmatic events transport massive amounts of heat and material as they develop along accretionary continental margins, and represent a primary source of continental crust. Fiordland, New Zealand possesses, perhaps, the most extensive middle and lower crustal exposure of these systems on earth. Therefore, this study area provides a significant opportunity to understand processes of continental crust formation in the mid-crust and how these events relate to the broader construction of continents. Herein, I document the four-stage geologic history of the Cozette Burn field area. Pre-existing structures along the Gondwana accretionary margin hosted a regional flare-up magmatic event that produced the Misty pluton and several other large plutons of the West Fiordland Orthogneiss (WFO). This study primarily focuses on the mid-crustal emplacement of the Misty pluton during oblique convergence along the accretionary margin, forming the upper-amphibolite facies Misty Shear Zone (MSZ). The exposures of the MSZ within the Cozette Burn preserve rare structural relationships between host rock and the intrusive Misty pluton. Together, these structures developed during end-stage contractional tectonics that constructed a long-lived (~270+ Ma) composite batholith. Heterogeneous ductile shearing defines the MSZ, with microstructural evidence indicating an interplay of high-temperature crystal plastic deformation along with partial melting of host rock and melt channeling. This resulted in focused, melt-assisted shearing under regional transpressive deformation. These accommodative processes provided an efficient mechanism for moving heat, fluids and magma sourced from the lower crust/mantle boundary into the mid-crust during 15-25 km of crustal thickening related to arc flare-up magmatism. This flare up magmatism and MSZ formation occurred during the final stages of crustal thickening along Gondwana continental margin. High-strain, mylonitic- ultramylonitic shear zones developed in a later phase of deformation, cutting MSZ fabrics near contacts between the Misty pluton and host rock. These more localized shear zones can be attributed to either accommodation of localized melt-pressure buildup or the shift to extensional tectonics. Brittle faulting cut these structures with oblique-thrust in the Tertiary. These mid-crustal structures carry economic relevance: thickened-crust events along accretionary continental margins produce deep-crustal sourced, metal-bearing magmas that are transferred into mid-crust prior to their hydrothermal emplacement as ore deposits in the upper crust. The lasting influence of these processes warrants consideration when assessing continental crust architecture at all scales.

North-eastern part of the Bohemian Massif is characterised by many NW-SE striking faults. The Sudetic Marginal Fault Zone (SMFZ) and Hronov - Poříčí Fault Zone (HPFZ) represent the major seismoactive dislocations in this area. Field structural investigations, including fault-slip data collection were carried out on a number of natural outcrops and quarries with the aim of establishing a robust and field-constrained model for the local brittle structural evolution of the studied areas. Almost 5000 faults and fractures have been measured and studied in 116 localities. Two principle sets of faults within the SMFZ are oriented in the N-S and W-E directions. The faults are mainly dipping under 80-90ř. The lineations found on the fault planes are mainly trending to the SW and W. The kinematic frequent analysis was performed due to the distribution of the fault types in the orientations. The faults were divided into the different tectonic phases based on their origin or reactivation and their relative age using the calculation of paleostress analysis. The paleostress analysis of the fault-slip data within the SMFZ resulted identification of six tectonic phases from the youngest to the oldest: strike-slip regime with maximum compression σ1 in the NNW-SSE direction, compressional regime with σ1 in the...

A principle concern for engineered CO2 storage is long-term security. Surface leakage (‘seepage’) of injected CO2 to the surface is economically and environmentally undesirable. Italy is a region of intense natural CO2 degassing; 308 CO2 seeps are catalogued which exhibit different surface characteristics, and a number CO2 rich reservoirs were discovered when drilling for hydrocarbons. These seeps and reservoirs provide excellent natural analogues for seeps that might arise from breached carbon stores. This thesis explores the geological controls on the crustal plumbing of CO2 fluids to model the processes governing CO2 seep locations and distribution, and characteristics; and their consequences on human health risk. Risk of human death from accidental CO2 poisoning at all seep types is low (10-8 yr-1) and several factors influence risk of human mortality. Seeps distribute on two spatial scales; on a local scale (<5 km) seeps are clustered and aligned with subsidiary geologic structures, while on large scales seep clusters are discrete, and align with regional structures. Within clusters, seep locations are influenced by fault maturity, the presence of lithological boundaries and seep manifestation, which is determined by the flow properties of the outcropping lithology and local topography. Sealing and seeping CO2 reservoirs are identified, and their geological characteristics compared. Italian reservoirs successfully retain large CO2 columns at a range of reservoir conditions. Reservoirs which have hydrostatic pressure conditions in the overburden, determined from well logs, are located close to surface CO2 seeps and recent extensional faults. Where there is significant overpressure above hydrostatic in the overburden, there are no seeps present above the reservoir structure. Overpressure of reservoir fluids may enhance fluid flow rates but is not a necessary condition for CO₂ leakage. Geothermal conditions influences the style of leakage at depths and towards the surface. Total CO2 degassing from dry Italian CO2 seeps is 3.5 ± 0.5 Mt(CO2)yr-1. It would take thousands of years for the effectiveness of a commercial scale store to be significantly reduced if it leaks to form a single seep with the mean flux rates modeled in Italy. If a seep cluster develops, the storage effectiveness will reduce more rapidly, and could negate engineered CO₂ storage as a climate mitigation strategy. The research presented in this thesis contributes to a body of knowledge which directly informs site selection procedure for carbon storage and maximise the long term storage potential for CCS. Thorough scientific understanding of the geological processes governing fluid escape is crucial to assure the scientific, political and public communities that safe, long-term carbon storage can be realised as an effective climate mitigation technology.

In this thesis, I present results that broadly fall into two themes. The first involves understanding active tectonic and magmatic processes at mid-ocean ridges. The second involves using small stress changes due to the tides to probe earthquake processes at mid-ocean ridges. The four main results of my thesis are as follow: (1) The spatiotemporal evolution of an eruption at a fast-spreading mid-ocean ridge, the East Pacific Rise, is now characterized and understood to be mainly controlled by the buildup of tectonic stress to a critical level rather than magma overpressure. (2) Microearthquakes at the East Pacific Rise are found to be strongly modulated by tides in the years before an eruption but not immediately after the eruption, suggesting the potential utility of tidal triggering strength for eruption forecasting. (3) Earthquake size-frequency distribution, often quantified using the b value, is shown to vary systematically with tidal stresses which lends support to the use of earthquake b value as an in-situ stressmeter. (4) The 2015 Axial Seamount eruption is revealed to be preceded by variable rates of melt influx into the shallow reservoir, highlighting the short-timescale variability of magmatic systems as they are primed for an eruption.

In order to better understand the interactions between climate change, landscape erosion and sedimentation, a detailed study was conducted on Plio-Pleistocene non-marine deposits of the Palm Spring Group in the Fish Creek-Vallecito basin, California, USA. Three inter-related studies focused on (1) local response to global climate change in late Pliocene-early Pleistocene time, (2) large-scale evolution of lithofacies architecture, and (3) climate modulation of late Pliocene sediment flux on Milankovitch time scales. Stable isotopes and paleosol classification reveal that between ~4.0 and 0.75 Ma, aridity increased in the study area concurrent with a shift towards a less intense and more winter-dominated precipitation regime. These changes are interpreted to reflect the long-term waning of summer monsoon precipitation in southern California. A dramatic and enigmatic reorganization of basin strata occurred at 2.9 Ma. Detailed basin analysis shows that locally-derived sediment was supplied by the predecessors of two modern drainages, Vallecito and Carrizo creeks. Initial progradation of alluvial deposits from these two sources across the Colorado River delta plain began between 4.0-3.4 Ma. At 2.9 Ma, rapid progradation of these two deposystems was coeval with emplacement of a megabreccia and transgression of Borrego Lake. My data indicate that tectonic realignments at both local and regional scales drove this reorganization. Time series analysis of rock magnetic data from a densely-sampled stratigraphic section of the lacustrine Tapiado Formation reveals that between 2.9 and ~2.75 Ma landscape denudation in the Carrizo Creek catchment was partly modulated by orbital obliquity. Peaks in landscape denudation implied by my data correspond to obliquity highs. More frequent high intensity precipitation events (i.e. monsoons and tropical storms) probably drove increased erosion during these time periods relative to obliquity lows. The breakdown of this relationship at around 2.75 Ma corresponds to a dramatic increase in northern hemisphere glaciation and may reveal a reduction in monsoonal influence in southern California. A geologic map of the Fish Creek-Vallecito basin is included as a supplemental file to this dissertation. This dissertation contains previously published and unpublished coauthored material.