This master’s thesis deals with design and fabrication of MEMS microhotplate platform for chemical gas sensors. The theoretical part describes MEMS, sensors and processes and technologies needed for fabrication of micro hotplate. The practical part includes simulations, masks and step by step microhotplate fabrication. Fabricated heating membrane was characterized and compared to theoretical values from simulations and to similar devices presented in literature.

This thesis deals with the use of non-metallic highly thermally conductive materials, more concrete-ly special plastic materials, enriched with highly thermally conductive additives, for the purpose of passive cooling of a given heat source. The thesis compares the effectivity of these heat sinks with the classically used materials, specifically aluminium. The thesis is divided into two main sections, theoretical and practical. The theoretical part deals with a constantly growing need of LED (Light Emitting Diode) chips cooling in automotive head-lamps, where the new materials could be put into effect, analyses possible replacement of classic aluminium heat sinks with different materials with a significantly lower thermal conductivity and introduces problems of such materials. The practical part applies the problematic described in the theoretical one on the actually produced heat sinks, which are compared among themselves, with regard to their method of production, as well as with aluminium counterpart in different conditions. Furthermore, the problematic of de-signing a heat sink made from material which is characteristic for its highly anisotropic thermal con-ductivity is dealt with. The end of the thesis shows the importance of heat dissipation via radiation, which can have a great significance in case of plastic heat sinks and in a specific applications.

A graphite foam was developed at Oak Ridge National Laboratory (ORNL) by Dr. James Klett and license was granted to POCO Graphite, Inc. to manufacture and market the product as PocoFoam™. Unlike many processes currently used to manufacture carbon foams, this process yields a highly graphitic structure and overcomes many limitations, such as oxidation stabilization, that are routinely encountered in the development of carbon foam materials. The structure, thermal properties, electrical resistivity, isotropy, and density uniformity of PocoFoam™ were evaluated. These properties and characteristics of PocoFoam™ are compared with natural and synthetic graphite in order to show that, albeit similar, it is unique. Thermal diffusivity and thermal conductivity were derived from Fourier's energy equation. It was determined that PocoFoam™ has the equivalent thermal conductivity of metals routinely used as heat sinks and that thermal diffusivity is as much as four times greater than pure copper and pure aluminum. SEM and XRD results indicate that PocoFoam™ has a high degree of crystalline alignment and near theoretical d spacing that is more typical of natural flake graphite than synthetic graphite. PocoFoam™ is anisotropic, indicating an isotropy factor of 0.5, and may yield higher thermal conductivity at cryogenic temperatures than is observed in polycrystalline graphite.

In this thesis, two important thermo-physical properties of nanofluids: thermal conductivity and viscosity together with shelf stability of them are investigated. Nanofluids are defined as colloidal suspension of solid particles with the size of lower than 100 nanometer. Thermal conductivity, viscosity and stability of nanofluids were measured by means of TPS method, rotational method and sedimentation balance method, respectively. TPS analyzer and viscometer were calibrated in the early stage and all measured data were in the reasonable range. Effect of some parameters including temperature, concentration, size, shape, alcohol addition and sonication time has been studied on thermal conductivity and viscosity of nanofluids. It has been concluded that increasing temperature, concentration and sonication time can lead to thermal conductivity enhancement while increasing amount of alcohol can decrease thermal conductivity of nanofluids. Generally, tests relating viscosity of nanofluids revealed that increasing concentration increases viscosity; however, increasing other investigated parameters such as temperature, sonication time and amount of alcohol decrease viscosity. In both cases, increasing size of nanofluid results in thermal conductivity and viscosity reduction up to specific size (250 nm) while big particle size (800 nm) increases thermal conductivity and viscosity, drastically. In addition, silver nanofluid with fiber shaped nanoparticles showed higher thermal conductivity and viscosity compared to one with spherical shape nanoparticles. Furthermore, effect of concentration and sonication time have been inspected on stability of nanofluids. Test results indicated that increasing concentration speeds up sedimentation of nanoparticles while bath sonication of nanofluid brings about lower weight for settled particles. Considering relative thermal conductivity to relative viscosity of some nanofluids exposes that ascending or descending behavior of graph can result in some preliminary evaluation regarding applicability of nanofluids as coolant. It can be stated that ascending trend shows better applicability of the sample in higher temperatures while it is opposite for descending trend. Meanwhile, it can be declared that higher value for this factor shows more applicable nanofluid with higher thermal conductivity and less viscosity. Finally, it has been shown that sedimentation causes reduction of thermal conductivity as well as viscosity. For further research activities, it would be suggested to focus more on microscopic investigation regarding behavior of nanofluids besides macroscopic study.

Nanofluids consist of nanometer-sized particles or fibers in colloidal suspension within a host fluid. They have been studied extensively since their creation due to their often times anomalous and unique thermal transport characteristics. They have also proven to be quite valuable in terms of the scientific knowledge gained from their study and their nearly unlimited industrial and commercial applications. This research has expanded the science of nanofluids into a previously unexplored field, that of cryogenic nanofluids. Cryogenic nanofluids are similar to traditional nanofluids in that they utilize nanometer-sized inclusion particles; however, they use cryogenic fluids as their host liquids. Cryogenic nanofluids are of great interest due to the fact that they combine the extreme temperatures inherent to cryogenics with the customizable thermal transport properties of nanofluids, thus creating the potential for next generation cryogenic fluids with enhanced thermophysical properties. This research demonstrates that by combining liquid oxygen (LOX) with Multi-Walled Carbon Nanotube (MWCNT) inclusion particles, effective thermal conductivity enhancements of greater than 30% are possible with nanoparticle volume fractions below 0.1%. Three distinct cryogenic nanofluids were created for the purposes of this research, each of which varied by inclusion particle type. The MWCNT's used in this research varied in a number of physical characteristics, the most obvious of which are length and diameter. Lengths vary from 0.5 to 90 microns and diameters from 8 to 40 nanometers. The effective thermal conductivity of the various cryogenic nanofluids created for this research were experimentally determined by a custom made Transient Hot Wire (THW) system, and compared to each other and to more traditional nanofluids as they vary by type and particle volume fraction. This work also details the extensive theoretical, experimental, and numerical aspects of this research, including a rather detailed literature review of many of the salient sciences involved in the study of cryogenic nanofluids. Finally, a selection of the leading theories, models, and predictive equations is presented along with a review of some of the potential future work in the newly budding field of cryogenic nanofluids.

Graphene is a form of carbon with unique thermal and structural properties, giving it high potential in many applications, from electronics to driveway heating. Advanced fabrication techniques putting small, graphene-like structures in a polymer matrix could allow for incorporation of some of the benefits of graphene into very lightweight materials, and allow for broader commercialization. Measuring the thermal properties of these thin-film samples is a technical capability in need of development for use with the specific specimens used in this study. Relating those thermal properties to the microstructural composition was the focus of this work. Several conclusions could be drawn from this study which will help guide future development efforts. Among these findings, it was found that increasing carbon content only improves thermal and electrical conductivity if the samples were of low porosity. Samples of approximately identical overall carbon content and void content had higher thermal conductivity if some carbon nanotubes were added in place of graphite. Nanotubes also appeared to reduce variability in thermal conductivity between pressed and unpressed samples, allowing for more predictable properties in fabrication.

Thermal transport properties are critical for applications ranging from thermal management to energy conversion. Passive thermal management has been an area of study for over a century and has only grown as technology has advanced because it requires no additional energy to remove heat. Changing the nanostructure of the materials involved in passive heat transfer methods, either by geometric changes or stoichiometric changes, can greatly improve the effectiveness of this heat transfer method. In order to explore this further, this work employs LAMMPS molecular dynamics (MD) simulation software to calculate the lattice thermal conductivity (λp) of a nanoparticle (NP) and material used indifferent passive heat transfer methods after either modifying their geometry or stoichiometry. The NPs this work will simulate are single-wall carbon nanotubes (SWCNTs), which have been well known for high λp, and their applications in improving thermal conductivity in matrix materials. The material this work will simulate is magnesium silicide (Mg2Si), a thermoelectric material. Thermoelectric materials, in general, become more efficient in converting heat into electrical power as their λp decreases. λp will be calculated for SWC-NTs of varying lengths, diameters, and at varying equilibration temperatures (Teq). λp will be calculated for samples of pure Mg2Si and Mg2Si with off-stoichiometry over a range of Teq values. Two methods will be used to induce the off-stoichiometry: atomic silicon (Si) substitutionals, and Si NPs. A range of stoichiometric ratios will be applied to the material by both methods, and then λp will be calculated for each of these cases. This is done so as to observe which method of stoichiometric change, given the same stoichiometric ratio, decreases λp greater, and, therefore, causes Mg2Si to be a better thermoelectric material. It is expected that increases in length will increase the λp of the SWCNT, while increases in diameter and Teq will decrease λp. It is expected that increases in atomic percent (a/o) Si and Teq will decrease λp regardless of the method of stoichiometric change, and that the Si NP method will decrease λp more than the atomic Si substitutional method.

Large Liquid Hydrogen (LH2) storage tanks are vital infrastructure for NASA. Eventually, air may leak into the evacuated and perlite filled annular region of these tanks. Although the vacuum level is monitored in this region, the extremely cold temperature causes all but the helium and neon constituents of air to freeze. A small, often unnoticeable pressure rise is the result. As the leak persists, the quantity of frozen air increases, as does the thermal conductivity of the insulation system. Consequently, a notable increase in commodity boiloff is often the first indicator of an air leak. Severe damage can then result from normal draining of the tank. The warming air will sublimate which will cause a pressure rise in the annulus. When the pressure increases above the triple point, the frozen air will begin to melt and migrate downward. Collection of liquid air on the carbon steel outer shell may chill it below its ductility range, resulting in fracture. In order to avoid a structural failure, as described above, a method for the safe removal of frozen air is needed. Two potential methods for air removal are evaluated here. The first method discussed is the connection of a vacuum pump to the annulus which provides pumping in parallel with drainage of LH2. The goal is to keep the annular pressure below the triple point so that the air continues to sublimate, thus eliminating the threat that liquefaction poses. The second method discussed is the application of heat to the bottom of the outer tank during tank drain. Though liquefaction in the annular space will occur, the goal of the heater design is to keep the outer shell above the embrittlement temperature, so that cracking will not occur. In order to evaluate these methods, it is first necessary to characterize some the physical properties and changes that take place in the system. A thermal model of the storage tank was created in SINDA/FLUINT (C&R Technologies, 2014) to identify locations where air can freeze. This model shows the volume that is capable of freezing air under varying conditions. It is also necessary to characterize the changes in thermal conductivity of perlite which has nitrogen frozen into its interstitial spaces. The details and results of an experiment designed for that purpose is outlined. All data, including operational data from existing LH2 tanks, is compiled and a physics-based evaluation of the two proposed air removal techniques is performed. Due to small pumping capacities at low pressure and the large quantity of air inside the annulus, the pumping option is not deemed feasible. It would take many years to remove a significant amount of air by pumping while maintaining the annular pressure below the necessary triple point. Application of heating devices is a feasible option. For a specific case, it is shown that approximately 105 kilowatts of power would be required to vaporize the air in the annulus and keep the temperature of the outer tank wall above the freezing point of water. Several engineering solutions to accomplish this are also discussed. There are many unknowns and complexities in addressing the problem of safely removing frozen air from the annulus of an LH2 storage sphere. The work that follows utilized: research, modeling, experimentation, analysis, and data from existing tanks to arrive at possible solutions to the problem. Heating solutions may be implemented immediately and could result in significant savings to the user.

Traditionally, geothermal boreholes have utilized the ground energy for space heating and cooling. In this system, a circulation loop is placed in a small-diameter borehole typically extending to a depth of 200-300 ft. The hole is then backfilled with a mixture of sand, bentonite and/or cement. The loop is connected to a geothermal heat pump and the fluid inside the loop is circulated. The heat energy is fed into the ground for cooling in the summer and withdrawn from the ground for heating in the winter. Geothermal heat pumps work more efficiently for space heating and cooling compared to air-source heat pumps.  The reason is ground-source systems use the ground as a constant temperature source which serves as a more favorable baseline compared to the ambient air temperature. A significant cost associated with any deep geothermal borehole is the drilling required for installation. Because Energy Piles perform the dual function of exchanging heat and providing structural support, and are only installed at sites where pile foundations are already required, these systems provide the thermal performance of deep geothermal systems without the additional drilling costs. Low maintenance, long lifetime, less variation in energy supply compared to solar and wind power, and environmental friendliness have been cited as additional Energy Pile advantages. Case studies show that they can significantly lower heating/cooling costs and reduce the carbon footprint. Energy cost savings for typical buildings outfitted with Energy Piles could be as much as 70 percent. The use of Energy Piles has rapidly increased over the last decade, especially in Europe where more than 500 applications are reported. Primary installations have been in Germany, Austria, Switzerland and United Kingdom. Notable projects include the 56-story high Frankfurt Main Tower in Germany, Dock E Terminal Extension at Zurich International Airport in Switzerland and the One New Change building complex in London U.K. Energy piles have seen very little use in the North America, only a handful of completed projects are known; Marine Discovery Center in Ontario, Canada, Lakefront Hotel in Geneva, New York and the Art Stable building in Seattle, Washington. Energy Piles are typically installed with cast-in-place technology (i.e. drilled shafts, continuous flight auger piles, micropiles etc.) while some driven pile applications are also reported. Other types of geotechnical structures in contact with the ground, such as shallow foundations, retaining walls, basement walls, tunnel linings and earth anchors, also offer significant potential for harnessing near-surface geothermal energy. Energy Pile design needs to integrate geotechnical, structural and heat exchange considerations. Geotechnical characteristics of the foundation soils and the level of the structural loads are typically the deciding factors for the selection and dimensioning of the pile foundations. The geothermal heat exchange capacity of an Energy Pile is a key parameter to be considered in design. Thermal characteristics of the ground as well as the heating and cooling loads from the structure need to be considered for the number of piles that will be utilized as heat exchangers. Therefore, the thermal properties of the site need to be evaluated for an Energy Pile application in addition to the traditional geotechnical characterization for foundation design. Energy Piles bring new challenges to geotechnical pile design. During a heat exchange operation, the pile will expand and contract relative to the soil as heat is injected and extracted, respectively. These relative movements have the potential to alter the shear transfer mechanism at the pile-soil interface.  Furthermore, the range of temperature increases near the pile surface, though limited by practical operational guidelines, can have a significant effect on pore pressures generation and soil strength. This dissertation provides answers for several research questions including the long-term performance of Energy Piles, the applicability of the thermal conductivity tests to Energy Piles.  Furthermore, it presents the results and a detailed discussion about the full scale in-situ thermo-mechanical pile load test conducted at Virginia Tech. / Ph. D.

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