This diploma thesis is focused on the design of technological modifications of the existing industrial unit „waste-to-energy“, used for thermal treatment of process waste gases containing VOC and CO while flue gas is produced. The main objective of the existing unit modification is to improve its operating parameters considering economy, ecology and energy utilization. In the first part, the current industrial plant was presented with all necessary process data. Furthermore, all the key equipment used for the waste gases treatment or for the utilization of waste heat was identified. In the main part of the thesis there are performed modifications of the existing unit including the technology of existing heat exchangers intensification, the design of new and more efficient heat exchangers and finally the catalytic oxidation technology implementation for the decomposition of pollutants contained in the waste gas. The result of the thesis is a technical, economic and ecological comparison of the proposed technological modifications with the existing operation.

This master’s thesis is focused on the description and processing of the cell method, which is generally recommended for prediction of fluids temperature profiles in heat exchanger. In the thesis the basic equations for calculating heat transfer are presented and is also described the current situation in the field of computational prediction of fluids temperature profiles in heat exchangers. The cell method is solved by using the software Maple and is applied to the specific case of industrial heat exchangers. The results obtained by the cell method are compared with the results obtained by educational version of software HTRI Xchanger Suite. By this comparison explicitness of the cell method is assessed.

The master’s thesis topic is the feasibility study of new biomass source construction in power heating plant Brno-North. The first part is focused on historical and current conditions and future development of heat distributions networks and sources of Brno. The power heating plant operation Brno-North is described in more detail including the current heat scheme of operation and plan for the future development. Next chapters are focused on projection of new biomass source. At first, it is defined heat output, operation range and parameters of the new source based on the data of real needs after the heating network modernization. Afterward, selected conceptual variants of the new source are discussed in more detail and for each of the variants are performed heat balance calculation and assembled heat scheme of operation. At the same time it is processed warehouse management calculation and economic analysis of the project. The final chapter evaluates the technical and economic parameters of variants and recommends the most suitable variant of the project.

<p>The water crisis is increasing with every passing day due to climate change and increase in demand. Different desalination methods have been developed over the years to overcome this shortage of water. Reverse Osmosis is the most widely used desalination technology, but cannot treat many fouling-prone and high salinity water sources. A new desalination technology, Membrane distillation (MD), has the potential to purify wastewater as well as highly saline water up to a very high purity. It is a thermal energy-driven desalination method, which can operate on low temperature waste heat sources from industries, powerplants and renewable sources like solar power. Among the different configurations of MD, Air Gap Membrane Distillation (AGMD) is the most versatile and flexible. However, the issue that all MD technology, including AGMD face, is the low energy efficiency. Different sections of AGMD system have been modified and improved over the years through consistent research to improve its energy efficiency, but one section that is still new and unexplored, and has a very high potential to improve the energy efficiency of AGMD, is the ‘air gap’.</p><p> </p><p> </p><p>The aim of this research is to tap into the potential of the air gap and increase the energy efficiency of the AGMD system. It is known that decreasing the air gap thickness improves the energy efficiency parameter called Gained output ratio (GOR) to a great extent, especially at very small air gap thickness. The minimum gap thickness that maximizes the performance is smaller than the current gap thicknesses used. But it is difficult to attain such smaller air gap thickness (< 2mm) without the constant risk of flooding. Flooding can be prevented, and smaller air gap thickness can be achieved if instead of film wise condensation on the condensing surface, a different condensation flow regime is formed. This study tests different novel condensing surfaces like Slippery liquid infused porous surfaces (SLIPS) and Superhydrophobic surfaces (fabricated with different methods) inside the AGMD system with a goal of attaining smaller air gap thickness and improve the performance of AGMD system for the first time. The performance of these surfaces is compared with plain copper surface as well as with each other. Finally, numerical models are developed using the experimental data for these surfaces.</p><div><div><div> </div> </div> </div>

Dans ce travail, la production in-situ d'hydrogène (pur) à partir de vapo-reformage d’éthanol (ESR) dans un réacteur catalytique à membrane (MR) a été étudiée. Un mélange d'éthanol pur et distillé a été utilisé comme combustible. Le réacteur est constitué d’un catalyseur Pd-Rh/CeO2 et d’une membrane Pd-Ag: l’ensemble est désigné par « reformeur ». Les expériences sur ce reformeur ont été effectuées dans diverses conditions de fonctionnement: température, pression, débit de combustible et rapport molaire de l'eau-éthanol (rapportSC). La performance du réacteur catalytique à membrane (CMR) a été étudiée en termes de facteur de production d'hydrogène théorique, d’efficacité de production de l’hydrogène et de la part d’hydrogène récupérée. L’évaluation thermodynamique du reformeur a été présentée. L'analyse exergétique a été réalisée sur la base des résultats expérimentaux visant non seulement à comprendre la performance thermodynamique du reformeur, mais aussi d'introduire l'application de l'analyse exergétique dans les études CMRs. L'analyse exergétique a fourni des informations importantes sur l'effet des conditions d'exploitation et les pertes thermodynamiques, et a donné lieu à la compréhension des meilleures conditions de fonctionnement. Outre les évaluations expérimentales et thermodynamiques du reformeur, la simulation de la dynamique de la production d'hydrogène (perméation) a été effectuée comme la dernière étape pour étudier l'applicabilité d'un tel système dans le cadre d'une utilisation finale réelle, qui peut être l’alimentation d’une pile à combustible. La simulation présentée dans ce travail est semblable aux ajustements de débit d'hydrogène nécessaires pour régler la charge électrique d'une pile à combustible répondant à des besoins variables. / In this work, in-situ production of fuel cell grade hydrogen (pure hydrogen) via catalytic ethanol steam reforming (ESR) in a membrane reactor (MR) was investigated. A mixture of pure ethanol and distilled was used as the fuel. ESR experiments were carried out over a Pd-Rh/CeO2 catalyst in a Pd-Ag membrane reactor – named as the fuel reformer – at variety of operating conditions regarding the operating temperature, pressure, fuel flow rate, and the molar ratio of water-ethanol (S/C ratio). The performance of the catalytic membrane reactor (CMR) was studied in terms of pure hydrogen production, hydrogen yield, andhydrogen recovery.Thermodynamic evaluation of the CMR was presented as a supplement to the comprehensive investigation of the overall performance of the mentioned pure hydrogen generating system. Exergy analysis was performed based on the experimental results aiming not only to understand the thermodynamic performance of the fuel reformer, but also to introduce the application of the exergy analysis in CMRs studies. Exergy analysis provided important information on the effect of operating conditions and thermodynamic losses, resulting in understanding of the best operating conditions.In addition to the experimental and thermodynamic evaluation of the reforming system, the simulation of the dynamics of hydrogen production (permeation) was performed as the last step to study the applicability of such a system in connection with a real end user, which can be a fuel cell. The simulation presented in this work is similar to the hydrogen flow rate adjustments needed to set the electrical load of a fuel cell, if fed on line by the studied pure hydrogen generating system.

The aim of the dissertation is proposing and solving energy convection systems for nuc-lear power plants with a sodium fast reactor of the 4th generation. The first part of the dissertation deals with collection and evaluation of information available about nuclear power plants with sodium fast reactor which use nuclear or non-nuclear reheating to increase thermal efficiency. On the basis of the acquired information, thermal schemes are developed and thermal effi-ciency is determined for the systems working in both Rankine thermal cycle and Brayton thermal cycle. In the further part of the dissertation thermal calculation of the reheater for nuclear and non-nuclear reheating is made for the systems working in Rankine thermal cycle. At the end of this dissertation, an apparatus suitable for these systems is suggested and the systems are evaluated in terms of technical implementation and nuclear safety.

El concentrador solar Fixed Mirror Solar Concentrator (FMSC) apareció en los años 70 con la finalidad de reducir costes en la producción de energía termoeléctrica. Este diseño consiste en un concentrador de reflector estacionario y foco móvil, presenta buena integrabilidad en cubiertas, y es capaz de alcanzar temperaturas entre 100 y 200ºC manteniendo una eficiencia aceptable. En esta tesis se expone una metodología para determinar el comportamiento del FMSC. Se ha desarrollado una herramienta de cálculo basada en el método de ray-tracing, que simula el trazado de los rayos solares en el sistema óptico. Con esta herramienta se ha analizado el comportamiento óptico y térmico del FMSC, y de la versión con espejos curvos Curved Slats Fixed Mirror Solar Concentrator (CSFMSC). Se ha realizado un análisis paramétrico para conocer la influencia de los distintos parámetros en el modificador de ángulo (IAM), y para obtener los diseños óptimos a una temperatura de 200ºC para tres climas en diferentes latitudes. Se han comparado los valores teóricos obtenidos mediante ray-tracing con dos prototipos ensayados, obteniendo un buen ajuste en ambos casos. Los ensayos han sido utilizados para determinar la curva de rendimiento de uno de los prototipos. Se ha hecho uso del método propuesto en la norma EN-12975-2:2006, combinado con valores de IAM obtenidos mediante ray-tracing. Se prueba que esta combinación puede ser útil para obtener la curva de rendimiento de colectores complejos con un modelo biaxial para el IAM. / The Fixed Mirror Solar Concentrator (FMSC) appeared during the 70s with the aim of reducing costs in the production of electricity in solar thermal power plants. This design consists of a concentrator with fixed reflector and moving receiver, has a very good integrability into building roofs and can reach temperatures between 100 and 200ºC with an acceptable efficiency. In this Thesis a methodology is presented for the determination of the behaviour of the FMSC. A simulation tool based on the forward ray-tracing method has been developed. The optical and thermal behaviour of the FMSC and its curved mirror variation called the Curved Slats Fixed Mirror Solar Concentrator (CSFMSC), have been analyzed with this tool. A parametric analysis has been carried out in order to determine the influence of the different parameters on the Incidence Angle Modifier (IAM) and to determine the optimal designs at a temperature of 200ºC for three different climates at different latitudes. The theoretical values obtained from the ray-tracing code have been compared with two experimental prototypes. The experimental and numerical results obtained show a good fit. The efficiency curve of one of the prototypes has been determined from the experimental tests. The methodology proposed in the norm EN-12975-2:2006 has been used in combination with IAM values obtained by ray-tracing. It has been shown that this combination can be effectively used to obtain the efficiency curve of complex collectors with a bi-axial IAM model.

The path to future aero-engines with more efficient engine architectures requires advanced thermal management technologies to handle the demand of refrigeration and lubrication. Oil systems, holding a double function as lubricant and coolant circuits, require supplemental cooling sources to the conventional fuel based cooling systems as the current oil thermal capacity becomes saturated with future engine developments. The present research focuses on air/oil coolers, which geometrical characteristics and location are designed to minimize aerodynamic effects while maximizing the thermal exchange. The heat exchangers composed of parallel fins are integrated at the inner wall of the secondary duct of a turbofan. The analysis of the interaction between the three-dimensional high velocity bypass flow and the heat exchangers is essential to evaluate and optimize the aero-thermodynamic performances, and to provide data for engine modeling. The objectives of this research are the development of engine testing methods alternative to flight testing, and the characterization of the aerothermal behavior of different finned heat exchanger configurations. A new blow-down wind tunnel test facility was specifically designed to replicate the engine bypass flow in the region of the splitter. The annular sector type test section consists on a complex 3D geometry, as a result of three dimensional numerical flow simulations. The flow evolves over the splitter duplicated at real scale, guided by helicoidally shaped lateral walls. The development of measurement techniques for the present application involved the design of instrumentation, testing procedures and data reduction methods. Detailed studies were focused on multi-hole and fine wire thermocouple probes. Two types of test campaigns were performed dedicated to: flow measurements along the test section for different test configurations, i.e. in the absence of heat exchangers and in the presence of different heat exchanger geometries, and heat transfer measurements on the heat exchanger. As a result contours of flow velocity, angular distributions, total and static pressures, temperatures and turbulence intensities, at different bypass duct axial positions, as well as wall pressures along the test section, were obtained. The analysis of the flow development along the test section allowed the understanding of the different flow behaviors for each test configuration. Comparison of flow variables at each measurement plane permitted quantifying and contrasting the different flow disturbances. Detailed analyses of the flow downstream of the heat exchangers were assessed to characterize the flow in the fins¿ wake region. The aerodynamic performance of each heat exchanger configuration was evaluated in terms of non dimensional pressure losses. Fins convective heat transfer characteristics were derived from the infrared fin surface temperature measurements through a new methodology based on inverse heat transfer methods coupled with conductive heat flux models. The experimental characterization permitted to evaluate the cooling capacity of the investigated type of heat exchangers for the design operational conditions. Finally, the thermal efficiency of the heat exchanger at different points of the flight envelope during a typical commercial mission was estimated by extrapolating the convective properties of the flow to flight conditions. / Villafañe Roca, L. (2013). Experimental Aerothermal Performance of Turbofan Bypass Flow Heat Exchangers [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/34774 / TESIS