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Hydrogen electrochemistry in room temperature ionic liquidsMeng, Yao January 2012 (has links)
This thesis primarily focuses on the electrochemical properties of the H<sub>2</sub>/H<sup>+</sup> redox couple, at various metallic electrodes in room temperature ionic liquids. Initially, a comprehensive overview of room temperature ionic liquids, RTILs, compared to conventional organic solvents is presented which identifies their favourable properties and applications, followed by a second chapter describing the basic theory of electrochemistry. A third chapter presents the general experimental reagents, instruments and measurements used in this thesis. The results presented in this thesis are summarized in six further chapters and shown as follows. (1) Hydrogenolysis, hydrogen loaded palladium electrodes by electrolysis of H[NTf<sub>2</sub>] in a RTIL [C<sub>2</sub>mim][NTf<sub>2</sub>]. (2) Palladium nanoparticle-modified carbon nanotubes for electrochemical hydrogenolysis in RTILs. (3) Electrochemistry of hydrogen in the RTIL [C<sub>2</sub>mim][NTf<sub>2</sub>]: dissolved hydrogen lubricates diffusional transport. (4) The hydrogen evolution reaction in a room temperature ionic liquid: mechanism and electrocatalyst trends. (5) The formal potentials and electrode kinetics of the proton_hydrogen couple in various room temperature ionic liquids. (6) The electroreduction of benzoic acid: voltammetric observation of adsorbed hydrogen at a Platinum microelectrode in room temperature ionic liquids. The first two studies show electrochemically formed adsorbed H atoms at a metallic Pt or Pd surface can be used for clean, efficient, safe electrochemical hydrogenolysis of organic compounds in RTIL media. The next study shows the physicochemical changes of RTIL properties, arising from dissolved hydrogen gas. The last three studies looked at the electrochemical properties of H<sub>2</sub>/H<sup>+</sup> redox couple at various metallic electrodes over a range of RTILs vs a stable Ag/Ag<sup>+</sup> reference couple, using H[NTf<sub>2</sub>] and benzoic acid as proton sources. The kinetic and thermodynamic mechanisms of some reactions or processes are the same in RTILs as in conventional organic or aqueous solvents, but other remarkably different behaviours are presented. Most importantly significant constants are seen for platinum, gold and molybdenum electrodes in term of the mechanism of proton reduction to form hydrogen.
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Návrh otopné soustavy a nuceného větrání pro dvougenerační vilu / Space heating and ventilation in a two-generation houseKazda, Jan January 2018 (has links)
This Master's thesis deals with the evaluation of a current state of two-generation villa and its following proposal of the optimization. Evaluation includes calculation of heat loss of a current state. Optimization is based on the reduction of heat loss in the building, pressure balance of the system, change of heat source and installation of balanced ventilation. Chapter describing regulation of technology follows and in conclusion indicative price for the whole suggested technology is calculated.
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Pokročilé metody aplikace tepelné techniky při návrhu vytápění budovy / Advanced methods of application of thermal techniques in the design of heating buildingsMikoláš, Petr January 2019 (has links)
The diploma thesis is divided into three parts. The first part is theoretical devoted to the introduction of BETONG building material. And next It is also devoted to themes of low - energy buildings and nearly zero-energy buildings, heat sharing and thermal comfort. In the second part is the concept of the heating system elaborated in three variants of the design in the scope of the study for the new family house. The third part is devoted to use of shell blocks of the BETONG with internal contact insulation compared to other masonry systems.
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Výpočtové hodnocení konstrukčních staviv z hlediska energetické náročnosti budovy / Computational structural assessment of buildings in terms of energy performanceKaplan, Václav January 2017 (has links)
This thesis deals with the computational comparison of the energy performance of buildings of various construction materials. The work aims at assessing the building as a thermal system. The theoretical part describes the methods for calculating the energy performance of buildings. The experimental part of the work focuses on quantifying the heat consumption of specific buildings in terms of thermal stability and it is later compared with the results calculated in accordance with the applicable technical standards.
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Energeticky uvědomělá optimalizace budovy / Energy-conscious building optimizationRyšavá, Veronika January 2020 (has links)
The aim of the diploma thesis is to design austerity measures of an apartment building in the form of an energy card. The theoretical part deals with heat pumps. The computational part solves the evaluation of the current state of the building, the proposal of two variants, the assessment in terms of energy and economic and recommendations of the selected variant. There is also an experimental measurement specializing in thermovision imaging. The project contains energy certificates of individual states of the solved object.
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Termomechanický model pneumatiky / Thermomechanical tire modelVaníček, Jan January 2021 (has links)
This diploma thesis is about thermomechanics of passenger car tires. The research part dealing with existing tire models is followed by the practical part. The practical part is based on the designs of thermomechanical models. The first model determines a dependence of temperature on the air pressure inside a tire when a temperature changes. The second thermomechanical model captures all the heat fluxes which affect a tire while a vehicle is in motion. The third thermomechanical model calculates temperatures of parts of the tire during driving tests. All models are programmed in MATLAB.
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Využiti ozonu při čistění odpadních vod / Utilisation of ozone for wastewater treatmentHásová, Eva January 2008 (has links)
Diploma thesis will be dealt with the utilization of ozone wastewater treatment. Experimental part will be focused on study of ozone utilization in two different reactors (bubble column, jet loop reactor). Reactors will be compared by overall mass transfer coefficient and saturation concentration. Ozonization will be applied because of biological resistent and toxic compound 2-mercaptobenzothiazole disposal. Changes of biological decomposition will be measured and assessed by respirometric measurements.
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Vývoj nového samonosného zateplovacího systému s ohledem na dynamické namáhání / Development of a new self-supporting insulation system with respect to dynamic stressMachala, David January 2014 (has links)
This diploma thesis deals with suggestion of self-supporting insulating system that can be used for objects which insulating is more or less complicated. In this thesis are theoretically processed information about insulation systems while focus is on their structure, composition and principle of operation. Further, there is theoretically designed self-supporting insulating system which is practically built after theoretically composed testing for finding its basic properties. The most appropriate process of realization is formulated at the end after evaluation of the individual tests.
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Účinnost rozvodů tepla / The efficiency of heat distributionVích, Pavel January 2015 (has links)
This diploma thesis focuses on the analysis of heat loss of heating distribution in the industrial area. The aim of this labor is to determine heat loss heat distribution kept in non manholed canal and evaluate economic return to build a local source of heat for the office building. For this building is in two variants resolve the reconstruction of the existing heating system. For the first variant is designed the local gas condensing boiler and for second variant existing central heat source. The experimental part of this labor compares the measured and calculated values of boundary conditions of hot-water pipes kept in non manholed canal.
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Srovnání nákladů rodinných domů s nosnou konstrukcí z tenkostěnných ocelových profilů / Cost comparison of family houses with structures of thin-walled steel profilesPozděnová, Barbora January 2015 (has links)
The aim of this thesis is to find the best option of the building technology for a house. The thesis is divided into two sections – theoretical and practical. The theoretical section consists of three parts. The first part deals with theory of costs and pricing. Second part specifies types of the budgeting used in Czech Republic and the last part is focused on description of the selected construction systems used for building a house. Second section deals with description and the layout of the house, for which three budgets are set with a respect to the used option of the construction system. Furthermore, a comparison of the technical parameters as well as the costs analysis according to the TSKP is made. Finally, the optimal variant is selected with respect to the price and technical properties.
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