<div><p><br></p></div><p>This study makes use of a Time-Resolved Raman Spectroscopy (TRRS) system developed in the Purdue Civil Engineering spectroscopy laboratory to advance technology critical to enable field deployment of Raman spectroscopic systems, with a primary focus on developing solutions to overcome two specific barriers to Raman analysis in the natural environment: (1) obtaining Raman spectra of chemical compounds at field-relevant concentrations, and (2) realizing economical spatial monitoring. To inform both streams of activity, this work first explores the role of component choice and apparatus design on Raman system output. A component-level Raman system transfer function is developed in terms of intensity, wavelength, and time which yields detailed insight into system performance that greatly exceeds traditional single “system factor” treatments of apparatus effects. The modelling frame provided by the transfer function is universally applicable in that it is inclusive of the majority of component choices that may be encountered in any open-path or closed-path Raman system, and is likely to be valuable in efforts to assess the performance benefits and limitations of system designs, modify or tailor apparatus layouts, facilitate experiment design, and compare results obtained on different systems. </p><p><br></p><p>The system characterization offered by the transfer function is then employed to develop a multi-photon counting algorithm realized through digital signal processing (DSP) which captures photon arrivals traditionally ignored in conventional counting methods. This approach increases acquired Raman intensity for any given analyte by using detector output voltage or a voltage-time product as an energy proxy – an approach that is likey broadly applicable to any spectroscopic techniques employing detectors that make use of the photoelectric effect. In experiments carried out on analytes (nitrate, isopropanol, and rhodamine 6G) in aqueous solutions, enhanced observations enabled by the multi-photon counting algorithm are shown to increase observed Raman intensities of low Raman-yield solutions 2.0-3.1-fold compared to single-threshold analysis, and also extend the upper observation limit of strong Raman-yield solutions that would traditionally saturate detectors using a binary photon counting scheme. Notably, the improved performance offered by the multi-photon counting algorithm is realized through comparison of multi-photon and conventional counting algorithms applied to the same data in a post-processing exercise, thus eliminating any effects of test-to-test variation on results, and highlighting the ability to employ the developed counting approach without modification of traditional systems.</p><p><br></p><p>Additional insights from the system transfer function are also used to inform exploration of a novel approach to enable spatial environmental monitoring via Raman spectroscopy by combining fiber optics, optical switch technology, and the Raman system prototype. Tests designed to evaluate the system configured as a multiplexed optically switched fiber optic network demonstrate the potential to deliver excitation and collect Raman scattering from different desired monitoring locations with a sole excitation source and a single detector over substantial distances. Using nitrate as an example compound of interest, it is demonstrated that the system has a detection limit of 5 ppm within approximately 1.5 meters, which increases to 15 ppm at 100 m, and 38 ppm at 200 m. Modelling informed using the developed system transfer function highlights that improving the prototype by eliminating fiber connectors and making use of commercially available visible-light optimized fiber can substantially extend the range of the system, offering a 15-ppm nitrate detection limit at 2100 m. As increases in laser power, testing time, and collection optic efficiency are all also straightforward and viable, the prototype demonstrates realistic potential to achieve field relevant detection sensitivity over great distance.</p><p><br></p><p>As a final demonstration of system potential, a set of experiments on aqueous nitrate solutions is performed to understand the influence of turbidity, fluorescence, optics size, and varied raw data integration lengths on Raman observations. Results demonstrate that cumulative advances in the TRRS system establish a new generation of Raman spectroscopic sensing amenable to long-term environmental monitoring over significant spatial extent in complex in-situ conditions. Specific advances made herein include enhanced power delivery and scattered light collection informed by the system transfer function, increases in sensitivity from multi-photon counting, and incorporation of optical multiplexing. Overall, the Time-Resolved Raman Spectroscopic System (TRRS) now offers a set of capabilities that bring in-field deployment within practical reach.</p>

Linear time-invariant (LTI) dynamic networks are described by their dynamical structure function, and generally, they have many possible state space realizations. This work characterizes the necessary and sufficient conditions on a state transformation that preserves the dynamical structure function, thereby generating the entire set of realizations of a given order for a specific dynamic network.

We develop a theory of vectorial wave coupling in cubic photorefractive crystals placed in an alternating ac-field to enhance the nonlinear response. First we analytically and numerically investigate the dependences of the first Fourier harmonics of the space-charge field, induced in an AC-biased sillenite crystal by a light-interference pattern, on the light contrast m. The data obtained was used to extend the vectorial beam-coupling theory on the whole contrast region. In particular, we proved in the general case that despite of essential differences between thediffusion and AC nonlocal responses the later keeps the light interference fringes straight during the interaction. This fundamental feature allows, under certain restrictions, to reduce the nonlinear problem of vectorial coupling to the known linear problem of vectorial Bragg diffraction from a spatially uniform grating, which admits an exact solution. As a result, the nonlinear vectorial problem can be effectively solved for a number of practically important cases.The developed theory was applied to describe the transformation of a momentary phase changes of one of the input beams into the output intensity modulation (so-called grating translation technique). In contrast to the previous studies, we take into account the change of the space-charge field amplitude across the crystal (the coupling effects). The theory developed is employed to optimize the conditions for the linear signal detection under polarization filtering for the transverse and longitudinal optical configurations. We also analyze the possibility of the linear detection without polarization filtering.Illumination of AC-biased photorefractive BTO crystals with a coherent light beam results in development of strong nonlinear scattering. We investigate the angular and polarization characteristics of the scattered light for the diagonal optical configuration and different polarization states of the pump.

Η πληθώρα των εφαρμογών που μπορεί να εξυπηρετήσει η τεχνολογία Υπερευρείας Ζώνης (UWB), από τα ασύρματα προσωπικά δίκτυα υψηλών ταχυτήτων, μέχρι τα ασύρματα δίκτυα αισθητήρων με δυνατότητες ακριβούς εντοπισμού θέσης, και τα ασύρματα δίκτυα ιατρικών αισθητήρων, έχει προκαλέσει έντονο ερευνητικό ενδιαφέρον γύρω από τις υλοποιήσεις UWB συστημάτων. Η ασυνήθιστα μεγάλη περιοχή συχνοτήτων που έχει ανατεθεί στο UWB, από τα 3.1-10.6 GHz, επιτρέπει την επίτευξη υψηλών ταχυτήτων με απλά σχήματα διαμόρφωσης, ωστόσο, λόγω της διαμοίρασης του φάσματος με τις υφιστάμενες τεχνολογίες ασύρματης δικτύωσης, οι UWB εκπομπές πρέπει να περιορίζονται σε ισχύ κάτω από το κατώφλι των -41.3 dBm/MHz, ικανοποιώντας πολύ αυστηρές μάσκες εκπομπής που εισάγουν έντονες προκλήσεις στη σχεδίαση των πομπών. Η υλοποίηση αναδιατάξιμων UWB πομπών σε σύγχρονες CMOS τεχνολογίες, με υψηλή φασματική ευελιξία, ταχύτητα και ποιότητα διαμόρφωσης, καθώς και με χαμηλή κατανάλωση, αποτέλεσε το αντικείμενο της συγκεκριμένης διατριβής. Υιοθετώντας την αρχιτεκτονική Multi-Band Impulse-Radio (MB-IR) σε συνδυασμό με την τεχνική Direct Sequence BPSK, η έρευνα προσανατολίστηκε προς την ανάπτυξη καινοτόμων μονάδων βασικής ζώνης, με στόχο την ενεργειακά αποδοτική αντιστροφή Γκαουσιανών μορφοποιημένων παλμών υψηλής ποιότητας φάσματος και διάρκειας μικρότερης ακόμα και από 1 nsec. Προς αυτή την κατεύθυνση, αναπτύχθηκε μια καινοτόμα γεννήτρια Γκαουσιανών παλμών με πολύ χαμηλούς πλευρικούς λοβούς στο φάσμα, τυπικά κάτω από -40 dB, ώστε να υποστηρίζονται οι αυστηρότερες μάσκες εκπομπής ή και μελλοντικές. Η σχεδίασης της προτεινόμενης γεννήτριας είχε ως κριτήριο την ευέλικτη ρύθμιση της διάρκειας των παραγόμενων παλμών, και αξιοποίησε τη χαρακτηριστική μεταφοράς τάσης ενός ωμικά φορτωμένου, ασύμμετρου CMOS αντιστροφέα. Η γεννήτρια βασίζεται κυρίως σε ψηφιακά κυκλώματα πολύ χαμηλής τάσης και, σε σύγκριση με τις υφιστάμενες υλοποιήσεις, παρουσιάζει σημαντικό προβάδισμα στον τομέα της ταχύτητας, καθώς και στο πλάτος εξόδου, η μεγάλη τιμή του οποίου χαλαρώνει σημαντικά τη σχεδίαση του RF front end. Η γεννήτρια μελετήθηκε διεξοδικά, διεξήχθη ανάλυση κλιμάκωσης, έγινε εξαγωγή σχεδιαστικών εξισώσεων και αναπτύχθηκαν εργαλεία λογισμικού για την αυτοματοποιημένη σχεδίασή της. Για περαιτέρω αύξηση της ταχύτητας των παλμικών σημάτων εφαρμόσθηκε ειδική σχεδίαση, η οποία αντιπραγματεύεται την ταχύτητα με το επίπεδο των λοβών του φάσματος. Για την αποδοτική BSPK διαμόρφωση των Γκαουσιανών παλμών αναπτύχθηκε ειδική τοπολογία “Μεταγωγής Σήματος Πυροδότησης Πλήρους Ισορροπίας με Up-Conversion”. Η τοπολογία αυτή, σε αντίθεση με τις ανταγωνιστικές τοπολογίες, αποφεύγει την αντιστροφή του παλμού με αναλογικά κυκλώματα υψηλής κατανάλωσης, αλλά και την αναλογική μεταγωγή, καθώς η διαμόρφωση λαμβάνει χώρα πριν από την παραγωγή των παλμών. Παράλληλα, επιτυγχάνονται υψηλοί ρυθμοί, καθώς και υψηλή ποιότητα διαμόρφωσης λόγω των ισορροπημένων μονοπατιών της τοπολογίας. Η γεννήτρια μαζί με το διαμορφωτή αποτελούν τις καινοτόμες παρεμβάσεις στη μονάδα Βασικής Ζώνης του προτεινόμενου πομπού. Για την ολοκλήρωση της λειτουργικότητας του πομπού, αναπτύχθηκε ένα RF front end, το οποίο αποτελείται από έναν διπλά ισορροπημένο μίκτη, έναν LO buffer, ένα μετατροπέα διαφορικού σήματος σε απλό, και έναν ενισχυτή ισχύος, ο οποίος είναι προσαρμοσμένος στα 50 Ohms, χωρίς να απαιτεί κανένα εξωτερικό στοιχείο. Το RF front end ολοκληρώθηκε μαζί με τη μονάδα βασικής ζώνης, και ο ολοκληρωμένος πομπός κατασκευάστηκε σε τεχνολογία CMOS 130 nm. Το ολοκληρωμένο προσαρτήθηκε στην RF πλακέτα συστήματος με την τεχνική Chip on Board. Για την επιτυχία του συστήματος με την πρώτη προσπάθεια έγινε συσχεδίαση σε επίπεδο IC-Package-PCB, δίνοντας ιδιαίτερη έμφαση στα ζητήματα Signal/Power Integrity. Ο πομπός παρουσίασε την υψηλότερη ταχύτητα από τις ανταγωνιστικές MB-IR UWB υλοποιήσεις, ίση με 1.5 Gbps, με αντίστοιχη ενεργειακή αποδοτικότητα 21 pJoule/bit και μέτρο διανυσματικού σφάλματος 5.5%. Ο πομπός βελτίωσε τους πλευρικούς λοβούς στο φάσμα περισσότερο από 10 dB, ενώ η διατριβή, εκμεταλλευόμενη την αναδιαταξιμότητα του πομπού, παρουσιάζει, επιπλέον, τις πρώτες μετρήσεις σε ταχύτητες εκατοντάδων Mbps για ικανοποίηση της χαμηλής ζώνης της πρόσφατα θεσμοθετημένης, και εξαιρετικά αυστηρής, ευρωπαϊκής μάσκας εκπομπής. / The multitude of applications that Ultra-Wideband (UWB) technology can serve, from high-speed Wireless Personal Area Networks, to Wireless Sensor Networks with precision Geolocation abilities, and Wireless Medical Networks, has attracted intense research interest in the implementation of UWB systems. The unusually wide range of frequencies assigned to UWB, from 3.1-10.6 GHz, allows UWB systems employing low order modulation schemes to enjoy high throughput at low power consumption. However, since UWB shares the spectrum with existing wireless networking technologies, UWB emissions must be limited to a power spectral density below the threshold of -41.3 dBm/MHz, satisfying very stringent emission masks and introducing great challenges in the design of UWB transmitters. The subject of this thesis is the design of low power, fully integrated, reconfigurable CMOS UWB transmitters, with high spectral flexibility, high speed and high modulation quality. Adopting the Multi-Band Impulse-Radio architecture, in conjunction with the Direct Sequence BPSK modulation, the research focused on the development of a baseband unit, able to precisely invert Gaussian shaped, subnanosecond pulses. The key contributions of this thesis are a CMOS Gaussian Pulse Generator and a BSPK modulation topology, which jointly constitute the proposed baseband unit. The Pulse Generator (PG) is based on non-linear shaping, so as to facilitate the configurability of the output pulse duration, and exploits the voltage transfer characteristic of a Resistive Loaded Asymmetrical CMOS Inverter, which results in spectral sidelobes typically better than -40 dB. The PG incorporates mostly-digital low voltage circuits, while the MOSFET devices that undertake the pulse shaping avoid exclusive operation in weak inversion, in contrast to previous implementations. Consequently, the proposed CMOS PG is able to support higher throughput, as well as higher output amplitude, which relaxes considerably the design of the RF front end. This thesis presents a systematic design procedure and a scaling analysis of the non-linear pulse shaper. Moreover, in order to further increase the speed, a special PRF boost technique is proposed, which trades off speed and spectral efficiency for the spectral sidelobes level. Regarding the BPSK modulator, this work introduces the “Trigger Switching Fully Balanced Up-Conversion” topology, which avoids the use of power-hungry and distortion-prone analog circuits for the accurate inversion of the subnanosecond shaped pulses, as well as avoids the application of analog waveform switching to the baseband pulses, since the baseband modulation takes place before the generation of the pulses. The digital nature of the switching lends itself to high data rates, while the balanced paths of the topology ensure high modulation quality with minimal design effort. Wafer probing measurements confirmed the high performance of the baseband unit. The functionality of the transmitter was completed by the development of an RF front end which consists of a double balanced mixer, an LO buffer, a differential to single-ended (DtoSE) converter, and a power amplifier which is ready to drive a 50 Ohms load without requiring any off-chip components. The integrated transmitter, which incorporates the proposed baseband unit and the RF front end, was fabricated in 130 nm CMOS technology. The transmitter RFIC was directly attached to the system RF PCB using the Chip-on-Board packaging option. The First-Pass success of the system was ensured by paying particular attention to Signal/Power Integrity issues and following an IC-Package-PCB co-design procedure. The transmitter was measured up to 1.5 Gbps, which, to the author’s knowledge, was the highest speed amongst the competitive Multi-Band Impulse-Radio UWB implementations in the literature. The corresponding energy efficiency was 21 pJoule/bit and the Error Vector Magnitude (EVM) 5.5%, while the proposed transmitter improved the spectral sidelobes by over 10 dB. Exploiting the reconfigurability of the transmitter, this thesis presents the first measurements at multi-Mbps speeds that completely meet the final version of the European spectrum emission mask.