The main goal of this Thesis was to measure tritium activity in the Vltava River and in the vicinity of Temelín Nuclear Power Plant (hereinafter referred to as JETE) with the following objectives: Possibility to use the outlet of waste water damping unit (hereinafter referred to as VTOOV) as a control alerting system for nonstandard events in JETE, furthermore, monitoring of possible correlations between volume activity of tritium measured in VTOOV and activity above the limit value of the first quality class in selected sections of the Vltava River as well as comparison of the measured values with the results of other authors, and, finally, assessment of the relevance of the water quality estimated by the volume activity of tritium to the water quality according to other ingredients, i.e., stable isotopes of some metals and risk elements as well as general physical and chemical indicators. Theoretical part of the Thesis deals with radioactivity in general, activity of tritium, with regard to operation of nuclear plants, over the world and, especially, in the Czech Republic. The actual work consisted of collection of samples at predetermined places, preparation of these samples for measurement and measurement of tritium activity using scintillation spectrometer with liquid scintillator. Furthermore, basic chemical and physical properties of water, concentration of selected elements and also some anions were determined. The collected data were used for classification of waters from individual collection places into quality classes according to ČSN 75 7221. In all analyzed cases no activities were found which exceeded the limit values of liquid outlets from Temelín Nuclear Power Plant, given by regulations issued on waters by the District Health Office in Ceske Budejovice according to §8 of Act No. 138/73 Coll., in compliance with SÚJB requirements. This Thesis could be beneficial for possible utilization of VTOOV as a control alerting system for nonstandard events in JETE and also for assessment of impact of wastewaters from JETE on waters of the Vltava River.

The State Office for Nuclear Safety (SONS) and the National Radiation Protection Institute (NRPI) are involved in independent monitoring of surrounding areas of nuclear power plants (NPPs), in accordance with the Czech legislative requirements (Decree No. 319/2002 Coll. on radiation monitoring network (RMS), as amended by Decree No. 27/2006 Coll.). The monitoring includes surveillance of environmental samples, in which radionuclides can be detected in case of emergency event, i.e. radioactivity release from the NPP. Another part of the monitoring is measurement of photon dose equivalent, continuously in the air (early detection network - SVZ) or using thermoluminescent dosimeters (TLD) placed in SONS monitoring points in the NPP vicinity. Environmental sampling and evaluation of photon dose equivalent in the air is carried out in regular intervals. The 137Cs and 131I activity is measured by gamaspectrometry method used with Gamat evaluation program, according to SONS internal procedure (VDMI). Tritium activity in surface water is measured by liquid scintillation spectrometer Beta TriCarb made by Canberra Packard Company, according to methodology CSN ISO 9698 (757635). Evaluation of dose equivalent rate is carried out continuously by LB 6360 proportional probe and LB 6500-3 Geiger-Muller tube located in RC Building in Ceske Budejovice. TLD evaluation is carried out by NRPI laboratory in Prague and the results are sent to SONS RC Ceske Budejovice. Goal of this work is to provide a set of results of the independent monitoring in surrounding areas of Temelin NPP (ETE) carried out between 1999 and 2009, by determination of volume, mass or surface activity of environmental samples (137Cs and 131I) and spot samples of water (3H) taken from SONS monitoring points near ETE . The set of such results should provide a baseline reference values for normal (pre-accident) situations. Additionally, based on the long term of the ETE surrounding surveillance, it can be shown that the ETE operation represents no threat to the health of the critical population group, and that the radiation situation in the ETE surrounding is stable. It can be also shown that the ETE operator meets requirements and conditions of authorized limits for discharging radionuclides into the environment. Procedures and method of independent environmental monitoring in the ETE surrounding during emergency events can be proposed on the basis of many years of experience with proven methodologies, experience with sampling locations, staffing and organization of measurement.

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Foram desenvolvidos métodos de determinação de urina e trítio em urina. Para o urânio foi adaptada a técnica de análise por fluorimetria em meio sólido. O limite de sensibilidade foi de 5. 10-4µg U/0,1 ml e o erro foi de cerca de 10% para concentrações em torno de 0,05 µg U/0,1 ml. Foi padronizado para o trítio o método de análise por cintilação em meio líquido. O método determina quantidades de trítio até pelo menos 8,10-3µCi/ml e o erro foi de cerca de 4% para concentrações de trítio em torno de 0,34 µCi/l. Depois de adaptadas, as técnicas foram aplicadas a amostras de urinas de trabalhadores expostos a compostos de urânio ou trítio com a finalidade de verificar possível contaminação interna por estes radioisótopos. / Abstract not available.

Kyoto University (京都大学) / 0048 / 新制・論文博士 / 博士(工学) / 乙第12335号 / 論工博第4013号 / 新制||工||1466(附属図書館) / 27190 / UT51-2009-D550 / (主査)教授 森山 裕丈, 教授 伊藤 秋男, 教授 高木 郁二 / 学位規則第4条第2項該当

Deep well injection into non-potable saline aquifers of treated domestic wastewater has been used in Florida for decades as a safe and effective alternative to ocean outfall disposal. The objectives of this study were to determine the fate and transport of injected wastewater at two deep well injection sites in Miami Dade County, Florida, USA. Detection of ammonium in the Middle Confining units of the Floridan aquifer above the injection zone at both sites has been interpreted as evidence of upward migration of injected wastewater, posing a risk to underground sources of drinking water. Historical water quality data, including ammonia, chloride, temperature, and pH from existing monitoring wells at both sites from 1983 to 2008, major ions collected monthly from 2006 and 2008, and a synoptic sampling event for stable isotopes, tritium, and dissolved gases in 2008, were used to determine the source of ammonium in groundwater and possible migration pathways. Geochemical modeling was used to determine possible effects of injected wastewater on native water and aquifer matrix geochemistry. Injected wastewater was determined to be the source of elevated ammonium concentrations above ambient water levels, based on the results of major ion concentrations, tritium, dissolved noble gases and 15N isotopes analyses. Various possible fluid migration pathways were identified at the sites. Data for the south site suggest buoyancy-driven vertical pathways to overlying aquifers bypassing the confining units, with little mixing of injected wastewater with native water as it migrated upward. Once it is introduced into an aquifer, the injectate appeared to migrate advectively with the regional groundwater flow. Geochemical modeling indicated that CO2 -enriched injected wastewater allowed for carbonate dissolution along the vertical pathways, enhancing permeability along these flowpaths. At the north site, diffusive upward flow through the confining units or offsite vertical pathways were determined to be possible, however no evidence was detected for any on-site confining unit bypass pathway. No evidence was observed at either site of injected wastewater migration to the Upper Floridan aquifer, which is used as a municipal water supply and for aquifer storage and recovery.

This study investigates the runoff process and groundwater behavior in a subarctic watershed called Wolf Creek Research Basin, in Whitehorse, Yukon Territory, Canada. This basin is underlain by discontinuous permafrost that is typical of high latitude watersheds. Goundwater supports the stream flow year round and dominated the hydrology in most of the study period as baseflow. The baseflow was concentrated in dissolved ions. However, the baseflow was diluted during the melt season in May and June of 2012. Multiple chemical and isotopic tracers were used to develop a robust three-component (groundwater, soilwater and precipitation) mixing model for runoff generation. The concentrations of weathering ions decreased with the increased discharge during the melt. Soilwater was responsible for about 60% of the streamwater on the hydrograph in the melt season. The infiltration of the meltwater from the snowpack and the thawed water from the seasonal frost to the baseflow existed. The tritium concentrations indicated that there was fast moving hydrogeological system within the basin. The baseflow was also characterized as relatively enriched in both 13C and 14C, and concentrated in DIC. DIC was the major loss of carbon in Wolf Creek Research Basin.Le pergélisol est grandement sous-jacent dans les bassins-versants à haute latitude. Cette étude examine le processus de ruissellement et le comportement des eaux souterraines dans un bassin-versant subarctique de Wolf Creek, à Whitehorse, territoire du Yukon au Canada. Les eaux souterraines soutenaient l’écoulement fluvial et dominaient l’hydrographe comme débit de base durant la majorité de la période d’étude. Le débit de base était concentré d’ions dissipés. Par contre, le débit de base était dilué durant la saison des fontes au mois de mai et juin 2012. Plusieurs traceurs chimiques et isotopiques étaient utilisé afin de développer un modèle de trois composants (eau souterraine, eau interstitielle de sol et précipitation) de ruissellement. Les concentrations de la déségrégation des ions diminuaient avec l’augmentation du débit durant la fonte. Les eaux interstitielles des sols étaient responsables de 60% de l’eau de ruisseau sur l’hydrographe durant la saison de fontes. L’infiltration de l’eau de fonte du manteau neigeux et l’eau du gel du débit de base existaient. Les concentrations de tritium indiquent qu’il y avait un système hydrogéologique qui se déplaçait à grande vitesse dans les limites du bassin. Le débit de base était aussi caractérisé comme étant enrichi en 13C et 14C, avec des concentrations en carbone inorganique dissous.

京都大学 / 0048 / 新制・課程博士 / 博士(エネルギー科学) / 甲第18388号 / エネ博第300号 / 新制||エネ||62(附属図書館) / 31246 / 京都大学大学院エネルギー科学研究科エネルギー変換科学専攻 / (主査)教授 小西 哲之, 教授 宇根﨑 博信, 准教授 笠田 竜太 / 学位規則第4条第1項該当 / Doctor of Energy Science / Kyoto University / DFAM

京都大学 / 0048 / 新制・課程博士 / 博士(エネルギー科学) / 甲第18609号 / エネ博第305号 / 新制||エネ||62(附属図書館) / 31509 / 京都大学大学院エネルギー科学研究科エネルギー変換科学専攻 / (主査)教授 小西 哲之, 教授 星出 敏彦, 教授 岸本 泰明 / 学位規則第4条第1項該当 / Doctor of Energy Science / Kyoto University / DFAM