Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Earth and Planetary Science, 1979. / Microfiche copy available in Archives and Science. / Bibliography: leaf 93. / by Carolyn Alexandria Morrow. / M.S.

The Dinner Creek Tuff is a mid-Miocene rhyolitic to dacitic ignimbrite, consisting of four cooling units with 40Ar/39Ar ages 16--15 Ma. Previous geologists have suspected that the source of the tuff is located in northwestern Malheur County, eastern Oregon. This broad area is called the Dinner Creek Tuff Eruptive Center. This thesis summarizes field work, XRF/ICP-MS geochemistry, thin section petrography, and SEM feldspar analysis from the summers of 2015 and 2016. The main purpose of this study is to identify sources for the Dinner Creek Tuff units within the Dinner Creek Tuff Eruptive Center. The secondary purpose is to map lava flows that pre-date and post-date the Dinner Creek Tuff, and correlate them with regionally extensive volcanic units. Two volcanic centers related to the Dinner Creek Tuff were identified. The southern volcanic center, centered at Castle Rock, is a caldera and source of the Dinner Creek Tuff unit 1 (DIT1). Rheomorphic, densely welded DIT1 is over 300 m thick along the east side of Castle Rock. The northwestern margin of the caldera has been uplifted along faults, showing vertically foliated tuff dikes and associated mega-breccia deposits. Up to 200 m of incipiently welded tuffs, and fluvial volcanoclastic sediments were deposited on the caldera floor, which has been uplifted due to resurgence and regional extension, creating the complex structural relationships between the volcanic units. The northern volcanic center is located at Ironside Mountain, where densely welded rheomorphic Dinner Creek Tuff unit 2 (DIT2) is exposed in outcrops over 600 m thick. The top of the DIT2 consists of glassy, moderately welded tuff. Sources for the DIT2 are tuff dikes along the south and western flanks of Ironside Mountain. The thick deposits of DIT2 at Ironside Mountain indicate that the mountain is an uplifted caldera, herein named the Ironside Mountain caldera. Uplift may have been due to resurgence, but it is most likely due to normal faulting along the Border Fault, a major regional normal fault that strikes across the northern margin of the caldera. Pre-Dinner Creek Tuff lava flows occur throughout the study area, and can be correlated with the Strawberry Volcanics and the Basalt of Malheur Gorge. A distinct lava flow, herein called the Ring Butte trachy-basalt occurs within the center of the study area, and is distinct from regional lava flows. Following the eruptions of the Dinner Creek Tuff units 1 & 2, aphyric basaltic-andesite and icelandite intrude into, and overlie the intra-caldera tuffs and caldera floor sediments at both calderas. These aphyric lavas are similar in appearance and stratigraphic position with the regionally extensive Hunter Creek basalt. Porphyritic olivine basalt overlies the aphyric Hunter Creek basalt at the Castle Rock caldera. This porphyritic lava is similar in appearance and major/trace element geochemistry to the regional Tim's Peak basalt.

Large-volume silicic ignimbrites erupt from reservoirs that vary in composition, temperature, volatile content and crystallinity. The 9.7 Ma Devine Canyon Tuff (DCT) of eastern Oregon is a large-volume (>250 km3), compositionally zoned and variably welded ignimbrite. The ignimbrite exhibits heterogeneous trace element compositions, variable volatile content and crystallinity. These observations were utilized in the investigation into the generation, accumulation and evolution of the magmas composing the DCT. Building off previous research, pumices were selected from the range of trace element compositions and analyzed with respect to crystallinity, mineral abundances and assemblages. The DCT displays a gradational trace element enrichment and decrease in crystallinity from least evolved, dacite, at ~22% crystals to most evolved high-silica rhyolite at 3% crystals. Two distinct mineral populations of feldspar and clinopyroxene were identified in previous work, one belonging to the rhyolitic magma and the other to the dacitic magma. Volatile content derived from melt inclusion Fourier Transform Infrared (FTIR) spectrometer analysis revealed an increase in water content from 1.2 to 3.7 wt.% in the most evolved rhyolite. The DCT exhibits low and variable δ18O signatures, 4.52‰ to 5.76‰ , based on δ18O values measured on quartz and sanidine. Low δ18O signatures of all DCT rhyolites suggest the incorporation of hydrothermally altered crust into the melt. Furthermore, quartz phenocrysts from all high-silica rhyolite groups display dark oscillatory zoned cores and Ti-rich bright rims. These data provide insight into how these magmas were generated and subsequently stored in the crust. Commonalities of petrographic and compositional features among rhyolites, especially the zoning characteristics of quartz phenocrysts, exclude the possibility of storage and evolution in multiple reservoirs. Envisioning a scenario where all magmas are stored within a single reservoir prior to eruption and assuming rhyolites A and D are the product of partial melting. The mixing of A and D rhyolites produced rhyolite B, and subsequent mixing of intermediate rhyolite B and end-member rhyolite D generated rhyolite C. However, some trace element inconsistencies, between mixing model and observed intermediate rhyolites suggest a secondary process. Post mixing, rhyolites B and C require some modification by fractional crystallization to account for LREE and other inconsistencies between mixed models and observed rhyolites. Finally, the origin of the dacite is likely through mixing of group D rhyolite and an intrusive fractionated basalt, which could have led to the eruption of the Devine Canyon Tuff.

The locality of Zwartbas is situated at the border of Namibia and South Africa about 15 km west of Noordoewer. The mapped area is confined by the Tandjieskoppe Mountains in the north and the Orange River in the south. Outcropping rocks are predominantly sediments of the Nama Group and of the Karoo Supergroup. During the compilation of this paper doubts arose about the correct classification of the Nama rocks as it is found in literature. Since no certain clues were found to revise the classification of the Nama rocks, the original classification remains still valid. Thus the Kuibis and Schwarzrand Subgroup constitute the Nama succession and date it to Vendian age. A glacial unconformity represents a hiatus for about 260 Ma. This is covered by sediments of the Karoo Supergroup. Late Carboniferous and early Permian glacial deposits of diamictitic shale of the Dwyka and shales of the Ecca Group overlie the unconformity. The shales of the Dwyka Group contain fossiliferous units and volcanic ash-layers. A sill of the Jurassic Tandjiesberg Dolerite Complex (also Karoo Supergroup) intruded rocks at the Dwyka-Ecca-boundary. Finally fluvial and aeolian deposits and calcretes of the Cretaceous to Tertiary Kalahari Group and recent depositionary events cover the older rocks occasionally. / Die Lokalität Zwartbas liegt an der namibisch-südafrikanischen Grenze, etwa 15 km westlich von Noordoewer. Das Kartiergebiet wird durch die Tandjiesberge im Norden und den Oranje Fluß im Süden begrenzt. Die anstehenden Gesteine bestehen hauptsächlich aus Sedimenten der Nama Gruppe und der Karoo Supergruppe. Während der Erarbeitung dieser Abhandlung entstanden Zweifel an der Klassifikation der Nama Gesteine, so wie sie in der Literatur zu finden ist. Da keine sicheren Hinweise zur Revision der Klassifikation der Nama Gesteine gefunden wurden, bleibt die ursprünglich Klassifikation jedoch gültig. Die Kuibis und Schwarzrand Untergruppe bilden also die Nama Abfolge und datieren sie ins Vendian. Eine glaziale Diskontinuität repräsentiert einen Hiatus von etwa 260 Mio Jahren. Sie wird überlagert von Sedimenten der Karoo Supergruppe. Spät-karbone und früh-permische glaziale Ablagerungen von diamiktitischen Tonsteinen der Dwyka Gruppe und Tonsteine der Ecca Gruppe liegen über dieser Diskontinuität. Die Sedimente der Dwyka Gruppe sind fossilführend und enthalten Tufflagen. Ein Sill des jurassischen Tandjiesberg Dolerit Komplex (auch Karoo Supergruppe) intrudierte in die Gesteine an der Dwyka-Ecca Grenze. Schließlich bedecken lokal fluviatile und äolische Ablagerungen und Kalkkrusten der kretazischen und tertiären Kalahari Gruppe und jüngerer Ablagerungsereignisse die älteren Gesteine.

Thin, pyroclastic marker beds are preserved in argillaceous units of the Dwyka Group in southern Nambia and South Africa which are the earliest witnesses of volcanism in Karoo-equivalent strata of southern Africa. The aim of this study is to present the field appearance of these marker beds, to characterise their mineralogy, geochemistry and heavy mineral contents and to present new radiometric age data from their juvenile zircons. Carboniferous-Permian Karoo deposits in the Aranos Basin of southern Namibia include the glacially dominated, Carboniferous Dwyka Group and the shelf sediments of the overlying Permian Ecca Group. The Dwyka Group can be subdivided into four upward-fining deglaciation sequences, each capped by relatively fine-grained glaciolacustrine or glaciomarine deposits. The uppermost part of the second deglaciation sequence comprises a thick fossiliferous mudstone unit, referred to as the ”Ganigobis Shale Member”. An abundance of marine macro- and ichnofossils as well as extrabasinally derived ashfall tuff beds characterise the more than 40 m thick mudstones and provide the basis for an integrated high-resolution biostratigraphic and tephrostratigraphic framework. The Ganigobis Shale Member contains remains of paleoniscoid fishes, bivalves, gastropods, scyphozoa, crinoid stalks, sponges and sponge spicules, radiolaria, coprolites and permineralised wood. These mostly marine body and trace fossils record the extent of the first of a series of marine incursions into the disintegrating Gondwanan interior as early as the Carboniferous. Within the Ganigobis Shale Member 21 bentonitic tuff beds displaying a thickness of 0.1 and 2.0 cm were determined which in part can be traced laterally over tens of kilometres indicating an ashfall derivation. Further bentonitic tuff beds of the Dwyka Group were detected in cut banks of the Orange River near Zwartbas in the Karasburg Basin (southern Namibia). The 65 tuff beds vary between 0.1 and 4.0 cm in thickness. Due to a similar fossil content and age of the background deposits, the tuff beds are thought to have originated from the same source area as those from the Aranos Basin. Thin-sections reveal the derivation of the tuff beds as distal fallout ashes produced by explosive volcanic eruptions. The matrix consists of a micro- to cryptocrystalline clay mineral-quartz mixture. Rare fragments of splinter quartz, completely recrystallized ash-sized particles of former volcanic glass and few apatite and zircon grains are the only juvenile components. The tuff beds contain as non-opaque, juvenile heavy minerals mostly zircon, apatite, monazite and sphene but also biotite, garnet, hornblende and tourmaline. Geochemical analyses point to an original, intermediate to acid composition of the tuff samples. LREE enrichment and Eu-anomalies show that the parent magma of the tuff beds was a highly evolved calc-alkaline magma. Tectonomagmatic discrimination diagrams point to a volcanic arc setting. Bedding characteristics and the lack of any Carboniferous-Permian volcanic successions onshore Namibia makes an aeolian transport of the ash particles over larger distances likely. Siliceous ashes could thus have been transported by prevailing south-westerly winds from arc-related vents in South America to southern Africa. A second, more local source area could have been located in an intracontinental rift zone along the western margin of southern Africa which is indicated by north-south directed ice-flow directions in the Late Carboniferous. SHRIMP-based age determinations of juvenile magmatic zircons separated from the tuff beds allow a new time calibration of Dwyka Group deglaciation sequences II - IV and the Dwyka/Ecca boundary. Zircons of the Ganigobis Shale Member yield SHRIMP-ages of 302-300 Ma. This dates the uppermost part of the second deglaciation sequence in southern Namibia to the Late Carboniferous (Gzelian) and provides a minimum age for the onset of Karoo-equivalent marine deposition. The age of the uppermost argillaceous part of the third deglaciation sequence (297 Ma) was determined from zircons of a tuffaceous bed sampled in a roadcut in the Western Cape Province, South Africa. The deposits correlate with the Hardap Shale Member in the Aranos Basin of southern Namibia which are part of much more widespread Eurydesma transgression. The age of the Dwyka/Ecca boundary was determined by SHRIMP-measurements of juvenile zircons from two tuff beds of the basal Prince Albert Formation sampled in the Western Cape Province (South Africa). The zircons revealed ages of 289 - 288 Ma which date the Dwyka/Ecca boundary at about 290 Ma. According to these ages, deglaciation sequences II-IV lasted for 5 Ma on average. / Geringmächtige, bentonitische Tuffe treten in Tonsteinabschnitten der karbonen Dwyka Gruppe im südlichen Namibia und Südafrika auf. Sie repräsentieren die ersten Hinweise auf eine vulkanische Tätigkeit innerhalb der Karoosedimente im südlichen Afrika. Die vorliegende Dissertation faßt die Geländebeschreibung der Tuffe, ihre Petrographie, Mineralogie und Geochemie zusammen. Juvenile Zirkone der Tuffe erlaubten eine radiometrisches Altersermittlung mittels SHRIMP-Analyse. Sie stellen somit die ersten radiometrisch exakt ermittelten Altersdaten innerhalb der Dwyka Gruppe dar. Permokarbone Karoosedimente des Aranos Beckens in Südnamibia setzen sich aus der glazigenen Dwyka Gruppe des Karbons und den Schelfsedimenten der folgenden Ecca Gruppe des Perms zusammen. Die Dwyka-Gruppe kann dabei in vier Entgletscherungssequenzen unterteilt werden. Der oberste Bereich jeder Entgletscherungssequenz ist meist durch glaziomarine Ablagerungen gekenn-zeichnet. Im Fall der zweiten Entgletscherungssequenz handelt es sich um einen mehr als 40 m mäch-tigen, fossilführenden Tonsteinabschnitt, der als ‘Ganigobis Shale Member’ bekannt ist. Eine Vielzahl von meist marinen Makro- und Spurenfossilien (palaeoniskoide Fischen, Bivalven, Gastropoden, Scyphozoen, Crinoideenstielglieder, Radiolarien) sowie distale Aschentuffe bilden die Grundlage für eine hochauflösende, biostratigraphische und tephrostratigraphische Gliederung des ‘Ganigobis Shale Members’. 21 bentonitische, lateral verfolgbare Aschentuffe mit einer Mächtigkeit zwischen 0.1 und 2.0 cm wurden innerhalb des ‘Ganigobis Shale Member’ bestimmt. 65 weitere, bis 4.0 cm mächtige Aschentuffe der Dwyka Gruppe wurden in Uferbänken des Orange Rivers in der Nähe von Zwartbas im Karasburg Becken Südnamibias entdeckt. Aufgrund eines ähnlichen Fossilinhaltes der Hinter-grundsedimente und eines ähnlichen Alters der Tuffe kann von dem gleichen Herkunftsgebiet der Aschen ausgegangen werden. Dünnschliffe der Tuffe zeigen, daß es sich bei den Horizonten um distale Aschenfallablagerungen handelt, die durch explosiven Vulkanismus gefördert wurden. Die Matrix besteht aus einer mikro- bis kryptokristallinem Tonmineral-Quarz- Mischung. Idiomorpher, hexagonaler Quarz, Splitterquarze und Quarzfragmente, vollständig rekristallisierte Aschenkörner und vereinzelt Schwerminerale wie Apatit und Zirkon sind weitere juvenile Komponenten. Folgende transparente, juvenile Schwerminerale treten auf: Zirkon, Apatit, Monazit, Titanit, Biotit, Granat, Hornblende und Turmalin. Geochemische Analysen weisen auf eine intermediäre bis saure Ausgangszusammensetzung der Tuffe hin. Die Anreicherung der LREE und die Eu-Anomalien zeigen, daß die Zusammensetzung des Ausgangsmagma der Tuffe kalkalkalisch und sehr differenziert war. Tektonomagmatische Diskrimi-nationsdiagramme deuten eine Subduktionszone als Herkunftsgebiet der Tuffe an. Die Korngröße der Tuffe und das Fehlen jeglicher permokarboner, vulkanischer Abfolgen in Namibia läßt auf einen Transport der Aschen über größere Distanzen schließen. Saure Aschen könnten bei vorherrschenden südwestlichen Windrichtungen von Südamerika, wo saurer Inselbogenmagmatismus im Permokarbon bekannt ist, nach Südafrika und Namibia transportiert worden sein. Ein zweites, lokaleres Herkunfts-gebiet der Aschentuffe könnte innerhalb einer kontinentalen Riftzone am Westrand des südlichen Afrikas gelegen haben. Sie ist im Oberkarbon durch allgemein nord-südgerichtete Eisstromrichtungen im Aranos und Karasburg Becken (Südnamibia) und im Perm durch die marinen Ablagerungen der Whitehill Formation (Ecca Gruppe) angedeutet. Altersbestimmungen an den juvenilen Zirkonen ermöglichten sowohl eine neue Zeiteinschätzung der Entgletscherungssequenzen II - IV innerhalb der Dwyka Gruppe als auch eine zeitliche Neukali-brierung der Dwyka-/Ecca Grenze. Datierte Zirkone aus Tuffen des Ganigobis Shale Members ergaben SHRIMP-Alter von 302 - 300 Ma. Damit fallen der oberste Bereich der zweiten Entgletscherungssequenz und die in den marinen enthaltenen Fossilien in das Oberkarbon (Gzelian). Das Alter des Topbereichs der dritten Entgletscherungssequenz (297 Ma) wurde an Zirkonen einer tuffitischen Schicht aus der Provinz Westkap in Südafrika bestimmt. Die dort aufgeschlossenen Ablagerungen korrelieren mit dem Hardap Shale Member im Aranos Becken Süd-namibias und sind Teil der weltweit bekannten Eurydesma - Transgression. Das Alter der Dwyka / Ecca-Grenze wurde an juvenilen Zirkonen von Tuffen der basalen Prince Albert Formation (Ecca Gruppe) in der Provinz Westkap (Südafrika) bestimmt. Die U-Pb - Messungen an den Zirkonen ergaben Alter von 289 - 288 Ma, die die Dwyka / Ecca-Grenze bei circa 290 Ma festlegen.

The study of the subsurface flow and distribution of water is critical to the evaluation of the unsaturated zone for a potential geologic high-level radioactive waste repository. This site is located at Yucca Mountain, Nevada in the northern Mojave Desert. and was chosen on the basis of its low precipitation, deep unsaturated zone, and layered volcanic rocks providing the potential for natural hydraulic barriers to reduce the downward percolation of water through the waste storage area. The detailed characterization of hydrologic properties is necessary to evaluate the mechanisms responsible for the distribution and flow of water in the unsaturated zone. Analyses in this study have provided detailed hydrogeologic units with unique hydrologic properties and hydraulic parameters. Porosity was determined to be a useful physical property for predicting hydraulic parameters, as it relates to the largescale deterministic processes that created the volcanic rocks. The detailed property dataset, along with field measurements of moisture status, temperature, and chemistry, were used to evaluate the potential for lateral diversion in the rocks above the potential repository. It was determined that lateral diversion is a small-scale process in this natural system. On the basis of analyses performed in this study, it is suggested that large-scale diversion is not likely to occur at this site. This mechanism should not, therefore, be relied upon to perform as a natural hydraulic barrier to flow reducing percolation through the unsaturated zone. / Graduation date: 2002

Denna studie undersökte vad 17 föräldrar som deltog i TUFF-utbildning (teckenspråks- utbildning för föräldrar) ansåg vara viktigt/motiverande för att delta i teckenspråksutbildning. Forskningsansatsen som ramar in undersökningen är aktionsforskning och undersökningens design är en mixad metodstudie där mätinstrumenten är enkät, intervju med hjälp av intervjuguide och utvärderingsblankett. Samtliga föräldrar som deltog hade en annan språklig och kulturell bakgrund än svensk och var anmälda till en alternativ utbildning som planerades och genomfördes som ett samarbete mellan SPSM (Specialpedagogiska Skolmyndigheten) i Västra Regionen, Nordiska Folkhögskola (anordnare av TUFF, teckenspråksutbildning för föräldrar) och Kulturföreningen "mitt i det interkulturella mötet", som förkortas m.i.m och har sitt säte i Göteborg. Resultatet visar att det finns sex olika områden som bedöms som viktiga av föräldrarna för att delta i teckenspråksutbildning och att dessa omfattar sociokulturella och allmänna aspekter. Viktigast är att få teckenspråkundervisning som är anpassad till barnet/ungdomens situation och utvecklingsnivå, att få ta del av samhällsinformation som gäller personer i behov av teckenspråk (TSP) eller TAKK (Tecken som Alternativ och Kompletterande Kommunikation)och att få diskutera hur man bör göra med modersmålet med barn/ungdomar i behov av TSP/TAKK. I studien analyseras också om kursplanerna för den reguljära och den alternativa TUFF-utbildningen, i något avseende avspeglar de aspekter som föräldrarna anser är viktiga. / TAKK för Språket

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Geological evidence suggests large-scale continental extension during the breakup of the eastern Gondwana margin was the predominant force controlling rifting of New Caledonia from the eastern Gondwana margin and formation of the Tasman Sea in the Late Cretaceous. Tectonic models suggest slab-rollback forces elongated and thinned the crustal lithosphere detaching crustal fragments from the Gondwana margin. Current tectonic models lack detailed timing and placement of this crustal detachment with respect to New Caledonia based on lack of evidence (rocks). An isotope and paleomagnetic study was carried out on a bi-modal assemblage of volcanic rock exposed on the southwest side of New Caledonia in the Nouméa Basin. U/Pb isotope ages of zircon grains found within siliceous volcanic rock in the Nouméa Basin provide temporal evidence that volcanism persisted both before and after the breakup of the eastern Gondwana Continent (100-90 Ma) in the Late Cretaceous. Four isotope ages >97 Ma and a series (11 samples) ranging from 91-76 Ma constrain the siliceous volcanism of the Nouméa Basin to the Late Cretaceous. A paleomagnetic inquiry utilizing statistics of both McFadden/Reid and Fisher carried out on 16 Nouméa Basin siliceous and mafic in situ formations place the oldest volcanic units found within the Nouméa Basin at 650 S latitude as New Caledonia began to separate from Gondwana (~100 Ma). The data suggests a well-developed arc signature in the region, which persisted for at least 15 Ma in the Late Cretaceous. Compared to current tectonic models of the southwest Pacific Region from the Late Cretaceous to Eocene, our data suggests New Caledonia was further south on the eastern Gondwana supercontinent prior to rifting in the Late Cretaceous than current models. / Geologic background -- Tectonic setting -- Methods -- Sampling -- Results -- Discussion. / Department of Geological Sciences