The purpose of this study is to investigate the origin, source characteristics, evolution petrogenesis and emplacement mechanisms of Beypazari-Oymaaga&ccedil / granitoids. These granitoids are intruded into a metamorphic basement and nonconformably overlain by Neogene clastic rocks. Field work, petrographical and geochemical studies are carried out to determine the petrologic features and tectonic setting of the granitoid body. The Beypazari-Oymaaga&ccedil / pluton is a composite pluton with its host batholith, enclaves, aplite dykes and a pegmatite. The batholith is generally composed of quartz, K-feldspar, plagioclase and hornblende. Field observations and petrographic investigations indicate that the host batholith has granodiorite composition and shows distinct differences in the abundances of quartz, amphibole minerals (e.g., hornblende) and of enclaves. The samples taken from TavuktaSi Tepe contain relatively less amphibole and enclaves but more quartz. Compared with them, samples from the rest of the batholith have relatively abundant amphibole, K-feldspar megacrysts, and enclaves but less quartz. Enclaves derived from magma mixing/mingling processes are dioritic in composition. Geochemical data obtained from whole rock analyses show that the pluton is shallowly emplaced and has calc-alkaline, metaluminous to peraluminous chemistry. It is characterized by enrichments in LIL and LREE, especially in K, Rb and Th. Although, there is a distinct petrographic variation in the batholith, the geochemical characteristics are uniform throughout the pluton. The Oymaaga&ccedil / Granitoids which have I-type identity are typical representatives of magmatic arc environment. The present study suggests that the possible source of magma is the upper crust and can be compared with the coeval volcanism in Galatean Volcanic Arc.

xvii, 106 p. : ill., maps. A print copy of this thesis is available through the UO Libraries. Search the library catalog for the location and call number. / This dissertation establishes the age, depositional environment, composition, and climatic conditions for the Cape Blanco flora. The paleotemperature estimated by the Cape Blanco flora, the Temblor flora of California, and the Seldovia flora of Alaska are then compared with sea surface temperatures estimated from oxygen isotope analysis of benthic foraminifera. The unconformity-bound shallow marine sandstone of Floras Lake includes a redeposited tuff bed which contains fossil leaves at Cape Blanco. An 40 Ar/ 39 Ar age of 18.26 ± 0.86 Ma is presented for the tuff as well as a paleomagnetic stratigraphy of the sandstone. Sedimentary structures of the tuff bed are evidence that the tuff was deposited at or just above the strand line. The depth of tuff deposition was shallower than the adjacent marine sands, and this short-lived shoaling may have been a result of increased sediment supply. The fossil flora was an oak forest with numerous species of Fagaceae. Additional components include lanceolate Salicaceae leaves, entire margined Lauraceae, fragmentary Betulaceae, and lobed Platanaceae. Coniferous debris, charcoal, Equisetales, and Typhaceae forms are also figured. Ten leaf forms could not be confidently assigned to established names but are described, figured, and called angiosperm forms 1-10. In total 44 unique forms are identified. The size and margin type of the dicot specimens are quantified, and by comparison with known modern floras, a former mean annual precipitation of 201 (+86, -61) cm and a former mean annual temperature of 18.26 ± 2.6°C are estimated. The paleotemperature of the ∼17.5 Ma Seldovia Flora and the ∼17.5 Ma Temblor Flora are estimated using the same method, establishing a ∼0.7°C per degree of latitude temperature gradient for the northern hemisphere temperate zone. The leaf based gradient is steeper than the sea surface temperature gradient, of ∼0.26°C per degree of latitude as estimated from oxygen isotopic composition of foraminifera collected from ocean sediment cores. Both fossil leaf and isotope methods suggest that the early Miocene was ∼5°C warmer than today. This thesis includes unpublished co-authored material. / Committee in charge: Gregory Retallack, Chairperson, Geological Sciences; Rebecca Dorsey, Member, Geological Sciences; Joshua Roering, Member, Geological Sciences; Barbara Roy, Outside Member, Biology

Two mid-Miocene (16.5-15 Ma) rhyolite volcanic centers in eastern Oregon, the Buchanan rhyolite complex and Dooley Mountain rhyolite complex, were investigated to characterize eruptive units through field and laboratory analysis. Results of petrographic and geochemical analysis add to field observations to differentiate and discriminate the eruptive units. Additionally, new geochemical data are used to correlate stratigraphically younger and older basalt and ash-flow tuff units with regional eruptive units to constrain the eruptive periods with modern Ar-Ar age dates. Previous work at the Buchanan rhyolite complex was limited to regional mapping (Piper et al., 1939; Greene et al., 1972) and brief mention of the possibility of multiple eruptive units (Walker, 1979). Observed stratigraphic relationships and geochemical analysis were used to identify eight distinct eruptive units and create a geologic map of their distribution. Slight differences in trace element enrichment are seen in mantle normalized values of Ba, Sr, P, Ti and Nd-Zr-Hf and are used to differentiate eruptive units. New geochemical analyses are used to correlate the overlying Buchanan ash-flow tuff (Brown and McLean, 1980) and two underlying mafic units to the Wildcat Creek ash-flow tuff (~15.9 Ma, Hooper et al., 2002) and flows of the Upper Steens Basalt (~16.57 Ma, Brueseke et al., 2007), respectively, bracketing the eruptive age of the Buchanan rhyolite complex to between ~16.5 and ~15.9 Ma (Brueseke et al., 2007; Hooper et al., 2002). The Dooley Mountain rhyolite complex was thoroughly mapped by the U.S. Geological Survey (Evans, 1992) and geochemically differentiated in a previous Portland State University M.S. thesis (Whitson, 1988); however, discrepancies between published interpretations and field observations necessitated modern geochemical data and revisions to geologic interpretations. Field and laboratory studies indicate that the Dooley Mountain rhyolite complex consists of multiple eruptive units that were effusive domes and flows with associated explosive eruptions subordinate in volume. At least four geochemically distinct eruptive units are described with variations in Ba, Sr, Zr and Nb. Picture Gorge Basalt flows and Dinner Creek Tuff units found within the study area both overlay and underlie the Dooley Mountain rhyolite complex. These stratigraphic relationships are consistent with the one existing Ar-Ar age date 15.59±0.04 Ma (Hess, 2014) for the Dooley rhyolite complex, bracketing the eruptive period between ~16.0 and ~15.2 Ma (Streck et al., 2015; Barry et al., 2013). The findings of this study indicate that the Buchanan rhyolite complex and the Dooley Mountain rhyolite complex are the westernmost and northernmost rhyolite complexes among the earliest (16-16.5 Ma) mid-Miocene rhyolites associated with initiation of Yellowstone hot spot related volcanism.

Lead isotope compositions have been obtained from five major volcanic and intrusive rock suites and several ore deposits on Vancouver Island. Lead, uranium and thorium concentrations and strontium isotope ratios have been obtained for a subset of these samples. The rock suites examined are the Paleozoic Sicker Group, Triassic Karmutsen Formation, Jurassic Island Intrusions and Bonanza Group volcanic rocks, and the Eocene Catface intrusions. Isotope geochemistry of the Sicker Group is consistent with the interpretation that it formed as an island arc. Relatively high 207pb/204pb ratios indicate sediment involvement in the subduction process, which suggests that the Sicker Group formed close to a continent. Buttle Lake ore deposits display decreasingly radiogenic lead isotope ratios with time, suggesting that the associated magmas become increasingly primitive. This supports the hypothesis that these deposits formed during the establishment of rifting in a back-arc environment. Karmutsen Formation flood basalts display isotopic mixing between an ocean island-type mantle source and average crust. Isotopic evidence is used to support a Northern Hemisphere origin for these basalts. Mixing is apparent in the lead and strontium isotope signatures of the Island Intrusions and Bonanza Group volcanic rocks, between depleted mantle and crustal (possibly trench sediments) components. This is consistent with formation of these rocks in an island arc environment. Eocene Catface intrusions have relatively high 207pb/204pb indicating that crustal material was involved in their formation. There are two groups of plutons corresponding to an east belt and west belt classification. Galena from the Zeballos mining camp related to the Eocene Zeballos pluton indicates that the mineralization was derived from the pluton. Galena lead isotope data from Vancouver Island may be interpreted in a general way by comparison with data from deposits elsewhere of known age and origin. No single growth curve model can be applied. Lead isotope characteristics of Vancouver Island are clearly different from those of the North American craton, reflecting the oceanic affinities of this terrane. A new technique has been developed to compare 207pb/204pb ratios between samples with differing 206pb/204pb ratios. The procedure projects 207pb/204pb ratios along suitable isochrons until they intersect a reference value of 206pb/204pb. This technique can be used for interpreting lead isotope data from old terranes, in which lead and uranium may have undergone loss or gain, and if lead and uranium abundances have not been measured. / Science, Faculty of / Earth, Ocean and Atmospheric Sciences, Department of / Graduate

Rhyolite lava flows are found at two dome complexes at Graveyard Butte and Gordon Butte, Mount Hood Quadrangle, Oregon. At Graveyard Butte, the White River has cut a winding canyon 150 m deep, exposing at its base, a 40-meter-thick outcrop of flow-banded rhyolite (73 wt.% SiO2, 3.67±0.01 Ma) that laterally extends along the canyon wall for about 1 km. Stratigraphically above the flow-banded rhyolite is locally-erupted iron-rich andesites (lava flows, agglutinate and other pyroclastic rocks as well as clastic debris), a rhyolitic ash-flow tuff (74 wt.% SiO2), and the 2.77±0.36 Ma tholeiitic basalt lava flows of Juniper Flat (Sherrod and Scott, 1995). Roughly 2 km downstream, a phenocryst-poor, maroon-colored rhyolite (3.65±0.01 Ma) is visible again, forming steep canyon walls for about 1.6 km. A compositionally similar silicic unit is found 18 km to the northwest of Graveyard Butte at Gordon Butte. Exposed units along Gordon Butte's Badger Creek (3.64±0.03 Ma) and the southeastern upper slopes of Gordon Butte include rhyolite flows (69.6-72.1 wt.% SiO 2). The rhyolite lava flows at Graveyard Butte and Gordon Butte's Badger Creek are nearly chemically indistinguishable and both contrast with the younger rhyolitic ash-flow tuff at Graveyard Butte and lava flows on Gordon Butte's Upper Slopes. The rhyolites of Graveyard Butte and Badger Creek are richer in Nb and Zr (30-40 ppm and 487-530 ppm, respectively) than the younger rhyolitic tuff and Upper Slopes flows (13-19 ppm and 235-364 ppm, respectively) and share characteristics with A-type granitoids. The rhyolite lavas are porphyritic (~7%) with the porphyroclasts comprising primarily individual feldspars (250-500 µm in length) with ragged margins, oscillatory zoning and less commonly, spongy cores. Other phenocrystic phases include fayalitic olivine, Fe-rich clinopyroxene, and Fe-Ti oxides. A-type-like incompatible trace-element-enriched compositions as well as mineralogical indicators suggest rhyolite lava flows at Graveyard Butte and Gordon Butte's Badger Creek are likely generated in an extensional tectonic setting. A possible geotectonic framework for generation of these rhyolite lavas is the northward propagating intra-arc rift of the Oregon Cascades.

Volcanic rocks typically have only low to moderate arsenic concentrations, none-the-less, elevated levels of arsenic in ground waters have been associated with pyroclastic and volcaniclastic rocks and sediments in many parts of the world. The potential for arsenic leaching from these deposits is particularly problematic as they often comprise important water-bearing units in volcanic terrains. However, the role that chemical and mineralogical variations play in controlling the occurrence and mobility of arsenic from pyroclastic rocks is largely unexplored. This study uses chemical and X-ray diffraction data to characterize and classify 49 samples of ash-flow tuffs, and 11 samples of tuffaceous sediments. The samples exhibit a range of devitrification and chemical weathering. Total and partial digestion, and water extractions of samples are used to determine the total, environmentally available, and readily leachable fractions of arsenic present in all tuff samples. Leaching experiments were also performed with buffered solutions to determine the influence of elevated pH levels on arsenic mobility. The 49 tuff samples have a mean arsenic content of 7.5 mg kg-1, a geometric mean arsenic content of 4.8 mg kg-1, a median arsenic content of 5.2 mg kg-1, and a maximum arsenic concentration of 81 mg kg-1. The mean and median values are 2.8 - 4.4x the average crustal abundance of 1.7 mg kg-1 (Wedepohl, 1995), and consistent with previously reported values for volcanic glasses and felsic volcanic rocks (Onishi and Sandell, 1955; Wedepohl, 1995), although the maximum arsenic content is higher than previously reported (e.g., Casentini et al., 2010; Fiantis et al., 2010; Nobel et al., 2004). In addition, the arsenic concentrations of tuffs were found to be highly heterogenous, both between and within individual units, and in some cases, individual outcrops. Results of whole rock and leachate analyses indicate that there is no significant difference in the total arsenic content of tuffs as a result of devitrification or weathering, but both devitrified and weathered tuffs contain higher levels of environmentally available arsenic than unweathered glassy tuffs. Glassy tuffs did not produce any readily leachable arsenic, while individual devitrified and weathered tuffs both generated aqueous concentrations that exceeded regulatory limits after 18 hours. Leaching of weathered tuffs produced higher levels of arsenic at high (~9-11) pH than in tests conducted at circum-neutral pH. Devitrified and glassy tuffs showed no increase in leachable arsenic with increasing pH. The results of this study indicate that devitrification and weathering processes determine the host phases, degree of adsorption, and overall mobility of arsenic from ash-flow tuffs. Tuffs that have undergone different types of alteration are likely to have different host phases of arsenic, and different mechanisms that mobilize arsenic into the environment. Potential host phases and mobility mechanisms are discussed, and a conceptual model of arsenic behavior in ash-flow tuffs is proposed.

No description available.

Dans le cadre du projet Européen GTS Next, nous avons obtenu des nouvelles contraintes sur l’âge des étages du Crétacé Supérieur à partir de plusieurs techniques de géochronologie et d’interprétations stratigraphiques au Canada et au Japon. Dans le bassin sédimentaire du Western Interior Canada, nous proposons une nouvelle détermination de l’âge de la limite Crétacé - Tertiaire (K/Pg) enregistrée dans la coupe de Red Deer River (Alberta). Il a été possible de calibrer par cyclostratigraphie haute-résolution cette série sédimentaire fluviatile non-marine et d’identifier 11-12 cycles associés à la précession orbitale de la Terre. En considérant la technique 40Ar/39Ar intercalibrée avec la cyclostratigraphie, l’âge apparent de la base du chron magnétique C29r suggère que la limite K/Pg se trouve entre un minimum et un maximum de l’excentricité, avec une durée pour C29r de 66.30 ± 0.08 à 65.89 ± 0.08 Ma. En supposant que le cycle contenant le niveau de charbon soit associé à un cycle de précession, l’âge révisé de la limite Crétacé - Tertiaire est donné par la plus jeune des populations de zircon datée par U-Pb à 65.75 ± 0.06 Ma.La limite Campanien – Maastrichtien est également enregistrée dans ce même bassin canadien, et se trouve à environ 8 m sous le niveau de charbon No. 10 dans la formation de Horseshoe Canyon. L’étude cyclostratigraphique montre que le dépôt de cette séquence sédimentaire est directement influencé par les changements du niveau marin dû à la précession et dominés par l’excentricité Notre travail montre que la position de la limite Campanien – Maastrichtien dans ce bassin sédimentaire du Western Canada est placée à environ 2.5 cycles d’excentricité au dessus d’un niveau de téphra de la base de la coupe dont l’âge U-Pb est donné par la plus jeune population des zircons, et ~4.9 Myr avant la limite Crétacé - Tertiaire. Nous en déduisons un âge absolu de 70.65 ± 0.09 Ma pour la limite Campanien – Maastrichtien, ce qui est ~1.4 Myr plus jeune que les études récemment publiées.Enfin, à partir des isotopes du carbone et des foraminifères planctoniques enregistrés au centre d’Hokkaido (Pacifique Nord-Ouest), les coupes Crétacé du groupe Yezo ont été corrélée avec les séries européennes et nord-américaines. Plusieurs niveaux de téphra prélevés au sein des coupes de Kotanbetsu et Shumarinai ont été datés par les méthodes 40Ar/39Ar and U-Pb. Deux d’entre eux, placés de part et d’autre de la limite Turonien – Coniacien, ont donné des âges de 89.31 ± 0.11 et 89.57 ± 0.11 Ma, ce qui suggère un âge de 89.44 ± 0.24 Ma pour cette limite. En combinant notre résultat avec les âges récemment publiés, nous pouvons proposer un âge de 89.62 ± 0.04 Ma pour la limite Turonien – Coniacien. / As part of the wider European GTS Next project, I propose new constraints on the ages of the Late Cretaceous, derived from a multitude of geochronological techniques, and successful stratigraphic interpretations from Canada and Japan. In the Western Canada Sedimentary Basin, we propose a new constraint on the age of the K/Pg boundary in the Red Deer River section (Alberta, Canada). We were able to cyclostratigraphically tune sediments in a non-marine, fluvial environment utilising high-resolution proxy records suggesting a 11-12 precession related cyclicity. Assuming the 40Ar/39Ar method is inter-calibrated with the cyclostratigraphy, the apparent age for C29r suggests that the K/Pg boundary falls between eccentricity maxima and minima, yielding an age of the C29r between 65.89 ± 0.08 and 66.30 ± 0.08 Ma. Assuming that the bundle containing the coal horizon represents a precession cycle, the K/Pg boundary is within the analytical uncertainty of the youngest zircon population achieving a revised age for the K/Pg boundary as 65.75 ± 0.06 Ma. The Campanian - Maastrichtian boundary is preserved in the sedimentary succession of the Horseshoe Canyon Formation and has been placed ~8 m below Coal nr. 10. Cyclostratigraphic studies show that the formation of these depositional sequences (alternations) of all scales are influenced directly by sea-level changes due to precession but more dominated by eccentricity cycles proved in the cyclostratigraphic framework and is mainly controlled by sand horizons, which have been related by autocyclicity in a dynamic sedimentary setting. Our work shows that the Campanian - Maastrichtian boundary in the Western Canada Sedimentary Basin coincides with ~2.5 eccentricity cycles above the youngest zircon age population at the bottom of the section and ~4.9 Myr before the Cretaceous - Palaeogene boundary (K/Pg), and thus corresponds to an absolute age of 70.65 ± 0.09 Ma producing an ~1.4 Myr younger age than recent published ages. Finally, using advances with terrestrial carbon isotope and planktonic foraminifera records within central Hokkaido, Northwest Pacific, sections from the Cretaceous Yezo group were correlated to that of European and North American counterparts. Datable ash layers throughout the Kotanbetsu and Shumarinai section were analysed using both 40Ar/39Ar and U-Pb methods. We successfully dated two ash tuff layers falling either side of the Turonian - Coniacian boundary, yielding an age range for the boundary between 89.31 ± 0.11 Ma and 89.57 ± 0.11 Ma or a boundary age of 89.44 ± 0.24 Ma. Combining these U-Pb ages with recent published ages we are able to reduce the age limit once more and propose an age for the Turonian - Coniacian boundary as 89.62 ± 0.04 Ma.

In this thesis the pioneer settlement of northern Dalarna is investi­gated by means of a local study of lithic technology and raw material use on the Orsa 527 site in the area. This newly excavated site will be presented, for the first time in completion, in this thesis. The technological traits and raw material distribution on the site, which directly relate to the prehistoric people moving in this area during the Middle Mesolithic, are subsequently put into a larger regional perspective by comparing these results with other Middle Mesolithic sites in northern Dalarna and eastern Norway.             Through the theoretical framework of chaîne opératoire and methods, such as dynamical classification of blades, the study of knapping properties of local raw materials and the study of raw material composition on five other sites in the area, questions regarding cultural transition, mobility and contacts can be discussed.             The results of this work indicate that both technological and raw material parallels exist between eastern Norway and northern Dalarna during the Middle Mesolithic. This places these areas in a larger cultural sphere that was based on contacts and mobility during the pioneer settlement of the area.

Volcanic tuffs and tuffaceous sediments are frequently associated with elevated As groundwater concentrations even though their bulk As contents (~ 5 mg kg-1; Savoie, 2013) are only marginally greater than the average crustal abundance of 4.8 mg g-1 (Rudnick & Gao, 2003). Thus, As mobilization must be facilitated by conditions particular to these rocks. Alkaline desorption, anionic competition, reactive glass dissolution, and reductive dissolution of iron oxides are proposed processes of As release from volcanic rocks. Geogenic As contamination of groundwater in the southern Willamette Valley in western Oregon has been well-documented since the early 1960s, and previous studies have identified the Little Butte Volcanics Series and Fisher and Eugene Formations as the source of As contamination. This study examines 19 samples from 10 units of ash flow tuffs and tuffaceous sediments within the Fisher Formation and Little Butte Volcanics Series, representing a range of weathering and devitrification, to determine conditions of mobilization and mineralogical constraints that control As release into solution. Leachate studies were conducted over a range of pH from 7 to 11, phosphate concentrations from 10 μM to 100 mM, and in time series from 4 to 196 hours. Results demonstrate that silicic volcanic tuffs are capable of mobilizing As in concentrations above regulatory limits at pH conditions produced naturally by the tuffs (pH 8-9) or with moderate concentrations of P (10-100 μM). Alteration products, e.g. zeolites and clays, appear to be the primary host phases for mobile As. Samples that do not contain these alteration products tend to produce concentrations of As well below regulatory limits and often below the instrument detection limits of this study. The type of alteration may influence As mobilization: tuffs containing more clays tend to mobilize As through surficial desorption, and tuffs containing more zeolites tend to mobilize As by dissolution or formation of colloids. Additionally, one volcaniclastic sample demonstrates that extremely elevated concentrations of As, up to 1000 μg/L are possible as a result of oxidative dissolution of As-bearing sulfide phases.