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Yes / Considering the continuous development of sustainable development, energy saving, and emission reduction concepts, it is very important to reduce concrete's cement content in order to improve its environmental impact. Using reactive admixture to replace part of the cement in ultra-high performance concrete (UHPC) can effectively improve the overall performance of the concrete and reduce carbon dioxide emissions (CO2), which is an important aspect of environmental protection. Here, industrial waste residue (fly ash and slag), sea sand (SS), and manufactured sand (MS) were used to produce UHPC under standard curing condition, to reduce the material cost and make the it more environmentally friendly and sustainable. The effects of water-binder ratio, contents of cementitious materials, types of sands, and content of steel fibers on the mechanical performance of UHPC under standard curing were investigated experimentally. In addition, the effects of various factors on the depth under hydraulic pressure and electric flux of UHPC, mass loss, relative dynamic modulus of elasticity, flexural, and compressive strengths of UHPC specimens after freeze-thaw cycles were conducted to evaluate the impermeability, chloride, and freeze-thaw resistance of various UHPCs produced. The obtained experimental results show that the SS-UHPC and MS-UHPC prepared by standard curing exhibit high strength, excellent impermeability, and chloride resistance. The frost resistant grade of all groups of UHPCs prepared by standard curing are greater than F500 and had excellent freeze-thaw resistance, including those produced with local tap water or artificial seawater. The investigation presented in this paper could contribute to the production of new UHPCs of low cost and environmental-friendly and accelerate the application of UHPC in engineering structures.

This thesis presents the results of an effort to quantify the implications of using ultra-high performance concrete (UHPC) for shear walls in tall buildings considering structural efficiency and environmental sustainability. The Lattice Discrete Particle Model (LDPM) was used to simulate the response to failure of concrete shear walls without web steel bar reinforcement under lateral loading and constant axial compressive loading. The structural efficiency of UHPC with simulated compressive strength of f'c = 231 MPa was compared to that of a high-performance concrete (HPC) with f'c = 51.7 MPa simulated compressive strength. UHPC shear walls were found to have equal uncracked stiffness and superior post-cracking capacity at a thickness 58% of the HPC shear wall thickness, and at 59% of the HPC shear wall weight. Next, the environmental sustainability of UHPC with compressive strength f'c = 220-240 MPa was compared to that of an HPC with compressive strength f'c = 49 MPa with a life-cycle assessment (LCA) approach, using SimaPro sustainability software. At a thickness 58% of the HPC shear wall thickness, UHPC shear walls with 0% fiber by volume were found to have an environmental impact 6% to 10% worse than that of HPC shear walls, and UHPC shear walls with 2% fiber by volume were found to have an environmental impact 47% to 58% worse than that of HPC shear walls. The results detailed herein will allow for design guidelines to be developed which take advantage of UHPC response in shear. Additionally, this work may be implemented into topology optimization frameworks that incorporate the potential improvements in structural efficiency and sustainability through using UHPC. / Master of Science

Concrete technology has been in changeful evolution since the Roman Empire time. It is remarkable that the technological progress became of higher magnitude from the second part of the XX Century. Advances in the development of new cements, the appearance of the fibers as a reinforcement for structural applications, and specially the grand progress in the field of the water reducing admixtures enabled the emergence of several types of special concretes. One of the lasts is the Ultra High Performance Fiber Reinforced Concrete (UHPFRC), which incorporates advances of the Self-Compacting Concrete (SCC), Fiber-Reinforced Concrete (FRC) and Ultra High Strength Concrete (UHSC) technology. This exclusive material requires a detailed analysis of the components compatibility and a high control of the materials and processes. Mainly patented products have been used for the few structural elements carried out so far today, but the costs makes doubtful the development of many other potential applications. In accordance with the previously explained, a simplification of the UHPFRC components and processes is needed. This becomes the first main goal of this Ph.D. thesis, which emphasizes in the use of local available components and simpler mixing processes. Moreover, the singular properties of this material, between ordinary concrete and steel, allow not only the realization of slenderer structures, but also the viability of new concepts unthinkable with ordinary concrete. In this field is focused the second part of the Ph.D. thesis, which develops a bolted connection system between UHPFRC elements. This research summarizes, first of all, the subfamilies belonging to the HPC-UHPC materials. Afterwards, it is provided a detailed comparison between the dosage and properties of more than a hundred of mixtures proposed by several authors in the last ten years of technology. This becomes a useful tool to recognize correlations between dosages and properties and validate or no preconceived ideas about this material. Based on this state of art analysis was performed the later development of mixtures, on Chapter 4, which analized the effect of use of simpler components and processes on the UHPFRC. The main idea was use local components available in the Spanish market, identifying the combinations that provide the best rheological and mechanical properties. Steam curing use was avoided since a process simplification is intended. Diferent dosages were developed to be adapted to various levels of performance, and always trying to be as economical as possible. The concretes designed were selfcompacting and mainly combined two fiber types (hybrid), as the flexural performance was of greater relevance. The compressive strength obtained varied in the range between 100 and 170 MPa (cube L=100 mm), and the flexural strength between 15 and 45 MPa (prism 100 x 100 x 500 mm). Some of the components introduced are very rarely used in UHPFRC, as limestone coarse aggregate or FC3R, a white active residue from the petrol industry. As a result of the research, some simple and practical tips are provided for designers of UHPFRC dosage. At the end of this chapter, five dosages are characterized as examples of useful concretes for different requirement applications. In a second part, the idea of a bolted joint connection between UHPFRC elements was proposed. The connection system would be especially useful for struts and ties elements, as truss structures. The possible UHPFRC failure modes were introduced and two different types of tests were designed and performed to evaluate the joint capacity. The geometry of the UHPFRC elements was modified in order to correlate it with the failure mode and maximum load reached. Also a linear finite element analysis was performed to analyze the UHPFRC elements connection. This supported the results of the experimental tests to deduce formulations that predict the maximum load for each failure mode. Finally, a real size truss structure was assembled with bolted joints and tested to verify the good structural behavior of these connections. To conclude, some applications designed and developed at the Universitat Politècnica de València with the methods and knowledge acquired on UHPFRC are abstracted. In many of them the material was mixed and poured in a traditional precast concrete company, providing adequate rheological and mechanical results. This showed the viability of simpler UHPFRC technology enabling some of the first applications in Spain with this material. / Camacho Torregrosa, EE. (2013). Dosage optimization and bolted connections for UHPFRC ties [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/34790

Yes / Considering the continuous development of sustainable development, energy saving, and emission reduction concepts, it is very important to reduce concrete's cement content in order to improve its environmental impact. Using a reactive admixture to replace part of the cement in ultra-high-performance concrete (UHPC) can effectively improve the overall performance of the concrete and reduce carbon dioxide emissions, which is an important aspect of environmental protection. Here, industrial waste residue (fly ash and slag), sea sand (SS), and manufactured sand (MS) were used to produce UHPC under standard curing conditions to reduce the material cost and make it more environmentally friendly and sustainable. The effects of water-binder ratio, contents of cementitious materials, types of sands, and content of steel fibers on the mechanical performance of UHPC under standard curing were investigated experimentally. In addition, evaluations of the impermeability, chloride, and freeze-thaw resistance of various UHPCs produced were conducted by investigating the effects of various factors on the depth under hydraulic pressure and electric flux of UHPC, as well as the mass loss, relative dynamic modulus of elasticity, flexural strength, and compressive strength of UHPC specimens after freeze-thaw cycles. The obtained experimental results show that the SS-UHPC and MS-UHPC prepared by standard curing exhibit high strength, excellent impermeability, and chloride resistance. The frost-resistant grade of all groups of UHPCs prepared by standard curing was greater than F500 and had excellent freeze-thaw resistance, including those produced with local tap water or artificial seawater. The investigation presented in this paper could contribute to the production of new low-cost and environmentally friendly UHPCs and accelerate the application of UHPC in engineering structures.

Yes / Super-fine stainless wires (SSWs) with micron diameter and large specific surface area can simultaneously strengthen and toughen reactive powder concrete (RPC) at low volume fraction, so SSW reinforced RPC composites have potential for developing infrastructures bearing fatigue load or with aseismic requirements. In this paper, the uniaxial compressive fatigue characteristics of such composites under high stress levels were investigated, and the modification mechanisms of SSWs to RPC were revealed through failure state and microstructure analyses. The results showed that incorporating only 0.5 vol.% SSWs into RPC enables the fatigue life and energy dissipation capacity to increase by 252.0% and 262.3%, meanwhile, the fatigue limit strength of composites at the failure probability of 50% reaches up to 76.6% of static uniaxial compressive strength, due to the improvement effect on microstructure compactness, inhibiting effect on flaw initiation, and the ability to convert single main crack into radial multiple micro cracks centered on SSWs. Furthermore, the average maximum fatigue strain and residual strain of composites are improved by 73.7% and 87.2%, respectively, which can be ascribed to the bridging, debonding and being pulled-off effect of SSWs. It can be therefore concluded that the incorporation of SSWs endows RPC with excellent fatigue performance, thus further enlarging the application of composites. / The authors would like to thank the National Science Foundation of China (51908103 and 51978127), and the China Postdoctoral Science Foundation (2019M651116) for providing funding to carry out this investigation.

Yes / The development of ultra-high performance cementitious composite (UHPCC) represents a significant advancement in the field of concrete science and technology, but insufficient hydration and high autogenous shrinkage relatively increase the pores inside UHPCC, in turn, affecting the macro-performance of UHPCC. This paper, initially, optimized the pore structure of UHPCC using different types and dimensions of nanofillers. Subsequently, the pore structure characteristics of nano-modified UHPCC were investigated by the mercury intrusion porosimeter method and fractal theory. Finally, the fluid permeability of nano-modified UHPCC was estimated by applying the Katz-Thompson equation. Experimental results showed that all incorporated nanofillers can refine the pore structure of UHPCC, but nanofillers with different types and dimensions have various effects on the pore structure of UHPCC. Specifically, CNTs, especially the thin-short one, can significantly reduce the porosity of UHPCC, whereas nanoparticles, especially nano-SiO2, are more conducive to refine the pore size. Among all nanofillers, nano-SiO2 has the most obvious effect on pore structure, reducing the porosity, specific pore volume and most probable pore radius of UHPCC by 31.9%, 35.1% and 40.9%, respectively. Additionally, the pore size distribution of nano-modified UHPCC ranges from 10-1nm to 105nm, and the gel pores and fine capillary pores in the range of 3-50nm account for more than 70% of the total pore content, confirming nanofillers incorporation can effectively weaken pore connectivity and induce pore distribution to concentrate at nanoscale. Fractal results indicated the provision of nanofillers reduces the structural heterogeneity of gel pores and fine capillary pores, and induces homogenization and densification of UHPCC matrix, in turn, decreasing the UHPCC fluid permeability by 15.7%-79.2%. / National Science Foundation of China (51978127, 52178188 and 51908103), the China Postdoctoral Science Foundation (2022M720648 and 2022M710973) and the Fundamental Research Funds for the Central Universities (DUT21RC(3)039).

Yes / This paper numerically investigates flexural performance of Ultra-High Performance Concrete (UHPC) beam reinforced with Steel-Fibre-Reinforced Polymer (FRP) Composite Bars (SFCBs) in terms of flexural stiffness, moment capacity, deflection, ductility and energy dissipation. The effect of various parameters, include the inner steel core area ratio of SFCB, yield strength of inner steel core, elastic modulus and ultimate strength of outer-wrapped FRP, reinforcement ratio, type and strength of concrete were studied. The results demonstrate that the inner steel core area ratio of SFCB, reinforcement ratio and the elastic modulus of SFCB's outer FRP have significant effect on the overall flexural performance of SFCB reinforced UHPC beam. The overall flexural performance of SFCB reinforced UHPC beam is slightly improved by increasing the yield strength of inner steel core of SFCB, but not affected by the ultimate strength of SFCB's outer FRP when specimen occurred compression failure. The results also exhibit that the flexural performance of UHPC beam reinforced with SFCBs is significantly improved when compared to those of reinforced high strength concrete (HSC) beam and normal strength concrete (NSC) beam. The flexural stiffness and the moment capacity of SFCB reinforced UHPC beam at the ultimate point were 2.0 and 2.4 times, respectively, of those of reinforced NSC counterpart. / Natural Science Foundation of Jiangsu Province, China (BK20201436), the China Postdoctoral Science Foundation (2018M642335), the Science and Technology Project of Jiangsu Construction System, China (2018ZD047, 2021ZD06), the Science and Technology Project of Gansu Construction System, China (JK2021-19), the National Natural Science Foundation of China (51678514), the Science and Technology Innovation Fund of Yangzhou University, China (2020-65), the Open Foundation of Jiangsu Province Engineering Research Center of Prefabricated Building and Intelligent Construction, China (2021), the Science and Technology Cooperation Fund Project of Yangzhou City and Yangzhou University, China (YZU212105), the Practice and Innovation Plan for Postgraduates in Jiangsu Province, China (SJCX21_1589), the Blue Project Youth Academic Leader of Colleges and Universities in Jiangsu Province, China (2020) and the Deputy General Manager Science and Technology Project of Jiangsu Province, China (FZ20200869). References