<p> Fission-product bromine was isolated from a uranium target by the hot-atom reaction of the fission recoils with methane to form organic bromides. The organically-bound bromine was shown to be formed preferentially by primary (independently-formed) bromine with little contribution from secondary bromine. </p> <p> The delayed-neutron activity of the short-lived bromine isotopes was analyzed to obtain the relative yields of delayed neutrons from Br8?, Br88 and Br89 produced as primary fission products. The relative delayed-neutron yields are summarized below. (see abstract in text) </p> / Thesis / Doctor of Philosophy (PhD)

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The coordination- and organometallic chemistry of uranium complexes bearing the non-carbocyclic ancillary ligand XA2 (4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene) has been developed as a major focus of this thesis. A number of air-sensitive actinide chloro complexes and alkyl derivatives featuring reactive An–C bonds were prepared, and investigated using a variety of structural and spectroscopic analytical techniques, including X-ray diffraction, NMR spectroscopy, elemental analysis, and electrochemical methods. The research described in this thesis serves to expand the currently underdeveloped, fundamental chemistry of actinide complexes supported by non-carbocyclic (i.e. non-cyclopentadienyl) ligands. For example, the use of the prototypical xanthene-based ligand XA2 has led to neutral dialkyl uranium(IV) complexes which a) react with alkyl anions to yield anionic trialkyl ‘ate’ complexes, b) C–H activate neutral pyridines to yield organouranium(IV) species featuring cyclometalated pyridine-based ligands, and c) react with Lewis acids to yield rare examples of cationic monoalkyl uranium(IV) complexes featuring coordinated arene ligands. By altering the nature of the arene solvent/ligand, latent catalytic ethylene polymerization behaviour has also been unlocked in cationic XA2 uranium and thorium complexes, and this development may offer industrial relevance. Additionally, new NON-donor ligand designs featuring bulky terphenyl-based substituents (the "XAT" ligand) as well as 1-adamantyl groups (the "XAd" ligand) have been developed; a family of crystallographically-characterized dipotassium XAT complexes have been prepared which feature unprecedented potassium–alkane interactions, and the XAd ligand has been employed for the development of new organometallic thorium chemistry. The developments described in this thesis contribute to an emerging field and delineate new reactivities and structural motifs, providing important steps forward in organoactinide chemistry. / Thesis / Doctor of Philosophy (PhD)

The ranges and stragglings of fission fragments from the thermal neutron fission of U-235 have been measured. Particular attention was given to the preparation of very thin uranium sources, the design of a well collimated recoil system and the preparation of the fragment catcher. The ranges and range distributions in aluminum of fission products of mass numbers 95, 140, 141 and 147 have been obtained. The range values obtained agree with previous determinations within the experimental error. The refined techniques developed in this work have enabled differential range distributions to be obtained which are more precise than any previous determinations. / Thesis / Master of Science (MSc)

Thesis. 1976. M.S.--Massachusetts Institute of Technology. Dept. of Earth and Planetary Sciences. / Microfiche copy available in Archives and Science. / Bibliography: leaves 26-27. / M.S.

The role of structure and tectonics in the formation of hydrothermal ore deposits and the localization of high-grade mineralization associated with fractures is well documented. In this study we have characterized the structural setting associated with uranium mineralization in the Coles Hill uranium deposit by relating the observed metamorphic and structural features (mylonitic foliation and fractures) to regional tectonic activity. Drill cores and outcrops observed in this study show that NE/SW oriented fractures appear to be related to Mesozoic movement along the Chatham Fault. NW/SE oriented fractures cross cut and offset the NE/SW oriented fractures by1 to 2 cm and therefore post-date the NE/SW oriented fractures. NW/SE fracture orientations and parallel to the NW/SE regional cross faults and are suggested to relate to the formation of the cross faults during post Triassic basin inversion. Uranium mineralization is located within horizontal to shallowly dipping fractures suggesting uplift and erosion to form possible tension veins. The cross faults with NW/SE orientations created pathways in which uranium bearing hydrothermal fluids could migrate from the Triassic basin shales westward into the adjacent highly fractured crystalline rocks, precipitating uranium due to oxidation-reduction reactions. / Master of Science

THEREDA (Thermodynamic Reference Database) is a collaborative project, which has been addressed this challenge. The partners are Helmholtz-Zentrum Dresden-Rossendorf, Karlsruhe Institute of Technology (KIT-INE), Gesellschaft für Anlagen- und Reaktorsicherheit Braunschweig mbH (GRS), TU Bergakademie Freiberg (TUBAF) and AF-Consult Switzerland AG (Baden, Switzerland). The aim of the project is the establishment of a consistent and quality assured database for all safety relevant elements, temperature and pressure ranges, with its focus on saline systems. This implied the use of the Pitzer approach to compute activity coefficients suitable for such conditions. Data access is possible via commonly available internet browsers under the address http://www.thereda.de. One part of the project - the data collection and evaluation for uranium – was a task of the Helmholtz-Zentrum Dresden-Rossendorf. The aquatic chemistry and thermodynamics of U(VI) and U(IV) is of great importance for geochemical modelling in repository-relevant systems. The OECD/NEA Thermochemical Database (NEA TDB) compilation is the major source for thermodynamic data of the aqueous and solid uranium species, even though this data selection does not utilize the Pitzer model for the ionic strength effect correction. As a result of the very stringent quality demands, the NEA TDB is rather restrictive and therefore incomplete for extensive modelling calculations of real systems. Therefore, the THEREDA compilation includes additional thermodynamic data of solid secondary phases formed in the waste material, the backfill and the host rock, though falling into quality assessment (QA) categories of lower accuracy. The data review process prefers log K values from solubility experiments (if available) to those calculated from thermochemical data.