O mapeamento detalhado de uma área de ocorrência de rochas vulcânicas na borda sul da Provincia Magmática Paraná Etendeka (PMPE), entre as cidades de Gramado Xavier e Barros Cassal, RS, permitiu estabelecer a relação estratigráfica de três sequências vulcânicas ácidas geradas por eventos eruptivos associados a magmas-tipo quimicamente distintos. A sequência Caxias do Sul corresponde à primeira manifestação de vulcanismo ácido e é formada por diversos fluxos de lava e lava-domos, emitidos de forma continua, sem intervalos significativos entre as erupções, o que resultou em um espesso pacote de até 140 m de espessura. O final do magmatismo se deu de forma intermitente, com a deposição de arenito entre os últimos derrames. Estas rochas têm composição dacítica (68-70% SiO2) e textura inequigranular hipohialina afanítica a fanerítica fina, sendo compostas por microfenocristais (<2,3 mm) e micrólitos de plagioclásio (\'An IND.55-67\"), piroxênios (hiperstênio, pigeonita e augita) e Ti-magnetita imersos em matriz vítrea ou desvitrificada. Modelos de fracionamento sugerem que seu magma parental pode ter evoluído a partir de um líquido fracionado de basaltos tipo Gramado. As assinaturas geoquímicas e isotópicas (\'ANTPOT.87 Sr\'/\'ANTPOT.86 \'Sr\'IND.(i)\' 0,7192-0,7202) indicam que a evolução pode ter ocorrido em um sistema fechado, com participação, ao menos localmente, de um contaminante crustal mais oxidado. Estima-se que, previamente à erupção, apresentavam temperaturas próximas ao liquidus, de 980-1000ºC, 2% de H2O, fO2 \'10 POT.10,4\' bar, e devem ter residido em reservatórios localizados na crosta superior, a P~3 kbar. Um evento de recarga na câmara pode ter disparado o início da ascensão, que ocorreu com um gradiente dP/dT de 100bar/ºC e velocidades de 0,2 a 0,5 cm \'s POT.-1\' , propiciando a nucleação e crescimento de feno e microfenocristais. O magma teria alcançado a superfície a temperaturas de ~970ºC e viscosidades de \'10 POT.4\' a \'10 POT .5\' Pa.s. A segunda sequência vulcânica, aqui denominada Barros Cassal, é composta por diversos fluxos de lavas andesito basálticas, andesíticas e dacíticas (54-56; 57-58 e 64-66% SiO2, respectivamente), com frequentes intercalações de arenito, que atestam o comportamento intermitente deste evento. Estas rochas apresentam uma textura hipohialina a hipocristalina afanítica a fanerítica fina, cor preta a cinza escura e proporções variadas de vesículas e amígdalas. Todas são compostas por microfenocristais (<0,75 mm) de plagioclásio, augita e Ti-magnetita subédricos, anédricos ou esqueléticos, imersos em matriz vítrea ou desvitrificada. As assinaturas isotópicas das rochas que compõem esta sequência (e.g., \'ANTPOT.87 Sr\'/\'ANTPOT.86 \'Sr\' IND.(i)\' = 0,7125-0,7132) encontram-se dentro do campo dos basaltos toleíticos tipo Gramado, que pode ter sido o magma parental a partir do qual derivaram por cristalização fracionada. Estimativas baseadas nas condições de equilíbrio cristal-líquido indicam que os magmas mais evoluídos da sequência Barros Cassal, de composição dacítica, apresentavam temperaturas de 990 a 1010 ºC, 1,4 a 1,8% de H2O e viscosidades de \'10 POT.4\' Pa.s. As pequenas dimensões dos cristais e cálculos barométricos indicam que a cristalização se deu durante a ascensão, entre 2 e 3 km de profundidade (0,5 a 0,7 kbar de pressão), enquanto o magma ascendia a uma velocidade de 0,12 cm \'s POT.-1\' . Com o fim deste evento vulcânico, desenvolveu-se regionalmente uma expressiva sedimentação imatura (espessura >10 m) de arenitos arcosianos e conglomerados. O último evento vulcânico corresponde à sequência Santa Maria, composta por fluxos de lava e formação de lava domos de composição riolítica (70-73% SiO2), que atingiram espessuras totais de 150 a 400 m. Na base ocorrem feições de interação lava-sedimento (peperitos) e autobrechas (formadas na base e carapaça dos derrames, que constituem lobos nas porções mais distais). Obsidianas bandadas e outras feições indicativas de fluxo coerente são características da unidade. No centro da pilha, a sequência de riolitos constitui uma camada mais monótona de rochas dominantemente cristalinas com marcante disjunção vertical que correspondem à parte central de corpos de lava-domos, no topo predominam as disjunções horizontais. Estas rochas contém < 6% de fenocristais e microfenocristais (<1,2 mm) de plagioclásio (An40-60), Ti- magnetita e pigeonita imersos em matriz vítrea ou cristalina (maciça ou bandada) com até 20% de micrólitos. Modelos de fracionamento são consistentes com modelos em que o magma parental do riolito Santa Maria teria composição similar ao dacito Barros Cassal. As variações nas razões \'ANTPOT.87 Sr\'/\'ANTPOT.86 \'Sr\'ind.(i)\' (0,7230-0,7255) sugerem evolução em sistema aberto, envolvendo contaminação crustal. O magma teria evoluído em câmaras magmáticas localizadas a <12 km de profundidade (<3 kbar), a temperaturas entre 970 e 1000ºC, com fO 2 de ~\'10 POT.10-11\' bar e até 1% de H2O. A cristalização, que se iniciou dentro do reservatório, teria prosseguido durante a ascensão, que ocorreu em gradientes dP/dT de 100 bar/ºC e velocidades médias de 0,2 cm \'s POT.-1\' . O processo de nucleação de micrólitos ocorreu quando o magma ultrapassou o limite de solubilidade a 200 bar de pressão, apresentando temperaturas de 940-950ºC e viscosidades de \'10 POT.5\' a \'10 POT.7\' Pa.s. A alimentação por condutos fissurais, associada a altas taxas de extrusão, teriam elevado a tensão cisalhante próximo às paredes do conduto, gerando bandamentos com distintas concentrações de água. As bandas hidratadas funcionaram como superfícies de escorregamento, diminuindo a viscosidade efetiva, favorecendo a desgaseificação e aumentando a eficiência do transporte do magma desidratado até a superfície. A identificação de estruturas associadas à efusão de lavas, como dobras de fluxo, fluxos lobados, auto-brechas, além da identificação de estruturas de lava domos, contraria interpretações que propõem origem dominantemente piroclástica para o vulcanismo ácido na região, a partir de centros efusivos localizados em Etendeka, na África. / The detailed mapping of an area in the southern edge of the Paraná Etendeka Magmatic Province (PEMP), between the cities of Gramado Xavier and Barros Cassal, Rio Grande do Sul, Brazil, revealed three stratigraphic sequences generated by silicic volcanic eruptions associated to chemically distinct magma-types. The Caxias do Sul sequence corresponds to the first volcanic manifestation of silicic magmatism in the PMPE. It consists of several lava flows and lava domes which erupted continuously, without significant gaps between the events, and resulted in a thick deposit of up to 140 m. The deposition of layers of sandstone between the last lava flows show the intermittent ending of this volcanic event.. These rocks present dacitic composition (~68 wt% SiO2) and hipohyaline to phaneritic texture with microphenocrysts (<2.3 mm) and microlites of plagioclase (\'An IND.55-67\'), pyroxene (hypersthene, pigeonite and augite) and Ti-magnetite surrounded by vitreous or devitrified matrix. The fractionation models suggest that their parental magma may have evolved from a liquid which fractionated from Gramado-type basalts. Geochemical and isotopic signatures ( \'ANTPOT.87 Sr\'/\'ANTPOT.86 \'Sr\' IND.(i)\' 0.7192 to 0.7202) indicate that evolution may have occurred in a closed system, with the participation, at least locally, of a more oxidized crustal contaminant. It is estimated that prior to the eruption the magma might have reached a near-liquidus temperature (980-1000°C), with 2%H2O, fO2 \'10 POT.10.4\' bar, in the reservoirs located in the upper crust, at P~3 kbar. A recharge event in the camera may have triggered the ascension, which occurred with a dP/dT gradient of 100bar/°C and speeds from 0.2 to 0.5 cm.\'s POT.-1\' , leading to nucleation and growth of pheno and microphenocrysts. The magma may have reached the surface at a temperature of ~970 °C and viscosity of \'10 POT.4\' -\'10 POT.5\' Pa.s. The second volcanic sequence, Barros Cassal, is composed of several andesite basaltic, andesitic and dacitic lava flows (54-56, 57-58 and 64-66% SiO2, respectively), with frequent intercalations of sandstone, proving the intermittent behavior of this event. These rocks present aphanitic hipohyaline to hipocrystaline phaneritic texture, black to dark gray color and varied proportions of vesicles. They are all composed of microphenocrysts (<0.75 mm) of plagioclase, augite and subhedral, anhedral or skeletal Ti-magnetite, immersed in glassy or devitrified matrix. The isotopic signatures of the rocks that make up this sequence (eg. \'ANTPOT.87 Sr\'/\'86 ANTPOT. \'Sr IND.(i)\' = 0.7125 to 0.7132) are within the field of tholeiitic Gramado- type basalts, which may have been the parental magma from which they derived by fractional crystallization. Estimates based on the conditions of crystal-liquid equilibrium indicate that the most evolved magmas of the Barros Cassal Sequence, of dacitic composition, reached a temperature of 990-1010°C, 1.4 to 1.8% H2O, and viscosity of \'10 POT.4\' Pa.s. The small size of the crystals and the barometric models indicate that crystallization occurred during the rise, between 2 and 3 km depth (0.5 to 0.7 kbar pressure), while the magma ascended at a speed of 0.12 cm \'s POT.-1\' . With the end of this volcanic event, a significant immature sedimentation (thickness> 10 m) of feldspathic sandstone and conglomerates developed regionally. The last sequence corresponds to Santa Maria, composed of lava flows and lava domes of rhyolitic composition (70-73% SiO2). These deposits can be 150-400 m thick. Features as lava-sediment interaction (peperites) and autobreccias (formed at the base of the flows, which are lobated in the more distal portions) are common in the base of the volcanic pile. banded obsidian and other distinctive features of effusive flows are common in this unit. In the center of the stack, a more monotonous body flow predominates, with hipocrystalline textures and vertical disjunction (corresponding to the central portion of the lava dome). on the top, horizontal disjunctions predominate. These rocks contain <6 % of microphenocrysts and phenocrysts (<1.2 mm) of plagioclase (\'An IND.40-60\'), Ti-magnetite and up to 20% of pigeonite microlites. all these mineral phases occur immersed in glassy or crystalline (massive or banded) matrix. The fractionation models are consistent with models in which the parental magma of the Santa Maria rhyolite and the dacites of Barros Cassal Sequence have similar composition. Variations in \'ANTPOT.87 Sr\'/\'ANTPOT.86\'Sr IND.(i)\' (0.7230 to 0.7255) suggest open-system evolution, involving crustal contamination. The magma might have evolved into dacitic composition in magma chambers located at a depth of <12 km (< 3 kbar), at temperatures between 970 and 1000°C, fO2 of ~\'10 POT.10\'-\'10 POT.11\' bar and 1% of H2O. The crystallization began in the reservoir and might have continued during the ascent, which occurred in dP/dT gradients of 100 bar/°C, with average speeds of 0.2 cm s -1 . The microlites nucleation process occurred when the magma exceeded the solubility limit at 200 bar and displayed a temperature of 940-950°C and viscosity of 10 5 -10 7 Pa.s. The feeding through fissure conduits, associated to high- rate extrusion, might have increased the shear stress near the conduit walls, generating banding with different concentrations of water. Hydrated bands acted as slip surfaces, decreasing the effective viscosity, favoring degassing and increasing the efficiency of transport of dry magma to the surface. The identification of structures associated with lava effusion - like folds of flow, lobed flows, autobreccias, as well as lava dome structures - contradicts the current interpretation, which proposes one single pyroclastic origin, eruptive centers located in Etendeka, Africa, for all deposits of silicic composition in the PEMP.

A series of late Tertiary rhyolitic and dacitic flows, domes, and minor pyroclastic rocks form an elongate volanic mass along the northwestern Utah-northeastern Nevada border . The structure of the flow banding and the linear arrangement of vents indicate that the mass represents a multi-sourced extrusive complex which erupted through many fissure-type conduits. A 39 km2 area at the southern end of the mass was studied in detail in order to gain a better understanding of the eruptive nature and history of these Tertiary volcanic rocks. Age dating reveals that volcanism in the study area was episodic, and covered a period of at least 4 to 5 million years. The silicic volcanic rocks in the study area are similar chemically and mineralogically to other eruptive units within the Rhyolite Mts., which range from dacite (Si0 2 69%) to high-silica rhyolite (SiOz 75-77%). They also exhibit chemical characteristics similar to other silicic volcanic rocks of bimodal association in the western United States. Two-feldspar high-K rhyolite is the dominant volcanic rock in the study area, commonly found overlying rhyolitic vitric tuffs and agglomerates. Rhyolite from the southern portion of the study area is dated at 7.6 to 8.6 m.y.b.p. Dacitic samples contain phenocrysts of plagioclase, quartz, biotite, hornblende, and orthopyroxene. Dacitic volcanism is dated at 12.4 m.y.b.p. By analogy with other "bimodal" volcanic fields in the western U.S., it is assumed that these si 1 icic magmas are products of partial melting of crustal rocks. Evidence from a least squares differentiation model, along with the overall geochemical characteristics, indicates crystal fractionation as the dominant mechanism for the transition from dacite to rhyolite, with plagioclase as the dominant fractionating phase.

As técnicas de sensoriamento remoto têm se mostrado fundamentais como ferramenta auxiliar no mapeamento geológico básico. O avanço tecnológico gerado pelos novos sensores permite o desenvolvimento de técnicas mais apuradas na integração de dados litológicos e estruturais de várias fontes. Este trabalho buscou avaliar a potencialidade das imagens do sensor ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer) para identificação dos diferentes litotipos da área do Cerro Chato, em especial as unidades vulcânicas e hipabissais relacionadas. O Cerro Chato é caracterizado como uma feição geomorfológica situada à cerca de 15 km ao norte do município de Herval, na microrregião denominada Serra do Sudeste na porção sudeste do estado do Rio Grande do Sul. É constituído principalmente por uma seqüência de rochas efusivas e piroclásticas de composição riolítica relacionada a sistemas do tipo alta-sílica, vinculadas ao magmatismo granítico tardio do Batólito Pelotas. O objetivo deste trabalho foi testar e avaliar diversas técnicas de geoprocessamento buscando a diferenciação litológica, a identificação de alvos e a definição de morfoestruturas da área do Cerro Chato. O processamento utilizando a técnica de Transformação por Componentes Principais forneceu os melhores resultados realçando diferenças entre as rochas vulcânicas e hipabissais e as rochas encaixantes. Foram selecionadas as CP2 das imagens CP's 2, 3 e 5 na geração de uma composição colorida que permitiu delimitar três principais domínios de ocorrências das rochas de origem vulcânica no Cerro Chato. / The remote sensing techniques have been a very important and auxiliary tool to basic geological mapping. The new orbital sensors carried out a technologic increment that possibility the development of refined methods applied in the integration with diverse geologic data as petrology and structural. In this work were utilized images obtained from the ASTER sensor (Advanced Spaceborne Thermal Emission and Reflection Radiometer) to identify the lithologies in the Cerro Chato area, giving emphasis to the volcanic and hypabissal units. The Cerro Chato can be characterized as geomorphologic feature situated about 15 km to north of Herval town, in the Southeast Sierra micro region of the Rio Grande do Sul state, southernmost Brazil. It is constituted mainly by an effusive and pyroclastic rocks sequence of rhyolitic composition related to high silica systems, which magma has been associated to the younger granitic magmastim of the Pelotas Batholith. The main objective of this work was to test and evaluate diverse techniques of geoprocessment to try identifying different lithologic units and morphologic structures in the Cerro Chato area. The selective principal component analysis technique was used in the digital image processing, because it provided the best results enhancing the existent spectral differences between volcanic and country rocks. In this processing were selected the PC's2 images of the PC's 2, 3, and 5 to generated a color composite image that permitted the individualization of three main dominions of volcanic rocks in the Cerro Chato.

As técnicas de sensoriamento remoto têm se mostrado fundamentais como ferramenta auxiliar no mapeamento geológico básico. O avanço tecnológico gerado pelos novos sensores permite o desenvolvimento de técnicas mais apuradas na integração de dados litológicos e estruturais de várias fontes. Este trabalho buscou avaliar a potencialidade das imagens do sensor ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer) para identificação dos diferentes litotipos da área do Cerro Chato, em especial as unidades vulcânicas e hipabissais relacionadas. O Cerro Chato é caracterizado como uma feição geomorfológica situada à cerca de 15 km ao norte do município de Herval, na microrregião denominada Serra do Sudeste na porção sudeste do estado do Rio Grande do Sul. É constituído principalmente por uma seqüência de rochas efusivas e piroclásticas de composição riolítica relacionada a sistemas do tipo alta-sílica, vinculadas ao magmatismo granítico tardio do Batólito Pelotas. O objetivo deste trabalho foi testar e avaliar diversas técnicas de geoprocessamento buscando a diferenciação litológica, a identificação de alvos e a definição de morfoestruturas da área do Cerro Chato. O processamento utilizando a técnica de Transformação por Componentes Principais forneceu os melhores resultados realçando diferenças entre as rochas vulcânicas e hipabissais e as rochas encaixantes. Foram selecionadas as CP2 das imagens CP's 2, 3 e 5 na geração de uma composição colorida que permitiu delimitar três principais domínios de ocorrências das rochas de origem vulcânica no Cerro Chato. / The remote sensing techniques have been a very important and auxiliary tool to basic geological mapping. The new orbital sensors carried out a technologic increment that possibility the development of refined methods applied in the integration with diverse geologic data as petrology and structural. In this work were utilized images obtained from the ASTER sensor (Advanced Spaceborne Thermal Emission and Reflection Radiometer) to identify the lithologies in the Cerro Chato area, giving emphasis to the volcanic and hypabissal units. The Cerro Chato can be characterized as geomorphologic feature situated about 15 km to north of Herval town, in the Southeast Sierra micro region of the Rio Grande do Sul state, southernmost Brazil. It is constituted mainly by an effusive and pyroclastic rocks sequence of rhyolitic composition related to high silica systems, which magma has been associated to the younger granitic magmastim of the Pelotas Batholith. The main objective of this work was to test and evaluate diverse techniques of geoprocessment to try identifying different lithologic units and morphologic structures in the Cerro Chato area. The selective principal component analysis technique was used in the digital image processing, because it provided the best results enhancing the existent spectral differences between volcanic and country rocks. In this processing were selected the PC's2 images of the PC's 2, 3, and 5 to generated a color composite image that permitted the individualization of three main dominions of volcanic rocks in the Cerro Chato.

Foram realizadas medidas de espectroscopia gama simples, de espectroscopia gama-gama em anti-coincidência e coincidência em dezessete amostras de rochas vulcânicas irradiadas com nêutrons térmicos. Foram determinadas, utilizando cálculo covariante, 33 elementos químicos (Al, As, Ba, Ca, Ce, Cl, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mg, Mn, Na, Nd, Rb, Sb, Sc, Sm, Sr, Ta, Tb, Th, Ti, U, Yb, Zn e Zr), dos quais 21 elementos traço. Foi determinado o limite máximo de detecção para o irídio em 11 amostras. Foi obtido um valor máximo de 0,7 ppb. Os resultados foram comparados com o processo astrofísico de formação da Terra. A concentração de urânio e tório variou entre 3 ppm e 9 ppm, com exceção das amostras de Kilimanjaro, que variou entre 40 ppm e 45 ppm. Abaixo da concentração de 12 ppm presentes na crosta terrestre. Espera-se concentrações menores devido a estimativas de tório e urânio através do calor emitido pela Terra. Foram determinados 10/17 lantanídeos, com destaque para a abundância de Ce em Kilimanjaro, cujos valores obtidos foram de 272 (6) ppm e 319 (11) ppm. / Single gamma ray spectroscopy, gama-gama coincidence and anticoincidence spectroscopy have been performed to study 17 volcanic rocks irradiated with neutrons. We have determined, using covariant calculations, 33 chemical elements including 21 trace elements: Al, As, Ba, Ca, Ce, Cl, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mg, Mn, Na, Nd, Rb, Sb, Sc, Sm, Sr, Ta, Tb, Th, Ti, U, Yb, Zn e Zr. We set a maximum limit of detection for iridium in 11 samples. We have determined a maximum value of 0,7 ppb. The results were associated to the astrophysical process that led to the Earth formation. Thorium and uranium abundance ranged between 3 ppm e 9 ppm, except for the samples of Kilimanjaro, which ranged from 40 ppm to 45 ppm. Less than 12 ppm, the Earth\'s Crust abundance of thorium and uranium. Using the heat emitted by Earth to estimate the abundance of them led to significant lower values. We have also determined 10/17 lanthanides, like Ce that has an abundance of 272 (6) ppm and 319 (11) ppm, in the case of Kilimanjaro\'s samples.

As técnicas de sensoriamento remoto têm se mostrado fundamentais como ferramenta auxiliar no mapeamento geológico básico. O avanço tecnológico gerado pelos novos sensores permite o desenvolvimento de técnicas mais apuradas na integração de dados litológicos e estruturais de várias fontes. Este trabalho buscou avaliar a potencialidade das imagens do sensor ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer) para identificação dos diferentes litotipos da área do Cerro Chato, em especial as unidades vulcânicas e hipabissais relacionadas. O Cerro Chato é caracterizado como uma feição geomorfológica situada à cerca de 15 km ao norte do município de Herval, na microrregião denominada Serra do Sudeste na porção sudeste do estado do Rio Grande do Sul. É constituído principalmente por uma seqüência de rochas efusivas e piroclásticas de composição riolítica relacionada a sistemas do tipo alta-sílica, vinculadas ao magmatismo granítico tardio do Batólito Pelotas. O objetivo deste trabalho foi testar e avaliar diversas técnicas de geoprocessamento buscando a diferenciação litológica, a identificação de alvos e a definição de morfoestruturas da área do Cerro Chato. O processamento utilizando a técnica de Transformação por Componentes Principais forneceu os melhores resultados realçando diferenças entre as rochas vulcânicas e hipabissais e as rochas encaixantes. Foram selecionadas as CP2 das imagens CP's 2, 3 e 5 na geração de uma composição colorida que permitiu delimitar três principais domínios de ocorrências das rochas de origem vulcânica no Cerro Chato. / The remote sensing techniques have been a very important and auxiliary tool to basic geological mapping. The new orbital sensors carried out a technologic increment that possibility the development of refined methods applied in the integration with diverse geologic data as petrology and structural. In this work were utilized images obtained from the ASTER sensor (Advanced Spaceborne Thermal Emission and Reflection Radiometer) to identify the lithologies in the Cerro Chato area, giving emphasis to the volcanic and hypabissal units. The Cerro Chato can be characterized as geomorphologic feature situated about 15 km to north of Herval town, in the Southeast Sierra micro region of the Rio Grande do Sul state, southernmost Brazil. It is constituted mainly by an effusive and pyroclastic rocks sequence of rhyolitic composition related to high silica systems, which magma has been associated to the younger granitic magmastim of the Pelotas Batholith. The main objective of this work was to test and evaluate diverse techniques of geoprocessment to try identifying different lithologic units and morphologic structures in the Cerro Chato area. The selective principal component analysis technique was used in the digital image processing, because it provided the best results enhancing the existent spectral differences between volcanic and country rocks. In this processing were selected the PC's2 images of the PC's 2, 3, and 5 to generated a color composite image that permitted the individualization of three main dominions of volcanic rocks in the Cerro Chato.

Several hundred chemical analyses of early Proterozoic lavas of the Witwatersrand triad (incorporating the Dominion Group, Witwatersrand Supergroup and Ventersdorp Supergroup) in the Klerksdorp area, have revealed the presence of various distinct magma types. These essentially correspond to formally defined lithostratigraphic units, but several inconsistencies have necessitated the use of informal nomenclature. The lavas have been regionally metamorphosed to low-grade, greenschist facies assemblages. Original igneous textures are preserved, despite a metamorphic overprint. Metamorphism has resulted in a certain degree of random chemical remobilization. Ba, Sr, Rb, K₂0, Na₂0 and CaO have been highly mobile, and their usefulness in petrogenetic modelling is extremely limited. In contrast, Zr, Nb, Y, LREE's, Cr, Ni, Ti0₂ P₂0₅ and Al₂0₃ have remained immobile. Ti/Zr and Ti/P ratios together constitute efficient discriminating variables for characterizing the different magma types. Lava compositions range from primitive Mg-rich tholeiites to rhyolites, the bulk being tholeiitic andesites. Al₂0₃ contents do not exceed 15%, a feature which reflects the tholeiitic, as opposed to calcalkaline, character of these lavas. Two magma-types are present within the Dominion Group, which is a typical example of bimodal volcanism. The Dominion basic lavas are overlain by the Dominion acid porphyries, with a limited amount of interfingering. The basic lava suite is highly fractionated, with compositions ranging from Mg-, Cr- and Ni-rich tholeiites (close to primary mantle melts) to evolved tholeiitic andesites. The most primitive liquids evolved by 45% fractional crystallization of hornblende, followed by a further 70% crystallization of an orthopyroxene-plagioclase assemblage containing up to 3% sulphides. The Dominion porphyries are rhyolitic, display very limited compositional variation, and probably represent a crustal melt related to the same magmatic event which produced the basic lavas. The only lavas from the Witwatersrand Supergroup present in the Klerksdorp area are those of the Crown Formation (Jeppestown amygdaloid). These are tholeiitic dacites which display extremely limited compositional variation, and are unrelated to any of the other magmas of the Witwatersrand triad. The Ventersdorp Supergroup comprises 4 magma-types: The Kliprivierberg Group lavas at the base are subdivisible into 3 sub-types on the basis of Zr contents. (Zr>11Oppm) are the most evolved. They are tholeiitic andesites which display fairly limited compositional variation. It is likely that more evolved compositions are present in other areas where the porphyritic lavas which characterize this unit are better developed. The overlying Orkney lavas are characterized by 110ppm>Zr>90ppm. They are tholeiitic andesites of similar composition to the Alberton lavas, but have lower incompatible element levels, higher siderophile element levels, and are of extremely uniform composition. The uppermost Loraine/Edenville lavas range from magnesian tholeiites to tholeiitic andesites. They are distinguished by Zr< 90ppm, and contain the most primitive magmas af the Witwatersrand triad, with up to 17,5% MgO, 2600ppm Cr, 600ppm Ni and M-values up to 77. The most primitive liquids evolved by 38% fractional crystallization of orthopyroxene ∓ chromite, followed by 35% fractional crystallization of an extract containing clinopyroxene and plagioclase. The absence of olivine precipitation is a result of the inherently high Si0₂ content of the magma. The Loraine/Edenville, Orkney and Alberton lavas do not lie on a common liquid line of descent, but are probably consanguinous. The Platberg Group overlies the Kliprivierberg Group, and has a coarse-clastic sedimentary unit, the Kameeldoorns Formation, at the base. Three petrographically distinct porphyritic lava sequences overlie the Kameeldoorns Formation, namely the informal "Goedgenoeg formation", the Makwassie quartz-feldspar porphyries and the Rietgat Formation. Despite petrographic differences, the Goedgenoeg and Rietgat lavas are chemically indistinguishable and thus form a single magma-type. The Makwassie porphyries are dacitic in composition with a high proportion of feldspar and quartz phenocrysts. Rational variation trends are attributed to a nett loss of Si0₂ during secondary alteration. The porphyries are probably of crustal origin. The Goedgenoeg/Rietgat lavas display unusual chemistry and a broad, irrational compositional spectrum. They contain very high incompatible element levels, high nonnative quartz, as well as high MgO, M-values, Cr and Ni relative to the other tholeiitic andesites of the Witwatersrand triad. It is tentatively suggested that they are hybrid magmas containing both crust and mantle components, the former possibly represented by the Makwassie porphyries. Field evidence suggests that Platberg volcanism commenced directly after Klipriviersberg volcanism ceased, and was accompanied by a period of enhanced tectonic activity. The Platberg lavas thus probably reflect a crustal melting cycle associated with the Klipriviersberg magmatic event. The Allanridge lavas are the youngest rocks of the Witwatersrand triad. They are separated from the Platberg Group by a unit of flat-lying sediments, the Bothaville Formation, which was deposited after an extended period of peneplanation. The Allanridge lavas form a separate magma-type. They are tholeiitic andesites of similar composition to the Alberton lavas, but have higher incompatible element levels and are not consanguinous. The compositional similarities amongst the basic magma-types of the Witwatersrand triad suggests that all were generated in an hydrous mantle. Interelement ratio differences between the various magma-types nevertheless support the concept that the mantle was chemically heterogeneous during the early Proterozoic.

Several volcanic flows lie between Death Creek and Dairy Valley Creek, near Etna, Utah. The major, central portion of the volcanic flows is composed of dacite and dacite vitrophyre. An elongate ridge in the southeastern corner of the study area and several small outcrops in Death Creek Valley are composed of rhyolite and rhyolite vitrophyre. Additional rock types include conglomerate, volcanic ash, and tuffaceous sedimentary rock of the Tertiary Salt Lake Formation, Paleozoic limestone, and Tertiary basalt. Dacite and dacite vitrophyre samples are porphyritic, containing phenocrysts of plagioclase, quartz, biotite, amphibole, orthopyroxene, and iron-titanium oxides. Rhyolite and rhyolite vitrophyre samples are porphyritic, containing phenocrysts of plagioclase, alkali feldspar, quartz, and iron-titanium oxides, with minor amounts of biotite and amphibole. Plagioclase phenocrysts are complexly twinned, zoned, and corroded in dacitic samples; whereas, they are simply twinned, unzoned, and uncorroded in rhyolitic samples . Quartz and alkali feldspar phenocrysts contain glass-filled inclusions and are subrounded in rhyolitic samples. Average chemical analyses of five dacitic sample yield weight percent: SiO2, 69.11; TiO2, 0.31; Al2O3, 14.18; Fe2O3, 1.26; FeO, 1.23; MnO, 0.04; MgO, 0.54; CaO, 2.27; Na2O, 3.30; K2O, 4.07; P2O5, 1.23; H2O+, 1.89; H2O-, 0.46; total, 99.27. Average chemical analyses of three rhyolitic samples yield weight percent: SiO2, 76.66; TiO2, 0.12; Al2O3, 11.80; Fe2O3, 0.58; FeO, 0.43; MnO, 0.01; MgO, 0.09; CaO, 0.78; Na2O, 2.69; K2O, 5.26; P2O5, 0.02; H2O+, 1.17; H2O-, 0.22; total, 99.85. The volcanic flows of the study area are believed to be derived from fusion of sialic material within the crust which differentiated to form dacite and rhyolite. The dacite is believed to be the first magma extruded in the study area; whereas, the rhyolite represents the later extruded magma. Evidence supporting this relative emplacement is the restriction of rhyolite to the southeastern corner of the study area and the intrusion of rhyolite into dacite in the narrows of Death Creek Valley. The volcanic flows of the study area are believed to have been derived during the second stage of Basin and Range volcanism beginning approximately 14 million years ago. The study area rhyolite has chemical compositions similar to those rhyolites of bimodal basalt-rhyolite fields formed during the second stage of Basin and Range volcanism which includes high silica contents, higher alkali to calcium ratios, and greater sodium contents compared with rhyolite of calc-alkalic fields.

Basalt flows occur in the Snowville area of north-central Utah and the Table Mountain and Holbrook areas of south-central Idaho. All basalt flows are aphanitic in groundmass, and contain olivine, plagioclase, augite, and opaque oxides. They can be distinguished by texture. Snowville basalt has predominantly subophitic to intergranular textures. Table Mountain basalt is fine grained, with stumpy groundmass plagioclase and equant ilmenite crystals. Holbrook basalt has pilotaxitic to intergranular textures, with the presence of plagioclase phenocrysts and characteristic exsolution lamellae in Fe-Ti oxides. The olivine grains in Holbrook area are intensely oxidized to Fe-Ti oxides. Snowville basalt contains olivine phenocrysts (Fo88 -Fo44 ) in a groundmass of olivine (Fo63 -Fo47), augite (Wo42 -Wo36), and plagioclase (An77-An52). The lower flow unit of Table Mountain basalt contains olivine phenocrysts (Fo88-?) in a groundmass of augite (Wo44 En44 Fs17), and plagioclase (An58-An48). The upper flow unit of Table Mountain basalt has olivine phenocrysts (Fo82-Fo65), plagioclase phenocrysts (An73-An67), and plagioclase groundmass (An64-An55). The Holbrook basalt is composed of olivine phenocrysts (Fo67-Fo57)and plagioclase phenocrysts (An68-An43 ) in a groundmass of olivine (Fo59Fos53) augite (Wo39 En44 Fs17), and plagioclase (An67-An35). The basalts of the Snowville and Holbrook areas, represent petrographic, mineralogical, and chemical characteristics of both olivine-tholeiitic basalt and alkali-olivine basalt, whereas Table Mountain upper and lower flow units show their affinity with alkali-olivine basalt. Chemically, basalts from these three areas are consistently high in silica, magnesium, and alkali content. The Snowville basalt has a high Ba content and high strontium isotope ratio. Fractional crystallization models indicate that the basalt flows from the three different areas are genetically unrelated. The testing also suggests that the upper and lower flow units of the Table Mountain area are not genetically related. The basalts of the three areas also can not be evolved from the basalts found at Kelton, the Rozel Hills or Black Mountain. Basalts of the Snowville area have consistently higher magnesium and silica contents than Snake River basalt, Kelton area basalt, and Rozel Hills and Black Mountain basalt, indicating that they may represent what was initially a very primitive basaltic lava. High Ba content and strontium isotope ratio indicate that the Snowville basalt was contaminated by crustal material. Table Mountain and Holbrook basalt may have formed as a result of partial melting from a pyrolite or garnet peridotite mantle.

Two basalt flows and an andesite fissure eruption occur in the Rozel Hills - Black Mountain area in Box Elder County, Utah. Both basalt flows are aphanitic, and contain olivine, plagioclase, augite, and opaque oxides. They may be distinguished both chemically and on the basis of their textures. Unit 2 basalt is finer grained, and appears to be associated with a fault in the Black Mountain area. Chemically, it is similar to high-iron lavas in the Craters of the Moon, Idaho area. It has higher alkali, total iron, and titanium contents that Unit 1 basalt. Unit 1 basalt is similar to other tholeiitic basalts in the Basin and Range province. It is coarser-grained and has higher silicon, magnesium, aluminum, and calcium contents than Unit 2 basalt. While the basalts have characteristics of alkali-olivine basalts, such as absence of calcium-poor pyroxene, and a high alkali to silica ratio, both units are hypersthene- and olivine-nonnative and classified as olivine tholeiites. Subsurface basalt in the area appears to represent both lava types, but extensive alteration makes comparison difficult. Andesite from the area is aphanitic, and contains plagioclase, orthopyroxene, and opaque oxides. Temperatures of equilibration calculated from co-existing magnetite and ilmenite range f rom 1148°C to 745°C for basalt. Temperatures calculated from co-existing olivine and clinopyroxene range from 1009°C to 994°C. While the two basalt units cannot be related by fractional crystallization at surface conditions, some parent - daughter relations are likely within each unit, and the andesite is most likely a differentiation product of Unit 1 basalt. Partial melting of pyrolite and spinel lherzolite mantle compositions to produce Unit 1 and Unit 2 basalts was investigated. Since no unique temperature and pressure of equilbration for these melts and residu~l material from each mantle type was found, it is concluded that partial melting of a mantle of pyrolite or spinel lherzolite composition did not produce these lavas. Unit 2 basalt may be derived from Unit 1 basalt by fractionation of high pressure (8 kb) phases. This mechanism, similar to that proposed for the Craters of the Moon - Snake River Plain system, may account for an evolved basalt (Unit 2) with a lower silica content than a less differentiated basalt (Unit 1).