The effects of greenhouse gases have seen a significant rise in recent years due to the use of fossil fuels like gasoline and diesel. Conversion of the energy stored in these fossil fuels to mechanical work is an extremely inefficient process which results in a high amount of energy rejected in the form of waste heat. Thermoelectric materials are able to harness this waste heat energy and convert it to electrical power. Thermoelectric devices work on the principle of the Seebeck effect, which states that if two junctions of dissimilar materials are at different temperatures, an electrical potential is developed across them. Even though these devices have small efficiencies, they are still an extremely effective way of converting low grade waste heat to usable electrical power. These devices have the added advantage of having no moving parts (solid state) which contributes to a long life of the device without needing much maintenance. The performance of thermoelectric generators is dependent on a non-dimensional figure of merit, ZT. Extensive research, both past and ongoing, is focused on improving the thermoelectric generator's (TEG's) performance by improving this figure of merit, ZT, by way of controlling the material properties. This research is usually incremental and the high performance materials developed can be cost prohibitive. The focus of this study has been to improve the performance of thermoelectric generator by way of improving the heat transfer from the exhaust gases to the TEG and also the heat transfer from TEG to the coolant. Apart from the figure of merit ZT, the performance of the TEG is also a function of the temperature difference across it, By improving the heat transfer between the TEG and the working fluid, a higher temperature gradient can be achieved across it, resulting in higher heat flux and improved efficiency from the system. This area has been largely neglected as a source of improvement in past research and has immense potential to be a low cost performance enhancer in such systems. Improvements made through this avenue, also have the advantage of being applicable regardless of the material in the system. Thus these high performance heat exchangers can be coupled with high performance materials to supplement the gains made by improved figure of merits. The heat exchanger designs developed and studied in this work have taken into account several considerations, like pressure drop, varying engine speeds, location of the system along the fuel path, system stability etc. A comprehensive treatment is presented here which includes 3D conjugate heat transfer modeling with RANS based turbulence models on such a system. Various heat transfer enhancement features are implemented in the system and studied numerically as well as experimentally. The entire system is also studied experimentally in a scaled down setup which provided data for validation of numerical studies. With the help of measured and calculated data like temperature, ZT etc, predictions are also presented about key metrics of system performance. / Ph. D.

Wastewater treatment has developed as a mature technology over time. However, conventional wastewater treatment is a very energy-intensive process. Bioelectrochemical system (BES) is an emerging technology that can treat wastewater and also recover resources such as energy in the form of electricity/hydrogen gas and nutrients such as nitrogen and phosphorus compounds. Microbial electrolysis cell (MEC) is a type of BES that, in the presence of an additional voltage, can treat wastewater and generate hydrogen gas. This is a promising approach for wastewater treatment and value-added product generation, though it may not be sustainable in the long run, as it relies on fossil fuels to provide that additional energy. Thus, it is important to explore alternative renewable resources that can provide energy to power MEC. Waste heat is one such resource that has not been researched extensively, particularly at the low-temperature spectrum. This was utilized as a renewable resource by converting waste heat to electricity using a device called thermoelectric generator (TEG). TEG converted simulated waste heat from an anaerobic digester to power an MEC. The feasibility of TEG to act as a power source for an MEC was investigated and its performance compared to the external power source. Various cold sources were analyzed to characterize TEG performance. To explore this integrated TEG-MEC system further, a hydraulic connection was added between the two systems. Wastewater was used as a cold source for TEG and it was recirculated to the anode of the MEC. This system showed improved performance with both systems mutually benefitting each other. The operational parameters were analyzed for the optimization of the system. The integrated system could generate hydrogen at a rate of 0.36 ± 0.05 m3 m-3 d-1 for synthetic domestic wastewater treatment. For the practical application, it is necessary to estimate the cost and narrow the focus on the functions of the system. Techno-economic analysis was performed for MEC with cost estimation and net present value model to understand the economic viability of the technology. The application niche of the BES was described and directions for addressing the challenges towards a full-scale operation were discussed. The present system provides a sustainable method for wastewater treatment and resource recovery which can play an important role in human health, social and economic development and a strong ecosystem. / Doctor of Philosophy / An average person produces about 50-75 gallons of wastewater every day. In addition to the households, wastewater is generated from industries and agricultural practices. As the population increases, the quantity of wastewater production will inevitably increase. To keep our rivers and oceans clean and safe, it is essential to treat the wastewater before it is discharged to the water bodies. However, the conventional wastewater treatment is a very energy (and thus cost) intensive process. For low-income and developing parts of the world, it is difficult to adapt the technology everywhere in its present form. Furthermore, as the energy is provided mostly by fossil fuels, their limited reserves and harmful environmental effects make it critical to find alternative methods that can treat the wastewater at a much lower energy input. For a circular and sustainable economy, it is important to realize wastewater as a resource which can provide us energy, nutrients, and water, rather than discard it as a waste. Bioelectrochemical systems (BES) is an emerging technology that can simultaneously treat wastewater and recover resources in the form of electricity/hydrogen gas, and nitrogen and phosphorus compounds. Microbial electrolysis cell (MEC) is a type of BES that is used to treat wastewater and generate hydrogen gas. An additional voltage is supplied to the MEC for producing hydrogen. In the long run, this may not be sustainable as it relies on fossil fuels to provide that additional energy. Thus, it is important to explore alternative renewable resources that can provide energy to power MEC. Waste heat is a byproduct of many industrial processes and widely available. This was utilized as a renewable resource by converting waste heat to electricity using a device called thermoelectric generator (TEG). TEG converted simulated waste heat from an anaerobic digester to power an MEC. The mutual benefit for MEC and TEG was also explored by connecting the system electrically and hydraulically. Cost-estimation of the system was performed to understand the economic viability and functions of the system were developed. The present system provides a sustainable method for wastewater treatment and resource recovery which can play an important role in human health, social and economic development and a strong ecosystem.

Lately, car manufacturers have been put to a big challenge to reduce the CO2 emission of their entire fleets. Norms of pollutant emissions limit the ways to achieve the desired CO2 emission goals, as some of the solutions that would lead to lower CO2 emission also lead to higher pollutant emission. Waste Heat Recovery (WHR) could be a good solution to lower the CO2 emission of the Internal Combustion Engine (ICE) without increasing the pollutant emission. In the present thesis different WHR strategies are analysed and the results suggested it would be interesting to further study the Brayton cycle machine. Air Brayton Cycle (ABC) represents a way to recover a part of the heat energy of the ICE exhaust gases and transform it into mechanical energy. Recovered mechanical energy would then be returned to the crankshaft of the ICE, thereby reducing the amount of energy that has to be liberated by combustion of fuel which lowers the fuel consumption and CO2 emission. The study of ABC started with an analysis of the ideal cycle in order to obtain the theoretical maximum of the system. The study continued with an analysis of the semi ideal cycle where all losses are taken into account only by two efficiency coefficients. This analysis showed that for the diesel engine efficiency of the ABC is very low because of the low exhaust gas temperature. For the gasoline engine the cycle could be viable when the ICE is working under steady condition and higher load. These conditions could be fulfilled when the vehicle is driven on the highway. Detailed analysis was aimed at determining the cycle main losses. They were determined to be: pumping losses, losses caused by heat transfer and mechanical losses. Taking into account these main losses along with other direct and indirect losses it was concluded that the cycle is not viable for the types of the WHR machines that were considered in this study. In order for the cycle to be viable some other either existing or new machine type should be tested, that would lower the main losses and offer good isentropic and mechanical efficiency for desired conditions. / Últimamente los fabricantes de automóviles se han puesto el gran reto de reducir la emisión de CO2 en la totalidad de sus flotas. Las nuevas normativas para la reducción de las emisiones contaminantes limitan los medios para lograr los objetivos deseados en la emisión de CO2 porque algunas de las soluciones que llevan a la reducción en la emisión de CO2 también dan lugar a un incremento en la emisión de otros contaminantes. La recuperación de calor residual (WHR) podría ser una buena solución para reducir las emisiones de CO2 del motor de combustión interna (ICE) sin poner en peligro la emisión de contaminantes. En la presente Tesis se analizaron diferentes estrategias de WHR y se concluyó que sería interesante estudiar más a fondo la máquina de ciclo Brayton. El Ciclo Brayton de Aire (ABC) permite recuperar una parte del calor de los gases de escape del ICE y transformar este calor en energía mecánica. La energía mecánica recuperada se devuelve al cigüeñal del ICE, reduciendo de ese modo la cantidad de energía que tiene que ser liberada por la combustión del combustible, lo cual permite reducir el consumo de combustible y las emisiones de CO2. En esta Tesis se estudia el ABC mediante un análisis del ciclo ideal con el fin de obtener el máximo teórico del sistema. El modelo se mejora con un análisis del ciclo semi-ideal donde se tienen en cuenta todas las pérdidas mediante el uso de dos coeficientes generales. Este análisis muestra que para el motor diesel la eficiencia del ciclo ABC es muy baja debido a la baja temperatura del gas de escape. Para el motor de gasolina el ciclo podría ser viable cuando el ICE está trabajando bajo condiciones estacionarias y una carga mayor. Estas condiciones se podrían cumplir cuando el vehículo está circulando en autopista. El análisis detallado de este ciclo tiene como objetivo determinar las pérdidas principales de ciclo. Las pérdidas principales se identificaron como: las pérdidas de bombeo, las pérdidas causadas por la transferencia de calor y las pérdidas mecánicas. Teniendo en cuenta estas pérdidas principales junto con otras pérdidas directas e indirectas, se concluyó que el ciclo no es viable para los tipos de máquinas WHR que fueron considerados en este estudio. Para que el ciclo sea viable se tiene que buscar alguna otra máquina existente o un nuevo tipo de máquina que reduzca las principales pérdidas y ofrezca un buen rendimiento isentrópico y mecánico para las condiciones deseadas. / Últimament els fabricants d'automòbils s'han posat el gran repte de reduir l'emissió de CO2 de la totalitat de les seues flotes. Les noves normatives de reducció de les emissions contaminants limiten els mitjans per assolir els objectius desitjats d'emissió de CO2 perquè algunes de les solucions que porten a la reducció en l'emissió de CO2 també donen lloc a un increment a l'emissió de altres contaminants. La recuperació de calor residual (WHR) podria ser una bona solució per reduir les emissions de CO2 del motor de combustió interna (ICE) sense posar en perill l'emissió de contaminants. En la present Tesi s'han analitzat diferents estratègies WHR i es va concloure que seria interessant estudiar més a fons el cicle Brayton. El Cicle Brayton d'Aire (ABC) representa una manera de recuperar una part de la calor dels gasos d'escapament de l'ICE i transformar calor a l'energia mecànica. L'energia mecànica recuperada es retorna al cigonyal de l'ICE reduint d'aquesta manera la quantitat d'energia que ha de ser alliberada per la combustió del combustible permitint la reducció del consum de combustible i les emissions de CO2. En aquesta Tesi s'ha començat estudiant un ABC amb una anàlisi del cicle ideal per tal d'obtenir el màxim teòric del sistema. Este model es millora amb una anàlisi del cicle semiideal on es tenen en compte totes les pèrdues amb tan sols dos coeficients d'eficiència. Aquesta anàlisi va mostrar que per al motor dièsel l'eficiència del cicle ABC és molt baixa a causa de la baixa temperatura del gas d'escapament. Per al motor de gasolina el cicle podria ser viable quan l'ICE està treballant sota condicions estacionàries i una càrrega més gran. Aquestes condicions es podrien complir quan el vehicle està circulant en autopista. L'anàlisi detallada del cicle va tenir com a objectiu determinar les pèrdues principals de cicle. Les pèrdues principals es van identificar com: les pèrdues de bombament, les pèrdues causades per la transferència de calor i les pèrdues mecàniques. Tenint en compte aquestes pèrdues principals juntament amb altres pèrdues directes i indirectes, es va concloure que el cicle no és viable per als tipus de màquines WHR que van ser considerats en aquest estudi. Perquè el cicle puga ser viable s'ha de buscar alguna altra màquina existent o un nou tipus de màquina que puga reduir les principals pèrdues i puga oferir un bon rendiment isentròpic i mecànic per a les condicions desitjades. / Kleut, P. (2016). Recuperation of the exhaust gases energy using a Brayton cycle machine [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/76807

Regulations for ICE-based transportation in the EU seek carbon dioxide emissions lower than 95 g CO2/km by 2020. In order to fulfill these limits, improvements in vehicle fuel consumption have to be achieved. One of the main losses of ICEs happens in the exhaust line. Internal combustion engines transform chemical energy into mechanical energy through combustion; however, only about 15-32% of this energy is effectively used to produce work, while most of the fuel energy is wasted through exhaust gases and coolant. Therefore, these sources can be exploited to improve the overall efficiency of the engine. Between these sources, exhaust gases show the largest potential of Waste Heat Recovery (WHR) due to its high level of exergy. Regarding WHR technologies, Rankine cycles are considered as the most promising candidates for improving Internal Combustion Engines. However, the implementation of this technology in modern passenger cars requires additional features to achieve a compact integration and controllability in the engine. While industrial applications typically operates in steady state operating points, there is a huge challenge taking into account its impact in the engine during typical daily driving profiles. This thesis contributes to the knowledge and characterization of an Organic Rankine Cycle coupled with an Internal Combustion Engine using ethanol as working fluid and a swash-plate expander as expansion machine. The main objective of this research work is to obtain and quantify the potential of Organic Rankine Cycles for the use of residual energy in automotive engines. To do this, an experimental ORC test bench was designed and built at CMT (Polytechnic University of Valencia), which can be coupled to different types of automotive combustion engines. Using these results, an estimation of the main variables of the cycle was obtained both in stationary and transient operating points. A potential of increasing ICE mechanical efficiency up to 3.7% could be reached at points of high load installing an ORC in a conventional turbocharged gasoline engine. Regarding transient conditions, a slightly simple and robust control based on adaptive PIDs, allows the control of the ORC in realistic driving profiles. High loads and hot conditions should be the starting ideal conditions to test and validate the control of the ORC in order to achieve high exhaust temperatures that justify the feasibility of the system. In order to deepen in the viability and characteristics of this particular application, some theoretical studies were done. A 1D model was developed using LMS Imagine.Lab Amesim platform. A potential improvement of 2.5% in fuel conversion efficiency was obtained at the high operating points as a direct consequence of the 23.5 g/kWh reduction in bsfc. To conclude, a thermo-economic study was developed taking into account the main elements of the installation costs and a minimum Specific Investment Cost value of 2030 €/kW was obtained. Moreover, an exergetic study showed that a total amount of 3.75 kW, 36.5% of exergy destruction rate, could be lowered in the forthcoming years, taking account the maximum efficiencies considering technical restrictions of the cycle components. / Las normativas anticontaminantes para el transporte propulsado por motores de combustión interna alternativos en la Unión Europea muestran límites de emisión menores a 95 g CO2/km para el año 2020. Con el fin de cumplir estos límites, deberán ser realizadas mejoras en el consumo de combustible en los vehículos. Una de las principales pérdidas en los Motores de Combustión Interna Alternativos (MCIA) ocurre en la línea de escape. Los MCIA transforman la energía química en energía mecánica a través de la combustión; sin embargo, únicamente el 15-32% de esta energía es eficazmente usada para producir trabajo, mientras que la mayor parte es desperdiciada a través de los gases de escape y el agua de refrigeración del motor. Por ello, estas fuentes de energía pueden ser utilizadas para mejorar la eficiencia global del vehículo. De estas fuentes, los gases de escape muestran un potencial mayor de recuperación de energía residual debido a su mayor contenido exergético. De todos los tipos de Sistemas de Recuperación de Energía Residual, los Ciclos Rankine son considerados como los candidatos más prometedores para mejorar la eficiencia de los MCIA. Sin embargo, la implementación de esta tecnología en los vehículos de pasajeros modernos requiere nuevas características para conseguir una integración compacta y una buena controlabilidad del motor. Mientras que las aplicaciones industriales normalmente operan en puntos de operación estacionarios, en el caso de los vehículos con MCIA existen importantes retos teniendo en cuenta su impacto en el modo de conducción cotidianos. Esta Tesis contribuye al conocimiento y caracterización de un Ciclo Rankine Orgánico acoplado con un Motor de Combustión Interna Alternativo utilizando etanol como fluido de trabajo y un expansor tipo Swash-plate como máquina expansora. El principal objetivo de este trabajo de investigación es obtener y cuantificar el potencial de los Ciclos Rankine Orgánicos (ORC) para la recuperación de la energía residual en motores de automoción. Para ello, una instalación experimental con un Ciclo Rankine Orgánico fue diseñada y construida en el Instituto Universitario "CMT - Motores Térmicos" (Universidad Politécnica de Valencia), que puede ser acoplada a diferentes tipos de motores de combustión interna alternativos. Usando esta instalación, una estimación de las principales variables del ciclo fue obtenida tanto en puntos estacionarios como en transitorios. Un potencial de mejora en torno a un 3.7 % puede ser alcanzada en puntos de alta carga instalando un ORC en un motor gasolina turboalimentado. Respecto a las condiciones transitorias, un control sencillo y robusto basado en PIDs adaptativos permite el control del ORC en perfiles de conducción reales. Las condiciones ideales para testear y validar el control del ORC son alta carga en el motor comenzando con el motor en caliente para conseguir altas temperaturas en el escape que justifiquen la viabilidad de estos ciclos. Para tratar de profundizar en la viabilidad y características de esta aplicación particular, diversos estudios teóricos fueron realizados. Un modelo 1D fue desarrollado usando el software LMS Imagine.Lab Amesim. Un potencial de mejora en torno a un 2.5% en el rendimiento efectivo del motor fue obtenido en condiciones transitorias en los puntos de alta carga como una consecuencia directa de la reducción de 23.5 g/kWh del consumo específico. Para concluir, un estudio termo-económico fue desarrollado teniendo en cuenta los costes de los principales elementos de la instalación y un valor mínimo de 2030 €/kW fue obtenido en el parámetro de Coste Específico de inversión. Además, el estudio exergético muestra que un total de 3.75 kW, 36.5 % de la tasa de destrucción total de exergía, podría ser reducida en los años futuros, teniendo en cuenta las máximas eficiencias considerando restricciones técnicas en los componentes del ciclo. / Les normatives anticontaminants per al transport propulsat per motors de combustió interna alternatius a la Unió Europea mostren límits d'emissió menors a 95 g·CO2/km per a l'any 2020. Per tal d'acomplir aquests límits, s'hauran de realitzar millores al consum de combustible dels vehicles. Una de les principals pèrdues als Motors de combustió interna alternatius (MCIA) ocorre a la línia d'escapament. Els MCIA transformen l'energia química en energia mecànica a través de la combustió; però, únicament el 15-32% d'aquesta energia és usada per produir treball, mentre que la major part és desaprofitada a través dels gasos d'escapament i l'aigua de refrigeració del motor. Per això, aquestes fonts d'energia poden ser utilitzades per millorar l'eficiència global del vehicle. Considerant aquestes dues fonts d'energia, els gasos d'escapament mostren un potencial major de recuperació d'energia residual debut al seu major contingut exergètic. De tots els tipus de Sistemes de Recuperació d'Energia Residual, els Cicles Rankine són considerats com els candidats més prometedors per millorar l'eficiència dels MCIA. No obstant, la implementació d'aquesta tecnologia en els vehicles de passatgers moderns requereix un desenvolupament addicional per aconseguir una integració compacta i una bona controlabilitat del motor. Mentre que les aplicacions industrials normalment operen en punts d'operació estacionaris, en el cas dels vehicles amb MCIA hi han importants reptes a solucionar tenint en compte el funcionament en condicions variables del motor i el seu impacte en la manera de conducció quotidiana del usuari. Aquesta Tesi contribueix al coneixement i caracterització d'un Cicle Rankine Orgànic (ORC) acoblat amb un motor de combustió interna alternatiu (MCIA) utilitzant etanol com a fluid de treball i un expansor tipus Swash-plate com a màquina expansora. El principal objectiu d'aquest treball de recerca és obtenir i quantificar el potencial dels ORCs per a la recuperació de l'energia residual en motors d'automoció. Per aconseguir-ho, una instal·lació experimental amb un ORC va ser dissenyada i construïda a l'Institut "CMT- Motores Térmicos" (Universitat Politècnica de València). Esta installació pot ser acoblada a diferents tipus de MCIAs. Mitjançant assajos experimentals en aquesta installació, una estimació de les principals variables del cicle va ser obtinguda tant en punts estacionaris com en punts transitoris. Un potencial de millora al voltant d'un 3.7% pot ser aconseguida en punts d'alta càrrega instal·lant un ORC acoblat a un motor gasolina turboalimentat. Pel que fa a les condicions transitòries, un control senzill i robust basat en PIDs adaptatius permet el control del ORC en perfils de conducció reals. Les condicions ideals per a testejar i validar el control de l'ORC són alta càrrega al motor començant amb el motor en calent per aconseguir altes temperatures d'escapament que justifiquen la viabilitat d'aquests cicles. Per tractar d'aprofundir en la viabilitat i característiques d'aquesta aplicació particular, diversos estudis teòrics van ser realitzats. Un model 1D va ser desenvolupat usant el programari LMS Imagine.Lab Amesim. Un potencial de millora al voltant d'un 2.5% en el rendiment efectiu del motor va ser obtingut en condicions transitòries en els punts d'alta càrrega com una conseqüència directa de la reducció de 23.5 g/kWh al consum específic. Per concloure, un estudi termo-econòmic va ser desenvolupat tenint en compte els costos dels principals elements de la installació i un valor mínim de 2030 €/kW va ser obtingut en el paràmetre del Cost Específic d'Inversió. A més, l'estudi exergètic mostra que un total de 3.75 kW, 36.5% de la taxa de destrucció total d'exergia, podria ser recuperat en un pròxim, considerant restriccions tècniques en els components del cicle i tenint en compte les màximes eficiències que es poden aconseguir. / Royo Pascual, L. (2017). Study of Organic Rankine Cycles for Waste Heat Recovery in Transportation Vehicles [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/84013

no / An economizer is normally employed to perform heat recovery from hot exhaust gases to cold fluid. In this work, a newly designed economizer is devised to achieve high heat recovery in a pasteurized milk plant. In the economizer, the hot exhaust gas is divided into two channels flowing up on the left and right sides. After that, it is moving down passing over aligned banks of tubes, which water is flowing inside, in a triple passes fashion. Moreover, three dimensional (3D) models with heat transfer including fluid dynamic have been developed, validated by actual plant data and used to evaluate the performance of the economizer. Simulation results indicate that the newly designed economizer can recover the heat loss of 38% and can achieve the cost saving of 13%.

Exploitation of waste heat could achieve economic and environmental benefits, while at the same time increase energy efficiency in process sites. Diverse commercialised technologies exist to recover useful energy from waste heat. In addition, there are multiple on-site and offsite end-uses of recovered energy. The challenge is to find the optimal mix of technologies and end-uses of recovered energy taking into account the quantity and quality of waste heat sources, interactions with interconnected systems and constraints on capital investment. Explicit models for waste heat recovery technologies that are easily embedded within appropriate process synthesis frameworks are proposed in this work. A novel screening tool is also proposed to guide selection of technology options. The screening tool considers the deviation of the actual performance from the ideal performance of technologies, where the actual performance takes into account irreversibilities due to finite temperature heat transfer. Results from applying the screening tool show that better temperature matching between heat sources and technologies reduces the energy quality degradation during the conversion process. A ranking criterion is also proposed to evaluate end-uses of recovered energy. Applying the ranking criterion shows the use to which energy recovered from waste heat is put determines the economics and potential to reduce CO2 emissions when waste heat recovery is integrated in process sites. This thesis also proposes a novel methodological framework based on graphical and optimization techniques to integrate waste heat recovery into existing process sites. The graphical techniques are shown to provide useful insights into the features of a good solution and assess the potential in industrial waste heat prior to detailed design. The optimization model allows systematic selection and combination of waste heat source streams, selection of technology options, technology working fluids, and exploitation of interactions with interconnected systems. The optimization problem is formulated as a Mixed Integer Linear Program, solved using the branch-and-bound algorithm. The objective is to maximize the economic potential considering capital investment, maintenance costs and operating costs of the selected waste heat recovery technologies. The methodology is applied to industrial case studies. Results indicate that combining waste heat recovery options yield additional increases in efficiency, reductions in CO2 emissions and costs. The case study also demonstrates that significant benefits from waste heat utilization can be achieved when interactions with interconnected systems are considered simultaneously. The thesis shows that the methodology has potential to identify, screen, select and combine waste heat recovery options for process sites. Results suggest that recovery of waste heat can improve the energy security of process sites and global energy security through the conservation of fuel and reduction in CO2 emissions and costs. The methodological framework can inform integration of waste heat recovery in the process industries and formulation of public policies on industrial waste heat utilization.

Nowadays, European power production has to meet requirements than ever before. Environmentally oriented efforts end of coal mining and burning of coal, on which economies of a great number of countries depend. The main objective of these efforts is primarily the production of green energy from renewable energy sources and reduction of dependence on fossil fuels. However, the disadvantage of renewable sources (photovoltaics, wind farms) is their dependence on the weather conditions. As a result, there might be delays in supply of electricity, which must be compensated. One of the solutions is the launch of a combi cycle plant, which has the possibility of almost prompt start-up and electricity production. The combustion of gas and liquid fuels also ensures almost emission-free operation. In addition, thanks to the use of waste heat energy from the gas turbine, it is possible to operate the combi cycle unit with the character of a power plant and as a heating plant. The aim of this thesis is to search for combi cycles and balance calculation of the combi cycle heating plant under given conditions. In the last point, the approximate dimensions of the calculated heating plant are given.

<p><p>This report describes the work of developing a specification of requirements for Waste Heat Recovery Units. The main part of the paper describes how the work with the specification of requirements has been performed. One specific question to be answered is:</p><p>What are the customer’s demands in case of properties for the Waste Heat Recovery Units and how is that information collected as an order documentation to suit the business area Oil & Gas?</p><p>The report begins with a description of the assignment and continues with the aim and background. A theoretical part describes the different areas and methods that have been important during the process. Work on the specification has been carried out on site at the company where interviews of staff and the study of internal documents has been a significant part of the implementation.</p><p>The result is delivered to the company in the form of a specification of requirements for the Waste Heat Recovery Unit. This specification fulfills the requirements set initially and is a good starting point for the company to proceed with in contact with subcontractors. The conclusion of the work is that the establishment of a good specification of requirements is really important and that has been obvious during the work and progress of this project. The difficulty lied in getting the right information and to keep it simple and at same time durable.</p></p>

Large amounts of energy from heat sources such as waste-eat and geothermal energy are available worldwide but their potential for useful power-generation is largely untapped. This is because they are relatively low temperature difference (LTD) sources, in the range from 100 to 200 °C, and it is thermodynamically diffcult, for theoretical and practical reasons, to extract useful work at these temperatures. This work explores the suitability of a Stirling engine (SE) to exploit these heat sources. Elsewhere much work has been done to optimise Stirling engines for high temperature heat sources, but little is known about suitable engine layouts, and their optimal design and operational aspects at lower temperature differences. With the reduced temperature difference, changes from conventional engine designs become necessary and robust solutions for this novel application have to be identified. This has been achieved in four major steps: identification of a suitable engine type; thermodynamic optimisation of operating and engine parameters; optimisation of mechanical efficiency; and the development of conceptual designs for the engine and its components informed by the preceding analysis. For the optimisation of engine and operating parameters a model was set up in the commercial Stirling software package, Sage, which also has been validated in this thesis; suitable parameter combinations have been identified. This work makes key contributions in several areas. This first is the identification of methods for better simulating the thermodynamic behaviour of these engines. At low temperature differences the performance of Stirling engines is very sensitive to losses by fluid friction (and thus frequency), adiabatic temperature rise during compression, and the heat transfer from and to the surroundings. Consequently the usual isothermal analytical approaches produce results that can be misleading. It is necessary to use a non-isothermal approach, and the work shows how this may be achieved. A second contribution is the identification of the important design variables and their causal effects on system performance. The primary design variable is engine layout. For an engine having inherently low efficiency due to the low temperature difference it is important to choose the engine layout that provides the highest power density possible in order to minimise engine size and to save costs. From this analysis the double-acting alpha-type configuration has been identified as being the most suitable, as opposed to the beta or gamma configurations. An-other key design variable is working fluid, and the results identify helium and hydrogen as suitable, and air and nitrogen as unsuitable. Frequency and phase angle are other design variables, and the work identifies favourable values. A sensitivity analysis identifies the phase angle, regenerator porosity, and temperature levels as the most sensitive parameters for power and efficiency. It has also been shown that the compression work in low-temperature difference Stirling engines is of similar magnitude as the expansion work. By compounding suitable working spaces on one piston the net forces on the piston rod can be reduced significantly. In double-acting alpha-engines this can be achieved by choosing the Siemens as opposed to the Franchot arrangement. As a result friction and piston seal leakage which are two important loss mechanisms are reduced significantly and longevity and mechanical efficiency is enhanced. Design implications are identified for various components, including pistons, seals, heat exchangers, regenerator, power extraction, and crankcase. The peculiarities of the heat source are also taken into account in these design recommendations. A third key contribution is the extraction of novel insights from the modelling process. For the heat exchangers it has been shown that the hot and cold heat exchangers can be identical in their design without any negative impact on performance for the low-temperature difference situation. In comparison the high temperature applications invariably require different materials and designs for the two heat exchangers. Also, frequency and phase angle are found to be quite different (lower frequency and higher phase angle) from the optimum parameters found in high temperature engines. Contrary to common belief the role of dead volume has been found to play a crucial and not necessary detrimental role at low temperature differentials. Taken together, the work is positioned at the intersection of thermodynamic analysis and engineering design, for the challenging area of Stirling engines at low temperature differences. The work extracts thermodynamic insights and extends these into design implications. Together these help create a robust theoretical and design foundation for further research and development in the important area of energy recovery.

L'augmentation du prix du pétrole ainsi qu'une possible future réglementation des émissions de CO2 encourage les fabricants de véhicules industriels à trouver de nouvelles solutions pour améliorer encore la performance de la chaine cinématique. Dans ce cadre, deux solutions de récupérations d'énergie prometteuses sont très souvent rapportées dans la littérature: le système de récupération d'énergie par cycle de Rankine et le générateur thermoélectrique. Après un rappel des conditions limites du fonctionnement d'un camion long routier, cette thèse démontre tout d’abord la modélisation 0-D et 1-D (logiciels commerciaux utilisés) de ces deux systèmes de récupération d’énergie. Pour le générateur thermoélectrique, des études paramétriques (hauteur de jambe thermoélectrique, prix, puissance électrique produite) sont effectuées se basant principalement sur l'utilisation de deux matériaux prometteurs. Une conception du système Rankine est présentée et modélisée avec le solveur 1-D. Des validations partielles sont réalisées sur les composants (turbine). Ce modèle a ensuite permis d'étudier les transitoires du système ainsi que la charge en réfrigérant et un système de contrôle possible. Cette étude montre que le générateur thermoélectrique n’est pas encore mature pour son utilisation dans un camion long routier. Le système Rankine doit quant à lui être testé sur un camion prototype pour pouvoir véritablement estimer son potentiel final / Fuel price increase as well as future fuel consumption regulations lead truck manufacturers to further enhance the current powertrain. In such a context, two waste heat recovery technologies appear as promising: the Rankine system as well as the thermoelectric generator. After a reminding of truck boundary conditions, this thesis work defines 0-D and 1-D modeling (commercial tool used) for both systems.For the thermoelectric generator , parametric 1-D studies are done on the integration/design (number of thermoelements, price, electrical power) of a thermoelecric generator upstream the existing engine exhaust gas recirculation cooler. Main studies are done with thermoelectric materials but other materials are also considered. A Rankine system design is presented and modeled under a 1-D solver. Preliminary validations are presented. Transient aspects are evaluated to better understand the behavior of the system and its bottlenecks. The amount of refrigerant in the circuit and the control schematic are also addressed.From these studies, it appears that the thermoelectric generator technology is not yet mature for a long haul truck due to the low performance of thermoelectric materials. The Rankine system technology should handle a complete truck prototype testing to estimate its potential