Mawira Sitima is a thermal spring located in the village Sitima outside of Liwonde,Malawi. The spring is used by many of the local villagers to take baths, play around and wash clothes. Washing using detergents in springs may cause harm to the aquatic ecosystems and worsen the water quality, which might pose a health risk to people swimming in the spring. This study compared physico-chemical properties of Mawira Sitima and the soil and plants around it with standards, guidelines and other studies to assess thewater quality of the spring. The water quality of another hot spring, Mawira Liwonde, was also assessed and compared to Mawira Sitima to investigate the potential for recreationaluse of Mawira Sitima. The findings were then used to produce recommendations for future monitoring of relevant variables in the spring. The results indicate that the current water quality of Mawira Sitima is of no concern for the local health and has all basis to be of recreational use. A monitoring system including electrical conductivity, water temperature, pH, total phosphorous, copper, manganese, and iron was recommended based on correlations and trends. Monitoring of extreme meteorological conditions, such as heavy rainfall or drought, were also recommended. / Mawira Sitima är en varm källa belägen i byn Sitima utanför Liwonde, Malawi. Källan används av lokalbefolkningen för att bada, leka och tvätta kläder. Att tvätta med tvättmedel i källor kan skada de akvatiska ekosystemen och försämra vattenkvaliteten vilket kan leda till hälsorisker för de som använder källan. I denna studie jämfördes fysikaliska och kemiska parametrar i Mawira Sitima, och jorden och plantor runtom den, med standarder, riktlinjer och andra studier för att utvärdera vattenkvaliteten i källan. Vattenkvaliteten i en annan källa, Mawira Liwonde, utvärderades också och jämfördes med Mawira Sitima i syftet att undersöka potenitalen för fritidsbruk av Mawira Sitima. Undersökningsresultaten användes sedan för att föreslå ett framtida övervakningssystem av relevanta variabler i källan. Resultaten i studien visar på god vattenkvalitet i Mawira Sitima och stora möjligheter för fritidsbruk. Övervakningssystemet föreslogs innefatta elektrisk konduktivitet, vattentemperatur, pH, totalfosfor, koppar, mangan och järn baserat på korrelationer och trender. Även extremväder såsom stora mängder regn eller extrem torka rekommenderades ingå i övervakningssytemet

Thesis (MSc. (Chemistry)) -- University of Limpopo, 2021 / Surface water from the rivers serves as a source of water for many purposes including drinking, irrigation and animal farming. The quality of surface water deteriorates due to human, animals and industrial waste. Amongst these wastes, selenium and other trace elements contaminants are included. Selenium can either be essential or toxic depending on the concentration and oxidation state. The aim of this current study was to determine the concentrations of inorganic selenium [Se(IV) and Se(VI)] in water and sediment samples collected from Blood and Mokolo Rivers in Limpopo Province, South Africa. Water and sediment samples were collected from 10 different sampling sites from down to upstream of each river. Water samples were acidified with 1% ultra-pure HNO3 and analysed directly for total selenium concentration. The accuracy of the method was validated using SRM1643f (trace elements in water reference material). Sediment samples were digested using microwave assisted acid digestion for the determination of total concentration of selenium. The accuracy of the method was evaluated using SRM 8704 (sediment standard reference material). Total concentration of selenium in both water and sediment samples were quantified using ICP-MS. The total concentration of selenium in water samples from Blood and Mokolo River were found to be in the range of 0.0682 to 2.72 μg/L and 0.0851 to 25.4 μg/L respectively. The selenium concentrations in all sediment samples were found to be below instrument detection limit of 0.0571 ng/g in both rivers. An adopted SPE method using Dowex 1 x 2 resin (chloride form) as an adsorbent material to preconcentrate and separate Se(IV) and Se(VI) was used for the speciation in water samples. Both Se(IV) and Se(VI) were retained on the column. The retained Se(IV) and Se(VI) were eluted using 15 mL 1 M HNO3 and 3 M HNO3 respectively at a flow rate of 2 ml/min and diluted to the final volume of 20 mL. The instrument detection limit was 0.192 μg/L and 0.108 μg/L for Se(IV) and Se(VI) respectively. The validation of the method was performed by using SRM 1643f and solutions of known concentrations. The water samples were adjusted to an optimum pH of 6 throughout the speciation analysis. The Se(IV) had higher percentage recoveries of 95 – 114% than Se(VI) with 53%. vi Concentrations of Se(IV) and Se(VI) in Blood River ranged from 0.0411 to 0.820 μg/L and 0.0811 to 1.75 μg/L respectively. Concentrations of Se(IV) and Se(VI) in Mokolo River ranged from 0.135 to 2.79 μg/L and 0.0961 to 14.8 μg/L respectively. The inorganic selenium species in water samples were also determined by using the adopted online mode of HPLC-ICP-MS with Hamilton PRP-X100 column. The separation of the two species was achieved by using isocratic elution of 100 mM NH4NO3 at pH 8.5 in 8 min. The method was successfully validated using SRM 1643f. The LOD of 0.842 μg/L and LOQ of 2.81 μg/L for Se(IV) were achieved. The LOD of 0.690 μg/L and LOQ of 2.30 μg/L for Se(VI) were achieved. The Se(IV) and Se(VI) concentrations determined using HPLC-ICP-MS were found to be in good agreement with Se(IV) and Se(VI) concentrations obtained using SPE in both rivers. The presence of Se(IV) and Se(VI) in water samples in Blood and Mokolo Rivers indicates that industrial and agricultural activities taking place near the rivers have an effect on the quality of the water. The selenium in water may be due to wastes from industrial, municipal and agricultural runoffs. The absence of selenium in sediment samples suggests that the area where the rivers are located is not rich in selenium.

Human impacts from land and water development have degraded water quality and altered the physical, chemical, and biological integrity of Nevada's Walker River. Reduced instream flows and increased nutrient concentrations affect native fish populations through warm daily stream temperatures and low nightly dissolved oxygen concentrations. Environmental water purchases are being considered to maintain instream flows, improve water quality, and enhance habitat for native fish species, such as Lahontan cutthroat trout. This study uses the River Modeling System (RMSv4), an hourly, physically-based hydrodynamic and water quality model, to estimate streamflows, temperatures, and dissolved oxygen concentrations in the Walker River. Stream temperature and dissolved oxygen changes were simulated from potential environmental water purchases to prioritize the time periods and locations that water purchases most enhance stream temperatures and dissolved oxygen concentrations for aquatic habitat. Environmental water purchases ranged from 0.03 cms to 1.41 cms average daily increases. Modeling results indicate that increased water purchases generally affect dissolved oxygen in two ways. First, environmental water purchases increase the thermal mass of the river, cooling daily stream temperatures and warming nightly temperatures. This prevents conditions that cause the lowest nightly dissolved oxygen concentrations (moderate production impairment thresholds are

Thesis (M.Sc. (Zoology)) -- University of Limpopo, 2017 / In this study data was collected to establish if the water and sediment quality of the Steelpoort River has any effects on macro-invertebrate species. The Steelpoort River is a tributary of the Olifants River system but not much data about the water quality is available. The Steelpoort River is a perennial river (Ashton et al. 2001) situated west of Burgersfort and from there it flows in a north- easterly direction and converges with the Olifants River in the Drakensberg near Kromellenboog. High silt levels in the river, increases the risk of flooding and leads to the smothering of in-stream habitats resulting in loss of some invertebrate and fish species. Sampling of the water, sediment and macroinvertebrates was conducted quarterly at the Steelpoort River at five sites. One site was above the impoundment (De Hoop Dam) and the rest were below the impoundment. A handheld YSI 556™ Multi Probe System (MPS instrument and a Mettler Toledo SevenGo™ conductivity meter were used to measure the physico-chemical characteristics at the sites. The macroinvertebrates were sampled using the SASS 5 bio-assessment protocol (Goodyear & McNeill 1999, Dickens & Graham 2002). Macro-invertebrate samples were collected using a 400 mm x 400 mm SASS net with a 250 μm mesh size. The substrate was disturbed for a period of two minutes to free macro-invertebrates from the substrate. The SASS score for each site was evaluated in the field for three of the five samples. The macro-invertebrate samples were preserved in 70% ethanol and sorted to family level in the University of Limpopo’s Biodiversity laboratory. For the majority of the physico-chemical parameters the most elevated were detected downstream and lowest concentrations were detected upstream. Analysis of variance (ANOVA) indicated that there were no significant differences for electrical conductivity, salinity, and TDS, between the sites (p>0.05). There were however significant differences in the temperature, dissolved oxygen, turbidity, and pH concentrations (p<0.05). The majority of the metals and metalloids in the water (Fe, Mn, V, Co, Zn, Ba, and Cu) were highest at Tiershoek (Site1) and lowest at Steelpoort (Site 4) and Burgersfort Bridge (Site 5).The mean metal concentrations collected showed elevated levels for chromium, copper and zinc, which were above the CCME sediment guidelines. The most abundant macroinvertebrates were from the family Ephemeroptera which are pollution sensitive and good indicators of pollution in aquatic ecosystems. When using the interpretation of the SASS 5 results from Chutter 1995, the mean Average Score Per Taxa (ASPT) scores show that the water quality for Tiershoek (Site 1) and Polopark (Site 3) is natural but the habitat diversity has been reduced. For De Hoop (Site 2) and Steelpoort (Site 4), the mean ASPT score shows that there is some deterioration in the water quality. Finally, for Burgersfort Bridge (Site 5), the mean ASPT score indicates that there is major deterioration in the water quality. Primer statistical analysis indicated that the average dissimilarity between sites showed that the highest dissimilarity was between Tiershoek (Site 1) and Burgersfort Bridge (Site 5) which was conclusive with the results from the macro-invertebrate count and SASS, indicating that there is diverse difference from upstream to downstream. CCA indicated positive correlations between nutrients detected at Steelpoort with Athericidae, Tabanidae, Gomphidae, Baetidae, Elmidae, Planaria, Psephenidae, and Libellulidae which was indicated that water chemistry characteristics exert influence on macroinvertebrates. The results showed that there is degradation of the water quality in river from upstream to downstream with more pollution tolerant species being abundant at Steelpoort (Site 4) and Burgersfort Bridge (Site 5). The most favourable season was autumn and the least summer/spring and this may be attributed to the life cycle of the macro-invertebrate communities / NRF VLIR

Pollution from nonpoint sources is a leading cause of receiving water quality impairment. The largest source of nonpoint pollution is storm water runoff, which includes pollutants such as sediment, nutrients, metals, microorganisms, and organic compounds. Sediment is of particular importance because many pollutants are readily 5 adsorbed onto particles. In the Lake Tahoe basin, sediment is also significant because of its direct contribution to clarity attenuation. The most prudent control measure for mitigating sediment flux in the Lake Tahoe basin is infiltration, which captures runoff volume, allowing it to percolate into the soil and enter groundwater. All residential parcels in the Lake Tahoe basin are required to have an on-site infiltration system. These systems require rigorous maintenance to maintain full function. Negligence can lead to premature clogging from debris and accumulated sediment, and the cost of rehabilitating or replacing the system can be significant to homeowners. It is mandatory for a sediment trapping device to be installed to pretreat runoff discharged into the infiltration system; however, there is limited infomation regarding sediment trapping devices designed for residential use. The objective of this research was to evaluate the performance of an on-site stormwater treatment device in removing sediment from simulated stormwater runoff. The sediment trapping device consists of removable, porous 200-micron nylon inserts for filtration and is designed to mitigate premature clogging infiltrative runoff control measures. Laboratory analysis of a full scale device model was performed. Removal efficiency, effluent concentration, and bulk solids removal were assessed for perfomance evaluation. The device demonstrated a median removal efficiency from grab samples of 74%, median total suspended solids effluent concentration of 72 mg/L, and removed 89% of the total solids introduced into the system. Economic and sustainability implications of the device were also assessed.

No description available.

Stormwater runoff from urban areas is a major source of pollution to surface water bodies. The discharge of nutrients such as nitrogen and phosphorus is particularly damaging as it results in harmful algal blooms which can limit the beneficial use of a water body. Stormwater best management practices (BMPs) have been developed over the years to help address this issue. While BMPs have been investigated for years, their use has been somewhat limited due to the fact that much of the data collected is for specific applications, in specific regions, and it is unknown how these systems will perform in other regions and for other applications. Additionally, the research was spread across the literature and performance data was not easily accessible or organized in a convenient way. Recently, local governments and the USEPA have begun to collect this data in BMP manuals to help designers implement this technology. That being said, many times a single BMP is insufficient to meet water quality and flood control needs in urban areas. A treatment train approach is required in these regions. In this dissertation, the development of methodologies to evaluate the performance of two BMPs, namely green roofs and pervious pavements is presented. Additionally, based on an extensive review of the literature, a model was developed to assist in the evaluation of site stormwater plans using a treatment train approach for the removal of nutrients due to the use of BMPs. This model is called the Best Management Practices Treatment for Removal on an Annual basis Involving Nutrients in Stormwater (BMPTRAINS) model. The first part of this research examined a previously developed method for designing green roofs for hydrologic efficiency. The model had not been tested for different designs and assumed that evapotranspiration was readily available for all regions. This work tested this methodology against different designs, both lab scale and full scale. Additionally, the use of the Blaney-Criddle equation was examined as a simple way to determine the ET for regions where data was not readily available. It was shown that the methods developed for determination of green roof efficiency had good agreement with collected data. Additionally, the use of the Blaney-Criddle equation for estimation of ET had good agreement with collected and measured data. The next part of this research examined a method to design pervious pavements. The water storage potential is essential to the successful design of these BMPs. This work examined the total and effective porosities under clean, sediment clogged, and rejuvenated conditions. Additionally, a new type of porosity was defined called operating porosity. This new porosity was defined as the average of the clean effective porosity and the sediment clogged effective porosity. This porosity term was created due to the fact that these systems exist in the exposed environment and subject to sediment loading due to site erosion, vehicle tracking, and spills. Due to this, using the clean effective porosity for design purposes would result in system failure for design type storm events towards the end of its service life. While rejuvenation techniques were found to be somewhat effective, it was also observed that often sediment would travel deep into the pavement system past the effective reach of vacuum sweeping. This was highly dependent on the pore structure of the pavement surface layer. Based on this examination, suggested values for operating porosity were presented which could be used to calculate the storage potential of these systems and subsequent curve number for design purposes. The final part of this work was the development of a site evaluation model using treatment train techniques. The BMPTRAINS model relied on an extensive literature review to gather data on performance of 15 different BMPs, including the two examined as part of this work. This model has 29 different land uses programmed into it and a user defined option, allowing for wide applicability. Additionally, this model allows a watershed to be split into up to four different catchments, each able to have their own distinct pre- and post-development conditions. Based on the pre- and post-development conditions specified by the user, event mean concentrations (EMCs) are assigned. These EMCs can also be overridden by the user. Each catchment can also contain up to three BMPs in series. If BMPs are to be in parallel, they must be in a separate catchment. The catchments can be configured in up to 15 different configurations, including series, parallel, and mixed. Again, this allows for wide applicability of site designs. The evaluation of cost is also available in this model, either in terms of capital cost or net present worth. The model allows for up to 25 different scenarios to be run comparing cost, presenting results in overall capital cost, overall net present worth, or cost per kg of nitrogen and phosphorus. The wide array of BMPs provided and the flexibility provided to the user makes this model a powerful tool for designers and regulators to help protect surface waters.

To maintain the quality of receiving water bodies, it is desirable to remove total phosphorus (TP) in stormwater runoff. Many media filtration technologies have been developed to achieve TP and soluble reactive phosphorus (SRP) removal. Efficient media adsorption is essential to insure control of stormwater phosphorus inputs to the receiving water body. This project develops and analyzes a functionalized Biosorption Media (BAM) to remove phosphorus species from stormwater runoff. One goal of this project is to find the BAM values for coefficients such as maximum adsorption capacity (QM: 4.35E-05) for the media through SRP isotherm equilibrium experiments using the Langmuir and Freundlich models. In addition, an upflow column experiment was also performed to study BAM nutrient removal from stormwater runoff. Finally, the information from the isotherm and the column experiments are used to estimate the life expectancy or quantity required of the media, and to define the effectiveness of BAM in phosphorus removal. The result of this study shows that BAM is a feasible stormwater treatment that can remove 60% SRP and > 40% TP at temperature between 21-23°C. The media is adequately modeled by both the Langmuir and the Freundlich models over the concentration range of interest in stormwater.

No description available.

No description available.