Diatoms are a large and diverse group of algae which are distributed throughout the world in all types of aquatic systems and are one of the most important food resources in freshwater ecosystems. The need to sample diatoms arises from the necessity to know the history of the water quality. Diatom communities reflect the overall ecological integrity by integrating various stressors and as result provides a broad measure of their impacts. They are recognized as valuable organisms for bio assessment, due to their ease of identification, rapid life cycle and their visibility to the naked eye. Diatom communities provide interpretable indications of specific changes in the water quality Environmental gradients and assemblage composition in the Mnweni River catchment revealed that water chemistry, habitat structure, flow type and land use were the most important environmental factors for diatom assemblage composition in the Mnweni River. The results indicates that the diatom diversity and assemblage composition in the Mnweni River shows that changes in the water chemistry as well as organic pollution, but also indicate changes in the habitat character which is related to the water flow, river bank character and catchment land use. The diatom assemblages that were found at the sites are typical of clean or mildly enriched water conditions. The changing salinity in St. Lucia is the main physical factor that is driving the constant change in ecological conditions within the estuary. The changes in the diatom community structure in the estuarine system indicate the variable nature of the benthic communities under different salinity conditions. Contrary to the drought conditions that are being experienced, the diatom biomass did not show any significant changes or differences. This may be due to the rapid recovery ability that diatom communities exhibit in response to changes that are occurring in their environment. / Thesis (M.A.)-University of KwaZulu-Natal, 2006.

The degradation of wetlands and loss of their associated ecosystem services is widely recognised in South Africa, however, at present there is no standard method of biologically assessing wetland health in this country. Internationally, particularly in the U.S.A and Australia, wetland bioassessment techniques using macroinvertebrates are well established. A number of these wetland bioassessment protocols have been derived from local river biomonitoring techniques, as there is a belief that river and wetland ecology and macroinvertebrate assemblages at family level are similar. However, some authors consider wetland macroinvertebrate assemblages and ecological processes to differ greatly from those found in rivers, and believe that such techniques are not transferable. South Africa has a well established macroinvertebrate biomonitoring protocol for rivers called SASS5 (South African Scoring System Version 5). This study is a preliminary investigation into the extent to which the SASS5 scoring system is applicable to the assessment of nutrient enriched wetland water quality. Macroinvertebrates are particularly suitable as biomonitoring tools: they respond to a variety of stressors, have life cycles that allow for integrated responses to episodic pollution, and are relatively easy to identify to family level. When selecting wetlands for the development of a biomonitoring protocol, wetlands should all be of the same; classification (Le. palustrine), geomorphological and climate setting, hydrological regime and dominant vegetation class. Sampling was restricted to sedge-dominated palustrine wetlands in the midlands of KwaZulu-Natal, with similar hydro-geomorphological settings. Due to wetlands and rivers having different biotopes (e.g. no riffles present in wetlands), the SASS5 sampling protocol could not be used, thus a pilot investigation was undertaken to derive a suitable sampling technique for \ collecting a representative and diagnostic sample of aquatic macroinvertebrates from a wetland. This technique was developed based on published methods. Both sweep net and activity trap sampling were conducted, and each evaluated for their effectiveness at macroinvertebrate collection. Sweep net sampling was tested over a range of sweep intensities (2-6 sweeps), and activity traps were placed at four different depths: at the water surface, just below the surface, 0.10.15m below surface and on the substrate. A total of 32 taxa identified to family level were identified in the samples. Taxon diversity and composition did not differ in the activity traps placed at the four depth locations. Taxon diversity did not differ significantly between different sweep intensities; however there was a significant difference in taxon composition between the different sweep intensities and between activity trap and sweep net samples (p<0.05). Sixty-eight percent of taxa appeared more frequently in sweep net sampling compared to activity trap sampling. Six taxa were found exclusively in sweep net samples, and two taxa were recorded exclusively in activity traps. There was no trend in either method collecting more or missing any unique trophic group. In conclusion, activity traps are not required to supplement sweep net data, and a technique using a sweep net with a sweep intensity of five would be suitable to collect a representative sample of wetland macroinvertebrates. Using the derived technique, four reference and three wetlands impacted by dairy effluent were sampled. Six macroinvertebrate samples were collected from each of the seven wetland, together with data for selected physico-chemical variables, macrohabitat condition, biotope suitability and organism detectability. For each sample, the macroinvertebrates were identified and assigned a predetermined SASS5 tolerance score between 1 and 15, with higher scores indicating increased sensitivity to poor water quality. 11 A total of 39 taxa, identified to family level, were collected during sampling. SASS5 scores ranged from 15-82. Five of the wetlands had mean SASS5 scores of between 46 and 59. Five of the wetlands had an intra-wetland SASS5 score range greater than 30. ASPT values ranged from 3.3 to 5.5, and few high scoring (~8) taxa were collected. There was no significant difference in SASS5 scores between samples collected above, at and downstream of an effluent discharge point within the same impacted wetland. SASS5 scores for reference wetlands were also not significantly higher than those recorded for impacted wetlands. Comparison of ranked SASS5 scores and environmental data did suggest a relationship between the variables, but was not significant. Based on the SASS5 score water quality guidelines, all sampled wetlands were considered to have impacted water quality; however, this was not supported by the macrohabitat and physico-chemical results. Possible reasons for the low SASS5 scores include: the lack of 'stones in/out current' biotopes in wetlands, lower levels of dissolved oxygen present compared to rivers, and the limited detectability of organisms due to large amounts of substrate in the samples. A wetland adaptation of SASS5 would require the reassignment of modified scores to certain taxa based on their distribution in wetlands of varying water quality. The SASS5 score level of 100 and the ASPT value of 6 (as specified in the SASS5 score water quality guidelines) were found to be inappropriate for wetlands. It is suggested that, either the range of taxa tolerance scores be increased (1 to >15), or the score level of 100 be lowered. The ASPT value should also be reduced. Although SASS5 appears unsuitable for assessing wetlands, variations in taxon composition between sampled wetlands, identified through CA analysis, suggests that macroinvertebrates are responsive to changes in wetland condition, and thus have potential as indicators of wetland water quality. Nine taxa responsive to the presence of nitrogen have been identified as being potentially good indicators. iii Further research should focus on the testing of SASS5 throughout the year, in a range of wetland types, and in wetlands moderately to severely impacted by pollutants other than dairy effluent. It is recommended that a habitat or biotope index be developed and used in conjunction with any future wetland macroinvertebrate bioassessment protocols. / Thesis (M.Sc.)-University of KwaZulu-Natal, Pietermaritzburg, 2005.

Water, a fundamental and irreplaceable resource, is an all-pervasive issue that underpins the social fabric of every society. Rapid population growth and expansion of human activities increases the amount of waste and pollution generated and many local authorities are encountering serious water pollution problems, often concentrated in the lower reaches of catchments and adjacent coastal areas. This problem is predominantly acute in urbanized catchment areas, where waste is concentrated into localized areas, and the authorities are constantly under pressure to provide adequate management and mitigation measures. The Palmiet River system, located in the northern fringe of the city of Durban and draining the highly industrialized Pinetown region in KwaZulu-Natal, South Africa, illustrates a system that has been altered due to human impacts, particularly in its headwaters where the industrial sites are located and, in the lower catchment where a densely populated informal settlement occurs. A range of chemical and biotic indicators were monitored seasonally and these confirm the influence of the aforementioned human impacts on the quality of the Palmiet River system. Results from the present study were compared with studies conducted over a period of two decades and clearly demonstrate a pattern of increasing pollution loads for the upper and lower parts of the catchment. This study confirms that the Palmiet River is severely degraded in its lower reaches whilst the middle reaches of the catchment where a nature reserve is located is still in a fairly pristine condition. Additionally, the Palmiet River issues discussed in this thesis have direct impacts on the estuarine and adjacent marine ecosystems. / Thesis (M.A.)-University of KwaZulu-Natal, Durban,2005.

Water is characterised by both its quantity (availability) and its quality. Salinity, which is one of the major water quality parameters limiting use of a wide range of land and water resources, refers to the total dissolved solutes in water. It is influenced by a combination of several soil-water-salt-plant related processes. In order to develop optimum management schemes for environmental control through relevant hydrological modelling techniques, it is important to identify and understand these processes affecting salinity. Therefore, the various sources and processes controlling salt release and transport from the soil surface through the root zone to groundwater and streams as well as reservoirs are extensively reviewed in this project with subsequent exploration of some hydro salinity modelling approaches. The simulation of large and complex hydrological systems, such as these at a catchment scale, requires a flexible and efficient modelling tool to assist in the assessment of the impact of land and water use alternatives on the salt balance. The currently available catchment models offer varying degrees of suitability with respect to modelling hydrological problems, dependent on the model structure and the type of the approach used. The A CR U agrohydrological modelling system, with its physically-conceptually based characteristics as well as being a multi-purpose model that is able to operate both as a lumped and distributed model, was found to be suitable for hydro salinity modelling at a catchment scale through the incorporation of an appropriate hydro salinity module. The main aim of this project was to develop, validate and verify a hydro salinity module for the ACRU model. This module is developed in the object-oriented version of ACRU, viz. ACRU2000, and it inherits the basic structure and objects of the model. The module involves the interaction of the hydrological processes represented in ACRU and salinity related processes. Hence, it is designated as ACRUSalinity. In general, the module is developed through extensive review of ACRU and hydrosalinity models, followed by conceptualisation and design of objects in the module. It is then written in Java object-oriented programming language. The development of ACRUSalinity is based mainly on the interaction between three objects, viz. Components, Data and Processes. Component objects in ACRU2000 represent the physical features in the hydrological system being modelled. Data objects are mainly used to store data or information. The Process objects describe processes that can take place in a conceptual or real world hydrological system. The Process objects in ACRUSalinity are grouped into six packages that conduct: • the initial salt load determination in subsurface components and a reservoir • determination of wet atmospheric deposition and salt input from irrigation water • subsurface salt balance, salt generation and salt movement • surface flow salt balance and salt movement • reservoir salt budgeting and salt routing and • channel-reach salt balancing and, in the case of distributed hydro salinity modelling, salt transfer between sub-catchments. The second aim of the project was the validation and verification of the module. Code validation was undertaken through mass balance computations while verification of the module was through comparison of simulated streamflow salinity against observed values as recorded at gauging weir UIH005 which drains the Upper Mkomazi Catchment in KwaZuluNatal, South Africa. Results from a graphical and statistical analysis of observed and simulated values have shown that the simulated streamflow salinity values mimic the observed values remarkably well. As part of the module development and validation, sensitivity analysis of the major input parameters of ACRUSalinity was also conducted. This is then followed by a case study that demonstrates some potential applications of the module. In general, results from the module evaluation have indicated that ACRUSalinity can be used to provide a reasonable first order approximation in various hydrosalinity studies. Most of the major sources and controlling factors of salinity are accommodated in the ACRUSalinity module which was developed in this project. However, for a more accurate and a better performance of the module in diversified catchments, further research needs to be conducted to account for the impact of salt loading from certain sources and to derive the value of some input parameters to the new module. The research needs include incorporation in the module of the impact of salt loading from fertilizer applications as well as from urban and industrial effluents. Similarly, further research needs to be undertaken to facilitate the module's conducting salt routing at sub-daily time step and to account for the impact of bypass flows in heavy soils on the surface and subsurface salt balances. / Thesis (M.Sc.)-University of Natal, Pietermaritzburg, 2003.

This dissertation focussed on the Mvoti River system in KwaZulu-Natal, an important resource for the numerous towns and villages along its course. Catchment activities are varied with agriculture being the predominant activity, and industrial activities common in the lower catchment. The Mvoti River is intensively utilized, especially in its lower reaches, to the extent that it is referred to as a ‘working river’. Modifications of the chemical and physical characteristics of the system, and consequently the biological characteristics, have led to degradation of the system such that the functioning of the lower river has deteriorated in comparison to that of its pre-disturbance condition. There are three main aspects of the Mvoti system around which this dissertation is based, namely, water quality, geochemistry, and conservation of the system. The results of the water quality survey of the estuary revealed that the system is presently experiencing water which is of an inferior quality. Compared against the South African water quality standards, a majority of the parameters exceed acceptable limits and are likely to present negative impacts on aquatic health and potentially human health. Comparison of current results, and water quality data for the system dating back to 1964, revealed that this degradation is not new to the system, and the Mvoti Estuary has in fact been experiencing continued deterioration over the years. The second part of this study investigated heavy metal presence in the sediments of the lower system and elemental presence and distribution in the surface sediments of the middle and lower River respectively. Results indicated that even though selected heavy metals are present, they are of concentrations lower than those of two other South African and two other international systems they were compared with. Enrichment and contamination assessments reveal that contaminants are in all probability present as a result of anthropogenic sources. However, distribution patterns which show highest levels just after effluent disposal sites suggest that the contamination is presumably human-induced and, the predominance of larger grained sediments that do not have high adsorption capacities, suggest that contaminants are readily remobilized into the water column. The final part of this research investigates other environmental problems, and causes, both natural and anthropogenic, experienced by the estuary system. These stresses include poor water quality, reduced water quantity, sedimentation, alien vegetation invasions and loss of biodiversity. Strategies to address these issues are proposed, with the intention of improving the condition of the estuary. This is an attempt at ecological restoration, to restore the estuary to a condition as close to as possible, to its pre-disturbance condition. These strategies include controlling abstraction and discharge, eradicating alien vegetation, controlling sandmining, and improving the overall quality of the system. Also proposed is an estuary management plan (EMP) for the Mvoti system, as there is currently no plan of such a nature in place. The EMP will aid restoration attempts, increase public awareness, and via post-project monitoring and evaluation ensure the success and sustainability of any future projects. Significantly, the adoption of an EMP will be a major step towards the rehabilitation, conservation and protection of this already degraded system. / Thesis (M.Sc.)-University of KwaZulu-Natal, Westville, 2010.

Wetlands have been described as “one of the most globally threatened and important ecosystems”, with most wetlands providing a variety of important ecosystem services, including water quality enhancement. Despite their importance the loss of wetlands is more rapid than that of any other ecosystem, which is of particular concern in South Africa, where many communities are directly and indirectly dependent on wetlands for survival. Two useful wetland assessment tools are currently used in South Africa, but a system that assesses the extent to which wetland ecosystem services (water quality enhancement in particular) are lost as a result of wetland degradation in a landscape context does not currently exist. This study therefore aims to develop a method to determine the cumulative effect of wetland degradation on water quality, which involves the exploration and integration of a number of issues, including land-cover and its effects on water quality, wetland health and its influence on the provision of ecosystem services such as water quality enhancement, and the spatial configuration of wetlands in a landscape, and its effect on water quality at a landscape scale. The method that has been developed is applied to a case study that comprises a quaternary catchment of the upper reaches of the Goukou River Wetlands in the Western Cape of South Africa. Prioritisation criteria are also explored in a series of scenarios, and the criterion and rehabilitation method that gives the best outcome in terms of water quality enhancement is applied to the case study catchment. The workings of the method are scrutinized and benefits and limitations are subsequently highlighted. An important benefit of the methodology is that many previously inadequately explored issues are integrated into a single tool that allows for prioritisation of wetlands for rehabilitation and conservation. This was achieved with South African contexts in mind. Limitations include poor responses by potential questionnaire respondents, while the scope of the study limits the inclusion of detailed aspects which would have further enhanced the accuracy of the tool and of the level of water quality enhancement explored. The methodology that is developed in this research has also not been applied to catchments with good long term water quality data in order to improve its validity. Recommendations for future research are made, which include possible refinement of the system by accounting for factors not included in the current methodology, validation of the system by applying it to a catchment with good water quality data, and the creation of software to make the system easier to use. / Thesis (M.Sc.)-University of KwaZulu-Natal, Westville, 2009.

This study was conducted to understand the interactions between irrigation water management and water quality (agro-ecological interactions). The Uda Walawe basin, in Southern Sri Lanka was chosen as the study area. Fluctuations in water quality, especially microbiological water quality, affect human health. Since the source of domestic water (drinking and washing) in this region is from the irrigation system, there is a concern for the human health effects. All the potential water sources and the water use habits of the community were identified. The water quality of these sources was then monitored for a period of 5 months (August--December 2000). Second, the water management of the Uda Walawe irrigation system was linked to the differences in water quality. The best quality water was found to come from the shallow wells (seepage water from the irrigation system). Both quantity and quality of the water were shown to fluctuate with canal construction (earthen or concrete) and irrigation water management.

With the increasing degradation of rivers worldwide, an understanding of spatial and temporal patterns in freshwater quality is important. Water quality is highly variable in space and time, yet this is largely overlooked at the scale of stream catchments. I employed a landscape ecology approach to examine the spatial patterning of water quality in complex, impacted stream networks on the Canterbury Plains of the South Island of New Zealand, with the goal of understanding how land-use effects proliferate through stream systems. In particular, I used “snapshot” sampling events in conjunction with spatial modelling and longitudinal profiles to investigate the ways in which spatial and environmental factors influence the variability of water quality in stream networks. Spatial eigenfunction analyses showed that distance measures, which took into account variable connectivity by flow and distance along the stream between sites, explained more spatial variance in water quality than traditional distance metrics. Small upstream reaches were more spatially and temporally variable than main stems (under summer base-flow conditions). The extent of spatial variation in water quality differed between stream networks, potentially depending on linkages to groundwater and the surrounding landscape. My results indicated that the water quality of headwater streams can have a disproportionate influence over water quality throughout an entire network. I investigated spatio-temporal patterns in water quality more intensively in one stream network, the Cam River, in which I found consistent spatial pattern through time. The relative balance between nutrient inputs (pollution and groundwater) and in-stream conditions influenced the spatial pattern of water quality, as well as that of several ecosystem processes which I measured simultaneously. The spatially intensive and explicit approach has allowed identification of key factors controlling water quality and ecosystem processes throughout the Cam River. This research highlights the importance of taking a spatially explicit approach when studying stream water quality and that such an approach could be insightful and will contribute to solving current stream management problems.

The purpose of this study is to review existing literature of factors that influence farmers’ decision to participate in conservation programs. This study is also intended to collect county data and information on conservation programs and participation in the Kentucky River watershed region, which can be analyzed and used to draw differences in characteristics of the region that would suggest willingness to participate in a trading scheme for improvements in water quality. The results suggest that more participation in a trading scheme from some counties than others should be expected. Counties with more farms and larger farms will probably have higher rates of participation in conservation programs. The cost-share amounts being paid by current government programs must be considered as the minimum staring point to negotiate in a trading scheme. To target the impact of watersheds, such as the Kentucky River in the Mississippi system, that discharges significant amounts of pollutants into the Gulf of Mexico, policy makers and program administrators should be advising and stimulating the adoption of practices with the best abatement performance for such pollutants considering technical complementarity between practices.

Hawaii’s pristine ocean and tropical environment is a keystone of Hawaii tourism and the state economy. Water pollution from stormwater and development threatens the beach quality to both residents and tourists. In order to understand the lost nonmarket value, we assess changes in quality of beach characteristics including water and sand quality, swimming safety conditions, and congestion using a Discrete Choice Experiment of recreational beach users. Further, we study willingness to pay (WTP) for water management strategies in Hawaii using another discrete choice experiment, including structural and nonstructural Best Management Practices, testing, monitoring, and educational efforts. Using a mixed logit model, beach quality results suggest similar preferences among resident and tourists. Both groups consistently have higher WTP to avoid poor quality levels versus obtaining excellent levels. Additionally, water quality is the single most important attribute. For the policy discrete choice experiment, both parties exhibit similar ranking of WTP to initiate water quality management strategies, with improved testing methods followed by education having the highest WTP. Lastly, we use Benefit-Cost analysis to find that all significant management strategies may be viable, since WTP is greater than the predicted cost of implementation based on expert opinion of Hawaiian policy leaders.