Změny kvality vody v malých tocích, vyvolané vybudováním čistírny odpadních vod, představují doposud málo studované a přitom velmi aktuální téma současné hydrologie. Tato studie se zabývá popsáním těchto změn a faktorů, které je ovlivňují. Pro účely výzkumu bylo vybráno pět malých, zemědělsky využívaných povodí prvního řádu (čtyři povodí průměrně 6 km2 , jedno 16 km2 ). V každém zájmovém území byla vždy jedna vesnice od 640 do 2 500 obyvatel. Během 7 - 16 let trvajícího měsíčního monitoringu základních indikátorů kvality vody (O2, BSK5, CHSKCr, TOC, konduktivita, N-NH4, N-NO2, N-NO3, PC, P-PO4) byla zachycena stavba čistíren v obcích. Spolu s daty o účinnosti čistíren byly vyhodnoceny změny kvality vody v toku. Identifikované typy změn ukazují na problematické aspekty vývoje kvality vody v malých povodích. Kromě očekávaného rychlého a razantního snížení hodnot zátěže po výstavbě čistírny odpadních vod se vyskytují i odlišné projevy změn - pouze mírné snížení zátěže, stagnace, dokonce i zvýšení koncentrací sledovaných indikátorů. Mezi další typické změny patří navýšení hodnot 1-2 roky před uvedením čistírny do provozu a opožděná nitrifikace v toku způsobená nevhodným provozem čistírny. Mezi nejdůležitější faktory ovlivňující změny patří provoz čistírny, velikost průtoku recipientu, zemědělské...

yes / In this paper, a one-dimensional mathematical model based on coupled differential and algebraic equations has been developed for analysing the separation mechanism of a N-nitrosamine in a spiral-wound reverse osmosis process. The model is based on Spiegler and Kedem’s work on mass transport and Darcy’s law and concentration polarization to analyse the pressure drop and mass transfer coefficient in the module feed channel respectively. The model is built using the gPROMS software suite and validated using N-nitrosamine rejection experimental data from the literature, obtained by using a pilot-scale cross-flow reverse osmosis filtration system. Analysis results derived from the model corroborate experimental data.

Optimal operation of water reclamation facilities (WRFs) is critical for an indirect potable reuse (IPR) system, especially when the reclaimed water constitutes a major portion of the reservoir's safe yield. It requires timely and informed decision-making in response to the fluctuating operational conditions, e.g., weather patterns, plant performance, water demand, etc. Advanced integrated modeling techniques can be used to develop reliable operational strategies to mitigate future risks associated with water quality without needing high levels of financial investment. The Upper Occoquan Service Authority (UOSA) WRF, located in northern Virginia, discharges nitrified reclaimed water directly into a tributary of the Occoquan Reservoir, one of the major water supply sources for Fairfax County. Among the many operational challenges at UOSA, one is to regulate the nitrate concentration in its reclaimed water based on the denitrifying capacity of the reservoir. This study presents an integrated model that is used to predict future reservoir conditions based on the weather and streamflow forecasts obtained from the Climate Forecast System and the National Water Model. The application captures the dynamic transformations of the pollutant loadings in the streams, withdrawals by the water treatment plant, WRF effluent flows, and plant operations to manage the WRF performance. It provides plant operators with useful feedback for correctly targeting the effluent nitrates using an intelligent process simulator called IViewOps. The platform is powered by URUNME, a new software that fully automates the operation of the reservoir and process models integrating forecasting products, and data sources. URUNME was developed in C#.NET to provide out-of-the-box functionality for model coupling, data storage, analysis, visualization, scenario management, and decision support systems. The software automatically runs the entire integrated model and outputs data on user-friendly dashboards, displaying historical and forecasting trends, on a periodic basis. This decision support system can provide stakeholders with a holistic view for the design, planning, risk assessments, and potential improvements in various components of the water supply chain, not just for the Occoquan but for any reservoir augmentation type IPR system. / Doctor of Philosophy / In an indirect potable reuse (IPR) system, reclaimed water from an advanced wastewater treatment facility is blended with a natural water source, such as a reservoir, to augment drinking water supply. Reliable operation of such a system is critical, especially when the reclaimed water constitutes a major portion of the withdrawals from the reservoir for treatment and distribution. One example of such an IPR system is the Upper Occoquan Service Authority (UOSA) water reclamation facility (WRF) which discharges its reclaimed water into the Occoquan Reservoir, a key water resource for Fairfax County. Integrated environmental modeling (IEM) provides a comprehensive approach towards the design and operation of water resource systems in which water supply, drainage, and sanitation are simulated as a single entity rather than independent units. In IEM, different standalone models, each representing a single subsystem, are linked together to analyze the complex interactions between various components of the system. This approach can be used for developing operational support tools for an IPR system to ensure timely and informed decision-making in response to the fluctuating conditions, e.g., weather patterns, plant performance, water demand, etc. The overarching goal of this research was to integrate different models and the data sources and develop a decision support system (DSS) to manage the UOSA-WRF performance. This resulting integrated model is used to predict future reservoir conditions based on the weather and streamflow forecasts obtained from the National Weather Service. The application runs various future scenarios to capture the possible variations of the pollutant loadings in the streams, withdrawals by the water treatment plant, WRF effluent flows, and plant operations and provide feedback to plant operators. The entire integrated model is operated periodically to output data on user-friendly dashboards, displaying historical and forecasting trends. The DSS provides stakeholders with a holistic view for the design, planning, risk assessments, and potential improvements in various components of the water supply chain, not just for the Occoquan but for any reservoir augmentation type IPR system.

Este trabalho traz como contribuição o início sistemático de estudos para o projeto e execução de ozonizadores dedicados a estações de tratamento de água e esgotos domésticos com tecnologia totalmente nacional. O objetivo é desenvolver um sistema que apresente custo reduzido de fabricação, implantação, manutenção e também boa eficiência na produção de ozônio. Equipamentos auxiliares para bombeamento e tratamento do ar não são necessários, além de ser possível a ampliação do sistema. Devido ao caráter multidisciplinar, este trabalho aborda a problemática da geração de subprodutos danosos ao homem e ao meio ambiente pelo uso de desinfetantes tradicionais, bem como um processo alternativo de tratamento pelo emprego do ozônio. Após descrever os fenômenos físicos envolvidos no método das descargas corona, um tratamento matemático apresenta elementos para o projeto ótimo deste sistema. Contudo, para viabilizar o uso de materiais disponíveis no mercado, os valores adotados nos arranjos iniciais seguiram aproximadamente estas indicações. Os ensaios foram realizados e a produção de ozônio foi obtida por titulação iodométrica. Os primeiros resultados foram tabulados e comparados com valores informados pelos equipamentos de mercado. Sugestões de implantação em campo para trabalhos futuros são apresentadas. / Studies for the project and execution of ozonizers dedicated to the wastewater and water treatment with total national technology were presented. The aim of this work consists of developing a system which minimize the manufacturing process, implementation and maintenance costs and also improves the ozone production efficiency. Accessory pumping equipments has been eliminated with the use of Venture\'s system to inject the ozone in liquid and air treatment has not been used to reduce costs. While this system loses efficiency with air no treatable, it allows a parallel and serial set-up to improve its performance. To support this work, an extended bibliographical analyzes has been carried out, which due to its multidiscipline characteristic was separated into studies of the traditional disinfectant procedures, alternative ozone treatment and, the physical corona discharges phenomena. The two prototypes were developed and, their obtained with the iodometric titration method, was also compared with those of market equipments. These preliminary comparisons have shown that these prototypes have a good performance inclusive with one of them having an ozone production superior than one of market equipments. Suggestions of implantation in field and other improvements for future work are also presented.

Este trabalho traz como contribuição o início sistemático de estudos para o projeto e execução de ozonizadores dedicados a estações de tratamento de água e esgotos domésticos com tecnologia totalmente nacional. O objetivo é desenvolver um sistema que apresente custo reduzido de fabricação, implantação, manutenção e também boa eficiência na produção de ozônio. Equipamentos auxiliares para bombeamento e tratamento do ar não são necessários, além de ser possível a ampliação do sistema. Devido ao caráter multidisciplinar, este trabalho aborda a problemática da geração de subprodutos danosos ao homem e ao meio ambiente pelo uso de desinfetantes tradicionais, bem como um processo alternativo de tratamento pelo emprego do ozônio. Após descrever os fenômenos físicos envolvidos no método das descargas corona, um tratamento matemático apresenta elementos para o projeto ótimo deste sistema. Contudo, para viabilizar o uso de materiais disponíveis no mercado, os valores adotados nos arranjos iniciais seguiram aproximadamente estas indicações. Os ensaios foram realizados e a produção de ozônio foi obtida por titulação iodométrica. Os primeiros resultados foram tabulados e comparados com valores informados pelos equipamentos de mercado. Sugestões de implantação em campo para trabalhos futuros são apresentadas. / Studies for the project and execution of ozonizers dedicated to the wastewater and water treatment with total national technology were presented. The aim of this work consists of developing a system which minimize the manufacturing process, implementation and maintenance costs and also improves the ozone production efficiency. Accessory pumping equipments has been eliminated with the use of Venture\'s system to inject the ozone in liquid and air treatment has not been used to reduce costs. While this system loses efficiency with air no treatable, it allows a parallel and serial set-up to improve its performance. To support this work, an extended bibliographical analyzes has been carried out, which due to its multidiscipline characteristic was separated into studies of the traditional disinfectant procedures, alternative ozone treatment and, the physical corona discharges phenomena. The two prototypes were developed and, their obtained with the iodometric titration method, was also compared with those of market equipments. These preliminary comparisons have shown that these prototypes have a good performance inclusive with one of them having an ozone production superior than one of market equipments. Suggestions of implantation in field and other improvements for future work are also presented.

Water and wastewater treatment is a critical service provided for protecting human health and the environment. Over the past decade, increasing attention has been placed on energy consumption in water and wastewater systems for the following reasons: (1) Water and energy are two interrelated resources. The nexus between water and energy can intensify the crises of fresh water and fossil fuel shortages; (2) The demand of water/wastewater treatment services is expected to continue to increase with increasing population, economic development and land use change in the foreseeable future; and (3) There is a great potential to mitigate energy use in water and wastewater systems by recovering resources in wastewater treatment systems. As a result, the goal of this dissertation study is to assess the life cycle energy use of both water supply systems and wastewater treatment systems, explore the potential of integrated resource recovery to reduce energy consumption in wastewater systems, and understand the major factors impacting the life cycle energy use of water systems. To achieve the goal, an input-output-based hybrid embodied energy model was developed for calculating life cycle energy in water and wastewater systems in the US. This approach is more comprehensive and less labor intensive than the traditional life cycle assessment. Additionally, this model is flexible in terms of data availability. It can give a rough estimation of embodied energy in water systems with limited data input. Given more site specific data, the model can modify the embodied energy of different energy paths involved in water related sectors. Using the input-output-based hybrid embodied energy model, the life cycle energy of a groundwater supply system (Kalamazoo, Michigan) and a surface water supply system (Tampa, Florida) was compared. The two systems evaluated have comparable total energy embodiments based on unit water production. However, the onsite energy use of the groundwater supply system is approximately 27% greater than the surface water supply system. This was primarily due to more extensive pumping requirements. On the other hand, the groundwater system uses approximately 31% less indirect energy than the surface water system, mainly because of fewer chemicals used for treatment. The results from this and other studies were also compiled to provide a relative comparison of embodied energy for major water supply options. The comparison shows that desalination is the most energy intensive option among all the water sources. The embodied energy and benefits of reclaimed water depend on local situations and additional treatment needed to ensure treated wastewater suitable for the desired application. A review was conducted on the current resource recovery technologies in wastewater treatment systems. It reveals that there are very limited life cycle studies on the resource recovery technologies applied in the municipal wastewater treatment systems and their integrations. Hence, a life cycle study was carried out to investigate the carbon neutrality in a state-of-art wastewater treatment plant in Tampa, FL. Three resource recovery methods were specifically investigated: onsite energy generation through combined heat and power systems, nutrient recycling through biosolids land application, and water reuse for residential irrigation. The embodied energy and the associated carbon footprint were estimated using the input-output-based hybrid embodied energy model and carbon emission factors. It was shown that the integrated resource (energy, nutrient and water) recovery has the potential to offset all the direct operational energy; however, it is not able to offset the total embodied energy of the treatment plant to achieve carbon neutrality. Among the three resource recovery methods, water reuse has the highest potential of offsetting carbon footprint, while nutrient recycling has the lowest. A final application of the model was to study on the correlation between embodied energy in regional water supply systems and demographic and environmental characteristics. It shows that energy embodied in water supply systems in a region is related to and can be estimated by population, land use patterns, especially percentage of urban land and water source, and water sources. This model provides an alternative way to quickly estimate embodied energy of water supply in a region. The estimated embodied energy of water supply can further be used as a supporting tool for decision making and planning.

Due to the ever increasing concerns about pollutants and contaminants found in water, new treatment technologies have been developed. Ozonation is one of such technologies. It has been widely applied in the treatment of pollutants in water and wastewater treatment processes. Ozone has many applications such as oxidation of organic components, mineral matter, inactivation of viruses, cysts, bacteria, removal of trace pollutants like pesticides and solvents, and removal of tastes and odours. Ozone is the strongest conventional oxidant that can result in complete mineralisation of the organic pollutants to carbon dioxide and water. Because ozone is unstable, it is generally produced onsite in gas mixtures and is immediately introduced to water using gas/liquid type reactors (e.g. bubble columns). The ozone reactions are hence of the type gas liquid reactions, which are complex to model since they involve both chemical reactions, which occur in the liquid phase, and mass transfer from the gas to the liquid phase. This study focuses on two aspects: mass transfer and chemical reactions in multicomponent systems. The mass transfer parameters were determined by experiments under different conditions and the chemical reactions were studied using single component and multicomponent systems. Two models obtained from the literature were adapted to the systems used in this study. Mass transfer parameters in the semi-batch reactor were determined using oxygen and ozone at different flow rates in the presence and absence of t-butanol. t-Butanol is used as a radical scavenger in ozonation studies and it has been found to affect the gas-liquid mass transfer rates. An experimental study was carried out to investigate the effects of t-butanol concentrations on the physical properties of aqueous solutions, including surface tension and viscosity. It was found that t-butanol reduced both properties by 4% for surface tension and by a surprising 30% for viscosity. These reductions in the solution physical properties were correlated to enhancement in the mass transfer coefficient, kL. The mass transfer coefficient increased by about 60% for oxygen and by almost 50% for ozone. The hydrodynamic behaviour of the system used in this work was characterised by a homogeneous bubbling regime. It was also found that the gas holdup was significantly enhanced by the addition of t-butanol. Moreover, the addition of t-butanol was found to significantly reduce the size of gas bubbles, leading to enhancement in the volumetric mass transfer coefficient, kLa. The multicomponent ozonation was studied with two systems, slow reactions when alcohols were used and fast reactions when endocrine disrupting compounds were used. ii These experiments were simulated by mathematical models. The alcohols were selected depending on their volatilization at different initial concentrations and different gas flow rates. The degradation of n-propanol as a single compound was studied at the lowest flow rate of 200 mL/min. It was found that the degradation of n-propanol reached almost 60% within 4 hours. The degradation of the mixture was enhanced with an increase in the number of components in the mixture. It was found that the degradation of the mixture as three compounds reached almost 80% within four hours while the mixture as two compounds reached almost 70%. The effect of pH was studied and it was found that an increase in pH showed slight increase in the reaction. Fast reactions were also investigated by reacting endocrine disrupting chemicals with ozone. The ozone reactions with the endocrine disrupters were studied at different gas flow rates, initial concentrations, ozone concentrations and pH. The degradation of 17β-estradiol (E2) as a single compound was the fastest, reaching about 90% removal in almost 5 minutes. However estrone (E1) degradation was the lowest reaching about 70% removal at the same time. The degradation of mixtures of the endocrine disruptors was found to proceed to lower percentages than individual components under the same conditions. During the multicomponent ozonation of the endocrine disruptors, it was found that 17β-estradiol (E2) converted to estrone (E1) at the beginning of the reaction. A MATLAB code was developed to predict the ozone water reactions for single component and multicomponent systems. Two models were used to simulate the experimental results for single component and multicomponent systems. In the case of single component system, good simulation of both reactions (slow and fast) by model 1 was obtained. However, model 2 gave good agreement with experimental results only in the case of fast reactions. In addition, model 1 was applied for multicomponent reactions (both cases of slow and fast reaction). In the multicomponent reactions by model 1, good agreement with the experimental results was also obtained for both cases of slow and fast reactions.

PŘIBYLOVÁ, M. (2015): Impacts of the realization of investments in water infrastructure on the development of small municipalities. Master thesis. Charles University in Prague, Faculty of Science, Department of Social Geography and Regional Development, Prague, pp. 120. This thesis deals with the disposal of waste water in small municipalities. The theses addresses the impacts that may be caused by investment in the construction of water infrastructure. This investment is very expensive for small municipalities and could lead them into debt. The question to be answered is whether the construction of facilities for wastewater treatment is really important for small municipalities (and their development) and if it should be done in compliance with the EU directive. The task of the study is to assess the current situation of the requirement to build a system of wastewater treatment in small municipalities in Czechia. The study is written from the perspective of a social geographer and in particular in an economic and developing point of view. The theses is also trying to suggest an alternative and cheaper solution. The impacts of these investments could be identified on the basis of the relevant review of the literature and thanks to the responses from the interviews which were conducted both with...

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Abstract Electrocoagulation (EC) is an emerging technology that combines the functions and advantages of conventional coagulation, flotation, and electrochemistry in water and wastewater treatment. The aims of this work included doing an updated literary review of recent feasible applications of EC, which were found to be plentiful. Since the economic and practical operational key figures related to EC haven’t been extensively mapped out before, this was a prime objective of this part of the work. The aim of the next part of this work was to find new feasible applications for EC in the treatment of water and wastewater. The studied wastewaters included bio- and synthetic oil-in-water emulsions, various industrial nutrient-containing wastewaters, and peat bog drainage water containing humic substances (an interesting and topical problem, especially in Finland). These studies proved the feasibility of EC. In addition, larger-scale experiments were also conducted successfully, thus proving the scalability of the EC process. Extensive economic analyses of the studied EC applications were also done. The operational costs and energy consumption of EC were found to be very low—typically about 0.1–1.0 €/m3 and 0.4–4.0 kWh/m3. It has been forecasted that in the future there will be a shortage of virgin phosphorus. Therefore, another essential purpose of this work was to conduct a preliminary study on the feasibility of using EC for nutrient (especially phosphorus, but also nitrogen) removal and recovery from different types of real wastewater. Specifically, it may be possible to use EC sludges containing notable amounts of phosphorus and nitrogen as additives in granulated bio ash-based fertilizer products for various applications. This is a novel idea and a “hot topic” in the waste utilization sector and in circular and bioeconomy. / Tiivistelmä Elektrokoagulaatio (electrocoagulation, EC) on nosteessa oleva teknologia, joka yhdistää perinteisen koagulaation, flotaation ja sähkökemian hyödyt ja mahdollisuudet vesien ja jätevesien käsittelyssä. Tämän työn ensimmäisenä tavoitteena oli laatia kirjallisuuskatsaus EC:n viimeaikaisista käyttökelpoisista sovelluksista, joita löytyi runsaasti. Koska EC:n toiminnallisia ja taloudellisia avainlukuja ei ole kartoitettu kattavasti aiemmin, tämän tekeminen oli tämän osion tärkein tavoite. Väitöstyön seuraavana tavoitteena oli löytää uusia sovellutuksia EC:lle vesien ja jätevesien käsittelyssä. Tutkittuja vesiä olivat bio- ja synteettisistä öljyistä valmistetut öljy-vesiemulsiot, erilaiset teolliset ravinnepitoiset jätevedet ja humusainepitoiset turvesoiden valumavedet (kiinnostava ja ajankohtainen ongelma, erityisesti Suomessa). EC todettiin käyttökelpoiseksi teknologiaksi näissä kokeissa. Suuremman skaalan kokeilla todistettiin lisäksi EC-prosessin skaalautuvuus. Lisäksi, em. EC-sovellutuksista suoritettiin kattavat taloudelliset analyysit. EC:n käyttökustannukset ja energiankulutus todettiin erittäin pieniksi, tyypillisesti ne olivat välillä 0.1–1.0 €/m3 ja 0.4–4.0 kWh/m3. On ennustettu, että tulevaisuudessa on pulaa neitseellisestä fosforista. Tästä johtuen eräs tämän työn keskeisistä tarkoituksista oli suorittaa alustavia kokeita liittyen EC:n käyttökelpoisuuteen ravinteiden (erityisesti fosfori, mutta myös typpi) poistossa ja talteenotossa aidoista jätevesistä. Erityisesti jatkossa voisi olla järkevää hyödyntää runsaasti fosforia ja typpeä sisältäviä EC-sakkoja lisäaineina rakeistetuissa biotuhkapohjaisissa lannoitteissa eri sovellutuksissa. Tämä idea on uusi ja on jo herättänyt suurta kiinnostusta mm. kierto- ja biotaloussektoreilla.