Groundwater arsenic contamination is currently a global problem, and also a concern at numerous former industrial sites, agricultural sites, landfill sites and mining operations in the U.S. This dissertation aims to develop improved strategies of remediating these arsenic contaminated aquifers. It focuses on two distinct approaches of remediation: (1) mobilizing arsenic from contaminated aquifer sediments to decrease the quantity of arsenic at the source of contamination; and (2) immobilizing arsenic in situ, to decrease the mobility and bioavailability of this arsenic. Optimal remediation may well involve combinations of these two approaches. Arsenic mobilization using oxalic acid is effective because oxalic acid dissolves arsenic host minerals and competes for sorption sites on those minerals. In this dissertation, oxalic acid treatment was tested using sediments with contrasting iron mineralogies and arsenic contents from the Dover Municipal Landfill and the Vineland Chemical Company Superfund sites. Oxalic acid mobilized arsenic from both sites and the residual sediment arsenic was less vulnerable to microbial reduction than before the treatment. Oxalic acid thus could improve the efficiency of widely used pump-and-treat remediation. Oxalic acid did not remove all of the reactive iron(III) minerals in Vineland sediment samples, and thus released significant quantities of arsenic into solution under reducing conditions than the Dover samples. Therefore, the efficacy of pump-and-treat must consider iron mineralogy when evaluating its overall potential for remediating groundwater arsenic. Arsenic immobilization occurs by changing the chemical state, or speciation, of arsenic and other elements in the system. Arsenic is often assumed to be immobile in sulfidic environments. In this dissertation, sulfate reduction was stimulated in sediments from the Vineland Superfund site and the Coeur d'Alene mining district. Sulfate reduction in the Coeur d'Alene sediments was more effective at removing arsenic from solution than the Vineland sediments. The Vineland sediments initially contained abundant reactive ferrihydrite, and underwent extensive sulfur cycling during incubation. As a result, arsenic in the Vineland sediments could not be effectively converted to immobile arsenic-bearing sulfides, but instead a part of the arsenic was probably converted to soluble thioarsenates. Therefore, coupling between the iron and sulfur redox cycles must be fully understood for arsenic immobilization by sulfate reduction to be successful. Arsenic can also be immobilized by retention on magnetite (Fe3O4). Magnetite is stable under a wide range of aquifer conditions including both oxic and iron(III)-reducing environments. In this dissertation, a series of experiments were performed with sediments from the Dover and Vineland Superfund sites, to examine the potential of magnetite for use in arsenic immobilization. Our data suggest that the formation of magnetite can be achieved by the microbial oxidation of ferrous iron with nitrate. Magnetite can incorporate arsenic into its structure during formation, forming a stable arsenic sink. Magnetite, once formed, can also immobilize arsenic by surface adsorption, and thus serve as a reactive filter when contaminated groundwater migrates through the treatment zone. Reactive transport modeling is used for investigating the magnetite based arsenic immobilization strategy and for scaling laboratory results to field environments. Such modeling suggests that the ratio between iron(II) and nitrate in the injectant regulates the formations of magnetite and ferrihydrite, and thus regulates the long-term evolution of the effectiveness of the strategy. The results from field-scale models favor scenarios that rely on the chromatographic mixing of iron(II) and nitrate after injection. The studies in this dissertation demonstrate that the environmental fate of arsenic depends on the biogeochemical cycling of arsenic, iron, and to a lesser extent, sulfur. The development of effective groundwater arsenic remediation strategies depends on a good understanding of each of the involved processes, and their combinations.

Water quality from surface sources is fast deteriorating due to pollution from organic compounds. Among the organic compounds are chlorophenols, which are described as priority pollutants because of their detrimental effects. One way of removing them from water is by using membranes. However direct removal of chlorophenols using membranes is limited due to the inherent problem of membrane fouling. The thesis describes fabrication of thin film composite membranes modified with Ag-TiO2 and Ag-ZnO for enhancing filtration properties of the membranes for removal of 2-CP and 2,4-DCP and improving the antifouling properties of the modified membranes. Chlorophenols, 2- CP, 2,4-DCP and 2, 4, 6-TCP were determined from Vaal and Klip River using SPE- HLPC method. The SPE - HPLC method was validated by determining breakthrough volume, repeatability, reproducibility, linearity, MDL and LOQ. Nanoparticles (NPs), Ag, ZnO and TiO2 and nanocomposites (NCs), Ag-TiO2 and Ag-ZnO were synthesized using precipitation method and chemical reduction for Ag. The NPs and NCs were characterised using UV-Vis, FTIR, XRD, SEM and EDX. The synthesised NPs and NCS were evaluated for photocatalytic degradation of 2-CP and 2,4-DCP, antimicrobial activity against E.coli. and toxicity against Daphnia magna. Nanocomposites were then embedded into the PA thin film membrane surface using interfacial polymerisation and PES as a support material to produce the antifouling Ag-TiO2/PA-TFC and Ag-ZnO/PA-TFC membranes. The control PATFC membrane was prepared with no added NCs to the membrane. The membranes were characterised using ATR-FTIR, contact angle, SEM and AFM. The performance of the membranes was tested using permeation flux (using pure water and 2-CP / 2,4-DCP solutions as feed) against the neat PA-TFC membrane. Membranes were further tested for rejection of 2- CP and 2, 4 – DCP, antifouling properties and flux recoveries. The stability of the antifouling properties of the membrane was evaluated through silver release test. The performance of the membranes was tested using real water samples from Vaal and Klip Rivers. The SPE-HPLC method was repeatable, reproducible with % RSD less than 5%. Linearity range of (0.1-50 µg/ L) and recoveries of spiked water samples of more than 97% for 2-CP and 2,4-DCP but lower at 64 and 75% for 2.4.6-TCP were achieved. The Ag, TiO2 and ZnO NPs showed characteristic peaks of NPs with UV-Vis. The absorption peaks were all blue shifted due to quantum confinements. The crystalline structures were confirmed as face centred cubic, anatase and hexagonal wurzite for Ag, TiO2 and ZnO respectively. The morphology as observed from SEM showed spherically shaped nanoparticles with average sizes of 68.25 ± 4.7 and 50.92 ± 3.39 nm for Ag and TiO2 respectively. The ZnO NPs were rod -like shaped with average length = 603 nm ± 50.4 and a width = 82.92 ± 5. 40nm. Successful incorporation of silver into the TiO2 and ZnO structures was confirmed by elemental analysis, EDX. From SEM images, silver particles were distributed around TiO2 particles and ZnO rods. The presence of silver showed a remarkable improvement in photodegradation of 2-CP and 2,4-DCP from less than 40% to 86% with 2, 4- DCP. Silver modified TiO2 and ZnO showed antibacterial activity against E.coli. with minimum concentration of inhibition as low as 1.56 mg/L for both Ag-ZnO (5) and Ag-TiO2 (5). Silver was more toxic against Daphnia magna than Ag-ZnO (5) and AgTiO2 (5). The polyamide layer was confirmed by the presence of the amide I peak at 1650 cm1 and 1670 cm-1 in the Ag-TiO2/ PA-TFC and Ag-ZnO/ PA-TFC membranes. The appearance of NCs particles spread across the surface of the thin layer of the membranes as observed from surface SEM images confirming their incorporation into the PA layer. The presence of the NCs in the membranes improved water flux, water permeation, rejection of 2- CP, and 2,4-DCP, antifouling properties of the membranes and flux recoveries of more than 93 % was achieved. Silver release test revealed that Ag-ZnO/PA-TFC membrane performed better than AgTiO2/PA-TFC membrane because of the steady release of silver, which shows long lasting antifouling properties. When applied to real water samples from Vaal and Klip River, the prepared membranes showed better antifouling properties than the neat PA-TFC membrane

Disinfection by-products (DBPs) are a major group of water contaminants and their role in causing adverse health outcomes, including adverse pregnancy outcomes, endocrine disruption, respiratory related adverse health outcomes and cancer has been subject to extensive epidemiological and toxicological research and review. Determination of safe exposure to DBPs, particularly within drinking water supplies, has been a topic of extensive debate, with a wide range of acceptable levels set across the industrialized world. The focus of the research in this thesis was on two of the main health outcomes associated with DBP exposure, namely adverse pregnancy outcomes and asthma related symptoms. To assess adverse pregnancy outcomes in Perth, an extensive classification quantification of the major DBPs in Perth drinking water was conducted. A registrybased prevalence study was carried out to assess birth defects in relation to high, medium and low DBP areas (defined by the water sampling and analysis). It was found that women living in high THM areas are 22% (odds ratio (OR) 1.22, 95% confidence interval (95% CI) 1.01-1.48) more likely of having a baby with any birth defect. High exposure was also strongly associated with an increased risk of having a baby with a cardiovascular defect (62% increased risk). Low birth weight and prematurity were also assessed; however these outcomes were not associated with an increased risk through an increase in exposure. Following on from this analysis, a population risk assessment model was developed for DBPs in high exposure environments. This involved a three step process: (i) Firstly a questionnaire-based validation and reliability study was used to assess water consumption patterns of a population of pregnant women in Perth. (ii) Secondly a prediction model for teratogenic burden of DBPs in Perth was developed, related to the exposure patterns of the population of pregnant women involved in the validation and reliability study. (iii) Finally, combining the information collected in (i) and (ii), along with the regression slope estimates for birth weight from the prevalence study (defined in Section 2.2.1), a dose-response model for THMs and birth weight was developed. Predictive simulations for birth weights at given THM levels were then conducted. It was estimated that pregnant women in Perth are exposed to between 0.3 – 4.10 µg/day ingested TTHM, and of this, the more toxic brominated forms accounted for between 0.27 – 3.69 µg/day. Based on a dose-response model used, birthweights calculated for the ‘hypothetical’ exposures ranged from 3403.2g for the highest exposure to 3503.5g in the lowest exposure, which is a difference of over 100g. Although the resulting reduction in birth weight is not extreme, there is still a significant reduction in birth weight present as exposure to TTHMs increases. This is the first doseresponse model to be developed to assess an adverse pregnancy outcome based on pregnant women exposure data, and will be a useful tool for assessing varying exposures throughout not only Australia but also throughout the industrialised world, where DBP exposure is highly prevalent.

<p>Utan vatten inget liv. Människor är beroende av rent vatten för sin överlevnad. I många länder orsakar idag bristen på rent vatten sjukdomar och för tidig död. Världens problem med sötvatten i form av brist och svåra föroreningar orsakade av människan kan te sig kolossala. Befolkningsökning och ändrade levnadssätt påverkar. Industrier och jordbruk har stor påverkan men också den enskilda människans vattenanvändning har betydelse.</p><p> </p><p>I Sverige tycks den allmänna inställningen vara att vi inte har ett problem med vårt användande av vatten. Men vid en närmare undersökning av vårt innanhav Östersjöns problem med exempelvis övergödning och syrebrist och utsläppen av näringsämnen ifrån våra enskilda avlopp kan man ställa sig frågande. Även svenskens nyttjande av grundvattenreserver kan te sig olämpligt utifrån ett ekologiskt hållbart perspektiv. Att sedan detta vatten renas till dricksvattenkvalitet för att sedermera användas till att vattna fuktälskande växter som är planterade i gassande sol i en sandig torr jord kan vara förbryllande. Medvetenhet utifrån det lilla perspektivet, till exempel den svenska hemträdgården, kan vara åskådligt. Samtidigt kan det kanske också bidra till en i framtiden miljövänligare politik där målet är att rent sötvattnen skall finnas tillgängligt för alla i ett långt perspektiv.</p><p> </p><p>I denna litteraturstudie, möjligheten till en rationell vattenanvändning i den privata hemträdgården ur ett ekologiskt hållbart perspektiv. Flertalet olika metoder att hushålla med vatten och att tillvarata, rena och använda sig av nederbörd och gråvatten belyses. Resultatet är indelat i två delar; hushållning och rening. I den första redogörs på vilka sätt en effektivisering av vattenanvändandet kan gå till. Lättast och effektivast görs detta genom att dra ner på förbrukningen. Detta går enkelt att göra med några få tekniker. Till exempel att bättra på jordstruktur med organisktmaterial, att placera växter på platser som liknar deras naturliga habitat, minska avdunstning och forma platsen så att nederbörd kan ledas dit den behövs. Att se över hur extrabevattning ska tillämpas på effektivast sätt samt vilken vattenkälla detta vatten kommer ifrån tillhör också detta hushållande stycke. I den andra delen redogörs för olika metoder som kan tillämpas i en trädgård för att rena grå- och dagvatten så att trädgårdens naturliga potential till att vara en del av jordens naturliga kretslopp främjas. Lättast görs detta genom en begränsning av föroreningar redan vid deras källa. Därefter kan infiltrationsytor, infiltrationsplanteringar, biodiken, gröna tak, dammar, konstruerade våtmarker, rotzoner, UV-ljus och aquakulturer vara mer eller mindre användbara metoder som kan tillämpas i hemträdgården.</p><p> </p><p>Vattenfrågan bör klarläggas redan vid planeringen av byggnader och trädgård. Varje tomt måste sättas in i sitt sammanhang då dessa unika med speciella förutsättningar och problem. Hemträdgården är en utmärkt plats för experiment och utvecklingsarbete av ett hållbart vattenanvändande.</p> / <p>Without water there would be no life on earth. People depend of clean water for their survival. Today in many countries the lack of clean water is causing disease and premature death. World problems with fresh water in the form of shortage and severe pollution caused by humans may seem colossal. Industries and agriculture have a major impact but also the individual’s water-use has consequences.</p><p> </p><p>In Sweden the public opinion seems to be that we do not have a problem with our use of water. But with a closer look on facts that is not the case. For example our inland sea, Östersjön, and our contribution to its problems with euthrophication, lack of oxygen with the spillage of nutrients from the sewers and agriculture. Also the Swedish use of ground water may seem inappropriate in an ecological sustainable perspective. What is even more puzzling is that this water gets cleaned to a drinking water quality and then gets used for watering plants in the garden or to wash the car. Consciousness from the small perspective (as the Swedish private garden) can contribute to a future environmentally friendly politic that will lead to a sustainable water-use in a long perspective.</p><p> </p><p> </p><p>With this paper I would like to demonstrate, in a literature study, the possibility of a rational water-use in the private home garden from an ecological sustainable perspective.  Different methods of economising the water-use, gathering and cleaning stormwater and greywater will be illustrated. The result part will be divided into two parts; economization of water and cleaning of water.</p><p> </p><p>The first part describes the ways in which an efficiency of water-use can be preceded. The easiest way this is done is to cut down the consumption of water. This can easily be done with a few techniques. For example to improve the soil structure with organic material, placing of plants in places that resemble their natural habitat, reduction of evaporation and shaping pf the site so that precipitation can be managed where it is needed. Also to in which way irrigation is applied in the most efficient way and from which source this water is taken is presented in this part. The second part describes different methods of cleaning grey- and stormwater so the home garden’s natural potential to be a part of the earth’s natural rhythm is promoted.</p><p>Most easily this is done by stopping the pollution at the source. After that infiltration areas, bioswales, green roofs, ponds, constructed wetlands, reed beds, UV light and aquacultures can be more or less potential methods to be applied in the home garden.</p><p> </p><p>Water issues should be clarified already at the design process with homes and gardens. Each plot and garden is unique with its particular conditions and problems. Therefore needs every case to be seen in its particular context in order to obtain the optimal solution for that particular place.The home garden is a suitable place for experimental development of a sustainable water-use.</p>

This thesis examines the impact of urban water infrastructure on the Ottawa River through an exploration of the City of Ottawa's historical development from the early modern period to the present. The primary aim is to explain how the Ottawa River came to be removed or ignored from the City of Ottawa's urban development strategy. The thesis focuses on the periods of 1910-1920 (early modernity) and 1999-2012 (present). The theories applied are risk, risk management, normal accident theory and the politics of infrastructure. The data and information for this thesis were primarily retrieved from the City of Ottawa website as well as from the archives of the City of Ottawa. The thesis identifies several factors explaining why the Ottawa River has been mistreated over time, as well as the challenges involved in reforming present-day practices and infrastructure. Several recommendations to fix the situation are advanced.

Utan vatten inget liv. Människor är beroende av rent vatten för sin överlevnad. I många länder orsakar idag bristen på rent vatten sjukdomar och för tidig död. Världens problem med sötvatten i form av brist och svåra föroreningar orsakade av människan kan te sig kolossala. Befolkningsökning och ändrade levnadssätt påverkar. Industrier och jordbruk har stor påverkan men också den enskilda människans vattenanvändning har betydelse.   I Sverige tycks den allmänna inställningen vara att vi inte har ett problem med vårt användande av vatten. Men vid en närmare undersökning av vårt innanhav Östersjöns problem med exempelvis övergödning och syrebrist och utsläppen av näringsämnen ifrån våra enskilda avlopp kan man ställa sig frågande. Även svenskens nyttjande av grundvattenreserver kan te sig olämpligt utifrån ett ekologiskt hållbart perspektiv. Att sedan detta vatten renas till dricksvattenkvalitet för att sedermera användas till att vattna fuktälskande växter som är planterade i gassande sol i en sandig torr jord kan vara förbryllande. Medvetenhet utifrån det lilla perspektivet, till exempel den svenska hemträdgården, kan vara åskådligt. Samtidigt kan det kanske också bidra till en i framtiden miljövänligare politik där målet är att rent sötvattnen skall finnas tillgängligt för alla i ett långt perspektiv.   I denna litteraturstudie, möjligheten till en rationell vattenanvändning i den privata hemträdgården ur ett ekologiskt hållbart perspektiv. Flertalet olika metoder att hushålla med vatten och att tillvarata, rena och använda sig av nederbörd och gråvatten belyses. Resultatet är indelat i två delar; hushållning och rening. I den första redogörs på vilka sätt en effektivisering av vattenanvändandet kan gå till. Lättast och effektivast görs detta genom att dra ner på förbrukningen. Detta går enkelt att göra med några få tekniker. Till exempel att bättra på jordstruktur med organisktmaterial, att placera växter på platser som liknar deras naturliga habitat, minska avdunstning och forma platsen så att nederbörd kan ledas dit den behövs. Att se över hur extrabevattning ska tillämpas på effektivast sätt samt vilken vattenkälla detta vatten kommer ifrån tillhör också detta hushållande stycke. I den andra delen redogörs för olika metoder som kan tillämpas i en trädgård för att rena grå- och dagvatten så att trädgårdens naturliga potential till att vara en del av jordens naturliga kretslopp främjas. Lättast görs detta genom en begränsning av föroreningar redan vid deras källa. Därefter kan infiltrationsytor, infiltrationsplanteringar, biodiken, gröna tak, dammar, konstruerade våtmarker, rotzoner, UV-ljus och aquakulturer vara mer eller mindre användbara metoder som kan tillämpas i hemträdgården.   Vattenfrågan bör klarläggas redan vid planeringen av byggnader och trädgård. Varje tomt måste sättas in i sitt sammanhang då dessa unika med speciella förutsättningar och problem. Hemträdgården är en utmärkt plats för experiment och utvecklingsarbete av ett hållbart vattenanvändande. / Without water there would be no life on earth. People depend of clean water for their survival. Today in many countries the lack of clean water is causing disease and premature death. World problems with fresh water in the form of shortage and severe pollution caused by humans may seem colossal. Industries and agriculture have a major impact but also the individual’s water-use has consequences.   In Sweden the public opinion seems to be that we do not have a problem with our use of water. But with a closer look on facts that is not the case. For example our inland sea, Östersjön, and our contribution to its problems with euthrophication, lack of oxygen with the spillage of nutrients from the sewers and agriculture. Also the Swedish use of ground water may seem inappropriate in an ecological sustainable perspective. What is even more puzzling is that this water gets cleaned to a drinking water quality and then gets used for watering plants in the garden or to wash the car. Consciousness from the small perspective (as the Swedish private garden) can contribute to a future environmentally friendly politic that will lead to a sustainable water-use in a long perspective.     With this paper I would like to demonstrate, in a literature study, the possibility of a rational water-use in the private home garden from an ecological sustainable perspective.  Different methods of economising the water-use, gathering and cleaning stormwater and greywater will be illustrated. The result part will be divided into two parts; economization of water and cleaning of water.   The first part describes the ways in which an efficiency of water-use can be preceded. The easiest way this is done is to cut down the consumption of water. This can easily be done with a few techniques. For example to improve the soil structure with organic material, placing of plants in places that resemble their natural habitat, reduction of evaporation and shaping pf the site so that precipitation can be managed where it is needed. Also to in which way irrigation is applied in the most efficient way and from which source this water is taken is presented in this part. The second part describes different methods of cleaning grey- and stormwater so the home garden’s natural potential to be a part of the earth’s natural rhythm is promoted. Most easily this is done by stopping the pollution at the source. After that infiltration areas, bioswales, green roofs, ponds, constructed wetlands, reed beds, UV light and aquacultures can be more or less potential methods to be applied in the home garden.   Water issues should be clarified already at the design process with homes and gardens. Each plot and garden is unique with its particular conditions and problems. Therefore needs every case to be seen in its particular context in order to obtain the optimal solution for that particular place.The home garden is a suitable place for experimental development of a sustainable water-use.

University of Macau / Faculty of Science and Technology / Department of Civil and Environmental Engineering

The aim of this master thesis study was improvement of the required operational conditions for aerobic granulation in sequencing batch reactors (SBRs). In the first part of the study, membrane bioreactor sludge (MBS) and conventional activated sludge (CAS), were used to investigate the effect of suspended seed sludge type on granulation in SBRs. The MBS granules were found to be advantageous in terms of size, resistance to toxic effects, stability and recovery compared to CAS granules. During non-inhibitory conditions, sCOD removal efficiencies were 70&plusmn / 13% and 67&plusmn / 11% for MBS and CAS, and total nitrogen (TN) removal efficiencies were 38&plusmn / 8% and 26&plusmn / 8%, respectively. In the second part of the study, the effects of period sequence (anoxic-aerobic and aerobic-anoxic) on aerobic granulation from MBS, and sCOD, N removal efficiencies were investigated. Granules developed in anoxic-aerobic period sequence were more stable and larger (1.8-3.5 mm) than granules developed in aerobic-anoxic sequence. Under steady conditions, almost 95% sCOD, 90% Total Ammonia Nitrogen (TAN) and around 39-47 % of TN removal was achieved. Almost 100% denitrification in anoxic period was achieved in anoxic-aerobic period sequence and it was observed around 40% in aerobic-anoxic period sequence. The effects of influent sulfate (from 35.1 mg/L to 70.2 mg/L) on treatment efficiencies of aerobic granules were also investigated. The influent SO42- concentrations of 52.6 mg/L to 70.2 mg/L promoted sulfate reduction. The produced sulfide (0.24 mg/L to 0.62 mg/L) inhibited the ammonia-oxidizing bacteria (AOB) performance by 10 to 50%.

Effect of ionic strength on the efficiency of heavy metal removal and recovery from aqueous solutions via continuous mode polymer enhanced ultrafiltration (PEUF) method was examined. Application of PEUF to divalent ions of cadmium, nickel and zinc after their prior linking with polyethylenimine (PEI) results in complete removal of metal ions from single component aqueous solutions at high pHs. Binding ability and hence the extent of metal retention in high ionic strength medium exhibits differences between solutions containing single and multicomponent metal mixtures. In single component metal solutions, extent of retention decreases but binding order of metals remains unaffected both in low and high ionic strength medium. But, in binary component metal mixtures, with increase in ionic strength the binding order of metals changes. Fractional separation of Cd, Ni and Zn ions from equimolar binary and ternary mixtures of these metals and effect of ionic strength on fractional separation efficiency were investigated. Depending on pH and salt concentration and metal pairs present in the solution fractional separation can be achieved.Dynamic and static light scattering experiments were performed in order to gain insight about the conformational changes in PEI structure due to the pH and ionic strength alternations in solution. It was found that, the increase in ionic strength reduces the size of the macromolecules. A chemical equilibrium model was developed in order to estimate the apparent binding constants of metal-PEI complexes. Based on the data obtained from continuous and batch mode PEUF experiments apparent binding constants were estimated and compared to reveal the performance differences between these operational modes.

This study aims to investigate the possibility of using calcium-alginate as a coagulant in low turbidity waters. Jar tests were initially performed with synthetically prepared turbid waters to investigate the effect of alginate and calcium concentrations, alginate&rsquo / s molecular weight, rapid mixing time and speed (schedule), initial pH and alkalinity of synthetic water on turbidity removal efficiency of calcium-alginate system step by step. Alum as a coagulant was then used in jar tests conducted with synthetic water to compare with calcium-alginate in terms of its turbidity removal efficiency and produced sludge properties. Finally, raw water acquired from water treatment plant was tested for treatability by using calcium-alginate based on previously determined optimum parameters via jar tests. Experiments of calcium-alginate system with synthetic water showed that calcium was a key parameter in coagulation and high molecular weight alginate performed better in turbidity removal. Significant improvements in turbidity removal were observed when mixing schedules were rearranged / especially in case of increasing rapid mixing time following calcium dosing. Calcium-alginate system neither was notably affected by pH or alkalinity nor did significantly change the pH or alkalinity of the medium. Alum worked well in turbidity removal with additional adjustments of pH and alkalinity, however / alum produced higher quantities of sludge than calcium-alginate system. &ldquo / Raw water&ldquo / experiments with calcium-alginate did not result in desired level of turbidity removals due to the excessively different characteristics of this water compared to the synthetically prepared turbid water.