Wetlands are significant contributors to global biodiversity, supporting disproportionately high numbers of species relative to their area. Riparian areas associated with wetlands provide many services that are both ecologically and economically important, such as groundwater recharge, sediment capture and shoreline stabilization, flood mitigation, nutrient processing, increased water quality, carbon sequestration, and essential habitat for wildlife. Agricultural activity has resulted in the drainage or modification of between 40-70% of wetland basins within the Prairie Pothole Region of the northern Great Plains. The impacts of human activity on the remaining wetlands are difficult to estimate and there is no one optimal indicator or assessment method that is applicable to all regions or situations. Locally developed riparian health assessments, designed to evaluate wetland function under different grazing regimes, are cost-effective with the potential for broader use in wetland environmental assessment, monitoring, and management or restoration activities. In this study I investigated the hypothesis that riparian health assessments can distinguish between wetlands in five categories of land use that represent different levels of anthropogenic modification: ungrazed cultivated cropland, ungrazed native grassland, grazed native grassland, ungrazed tame perennial forage, and grazed tame perennial forage. Noting that current riparian health assessment protocols lack a community composition component other than the presence and distribution of invasive and disturbance species, I also sampled plant species frequency at each of my study sites. I found that wetlands in cultivated croplands had significantly lower riparian health scores than wetlands in both tame and native grasslands. Among tame and native sites, grazing status was more important than upland cover type in determining wetland health, with grazed wetlands receiving significantly lower scores than their ungrazed counterparts. Despite their functional similarity to wetlands within native grasslands, species composition of wetlands within ungrazed tame perennial forage more closely resembled that of wetlands in cultivated uplands. Although grazing negatively affected riparian ground cover and soil stability, it significantly reduced both the overall cover and distribution of invasive plant species along wetland reaches. These results suggest that upland revegetation and restoration of function to degraded wetlands is not necessarily followed by re-establishment of original riparian species composition. If biodiversity is a desired outcome of wetland restoration efforts, additional measures must be taken to enable the establishment and persistence of preferred plant species.

This dissertation is an empirical modeling investigation of the impact of forest harvesting, climate change and topography on stream nitrate fluxes in the Turkey Lakes Watershed (TLW), Ontario, Canada. Data used for this study include topography (DEM), climate (mean monthly temperature and total monthly precipitation), wet nitrogen deposition (total monthly nitrate-N and ammonium-N), nitrate water samples and streamflow in 13 headwater catchments within the TLW. First, a paired-watershed approach was used to examine the impact of forest harvesting intensity on stream water nitrate fluxes by developing transfer function noise (TFN) models that related monthly stream water nitrate fluxes of three treatment catchments to those of one control catchment. Second, TFN models were also developed to relate monthly stream nitrate fluxes in 13 catchments to the temperature, precipitation and wet nitrogen deposition to examine the spatially varying responses of stream nitrate fluxes to changes in climate and bulk deposition. Third, geographically weighted regression (GWR) was introduced to model the spatial and temporal relationships between topography and stream nitrate fluxes in 13 headwater catchments. The results showed that there existed a new phenomenon of clustered wave-up and wave-down of the stream nitrate increases caused by clearcut and selectioncut at the monthly scale, respectively. This phenomenon was never reported by previous studies because it was not possible to be identified with ordinary least squares (OLS) regression at an annual scale. There also existed significant responses of stream nitrate fluxes to wet nitrogen deposition in all catchments at the monthly scale over a long-term record between 1982 and 2003. These responses were previously thought to be lower and masked by the impact of climate variations. There further existed significant spatial and seasonal variability of the relationships between topography and stream nitrate fluxes across space and over time. This variability was largely ignored in previous studies with possibly misleading interpretation on the empirical relations. / Thesis (Ph.D, Geography) -- Queen's University, 2012-12-31 22:37:39.137

M. Tech. (Chemical Engineering, Faculty of Engineering and Technology), Vaal University of Technology / Acid mine drainage (AMD) is a serious problem associated with mining activities, and it has the potential to contaminate surface and ground water. The aim of this study was to evaluate the performance of constructed wetland and photocatalysis in treating AMD. Three identical unvegetated upflow constructed wetlands packed with natural zeolite (clinoptilolite) and coarse silica sand were made of a cylindrical plastic pipe, and the slurry photocatalyst was prepared using quartz material. A hydro-alcohol thermal method was used to prepare an anatase core-void-shell TiO2 photocatalyst. The results showed that the three unvegetated upflow constructed wetlands (CW) had relatively similar percentage removal of heavy metals despite their varying concentrations within the AMD. The removals were: Fe (86.54 - 90.4%); Cr (56.2 - 64.5%); Mg (56.2 - 67.88%); Ca (77.1 - 100%); and 100% removal was achieved for Be, Zn, Co, Ni, and Mn. The removal of sulphate was also 30%. Heavy metals concentration in CW packing material was significantly higher in the outlet of the constructed wetlands than in the inlet. The adsorption isotherms revealed that the experimental data fitted the Langmuir Isotherms better, which suggested a monolayer coverage of heavy metals on the surface of the adsorbents; thermodynamic studies showed that the nature of adsorption taking place was physical; the kinetics models showed that the adsorption was first order reaction. A higher photocatalytic reduction (62%) of Cr(VI) was obtained at pH 2, 30 mg/l Cr(VI) initial concentration, and three hours of irradiation time. It was also found that the presence of Fe(III) enhanced the reduction of Cr(VI). The core-void-shell TiO2 photocatalyst showed a better activity than the commercial P25 Degussa for the reduction of Cr(VI) to Cr(III). The kinetic studies showed that the reduction of Cr(VI) was first order reaction. Photocatalytic reduction of Cr(VI) in real AMD sample was achieved only for the Douglas North Discharge (DND) sample (68%), and the Fe(III) reduction was found to be 83%. Therefore it was concluded that the combination of constructed wetland and UV/ TiO2 photocatalysis employing anatase core-void-shell TiO2 as a photocatalyst has a potential to reduce the toxicity of Cr(VI)-laden acid mine drainage.

The Kukkal basin, Tamil Nadu, India, receives most of its rain from the southwest monsoon (SWM). A sediment core from Kukkal Lake preserves a continuous sediment record from the early-Holocene to present (9000 yr BP to present). The present lake is situated at an elevation of similar to 1887m a.s.l., in a small basin that appears to have alternated between a and wetland depositional environment. Climate proxies, including sediment texture, total organic carbon (TOC), total nitrogen (TN), C/N, pollen and geochemical composition indicate a steady progression to wetter conditions, with two stepwise changes at about 8000, and between 3200 and 1800 yr BP. The change at 8000 yr BP appears to correspond to a brief (100-150years) dry spell recorded elsewhere in India. The change at 3200-1800 yr BP consisted in a rapid intensification of the SWM, and may correlate with the initiation of the Roman Warm Period'. There is no clear evidence of changes at the times of the Medieval Warm Period' (MWP') and the Little Ice Age' (LIA'). The C/N ratio of the sediments ranges from 14.02 to 8.31, indicating that the organic matter originated from a mixture of lacustrine algae, vascular and terrestrial plants. Chemical weathering indices (Chemical Index of Alteration (CIA), Chemical Index of Weathering (CIW), and Plagioclase Index of Alteration (PIA)) are consistent with extreme silicate weathering. Pollen data show a development from savanna vegetation prior to about 8000 yr BP, followed by grassland with palms, the appearance of ferns just prior to 3200 yr BP and the establishment of the tropical humid forest between 3200 and about 1800 yr BP.

Differences in microbial function via extracellular enzyme activity (EEA) were investigated to determine the potential effects of hydrology and plant-soil-microbe interactions in a young non-tidal freshwater riparian wetland. To study these relationships, three plots were established along a moisture gradient (Wet, Intermediate, Dry) within VCU Rice Center Within each main plot, five subplots were left undisturbed while another five were cleared of all above-ground plant biomass. Homogenized soil cores (top 10 cm) were analyzed for pH, redox, C:N, soil organic matter (SOM) content, saturation, and temperature. Microbial function was assessed using extracellular enzyme analysis. For most enzymes, a site difference was observed due to soil moisture content, which had an effect on soil pH, redox potential, and plant community composition. For most extracellular enzymes the presence of vegetation was associated with higher activity. It is important to note that reestablishing native hydrologic and vegetated conditions are paramount in achieving previous functionality.

In Kampala, the capital of Uganda, there is an extensive use of water mixed with wastewater for irrigation of crops. The water is taken from Nakivubo channel that flows through the centre of the city, and since the wastewater treatment in the city is insufficient, the channel water might contain pharmaceuticals that are spread to the farmlands and the crops that are grown in Nakivubo wetland. The aim of this Master’s thesis was to examine the concentration of some selected pharmaceuticals in water, soil and crop samples collected from Nakivubo channel and the area surrounding it. The water was analysed from five measurement points in the Nakivubo channel and Lake Victoria. The solid samples comprised of soil and crops collected from cocoyam, maize and sugar cane fields in the Nakivubo area. The pharmaceutical analyses were carried out through pharmaceutical extraction (solid phase extraction and QuEChERS) and the use of LC-MS (liquid chromatography combined with mass spectrometry). The capacities of the water and soil to reduce pharmaceuticals were analysed and a risk assessment was made in order to determine if it was harmful to drink water from Lake Victoria, the source of drinking water for Kampala, or to eat the crops that were grown in the wetland. A majority of the pharmaceuticals studied (42 substances) were detected in the water samples (29 substances). The most common pharmaceuticals detected in the water were atenolol, carbamazepine, sulfamethoxazole and trimethoprim. The antibiotics trimethoprim and sulfamethoxazole showed the highest average concentrations in the various water samples (26100 ng/l and 3790 ng/l respectively). Fewer pharmaceuticals were detected in the soil compared to the water (11 substances). The pharmaceuticals most frequently found in the soil were carbamazepine and pyrimethamine and they also had the highest average concentrations along with trimethoprim, 4.6-9.4 ng/g, 8.4-14.0 ng/g and 39.6 ng/g, respectively. No pharmaceuticals could be detected in the edible part of maize and sugar cane, but lidocaine, trimethoprim and pyrimethamine were found in detectable concentrations in the yam (on average 1.2-2.2 ng/g). A significant negative correlation could be found between carbamazepine and total suspended solids (TSS) in the water (linear regression: y = -0.67x +3.98, R2 = 0.35, p < 0.05, n = 14). The risk assessment showed that the concentrations found in the yam and water in Lake Victoria together with the average daily intake of yam and drinking water was not hazardous to the people of Kampala. However, eating more than 0.5 kg of yam daily might pose a risk with regards to pyrimethamine. On the other hand, the concentration in the yam might decrease when it is boiled, and this has not been accounted for. / I Ugandas huvudstad Kampala är det vanligt att vatten blandat med avloppsvatten från den centrala Nakivubokanalen används för bevattning av grödor. Avloppsreningen i staden är bristfällig och som ett resultat släpps mycket orenat avloppsvatten ut i naturen. Det är dock oklart om det finns läkemedel i Nakivubokanalen som tas upp av jordbruksmark och grödor odlade i Nakivubos våtmark. Syftet med det här examensarbetet var att studera koncentrationen av utvalda läkemedel i vatten-, mark- och grödprover insamlade i och längs Nakivubokanalen. Prover från fem mätplatser studerades i kanalen och Victoriasjön. Mark och grödprover fanns tillgängliga som samlats in från jams-, sockerrör- och majsfält i och kring Nakivubos våtmark. Läkemedelsanalyserna genomfördes med hjälp av läkemedelsextraktion i form av fastfasextraktion och QuEChERS samt LC-MS (vätskekromatografi kombinerat med masspektrometri). Utöver läkemedelsanalysen studerades markens och vattnets förmåga att rena läkemedel. Det utfördes även en enkel riskbedömning för att se om det var farligt att äta grödor odlade i våtmarken eller dricka vatten från Victoriasjön, som är Kampalas dricksvattenkälla. De flesta (29 st) av de 42 studerade läkemedlen detekterades i vattenproverna. De vanligast förekommande läkemedlen i vattnet var atenolol, karbamazepin, sulfametoxazol, och trimetoprim. Trimetoprim och sulfametoxazol hade de högsta koncentrationerna i de olika mätpunkterna i vattnet i medeltal, 26 100 ng/l respektive 3790 ng/l. I marken detekterades 11 av de 42 läkemedelsämnena. De vanligast detekterade läkemedlen i marken var karbamazepin samt pyrimethamine och det var också dessa som hade högst koncentrationer i medeltal, tillsammans med trimetoprim. Dessa tre läkemedel hade koncentrationer på 4,6-9,4 ng/g; 8,4-14,0 ng/g respektive 39,6 ng/g. Inga läkemedel kunde detekteras i majsen och sockerrören, men jamsen hade detekterbara koncentrationer av både lidokain, trimetoprim och pyrimethamine (1,2-2,2 ng/g i medeltal). I vattnet erhölls ett signifikant negativt samband mellan karbamazepin och totalt suspenderat material (linjär regression: y = -0,67x + 3,98; R2= 0,35; p < 0,05; n = 14). Riskanalysen visade att det inte bör vara farligt att äta jamsen eller dricka vattnet från Victoriasjön givet de koncentrationer som uppmättes och de mängder jams och vatten som förtärs dagligen. Det kan dock utgöra en risk att äta mer än 0,5 kg jams om dagen.

Peatlands act as carbon sinks while representing major sources of biogenic gases such as methane (CH4) and carbon dioxide (CO2), two potent greenhouse gases. Gas production and release in these peats soils are also influenced by overall warm temperatures and water table fluctuations due to the naturally shallow water table in the Florida Everglades. Releases of biogenic gases from Florida Everglades peat soils are not well understood and the temporal distribution and dynamics are uncertain. The general objective of this work was geared towards a methodological approach which aimed to examine the feasibility of capacitance moisture probes to investigate biogenic gas dynamics in various Florida Everglades peat soils at high temporal resolution. This work has implications for establishing capacitance moisture probes as a method to monitor gas dynamics in peat soils at high temporal resolution and better understanding patterns of gas build-up and release from peat soils in the Everglades. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2016. / FAU Electronic Theses and Dissertations Collection

Anthropogenic impacts, such as habitat destruction and spread of exotic species, are contributing to the sixth major extinction event in Earth’s history. To develop effective management and conservation plans, it is important to understand the ecological drivers of at-risk populations, assess the ability of a population to adapt to environmental change, and develop research methods for long-term ecosystem monitoring. I used wading birds nesting in the Florida Everglades, USA as a model system to address the challenges of managing and monitoring populations within an ecosystem greatly impacted by anthropogenic activities. Specifically, my project investigated 1) the prey selection of wading bird species, and the role of prey and foraging habitat availability on annual nesting numbers, 2) the ability of using diet change to predict species adaptability to a rapidly changing environment, and 3) the use of sensory data to provide low-cost, long-term monitoring of dynamic wetlands. I found that tricolored herons, snowy egrets, and little blue herons consumed marsh fish larger than those generally available across the landscape. Additionally, number of nests initiated by tricolored herons, snowy egrets, and little blue herons was strongly correlated with the annual densities of large fish available within the Everglades landscape. Conversely, number of nests initiated by wood storks, great egrets, and white ibises was more correlated with the amount of foraging habitat availability across the nesting season. Wood stork diets changed considerably since the 1960’s, consisting of mainly sunfish and exotic fish as opposed to marsh fishes dominant in historical diet studies. Storks also consumed more exotic fish species than they did historically. This diet plasticity and the species’ ability to exploit anthropogenic habitats may be conducive to maintaining population viability as storks experience widespread human-induced changes to their habitat. Sensory-only data models generated complementary results to models that used site-specific field data. Additionally, sensory-only models were able to detect different responses between size classes of fish to the processes that increase their concentrations in drying pools. However, the degree to which sensory variables were able to fit species data was dependent upon the ability of sensors to measure species-specific population drivers and the scale at which sensors can measure environmental change. / Includes bibliography. / Dissertation (Ph.D.)--Florida Atlantic University, 2016. / FAU Electronic Theses and Dissertations Collection

Seagrass is a key stone component for the Indian River Lagoon (IRL) ecosystem, and therefore it is an important topic for many studies in the lagoon. This study focuses on the effects of seagrass beds on the hydrodynamics in the IRL. A hydrodynamic model based on the Delft3D modeling system has been developed for the southern IRL including the St. Lucie estuary, Ft. Pierce and St. Lucie Inlets, and adjacent coastal waters. The model is driven by freshwater inputs from the watershed, tides, meteorological forcing, and oceanic boundary forcing. The model has been systematically calibrated through a series of numerical experiments for key parameters, particularly the bottom roughness, and configuration including heat flux formulation and bottom bathymetry. The model skills were evaluated with quantitative metrics (point-to-point correlation, root-mean-square difference, and mean bias) to gauge the agreements between model and data for key variables including temperature, salinity, and currents. A three-year (2013-2015) simulation has been performed, and the results have been validated with available data including observations at HBOI Land-Ocean Biogeochemistry Observatory (LOBO) stations and in situ measurements from various sources. The validated model is then used to investigate the effects of 1) model vertical resolution (total number of model vertical layers), 2) spatial variability of surface winds, and 3) seagrass beds on the simulated hydrodynamics. The study focuses on the vicinity of Ft. Pierce Inlet, where significant seagrass coverage can be found. A series of numerical experiments were performed with a combination of different configurations. Overall, the experiment with 2-dimensional (2-D) winds, ten vertical layers and incorporating seagrass provided the most satisfactory outcomes. Overall, both vertical resolution and spatial variability of surface winds affect significantly the model results. In particular, increasing vertical resolution improves model prediction of temperature, salinity and currents. Similarly, the model with 2-D winds yields more realistic results than the model forced by 0-D winds. The seagrass beds have significant effects on the model results, particularly the tidal and sub-tidal currents. In general, model results show that both tidal and sub-tidal currents are much weaker due to increase bottom friction from seagrass. For tidal currents, the strongest impacts lie in the main channel (inter-coastal waterway) and western part of the lagoon, where strong tidal currents can be found. Inclusion of seagrass in the model also improves the simulation of sub-tidal currents. Seagrass beds also affect model temperature and salinity including strengthening vertical stratification. In general, seagrass effects vary over time, particularly tidal cycle with stronger effects seen in flood and ebb tides, and seasonal cycle with stronger effects in the summer than in winter. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2016. / FAU Electronic Theses and Dissertations Collection

O filo Myxozoa possui uma grande diversidade, sendo conhecidas cerca de 2300 espécies, as quais infectam principalmente peixes, mas também anfíbios répteis e aves. Para este estudo, coletas dos peixes de água doce foram realizadas no Pantanal Mato-grossense (estados de Mato Grosso e do Matogrosso do sul) e no Rio Mogi Guaçu e piscicultura do CEPTA/ICMBio (estado de São Paulo), visando estudos moleculares e morfológicos de mixosporídeos parasitas de 6 espécies de peixes. Os resultados das análises moleculares (amplificação e sequenciamento do gene 18S rDNA) e morfológicas revelaram a ocorrência de 11 espécies de mixosporídeos, sendo cinco parasitas comuns a Pseudoplatystoma corruscans e Pseudplatystoma fasciatum, três parasitas de Salminus brasiliensis, uma espécie parasita de Brycon hilarii, uma de Zungaru jahu e outra de Piaractus mesopotamicus. Das onze espécies, cinco ainda não são descritas pela literatura. A análise filogenética, utilizando o método de Neighbor-Joining, mostrou que o agrupamento das espécies ocorre principalmente de acordo com a proximidade filogenética de seus hospedeiros e que todas as espécies da América do Sul agruparam em um clado monofilético. Foi observado, em alguns pontos da árvore filogenética, que o tropismo de tecido e/ou órgão de infecção caracteriza um importante fator de seleção evolutiva. Com menor frequência também foi observado alguns agrupamentos resultantes de parasitas cuja maior relação aparente era a sua localização geográfica, porém, novos estudos ainda são necessários para determinar o verdadeiro papel deste fator na evolução dos mixosporídeos. / The phylum Myxozoa has a great diversity, with about 2300 known species, which infect mainly fishes, but also amphibians, reptiles and birds. In this study, freshwater fishes were caught in the Brazilian Pantanal wetland (Mato Grosso and Mato Grosso do Sul states) and in the Mogi Guaçu River and CEPTA/ICMBio\'s fishfarm (São Paulo state) aiming the molecular and morphological studies of myxosporeans parasites of 6 fish species. The results of molecular (amplification and sequencing of the 18S rDNA gene) and morphological analysis revealed the occurrence of 11 species of myxosporeans, five of them infecting both Pseudoplatystoma corruscans and Pseudoplatystoma fasciatum, three parasites of Salminus brasiliensis, one specie infecting Brycon hilarii, one infecting Zungaro jahu and another infecting Piaractus mesopotamicus. Of these eleven species, five are not yet described by literature. The phylogenetic analysis, using the Neighbor-joining method, showed that the species clustered mainly according to the phylogenetic distance of their hosts and that all species of South America were grouped in a monophyletic clade. In some positions of the phylogenetic tree was observed that tissue tropism and/or organ of infection characterized an important factor in evolutionary selection. Less frequently was also observed some groups containing species which the major apparent relation is its geographical position, however, new studies are still needed to determine the true role of this factor in the evolution of myxosporeans.