>Magister Scientiae - MSc / The evaluation of petroleum reservoirs has shifted from single approach to an integrated approach. The integration, analysis and understanding of all available data from the well bore and creating property models is an exceptional way to characterize a reservoir. Formulating, implementing, and demonstrating the applicability of the joint inversion of seismic and well-bore related observations, and the use of information about the relationship between porosity and permeability as the key parameters for identifying the rock types and reservoir characterization is a vital approach in this study. Correlating well and seismic data, potential reservoirs can be delineated and important horizons (markers) can be pointed out to better characterize the reservoir. This thesis aims to evaluate the potential petroleum reservoirs of the Wells K-A1, K-A2, K-A3 and K-H1 of the Shungu Shungu field in the Orange Basin through the integration and comparison of results from core analysis, wireline logs and seismic and attempt to produce a good reservoir model and by additionally utilizing Petrophysics and seismic and trying to better understand why the area has dry wells. Different rock types that comprise reservoir and non reservoirs are identified in the study and five Facie types are distinguished. Tight, fine grained sandstones with low porosity values ranging from 3% - 6% where dominant in the targeted sandstone layers. Porosity values ranging from 11% - 18% where identified in the massive sandstone lithologies which where hosted by Well’s K-A2 and K-A3. Low permeability values reaching 0.1mD exist throughout the study area. Areas with high porosity also host high water saturation values ranging from 70 – 84%. An improvement in the porosity values at deeper zones (3700m -3725m) and is apparent. Poroperm plots exhibit quartz cemented sandstones and density with neutron plot suggest that the sandstones in the area contain quarts and dolomite mineralization.Well K-A3, consist of a cluster by quartzitic sandstone, meaning there is a large amount of sandstone present. There are apparent high porosity values around the sandstone. What is apparent from this plot is that there are many clusters that are scattered outside the chart. This could suggest some gas expulsions within this Well. Sandstones within the 14B2t1 to 14At1 interval are less developed in the vicinity covered by well K-A2 than at the K-A1 well location. The main targeted sandstones belong to the lower cretaceous and lie just below 13At1. The four wells drilled in this area are dry wells. The areas/blocks surrounding this area have shown to possess encouraging gas shows and a comparative study could reveal better answers. At deeper zones of the well at an interval of 5350m -5750m, there are more developed sandstones with good porosity values. The volume of shale is low and so is the water saturation. The main target sandstones in the study area are the Lower Cretaceous sandstones which are at an interval 13At1. These sandstones are not well developed but from the property model of the target surface it can be seen that the porosity values are much more improved than the average values applied on all the zones on the 3D grid.

>Magister Scientiae - MSc / The fracture porosity and permeability of the Beaufort Seam 1 (BS1) and Ecca coal seams of the Waterberg Basin have been comprehensively characterised with the aid of geophysical wire‐line logs. The main aim of the thesis was to estimate the porosity and permeability of the coal seams using down‐hole wire‐line data; comparing results from injection falloff test to establish the validity of the technique as a fast an effective method. The study area is the largely under explored Karoo‐aged, fault bounded Waterberg basin Located in the Limpopo Province of South Africa. The study employed mainly the density and dual lateral resistivity logging data (Las format) from eight wells (WTB45, WTB48, WTB56, WTB58, WTB62, WTB65, WTB70 and WTB72). Density logging data was used for coal identification and fracture porosity estimation while fracture permeability was estimated from dual lateralog resistivity data. Analysis of fracture porosity required coal cementation indices and fracture width as an input parameter. These were estimated with the aid of water pump out test data, coal quality and gas analysis data provided by Anglo Coal in addition to the above mention logs. The collection of sheet coal model was used to represent anisotropic coal reservoirs with non‐uniform fracture system was used to represent these coals. The mathematical formulas used to estimate both fracture porosity and permeability took into account the above coal model. The theoretical formulas are a modification from both Darcy’s equation and Archie’s equations. The coal seams were encountered at depths ranging from 198m to 385m in the wells and were marked by low density and very high resistivity. From the estimated results the coal reservoirs are characterised by high cementation indices ranging from 0.82 to 2.42, very low fracture porosity and low fracture permeability. Estimated results show that coal reservoir fracture porosity ranged from 0.0002% to 0.33% for both BS1 and Ecca seams. Estimated results also show that coal reservoir permeability ranged from 0.0045mD to 6.05mD in the BS1 formation and from 0.01 to 0.107mD in the Ecca. Results when compared with those of injection falloff test shows that the estimated permeability is slightly lower as expected since the model did not account for coal anisopropy. The fracture permeability was found to decrease with increase in vitrinite content, coal rank, coal burial depth and increases with increase in inertinite content. On a basinal scale the model estimated permeability was found to increase slightly from the east to the west of the basin. The porosity decreases with increase cementation index for deeper coal seams and increases with increase cementation index for shallower coal seams.

>Magister Scientiae - MSc / The Bredasdorp Basin is one of the largest hydrocarbon producing blocks within Southern Africa. The E-M field is situated approximate 50 km west from the FA platform and was brought into commission due to the potential hydrocarbons it may hold. If this field is brought up to full producing capability it will extend the lifespan of the refining station in Mosselbay, situated on the south coast of South Africa, by approximately 8-10 years. This study is focused in block 9 off shore western part of the Bredasdorp Basin in the main Outeniqua Basin South Africa. Cretaceous Sandstone reservoirs are commonly heterogeneous consequently they may require special methods and techniques for description and evaluation. Reservoir characterization is the study of the reservoir rocks, their petrophysical properties, the fluids they contain or the manner in which they influence the movement of fluids in the subsurface. The main goal of the research is to assess the potentials of hydrocarbons in Cretaceous sediments in the Bredasdorp Basin through the integration and comparison of results from core analysis, production data and petrography studies for the evaluation and correction of key petrophysical parameters from wireline logs which could be used to generate an effective reservoir model for wells (E-BB1, E-BD2, EA01) in the Bredasdorp Basin. Porosity and permeability relationships, wire-line log data have been examined and analysed to determine how the porosity and permeability influence reservoir quality which further influences the potential of hydrocarbon accumulation in the reservoirs. The reservoir sandstone is composed mainly of fine to medium grained Sandstones with intercalation of finger stringers of Siltstone and Shale. In carrying out this research the samples are used to characterize reservoir zones through core observation, description and analyses and compare the findings with electronic data obtained from Petroleum Agency of South Africa (PASA). Secondary data obtained from (PASA) was analysed using softwares such as Interactive Petrophysics (IP), Ms Word, Ms excel and Surfer. Wireline logs of selected wells (E-BB1, E-BD2, E-A01) were generated, analysed and correlated. Surfer software also used to digitize maps of project area, porosity and permeability plotted using IP. Formation of the Bredasdorp Basin and it surrounding basins during the Gondwana breakup. The Bredasdorp Basin consists mainly of tilting half graben structures that formed through rifting with the break-up of Gondwanaland. The model also revealed that these faults segregate the reservoir which explains the pressure loss within the block. The production well was drilled, confining pressure relieved and pressure dropped hence production decreases. The age, transportation, deposition and thermal history of sediment in the basin, all plays a vital role in the type of hydrocarbon formation. Structural features such as faults, pore spaces determines the presence of a hydrocarbon in the reservoir. Traps could be stratigraphic or structural which helps prevent the migration of hydrocarbons from the source rock to reservoir rock or from reservoir rock to the surface over a period of time. The textural aspects included the identification of grain sizes, sorting and grain shapes. The diagenetic history, constructed from the results of the reservoir quality study revealed that there were several stages involved in the diagenetic process. It illustrated several phases of cementation with quartz, carbonate and dolomite with dissolution of feldspar. A potentially good reservoir interval was identified from the data and was characterized by several heterogeneous zones. Identifying reservoir zones was highly beneficial during devising recovery techniques for production of hydrocarbons. Secondary recovery methods have thus been devised to enhance well performance. As recommendation, additional wells are required to appraise the E-M structure and determine to what extent the cement present in the basin has affected fluid flow as well as the degree of sedimentation that could impede fluid flow. There are areas still containing untapped resources thus the recommendation for extra wells. This research may well be reviewed with more data input from PetroSA (wells, seismic and production data) for additional studies, predominantly with respect to reservoir modelling and flow simulation. Based on the findings of this research, summary of calculated Net Pay shows that in well E-BB1, reservoir (1) is at depth 2841.5m – 2874.9m has a Gross Thickness of 33.40m, Net Pay of 29.72 and Pay Summary of 29.57 and reservoir (2) has depth of 2888.1m – 2910.5m, Gross Thickness of 22.40m, Net Pay of 19.92m and Pay summary of 1.48m. Well E-AO1 has depth from 2669.5m – 2684.5m and Gross Thickness of 15.00m and has Net Pay of 10.37m and Pay Summary of 10.37m. Based on the values obtained from the data analysed the above two wells displays high potential of hydrocarbon present in the reservoirs. Meanwhile well E-BD2 has depth from 2576.2m – 2602.5m and has Gross Thickness of 350.00m, Net Pay of 28.96m and Pay Summary of 4.57 hence from data analysis this reservoir displays poor values which is an indication of poor hydrocarbon potentials.

<p>Sandstone and shale samples were selected within the systems tracts for laboratory analyses. The sidewall and core samples were subjected to petrographic thin section analysis, mineralogical analyses which include x-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and stable carbon and oxygen isotopes geochemistry to determine the diagenetic alteration at deposition and post deposition in the basin. The shale samples were subjected to Rock-Eval pyrolysis and accelerated solvent extraction (ASE) prior to gas chromatographic (GC) and gas chromatographic-mass spectrometric (GC-MS) analyses of the rock extracts, in order to determine the provenance, type and thermal maturity of organic matter present in sediments of the Orange Basin. The results revealed a complex diagenetic history of sandstones in this basin, which includes compaction, cementation/micritization, dissolution, silicification/overgrowth of quartz, and fracturing. The Eh-pH shows that the cements in the area of the basin under investigation were precipitated under weak acidic and slightly alkaline conditions. The &delta / 18O isotope values range from -1.648 to 10.054 %, -1.574 to 13.134 %, and -2.644 to 16.180 % in the LST, TST, and HST, respectively. While &delta / 13C isotope values range from -25.667 to -12.44 %, -27.862 to -6.954% and -27.407 to -19.935 % in the LST, TST, and HST, respectively. The plot of &delta / 18O versus &delta / 13C shows that the sediments were deposited in shallow marine temperate conditions.</p>

<p>Sandstone and shale samples were selected within the systems tracts for laboratory analyses. The sidewall and core samples were subjected to petrographic thin section analysis, mineralogical analyses which include x-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and stable carbon and oxygen isotopes geochemistry to determine the diagenetic alteration at deposition and post deposition in the basin. The shale samples were subjected to Rock-Eval pyrolysis and accelerated solvent extraction (ASE) prior to gas chromatographic (GC) and gas chromatographic-mass spectrometric (GC-MS) analyses of the rock extracts, in order to determine the provenance, type and thermal maturity of organic matter present in sediments of the Orange Basin. The results revealed a complex diagenetic history of sandstones in this basin, which includes compaction, cementation/micritization, dissolution, silicification/overgrowth of quartz, and fracturing. The Eh-pH shows that the cements in the area of the basin under investigation were precipitated under weak acidic and slightly alkaline conditions. The &delta / 18O isotope values range from -1.648 to 10.054 %, -1.574 to 13.134 %, and -2.644 to 16.180 % in the LST, TST, and HST, respectively. While &delta / 13C isotope values range from -25.667 to -12.44 %, -27.862 to -6.954% and -27.407 to -19.935 % in the LST, TST, and HST, respectively. The plot of &delta / 18O versus &delta / 13C shows that the sediments were deposited in shallow marine temperate conditions.</p>

Philosophiae Doctor - PhD / Sandstone and shale samples were selected within the systems tracts for laboratory analyses. The sidewall and core samples were subjected to petrographic thin section analysis, mineralogical analyses which include x-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and stable carbon and oxygen isotopes geochemistry to determine the diagenetic alteration at deposition and post deposition in the basin. The shale samples were subjected to Rock-Eval pyrolysis and accelerated solvent extraction (ASE) prior to gas chromatographic (GC) and gas chromatographic-mass spectrometric (GC-MS) analyses of the rock extracts, in order to determine the provenance, type and thermal maturity of organic matter present in sediments of the Orange Basin. The results revealed a complex diagenetic history of sandstones in this basin, which includes compaction, cementation/micritization, dissolution, silicification/overgrowth of quartz, and fracturing. The Eh-pH shows that the cements in the area of the basin under investigation were precipitated under weak acidic and slightly alkaline conditions. The δ18O isotope values range from -1.648 to 10.054 %, -1.574 to 13.134 %, and -2.644 to 16.180 % in the LST, TST, and HST, respectively. While δ13C isotope values range from -25.667 to -12.44 %, -27.862 to -6.954% and -27.407 to -19.935 % in the LST, TST, and HST, respectively. The plot of δ18O versus δ13C shows that the sediments were deposited in shallow marine temperate conditions. / South Africa

The latest Eocene and Oligocene was a time of marked paleoenvironmental change in Taranaki Basin, involving a transition from the accumulation of coal measures and inner shelf deposits to the development of upper bathyal environments. Up until the end of the Early Oligocene (Lower Whaingaroan Stage) Taranaki Basin had an extensional tectonic setting. Marine transgression culminated in the accumulation of condensed facies of the Matapo Sandstone Member of the lower part of the Ngatoro Group. During the Late Oligocene (Upper Whaingaroan Stage) Taranaki Basin's tectonic setting changed to one of crustal shortening with basement overthrusting westward into the basin on Taranaki Fault. The major part of the Ngatoro Group in thickness, including the Tariki Sandstone Member, Otaraoa Formation, Tikorangi Formation and Taimana Formation, accumulated in response to this change in tectonic setting. Various methods of stratigraphic and sedimentological characterisation have been undertaken to evaluate the stratigraphy of the Ngatoro Group. Wireline log records have been calibrated through particle sizing and carbonate digestion of well cuttings. A suite of wireline motifs have been defined for formations and members of the Ngatoro Group. The integration with other lithological and paleoenvironmental data sources has helped to better define the Late Eocene - Oligocene stratigraphy and sedimentary facies for eastern Taranaki Basin margin. U-Pb geochronology by laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) has been used to determine detrital ages for over 350 zircons from 13 samples of Late Eocene - Oligocene sandstone samples in eastern Taranaki Basin and correlative onshore North Island units. The spread of ages (1554 - 102 Ma) and the proportion of ages in particular age bands integrated with modal petrography data have aided provenance evaluation. A range of source rocks contributed to the Late Eocene - Oligocene sedimentary units analysed, mainly the Waipapa Terrane (Early Permian to Late Jurassic) as shown by 206Pb/238U zircon ages and the abundance of fine-grained sedimentary rock fragments observed in samples. The Median Batholith (i.e. Darran/Median Suite and Separation Point Suite) is also identified as a significant source, indicated by Early Triassic to Early Jurassic and Early Cretaceous 206Pb/238U zircon ages and an abundance of quartz in samples. Other minor sources identified include Murihiku and Caples Terranes, Rakaia Sub-terrane and possibly the Karamea Batholith. The Tariki Sandstone and the Hauturu Sandstone have the same source, with the main 206Pb/238U zircon ages of aggregated samples (124 - 116 Ma and 121 Ma, respectively) consistent with a Separation Point Suite/Median Batholith (124 - 116 Ma) source. Derivation of sediments from a landmass that existed to the east and southeast of the Wellington area has been inferred for the Late Eocene - Oligocene units, with subsequent migration of sediments northward into Taranaki Basin and the Waikato Region (i.e. Te Kuiti Group depocentre) via longshore drift. New provenance data have been used to revise understanding about the development of eastern Taranaki Basin margin through the Late Eocene to earliest Miocene. Three new paleogeography maps are presented for the Runangan (Late Eocene), Lower Whaingaroan (Early Oligocene) and Upper Whaingaroan (early-mid-Oligocene). New paleogeography interpretations illustrate a dramatic change in the basin development between Matapo Sandstone (Lower Whaingaroan) and Tariki Sandstone (Upper Whaingaroan) deposition, consistent with an Upper Whaingaroan age for the start of reverse movement on Taranaki Fault.

Philosophiae Doctor - PhD / The use of integrated approach to evaluate the quality of reservoir rocks is increasingly becoming vital in petroleum geoscience. This approach was employed to unravel the reason for the erratic reservoir quality of sandstones of the F-O gas field with the aim of predicting reservoir quality, evaluate the samples for presence, distribution and character of hydrocarbon inclusions so as to gain a better understanding of the fluid history. Information on the chemical conditions of diagenetic processes is commonly preserved in aqueous and oil fluid inclusion occurring in petroleum reservoir cements. Diagenesis plays a vital role in preserving, creating, or destroying porosity and permeability, while the awareness of the type of trap(s) prior to drilling serves as input for appropriate drilling designs. Thus an in-depth understanding of diagenetic histories and trap mechanisms of potential reservoirs are of paramount interest during exploration stage.This research work focused on the F-O tract located in the eastern part of Block 9 on the north-eastern flank of the Bredasdorp Basin, a sub-basin of Outeniqua Basin on the southern continental shelf, offshore South Africa. The Bredasdorp Basin experienced an onset of rifting during the Middle-Late Jurassic as a result of dextral trans-tensional stress produced by the breakup of Gondwanaland that occurred in the east of the Falkland Plateau and the Mozambique Ridge. This phenomenon initiated a normal faulting, north of the Agulhas-Falkland fracture zone followed by a widespread uplift of major bounding arches within the horst blocks in the region that enhanced an erosion of lower Valanginian drift to onset second order unconformity.This study considered 52 selected reservoir core samples from six wells(F-O1, F-O2, F-O3, F-O4, F-R1 and F-S1) in the F-O field of Bredasdorp Basin with attention on the Valanginian age sandstone. An integrated approach incorporating detailed core descriptions, wireline log analysis (using Interactive petrophysics), structural interpretation from 2D seismic lines (using SMT software) cutting across all the six wells, multi-mineral (thin section, SEM,XRD) analyses, geochemical (immobile fluid and XRF) and fluid inclusion(fluid inclusion petrography and bulk volatile) analyses were deployed for the execution of this study. Core description revealed six facies from the six wells grading from pure shale (Facies 1), through progressively coarsening interbedded sand-shale “heterolithic facies (Facies 2 - 4), to cross bedded and minor massive sandstone (Facies 5 - 6). Sedimentary structures and mineral patches varies from well to well with bioturbation, synaeresis crack, echinoid fragments, fossil burrow, foreset mudrapes, glauconite and siderite as the main observed features. All these indicate that the Valanginian reservoir section in the studied wells was deposited in the upper shallow marine settings. A combination of wireline logs were used to delineate the reservoir zone prior to core description. The principal reservoirs are tight, highly faulted Valanginian shallow-marine sandstones beneath the drift-onset unconformity, 1At1 and were deposited as an extensive sandstone “sheet” within a tidal setting. The top and base of the reservoir are defined by the 13At1 and 1At1 seismic events,respectively. This heterogeneous reservoir sandstones present low-fair porosity of between 2 to 18 % and a low-fair permeability value greater than 0.1 to 10 mD. The evolution of the F-O field was found to be controlled by extensional events owing to series of interpreted listric normal faults and rifting or graben generated possibly by the opening of the Atlantic. The field is on a well-defined structural high at the level of the regional drift-onset unconformity, 1At1.Multi-mineral analysis reveals the presence of quartz and kaolinite as the major porosity and permeability constraint respectively along with micaceous phases. The distribution of quartz and feldspar overgrowth and crystals vary from formation to formation and from bed to bed within the same structure. The increase in temperature that led to kaolinite formation could have triggered the low-porosity observed. Three types of kaolinite were recognized in the sandstone, (1) kaolinite growing in between expanded mica flakes; (2)vermiform kaolinite; and (3) euhedral kaolinite crystals forming matrix.Compositional study of the upper shallow marine sandstones in the Valanginian age indicates that the sandstones are geochemically classified as majorly litharenite having few F-O2 samples as subarkose with all F-O1 samples classified as sub-litharenite sandstone.Most of the studied wells are more of wet gas, characterized by strong response of C2 – C5 with F-O1 well showing more of gas condensate with oil shows (C7 – C11) based on the number of carbon atom present. In some cases,sulphur species (characterized by the presence of H2S, S2, CS2 and SO2) of probably thermal origin were identified while some log signatures revealed aromatic enriched sandstones possibly detecting nearby gas charges. The studied wells in the F-O field, based on fluid inclusion bulk volatile analysis are classified as gas discoveries except for F-O1 with gas condensate and oil shows.The integration of multi-mineral results and fluid inclusion studies show a dead oil stain with no visible liquid petroleum inclusion in the samples indicating the presence of quartz, kaolinite and stylolite as a major poro-perm constraint.