<p> With the increasing demand for data rate and transmission distance, the trend in fiber-optic communications is to build an ultra-high, long-haul transmission system. One of the challenges in this kind of systems comes from the fiber dispersion and dispersion slope. For the wide-band wavelength-division multiplexing (WDM) system or ultra-high bit rate optical time-division multiplexing (OTDM) system, the dispersion slope could be a serious problem to impair the system performance.</p> <p> Many studies have shown that the dispersion and dispersion slope affect the long-haul fiber transmission dramatically, especially for the high-capacity systems. Most of them recommend to totally compensate the dispersion and the dispersion slope simultaneously. And a lot of compensating techniques are proposed. However, it is not easy to realize the simultaneous compensation for the dispersion and dispersion slope in the practical systems. Therefore, the necessity of compensating the dispersion slope in wide-bandwidth systems should be verified.</p> <p> We focus on the study of ultra-high bit rate (160-Gb/s) single-channel fiber-optic transmission. The results show that the dispersion slope is not necessary for the dispersion-managed system when the optimal launch parameters are given. Then we present how to find out the optimum in fiber-optic systems and a novel optimizing technology, space mapping technology (SM) is introduced, which has been successfully applied to the electromagnetic area. An application of SM in optical systems is implemented. By using this smart optimization technique, lots of computational efforts for evaluating the fine model in optimization process are saved.</p> / Thesis / Master of Applied Science (MASc)

Eutrophication is a global problem that has a major impact on aquatic ecosystems. Over the past 50 years, the nutrient content of lakes and streams has increased as a result of urban development and agricultural sources. It can cause health problems for both humans and animals through direct contact or when consumed. In addition, it can result in the extinction of aquatic organisms. By studying the topography, soil chemistry, hydrology and human impact of areas, we can understand how nutrients are transported from their sources of origin to surface water, where they increase nutrient content. Understanding this is crucial to identify and prioritise areas that require action to reduce the effects of eutrophication. The purpose of this study was to trace potential sources of dispersion of nutrients to the surface water through analysis of these. The site chosen for the study was the area of Tvärålund where the stream Sjöbäcken and lake Tväråträsket are located, where 11 sampling points were also placed. These had the purpose of proving any emissions from ancillary activities. The results indicate that only one of the selected sampling points was contaminated from active point sources (individual sewers) while the remaining points showed a constant increase supported by a linear relationship between distance from the reference point and measured concentration.

This dissertation addresses several aspects pertaining to polarization in optical fibers and optical waveguide devices. In particular, the analysis and design of fibers that maintain polarization over long lengths, provide zero polarization-mode dispersion, and function as polarizers or mode filters are presented. First, optimum designs for high-birefringence as well as single-polarization single-mode fibers are studied. For high-birefringence fibers, several index profiles were obtained that provided high birefringence while achieving zero or very small dispersion in 1.3 μm and 1.55 μm windows. Also, few index profiles were found that resulted in single-polarization single-mode operation with zero or very small dispersion at about 1.3 μm and 1.55 μm. A wavelength range of 100 nm to 500 nm was achieved for truly single-mode operation. Second, a comprehensive analysis of polarization-mode dispersion in a multiple-clad fiber due to ellipticity of fiber cross-section is carried out. The analysis results are then used to design large effective area single-mode dispersion-shifted fiber that provides zero polarization-mode dispersion at the wavelength 1.55 μm. Effective area on the order of 122 μm² with mode-field diameter of about 10 μm have been attained for this design. Tolerance analysis on the transmission parameters due to ±1% and ±2% variations in the radii of the fiber layers is carried out. Finally, a wedge-shape dielectric waveguides bounded by conducting planes is introduced and analyzed. Conductor and dielectric losses for the fundamental mode in waveguides with wedge angle of π/n; n ≥ 1, and 2π/3 as a special case with noninteger azimuthal number have been evaluated. These waveguides generally support fewer number of modes for smaller wedge angles and the modes cannot be of TM type. They find applications as mode filters and polarizers.. / Ph. D.

Ultra-wideband (UWB) communications is expected to revolutionize high data-rate, short-distance wireless communications, providing data-rates in excess of 100 Mbps. However, the wireless channel distorts the transmitted signal by dispersing the signal energy over time. This degrades the output signal-to-noise ratio (SNR) of a correlation based matched-filter receiver, limiting the achievable data-rate and user capacity. Most wideband channel models do not account for all the identified dispersion mechanisms namely the frequency dispersion, the resonant dispersion and the multipath dispersion. The objective of this research is to model resonant dispersion based on the Singularity Expansion Method (SEM) and provide guidelines for UWB receiver design to meet the data capacity. The original contribution of this research is a novel pole dispersion channel model that includes resonant dispersion characterization. An empirical investigation supports our claim that a correlation type matched-filter receiver using a template signal based on the pole dispersion channel model overcomes distortion related losses. Various physical mechanisms responsible for dispersion in UWB communication systems are described in detail. The applicability of the proposed dispersive channel model is evaluated using the optimal matched filter (OMF) receiver. The SEM approach, which was originally proposed for target identification using short pulse radars, offers limited benefits of due to its susceptibility to noise. A combined fuzzy-statistical approach is proposed to improve the robustness of resonant dispersion channel modeling in presence of noise. A natural extension of this doctoral research is to improve buried landmine detection as well as breast tumor detection by applying statistical and fuzzy analysis to the backscatter response. Moreover, radar target identification using UWB short pulses stands to gain tremendously from this research. / Ph. D.

Amphiphilic tri- and penta-block copolymers containing a polyurethane central block with pendant carboxylic acid groups flanked by hydroxyl functional polyether tails were synthesized. Our intention was to investigate the activities of these copolymers as dispersants for magnetite nanoparticles in biological media. A benzyl alkoxide initiator was utilized to prepare poly(ethylene oxide) (BzO-PEO-OH), poly(propylene oxide) (BzO-PPO-OH) and poly(ethylene oxide-b-propylene oxide) (poly(BzO-EO-b-PO-OH)) oligomeric tail blocks with varying lengths of PEO and PPO. The oligomers had a hydroxyl group at the terminal chain end and a benzyl-protected hydroxyl group at the initiated end. The polyether oligomers were incorporated into a block copolymer with a short polyurethane segment having approximately three carboxylic acid groups per chain. The block co-polyurethane was then hydrogenated to remove the benzyl group and yield primary hydroxyl functionality at the chain ends. End group analysis by 1H NMR showed the targeted ratio of PEO to PPO demonstrating control over block copolymer composition. Number average molecular weights determined by both 1H NMR and GPC were in agreement and close to targeted values demonstrating control over molecular weight. Titrations of the pentablock copolymers showed that the targeted value of approximately three carboxylic acid groups per chain was achieved. Heterobifunctional poly(ethylene oxide) (PEO) and poly(ethylene oxide-b-propylene oxide) (PEO-b-PPO) copolymers were synthesized utilizing heterobifunctional initiators to yield polymers having a hydroxyl group at one chain end and additional moieties at the other chain end. For PEO homopolymers, these moieties include maleimide, vinylsilane, and carboxylic acid functional groups. Heterobifunctional PEO oligomers with a maliemide end group were synthesized utilizing a double metal cyanide coordination catalyst to avoid side reactions that occur with a basic catalyst. PEO oligomers with vinylsilane end groups were synthesized via alkoxide-initiated living ring-opening polymerization, and this produced polymers with narrow molecular weight distributions. Heterobifunctional PEO-b-PPO block copolymers were synthesized in two steps where the double metal cyanide catalyst was used to polymerize propylene oxide (PO) initiated by 3-hydroxypropyltrivinylsilane. The PPO was then utilized as a macroinitiator to polymerize ethylene oxide (EO) with base catalysis. Heterobifunctional PEO and PEO-b-PPO block copolymers possessing carboxylic acid functional groups on one end were synthesized by reacting the vinyl groups with mercaptoacetic acid via an ene-thiol addition. / Ph. D.

Air quality permits are required for the construction of all new surface mining operations. An air quality permit requires a surface mining operation to estimate the type and amount of pollutants the facility will produce. During surface mining the most common pollutant is particulate matter having an aerodynamic diameter less than 10 microns (PM10). The Industrial Source Complex (ISC3) model, created by the United States Environmental Protection Agency (U.S. EPA), is a model used for predicting dispersion of pollutants from industrial facilities, including surface mines and quarries. The use of this model is required when applying for a surface mining permit. However, the U.S. EPA and mining companies have repeatedly demonstrated that this model over-predicts the amount of PM10 dispersed by surface mining facilities, resulting in denied air quality permits. Past research has shown that haul trucks create the majority (80-90%) of PM10 emissions from surface mining operations. Therefore, this research concentrated on improving the ISC3 model by focusing on modeling PM10 emissions from mobile sources, specifically haul trucks at surface mining operations. Research into the ISC3 model showed that its original intended use was for facilities that emit pollutants via smoke stacks. The method used to improve the ISC3 model consisted of applying the dispersion equation used by the ISC3 model in a manner more representative of a moving haul truck. A new model called the Dynamic Component Program was developed to allow modeling of dust dispersion from haul trucks. To validate the Dynamic Component Program, field experiments were designed and conducted. These experiments measured PM10 from haul trucks at two different surface mining operations. The resulting analysis of the Dynamic Component Program, ISC3 model, and the actual field study results showed that the Dynamic Component Program was a 77% improvement over the ISC3 model overall. / Ph. D.

Optimum filter-and-sum beamforming is useful for array systems that suffer from spatially correlated noise and interference over large bandwidth. The set of finite impulse response (FIR) filter coefficients used to implement the optimum filter-and-sum beamformer are selected to optimize signal-to-noise ratio (SNR) and reduce interference from the certain directions. However, these array systems may also be vulnerable to dispersion caused by physical components such as antennas and cables, especially when the dispersion is unequal between sensors. The unequal responses can be equalized by using FIR filters. Although the problems of optimum-SNR beamforming, interference mitigation, and per-sensor dispersion have previously been individually investigated, their combined effects and strategies for mitigating their combined effects do not seem to have been considered. In this dissertation, combination strategies for optimum filter-and-sum beamforming and sensor dispersion correction are investigated. Our objective is to simultaneously implement optimum filter-and-sum beamforming and per-sensor dispersion correction using a single FIR filter per sensor. A contribution is to reduce overall filter length, possibly also resulting in a significant reduction in implementation complexity, power consumption, and cost. Expressions for optimum filter-and-sum beamforming weights and per-sensor dedispersion filter coefficients are derived. One solution is found via minimax optimization. To assess feasibility, the cost is analyzed in terms of filter length. These designs are considered in the context of LWA1, the first ``station'' of the Long Wavelength Array (LWA) radio telescope, consisting of 512 bowtie-type antennas and operating at frequencies between 10 MHz and 88 MHz. However, this work is applicable to a variety of systems which suffer from non-white spatial noise and directional interference and are vulnerable to sensor dispersion; e.g., sonar arrays, HF/VHF-band riometers, radar arrays, and other radio telescopes. / Ph. D.

With the recent resurgence of interest in double negative (DNG) materials and the reported construction of a metamaterial with DNG characteristics, applications of these materials become feasible and examination of the behavior of systems and devices a potentially fruitful topic. The most promising area of research, upon inquiry into past work related to DNG materials, proves to be dielectric waveguides. The present investigation, then, focuses on the inclusion of DNG materials in various planar dielectric waveguide configurations. These waveguides involve a core region surrounded by various numbers of symmetrically-placed cladding layers. The present investigation involves the review of the electromagnetic properties of DNG materials by a thorough analysis based on Maxwell's equations. The use of a negative index of refraction for these materials is justified. These results are then used to perform a frequency domain analysis of an N-layer formulation for dielectric waveguides which is general for any combination of DNG and double positive (DPS) materials. This N-layer formulation allows for the derivation of the characteristic equation, which relates the operating frequency and the propagation constant solutions, along with the cutoff conditions and field distributions. A causal material model which obeys the Kramers-Kronig relations and which is based on measurements of a realized metamaterial is studied and used in the investigation in order to produce realistic results. The N-layer formulation is then applied to the three-layer (slab) waveguide and known results are reviewed. A new interpretation of intramodal degeneracy is given, whereby degenerate modes are split into two separate modes, one with positive phase velocity and one with negative phase velocity but both with a causal positive group (energy) velocity. Next, the formulation is applied to the five-layer waveguide. New behaviors are observed in this case which are not seen for the three-layer waveguide, including the return of the fundamental mode in some cases, whereas it is never present for the three-layer guide, the absence of certain higher-order modes in some situations and the appearance of new modes. Additionally, for some configurations the order of the even and odd modes in the DNG frequency range is found to be reversed from that of conventional waveguides. The photonic crystal waveguide, which involves an infinite number of periodically placed cladding layers, is next studied using ray analysis, and a slight variation of the N-layer formulation is used to compare these results with those of the pseudo-photonic crystal waveguide. The pseudo-photonic crystal waveguide is identical to the photonic crystal waveguide with the exception that it has only large but finite number of layers. It is seen that the results of these two cases are similar for conventional modes, but the photonic crystal waveguide allows for new modes called photonic crystal modes which are inaccessible through conventional waveguides. Interesting phenomena such as mode crossings among the photonic crystal modes are observed and discussed. Using the results from the frequency domain analysis of the five-layer waveguide, a Fourier transform technique is used to study pulse propagation in a waveguide containing DNG materials. A Gaussian pulse is launched in the waveguide over the frequency range covering a portion of the positive- and negative-phase-velocity fundamental transverse electric (TE) modes. Splitting of the input pulse into two separate pulses is observed, where both of these new pulses have a causal, positive energy velocity. The interpretation of intramodal degeneracy given in previous discussions is buttressed with evidence from this portion of the investigation, thus completing the analysis and bringing the present study to its conclusion. / Ph. D.

A system to measure chromatic dispersion in single-mode optical fibers with near point wavelength resolution is described. Differential propagation constant data for the test fiber is collected by using an acousto-optic modulator to frequency-shift laser light passed to an optical heterodyne. Theoretical developments include a frequency-domain calculation technique for interpreting empirical results. The system is proven infeasible, however, due to inherent noise sensitivity / M.S.

To solve traffic congestion in Bangkok, the Bangkok Mass Transit system (BTS) constructed an overhead rail system with 24 stations. The BTS train station, S2, in this study area covers Silom road and obstructs the air pollutant dispersion in a congestion area. The 1: 200 physical model of the buildings along Silom road with the train station, S2, was simulated in this research to determine the air pollutant dispersion in the train station area. A tracer gas (CO₂) was emitted from a simulated line source with emission rates of 0.383, 0.681, 1.293, 2.586, 5.177 and 10.77 mg/min to simulate actual pollutant emission rates. The CO₂ gas was sampled at 55 locations in the model. The Kriging method was used to interpolate the data in the study area. . Emission rates were used to make the difference between measured CO₂ in the model area and ambient CO₂ large enough to be differentiated. Regression Analysis was used to relate analytically the mass emission rate to the CO₂ concentration. The results indicate that the maximum CO concentrations exceed the 30 ppm Bangkok standard along the Southeast side of Silom Road at the passenger platform level. Drivers will acquire more harmful levels of CO than pedestrians at street level, especially near the Southwest end of the train station. NO₂ concentrations do not exceed the standard (0.17 ppm) at street level. The highest predicted VOC is 1.05 ppm. These results may be used in the future for numerical modeling study. / Master of Science