Thesis (M.S.) in Mechanical Engineering--University of Maine, 2002. / Includes vita. Includes bibliographical references (leaves 59-62).

Thesis (Ph. D.)--University of Texas at Austin, 2000. / Vita. Includes bibliographical references (leaves 160-167). Available also in a digital version from Dissertation Abstracts.

The magnetic and physical properties of oxide-free, ligand passivated, iron nanoparticles were studied using superconducting quantum interference device (SQUID) magnetometry and synchrotron based X-ray radiation. Particles used for this study ranged in diameter between 2 and 10 nm, which made it possible to distinguish between bulk and surface effects in the nanoparticles’ properties. Additionally, the effects of two different weakly interacting ligands (2,4-pentanedione and hexaethylene glycol monododecylether) on the nanoparticles’ behavior were studied. The results of this study were compared to theoretical predictions of magnetic transition metal behavior in both thin films and nanoparticles, as well as experimental results from measurements of transition metal clusters formed in an inert carrier gas and measured with a Stern-Gerlach magnet. Magnetometry revealed that the iron nanoparticles have a magnetocrystalline anisotropy an order of magnitude greater than bulk iron. At the same time, these particles exhibit a saturation mass magnetization up to 209 Am2/kg, which is only slightly lower than bulk iron. The structural properties of these particles were characterized using high energy X-ray diffraction analyzed using the atomic pair distribution function method (PDF). The PDF analysis indicates that the Fe particles have a distorted and expanded form of the bcc lattice, which could, at least in part, explain the magnetocrystalline anisotropy of these nanoparticles. X-ray absorption fine structure (XAFS) was used to study the surface properties of the iron nanoparticles and further characterize their structural properties. XAFS showed that oxidized species of iron exist at the nanoparticles’ surface and can be attributed to iron/ligand interactions. The percentage of oxidized species scales with the surface to volume ratio of the nanoparticles, and therefore appears limited to the nanoparticle surface. The layer of Fe(II) species present at the nanoparticles’ surface accounts for the reduction in saturation mass magnetization values (when compared to bulk iron) observed in these particles. XAFS analysis also provided further confirmation of the nanoparticles’ expanded crystalline lattice. / text

The progressive growth of onshore shale production (both gas and liquids) to replace depleting and aging oil fields may benefit from the use of surface seismic shear wave data analysis for full characterization of shale reservoir properties and lead to optimum development of these resources. This includes descriptions of azimuthal anisotropy (HTI - transverse isotropy with a horizontal symmetry axis) for characterization of fractures and internal fracture systems. The objective of this study is to document a predicted distortion in polarization of propagating seismic shear waves upon reflection at a subsurface interface and to propose a correction to this distortion. The polarization distortion occurs even in wholly isotropic media. This correction is based on an understanding of shear amplitude behavior as a function of the reflection incidence angle, particularly differences in the reflection angle relation for different shear components. This study includes a demonstration of the efficacy of the proposed correction by applying it to simulated and real direct shear-wave source data. Such corrections should result in a minimized polarization distortion in the reflection process. The apparent consistency of a null value (zero crossing) of the SV-SV reflectivity (near 20-24 degrees) for common density and velocity contrasts as well as the remarkably regular behavior of the SV-SV and SH-SH reflectivity curves following a linear relation in sin2 and tan2 of the incidence angle and offers the opportunity for a simple and stable correction with minimal sensitivity to detailed knowledge of contrasts in velocity and density. The only independent information required for the correction is the angle of incidence where the SV-SV and SH-SH reflections vanish and the range of these angles is typically quite limited. Some key questions were addressed in gaining an understanding of shear wave polarization distortion upon reflection for varying model data: 1) how do we address reflected polarization distortion for purely isotropic medium for varying incidence angles? 2) How do we apply this correction for an isotropic and anisotropic media for both simulated and actual field data 3) How do we address applications to real data and how distorted amplitudes can be corrected to identify actual subsurface HTI anisotropy. Significantly, the polarization distortion correction is implemented as a simple extension of the established Alford rotation for normal incidence shear reflections of varying polarization. This extension leads to the improved analysis of direct shear-source 3D data with inherently distorted polarization. Thus, analysis may be applied to estimate HTI anisotropy previously not realizable in finite offset data subject to polarization distortion. Example applications to actual field data are included. Note that the polarization correction does remove the AVO effects often exploited in analysis of P-P data where polarization is not an issue that is, the AVO amplitude effect is essentially removed from the SV-SV and SH-SH oriented direct shear-wave profiles, which permits proper analysis of the polarization. Further, additional analysis of the polarization correction on field data with documented anisotropy will be required to fully develop the usefulness of this proposed correction. / text

Amplitude variation with offset (AVO) signatures in vertically transverse isotropic (VTI) media vary as the degree of the anisotropy contrast between layers varies. When the contrasts in two parameters (δ and ε) that quantify the VTI elastic anisotropy are varied, the fraction of energy that reflects from a given layer interface as a mode converted shear wave (R[subscript PS]) also varies for specified angles of incidence. Mode-converted (PS[subscript V]) AVO crossplots may potentially be used to map stratigraphic layers exhibiting intrinsic VTI anisotropy with the moderate to high degrees of weak elastic anisotropy that are often attributed to shale formations. Calculated values of reflected, mode-converted energy as a function of angle of incidence (R[subscript PS](i)) are plotted to determine what mode-converted seismic data indicate about the degree of VTI weak elastic anisotropy present in a given layer. These computations involve varying the degree of weak elastic anisotropy, in this case contrasts in Thomsen’s δ and ε parameters, so that the relationship between these parameters and the amplitude variation with offset (AVO) signature can be quantified. Once this relationship is understood, it may be possible to delineate sweet spot areas of shale formations in seismic data according to how the representative points plot on an AVO crossplot. For such crossplots, the y-intercepts of the reflectivity curves in a particular parameterized space are plotted on the x-axis while the slopes of the parameterized reflectivity curves in this parameterized space are plotted on the y-axis. The grouping of points on the mode-converted AVO crossplots according to the contrast in Thomsen’s δ and ε parameters for weak elastic anisotropy is encouraging. This grouping implies that it may indeed be possible to use an AVO attribute map to characterize a given organic shale formation according to its degree of intrinsic VTI anisotropy. This attribute map would be calibrated to known production data in the locality in order to locate which areas of the mode-converted AVO crossplot predict a likely production sweet spot. / text

I have developed a waveform inversion procedure to invert 3 component broadband seismic data for models of the anisotropic seismic structure of the Earth and applied the technique to an investigation of wave propagation through anisotropic media and earthquake data sampling the upper mantle beneath the East European platform. The procedure combines the conjugate-gradient and very fast simulated annealing methods and attempts to minimize a cross-correlation misfit function comparing data to synthetic seismograms. A series of inversion passes are performed over a range of frequency and time windows to progressively focus in on structural details. The intent is to obtain P and S velocity models that simultaneously match all components of the data (radial, vertical and tangential). The variables in the problem are the seismic velocities ([alpha] and [beta]) as a function of depth. When radial anisotropy is required this set is expanded to include the five variables that determine the seismic velocities in a radially anisotropic medium ([alpha subscript h, alpha subscript v, beta subscript h, beta subscript v, eta]). I investigate the propagation of seismic waves through radially anisotropic media, evaluate which elements of radial anisotropy are best resolved by seismic data and discuss strategies for identifying radial anisotropy in the Earth. S anisotropy, [beta]%, and the horizontal component of P velocity, [alpha subscript h], are typically well resolved by multicomponent seismic data. P anisotropy, [alpha]%, and [eta] are often poorly resolved and trade off with one another in terms of their effect on S[subscript V] arrivals. Erroneous structure will be mapped into models if anisotropy is neglected. The size of the erroneous structure will be proportional to the magnitude of anisotropy present and extend well below the anisotropic zone. The effects of anisotropy on P models produced with an isotropic assumption are most similar to the effects on isotropic S[subscript H] models. When comparing isotropic models, [alpha/beta subscript sh] is therefore often a better measure than [alpha/beta subscript sv] for characterizing mantle petrology. Isotropic S[subscript H], S[subscript V] and P models developed separately using the same data set can provide a good initial estimate of the presence, location and magnitude of anisotropy and those results can be used to create an initial model for an anisotropic inversion solving simultaneously for all 3 components of the data. Finally, I present models for the P and S velocity structure of the upper mantle beneath the East European platform including an analysis of radial anisotropy. The data are 3-component broadband seismograms from strike-slip earthquakes located near the edge of the platform and recorded in Russia and Europe. The timing, amplitude and interference characteristics of direct arrivals (S, P), multiply reflected arrivals (SS, PP), converted phases and surface waves provide very good radial resolution throughout the upper 400 km of the mantle. The platform is underlain by a radially anisotropic seismic mantle lid extending to a depth of 200 km with a largely isotropic mantle below. The model has a positive velocity gradient from 41 km to 100 km depth, and a relatively uniform velocity structure from 100 km to 200 km depth with high S[subscript H] and P[subscript H] velocities (4.77 km /s, 8.45 km/s). Shear anisotropy is uniform at 5% ([beta subscript H] > [beta subscript V]) from 41 to 200 km depth, drops to 2% from 200 to 250 km and is isotropic below that. The average shear velocity from 100 to 250 km is also uniform at 4.65 km/s and the drop in anisotropy is matched by a drop in [beta subscript H] to 4.70 km/s combined with an increase in [beta subscript V] to 4.60 km/s. Below 250 km there is a positive velocity gradient in both P and S velocity down to 410 km. P anisotropy is not well resolved, but P structure mimics the S[subscript H] velocity structure, suggesting that P is also anisotropic within the lid. / text

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Nanoplasmonics has opened up the gates for numerous innovations. Recent studies showed that metal nanoparticles, when introduced into the solar cells and organic light emitting diodes, would greatly enhance their efficiencies. Though these advances are promising, they require a tool for investigating the interactions occuring at the microscopic level to further optimize their performance. In that context, we are interested in understanding the energy transfer mechanism between molecules in the vicinity of metal nanoparticle. Time-resolved fluorescence intensity and anisotropy experiments on single and clusters of Silver-Silica core-shell nanoparticles coated with Rhodamine B(RB) dye molecules, (Ag-SiO2-RB) were performed. We witnessed the signature of the interaction between RB molecules and metal nanoclusters in the form of the enhanced fluorescence intensity decay rates. The fluorescence lifetime of RB in the vicinity of the nanoparticles was (600 +/- 100) ps, as compared to (2.4+/-0.3)ns in the absence of nanoparticle. While the anisotropy of RB molecules in the absence of nanoparticle has remained almost constant(0.075+/-0.029) over long times; anisotropy in the presence of particles showed wide range of values immediately after excitation. Surprisingly high anisotropy values, at about 10 ns after excitation, were observed with a mean of about (0.145+/-0.025). We interpret the high and low initial anisotropies of the clusters, relative to the case of RB alone, to be due to the interaction of dye molecules with collective plasmon modes of the clusters. / Thesis (Master, Physics, Engineering Physics and Astronomy) -- Queen's University, 2011-06-30 23:29:38.658

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