It was the purpose of this thesis to evaluate two-dimensional (2D) magneto-thermoelectric (MTE) phenomena in thinner regime. Mostly this work was motivated by the recent discovery of MTE properties in transition metal dichalcogenides (TMD). In general, TMD thin films have attracted much attention due to their very good electrical, optical, and electrochemical properties. However the total amount of studies of the MTE in TMD is rather small compared to the other properties, such as electric, opto-electric, and catalyst. Hence, in this thesis, we aimed to evaluate the MTE properties in TMD materials. Before we started to measure TMDs, we established a measurement platform and studied MTE properties in ferromagnetic CoFeB, and Weyl semimetal Co2MnGa.:1. Introduction a. Physical background i. Seebeck Effect ii. Anomalous Hall Effect and Anomalous Nernst Effect iii. Mott relation 2. Sample Preparation and evaluation a. Physical vapor deposition b. Mechanical Exfoliation c. Patterning Process 3. Data Evaluation 4. State of the art in Transition Metal Dichalcogenids a. Introduction b. TMD in use c. Magneto-thermoelectric properties in TMD 5. Magneto-thermoelectrical properties in CoFeB thin film a. Introduction b. Results and Discussion c. Conclusion 6. Anomalous Nernst and Anomalous Hall effect in Co2MnGa thin film a. Introduction b. Results and Discussion c. Summary 7. Anomalous Hall effect in exfoliated VS2 flake a. Introduction b. Experiment c. Results and Discussion d. Summary 8. Summary Acknowledgement and References

Doctor of Philosophy / Department of Physics / Yurii Maravin / This dissertation describes a comprehensive study of the Zgamma [to] eegamma/mumugamma/nu[bar]nugamma process. The data have been collected with the D0 detector at the Fermilab Tevatron p[bar]p collider with the center-of-mass energy of 1.96 TeV, and correspond to up to 3.6 fb[superscript]-1 of integrated luminosity. Firstly, in this study we perform a measurement of the Zgamma production cross section. The measured cross sections in both llgamma (l = e or mu) and nu[bar]nugamma channels are the most precise cross sections measured at hadron colliders to date, and they agree within uncertainties with the theoretical calculations to the next-to-leading order. We claim the first observation of the Zgamma [to] nu[bar]nugamma process at hadron colliders at 5.1 standard deviations statistical significance. We also conduct a search for anomalous Zgamma processes. Such anomalous Zgamma processes, where a Z boson couples to a photon, result in an increased cross section and an enhancement of the production of high-energetic photons. Thus, an observation of this kind might possibly indicate the presence of new physics. Having found no excess of data over the SM expectations, we set the most restrictive 95% C.L. limits on the anomalous trilinear Zgammagamma and ZZgamma gauge couplings (ATGC) at hadron colliders to date: |h[subscript]30[superscript]gamma| < 0.033, |h[subscript]40[superscript]gamma| < 0.0017, |h[subscript]30[superscript]Z| < 0.033, and |h[subscript]40[superscript]Z| < 0.0017, which mark almost three times improvement over the most recent results published to date. Three out of four current limits improve on the LEP limits, and are the tightest limits on ATGC in the world. Finally, we performed a search for narrow vector and scalar resonances that decay to Zgamma. Many extensions of the SM predict such resonances, thus making this search a test of the gauge sector of the SM. We found no significant deviation of data from the SM predictions, and hence we set 95% C.L upper limits on the production cross section of the resonances.

Renormalization group analysis is a useful tool for studying critical behaviour of stochastic systems. In this thesis, field-theoretic renormalization group will be applied to the scalar model representing directed percolation, known as Gribov model, in presence of the random velocity field. Turbulent mixing will be modelled by the compressible form of stochastic Navier-Stokes equation where the compressibility is described by an additional field related to the density. The task will be to find corresponding scaling properties.

Framework materials that contain molecular bridging ligands between metal nodes—as seen in coordination polymers—not only give rise to enhanced structural diversity, but also to a range of useful and unusual mechanical properties. This thesis demonstrates the general structure–property relationships that are developed for coordination polymers in order to enable prediction and design of their mechanical properties, and hence structural flexibility. Variable-temperature and -pressure diffraction experiments are employed for the determination of their mechanical properties, namely by calculating thermal expansion and compressibility coefficients. The anomalous and varied mechanical responses observed are rationalised by the important structural features, or the so-called mechanical building units (XBUs), of the coordination polymers. The XBUs are considered within the setting of framework topology, geometry, and composition in order to establish general design principles for targeting different degrees of flexibility within coordination polymers. The XBUs are identified first in silver(I) 2-methylimidazolate, Ag(mim), a framework which is comprised of structural motifs of varying strength, namely argentophilic interactions, hinge points and metal–ligand bonding. The anomalous mechanical responses in Ag(mim) are shown to be rationalised entirely by the XBUs present in the structure. The XBU abstraction is then applied to a range of other coordination polymers and shown to correspond directly with the anomalous responses known in these materials. The metal–ligand–metal linker XBU is investigated further in both cadmium imidazolate, Cd(im)₂, and zinc cyanide, Zn(CN)₂. Here, the linker chemistries are completely different between the two frameworks, but the diamondoid arrangement of the linkers, and thus the topology, is the same. The structural responses of the two frameworks are examined to unravel the extent of topology- and chemistry-driven mechanics. It is found that the topology dominates the atomic displacements of both frameworks, indicating the existence of common soft-mode dynamics which are likely to extend to other coordination polymers with the same topology. The three-dimensional framework-hinging XBUs in zinc isonicotinate, Zn(ISN)₂, and indium deuterium terephthalate, InD(BDC)₂, are considered next. These frameworks have the same topology but contrasting framework geometries, evident from the differing c/a-lattice parameter ratios. In this case, a geometric formalism is derived which can predict the direction of framework mechanical anisotropy in Zn(ISN)₂ and InD(BDC)₂ and other uniaxial coordination polymers. Finally, a family of ABX₃-type transition metal(II) formates are investigated, where both the B-site and A-site cations are varied. The chemical modifications give rise to variations in B- or A-site cation sizes, which are found to correlate with the magnitude of mechanical responses. These structure–mechanical property relationships—based upon framework topology, geometry and composition—are presented in separate chapters, and in each case generalised so that they can be applied to a range of coordination polymers. Hence the design principles determined here can provide the materials science community with an intuition on the type and magnitude of responses possible in these materials under different external stimuli.

Doctor of Philosophy / Department of Physics / Yurii Maravin / In this dissertation, you will find a study of di-boson production in pp collision with the Compact Muon Solenoid (CMS) detector at Large Hadron Collider (LHC). A study of Z+gamma process is performed on the data collected by the CMS during 2011 and corresponding to integrated luminosity L= 5 fb[superscript]-1. The study consists of two parts: cross section measurement and setting the limits on anomalous trilinear gauge couplings (aTGC) between a Z boson and a photon. The measured cross-section of Z+gamma agrees within the uncertainties with the standard model predicted cross section at next to leading order. Having found no excess in cross section measurement, we set the 95% con fidence level (C.L.) limit on aTGC. Another study discussed is a study of a low-scale walking Technicolor model with rho[subscript]T and a[subscript]T production in the fully leptonic fi nal state at 95% C.L. in proton-proton collisions at center of mass energy 10 TeV scenario using Monte Carlo simulation. We conclude that such processes can be excluded with 366 pb[superscript]-1 of data for rho[superscript]T masses up to 400 GeV and the observation would require 2.8 fb[superscript]-1 of data with 5 sigma precision.

The most common type of electric propulsion in space exploration is the Hall Effect Thruster (HET), mainly due to its high specific impulse and high thrust to power ratio. However, uncertainties about the thruster's lifetime prediction have prevented widespread integration of HETs. Among these limitations, wall erosion of acceleration channel is of greatest concern. The experimental methods of erosion are time consuming and costly, and they are often limited to one single configuration. Hence, developing a computational model not only decreases the costs but also shortens the design time of a HET. This thesis investigates the feasibility of a uid erosion modelling with a multi-physics software (COMSOL) to further decrease the time and the development cost. First of all, this thesis provides an overview of available plasma modelling techniques and the physics behind the erosion phenomenon. Moreover, the effective parameters and available modules in the multiphysics software as well as their theoretical background were studied and discussed in detail. The Electron Anomalous phenomenon and pressure instability are determined as the main limiting factors for such a model. A non-magnetized model is included to find an optimal value for pressure and to reduce the probability of pressure instability occurrence in magnetized model. To fulfill this task, several simulations for various pressure values (0.005 Torr, 0.05 Torr, and 0.5 Torr) were conducted. Next, the simulation of magnetized/full model has been carried out with addition of magnetic coils in non-magnetized model. To avoid the Electron Anomalous phenomenon, the Bohm diffusion approach was implemented. In addition, a full Particle-In-Cell (PIC) simulation of a typical HET (SPT-100) with the similar input parameters as in fluid model was conducted, and the results were compared and validated using experimental data. The PIC model was intended to be utilized to investigate the accuracy of erosion model in multiphysics software. The results of this thesis indicate that current application of erosion model in COMSOL is not possible whilst high accuracy of the erosion model based on PIC approach can be achieved. Finally, the application of semi-empirical method through direct input of magnetic field data can allow short time simulation of a HET in COMSOL to gain insight about the preliminary behaviour of plasma, however, the simulation of an erosion model requires either a built-in PIC algorithm in COMSOL or a PIC based code.

Le travail réalisé dans cette thèse porte sur l’étude du mouvement Brownien d’une suspension colloïdale sous champ de force optique faible et l’étude fondamentale des effets convectifs et de diffusion anormale. Nous avons construit un microscope à fond noir afin de suivre les particules et de reconstruire leurs trajectoires avec une résolution spatiale de 20 nm et une résolution temporelle de 8 ms. Ces trajectoires sont analysées statistiquement afin d’en extraire la contribution balistique induite par la force de pression de radiation appliquée par le laser d’illumination. En plus de l’effet mécanique du laser sur les particules, le fluide absorbe les radiations ce qui le chauffe et crée ainsi une différence de température entre la partie illuminée et la partie non illuminée de l’échantillon.Nous validons aussi les hypothèses de stationnarité et d’érgodicité qui sont fondamentales pour notre stratégie de mesure de force faible. L’analyse statistique fine de notre système nous permet de mettre en évidence et de caractériser des effets de diffusion anormale brownienne. Nos expériences révèlent en effet la présence de trajectoires anormales dont l’origine se comprend comme un effet d’interaction entre la particule suivie et le reste de l’ensemble colloïdal. / The work presented in this thesis deals with the study of the Brownian motion of a colloidal suspension under an external weak optical force, the study of convective effects and anomalous diffusion. We have built a dark field microscope in order to track the particles and reconstruct the Brownian trajectories with a spatial resolution of 20 nm and a temporal resolution of 8 ms.Statistical analysis of the trajectories has allowed us to extract the ballistic contribution induced by the radiation pressure force exerted by irradiating a laser on the particles. In addition to the mechanical effect of the laser on the particles, the fluid absorbs the radiation. Consequently, the temperature of the fluid rises and results in a thermal difference between the illuminated and the non-illuminated areas of the sample. In order to validate our weak force measurement, we have investigated two fundamental hypotheses in statistical physics: ergodicity and stationary aspect. A closer statistical analysis enables us to demonstrate and characterize the effect of anomalous Brownian diffusion. Our experiments have revealed the existence of anomalous trajectories, which can be understood as an effect of the interactions between the particles.

Este trabalho apresenta o estudo das propriedades físicas de amostras de KxMoO2-? e MoOy. São reportados resultados de difratometria de raios X e de nêutrons, cálculo de densidade de estados pela teoria do funcional da densidade, medidas de espectroscopia de fotoemissão, resistividade elétrica, magnetização, calor específico e expansão térmica. Resultados de difratometria de raios X e de nêutrons, com ajustes baseados em simulações realizadas com o programa GSAS, permitiram selecionar as amostras monofásicas e de boa qualidade. As medidas de espectroscopia de fotoemissão mostram que a existência de alta fração Mo3+/Mo4+ em diversas amostras de KxMoO2-? e MoOy é a responsável pela anomalia da resistividade elétrica descrita pela lei de potência prevista no modelo do líquido de Luttinger (LL). A observação da anomalia nas curvas de resistividade elétrica em amostras de MoO2 deficientes em oxigênio suporta que tal comportamento está relacionado à presença de íons Mo3+ e não com a presença de K. Resultados de magnetização e resistividade elétrica confirmaram a existência de supercondutividade no sistema K-Mo-O. Foi observada que a temperatura crítica (TC) é função da composição inicial de K, sendo que foi encontrada a mais alta TC reportada para este sistema (TC ~9,5 K). Medidas de magnetização mostraram ainda a coexistência de supercondutividade e magnetismo no composto KxMoO2-?. Foi ainda observada uma transição do tipo metal de Bose para isolante em uma amostra de KxMoO2-? que reforça a evidência da formação de pares de Cooper nesse sistema. Por fim, medidas de calor específico, expansão térmica e resistividade elétrica evidenciaram a existência de uma transição de fase de primeira ordem em altas temperaturas (entre 250 e 270 K) tanto em amostras policristalinas de KxMoO2-? e MoOy quanto em monocristais de MoO2. A transição observada no MoO2 nunca foi reportada para este material. Esta transição é discutida com base na movimentação dos átomos de Mo existentes nas ligações unidimensionais de Mo-Mo e nas distorções dos octaedros de MoO6 presentes na sua estrutura cristalina. / This work presents the study of physical properties in polycrystalline samples of KxMoO2-?, and MoOy. We present results of X-ray and Neutrons diffraction patterns, density of states calculations by density functional theory, photoemission spectroscopy, electrical resistivity, magnetization, specific heat, and thermal expansion measurements. X-ray and neutrons diffraction results as well as calculations of the structure and diffractograms carried out by simulations using GSAS shown which the samples are high quality. Photoemission spectroscopy measurements shown the existence of Mo3+/Mo4+ in high fraction for KxMoO2-? and MoOy which are responsible to electrical anomalous behavior described by powder law predicted in the Luttinger Liquid theory. The observation of anomalous is related to Mo3+ ions in the samples. Magnetization and electrical resistivity confirm the existence of superconductivity in K-Mo-O system. It was observed that the critical temperature (TC) is a function of the starting composition of K and the higher TC found out and reported for this system (TC ~9.5 K). Magnetization measurements also have shown the coexistence of superconductivity and magnetism in KxMoO2-?. It was observed a Bose metal-insulator transition in K0.05MoO2-? which further evidence of the formation of Cooper pairs in the system. Finally, specific heat measurements, thermal expansion and electrical resistivity evidenced the existence of first order phase transition in high temperatures (between 250 and 270 K) in KxMoO2-? and MoOy polycrystalline as well as MoO2 single crystal. This transition is discussed looking for Mo atoms moving in the one-dimensional links Mo-Mo and of the distortions of MoO6 octahedra in the crystalline structure.

Esta pesquisa compara pessoas que alegam experiências anômalas e que não as alegam quanto aos cinco grandes fatores da personalidade, indicadores de transtornos mentais e atribuições de causalidade. O recorte incide sobre experiências caracteristicamente contemporâneas, que mencionam objetos voadores não-identificados (óvnis) e eventos correlatos, como alegadas visões de alienígenas. As variáveis foram escolhidas para o estudo devido ao seu papel teórico na edificação das experiências e aos achados contraditórios da literatura a respeito. O tema foi escolhido por se tratar de uma das categorias menos investigadas de experiências anômalas, especialmente no Brasil, mas cuja elevada prevalência e conotações psicossociológicas são particularmente relevantes na contemporaneidade. As variáveis são investigadas pelo uso de instrumentos apropriados para o contexto brasileiro e por roteiros de entrevista semi-abertos que possibilitaram abordar as experiências e atribuições de causalidade. Concluo que as experiências não podem ser prontamente explicadas enquanto resultantes de tendências de personalidade como dificuldades emocionais no enfrentamento da realidade e busca por estimulação e fantasia, tampouco como consequentes a transtornos mentais formais. Contudo, outras características de personalidade e discutíveis indicadores pré-mórbidos sinalizam possibilidades para novos estudos. Finalmente, as atribuições causais revelam complexas relações entre variáveis psicossociais e biológicas sem as quais as experiências óvni e seus protagonistas não podem ser contextualizados e compreendidos / This research compares people who claim to have had anomalous experiences and those who do not, in what refers to the Big Five personality factors, indicators of mental disorder and causal attributions. The delimitation focuses on the typical contemporary experiences of unidentified flying objects (UFOs), and related events such as alleged visions of aliens. The variables were chosen because of their theoretical role in building the experience and the contradictory findings about them found in literature. The theme was chosen because it is one of the less investigated anomalous experiences, especially in Brazil, but its high prevalence and psycho-sociological connotations are particularly relevant in contemporary context. The variables are investigated by using instruments appropriate for the Brazilian context and scripts for semi-open interviews that allow to explore the experiences and causal attributions. I conclude that the experiences can not be readily explained as resulting from personality traits as emotional difficulties facing reality and search for stimulation and fantasy, nor as resulting from formal mental disorders. However, other personality characteristics and possible premorbid indicators suggest possibilities for further research. Finally, causal attributions reveal complex relationships between biological and psychosocial variables without which the protagonists and their UFO experiences cannot be contextualized and understood

Neste trabalho consideramos extensões do Modelo Padrão contendo vértices quárticos anômalos parametrizados por operadores efetivos de dimensão oito. Estes alteram o comportamento das amplitudes do tipo VV VV , onde V pode ser o fóton, o bóson Z, o bóson W ou o Higgs. Para essa extensão ser consistente, ela tem que obedecer o teorema ótico. Entretanto, as amplitudes geradas por estes operadores efetivos tendem a aumentar conforme a energia do centro de massa aumenta. Estudaremos o comportamento dessas amplitudes e determinaremos se há violação de unitariedade. Para isso utilizamos também o formalismo da base de helicidade. / In this work we consider Standard Model extensions containing anomalous quartic vertex parametrized by effective dimension-eight operators. These modify the behaviour of the scat- tering amplitudes VV VV , where V can be photon, Z boson, W boson and Higgs. To this extension be consistent, it has to obey the optical theorem. However, the amplitudes generated by these effective operators tends to grow as the center of mass energy increase. We will study the behaviour of these amplitudes and we will determine if there is unitarity violation. For this it was also used the helicity base formalism.