<p> Metal contamination from anthropogenic activities is of great concern due to the associated detrimental effects on ecosystem health. An increase in metal concentrations in the dissolved phase creates greater ecosystem impacts. Thus, the relative extent of metal distribution between sediment and dissolved compartments, and an understanding of the factors that control this partitioning is key to assessing metal impacts. In this thesis, metal concentrations were determined for a suite of 12 metals (Cr, Mn, Co, Cu, Sn, Ag, As, Ni, Zn, Cd, Se and Fe) associated with three compartments, dissolved, surficial bed sediment and suspended particulate matter (SPM) in Hamilton Harbour, Ontario. Due to highly dynamic interactions of anthropogenic impacts that may work together to affect metal distributions as well as processes that occur over small or rapid scales, a high-resolution temporal and spatial scale was used to evaluate these metal distributions over a seasonal timeframe. </p> <p> Concentrations of metals amongst sediment fractions indicated that sediment metal uptake was largely controlled by the concentration of the sediment associated amorphous and crystalline oxyhydroxide fractions accounting for up to 90% of total sediment bound metal, even though the oxyhydroxides only accounted for a maximum of 23% of the total sediment mass for both surficial bed sediment and SPM compartments. The formation and dissolution of amorphous oxyhydroxides is commonly a microbially mediated process. Thus, these results underscore the important role of oxyhydroxides and the microbial processes that contribute to their formation and dissolution m controlling metal dynamics, and likely metal impacts in Hamilton Harbour. </p> <p> Metal partitioning was found to be both spatially and temporally variable for all compartments, temporally ranging 0.5 to 4 orders of magnitude for a given element; indicating highly dynamic metal exchanges between sediment and solution compartments and fluctuating distributions over the time and spatial scales examined. </p> <p> The suite of variables that are considered to control metal distribution between dissolved and sediment compartments, and thus impact metal toxicity (i.e., temperature, pH, specific conductivity, oxidation-reduction potential, dissolved organic carbon concentration, SPM concentration (for SPM associated metals only), fraction concentrations i.e. g carbonate /g solid, g amorphous oxyhydroxide I g solid, etc., and dissolved metal concentrations) did not constrain the variability in observed metal distribution behaviour, indicating that other factors in this system, such as hydrodynamic disturbances associated with shipping traffic and channelized water currents, as well as specific point source metal discharges, may play a larger role in determining metal partitioning in Hamilton Harbour, compared to less anthropogenically, impacted systems. Furthermore, no one master variable defming metal partitioning between the dissolved and sediment compartments was found, rather relationships controlling metal distribution behavior were site, compartment, sediment fraction and element specific highlighting the challenges for the development of a Harbour-wide management plan for priority metal contaminants. The results presented in this thesis, show that it is necessary to consider metal, site and compartment specific conditions as well as fully addressing temporal variability in metal behaviour. In addition, the results of this thesis point to the need to address hydrodynamic disturbance and point source influences on metal behaviour in Hamilton Harbour and likely extend to other multi-impacted metal contaminated systems. </p> / Thesis / Master of Science (MSc)

I investigated the use of nitrogen isotopes as a tracer of sewage contamination on coral reefs. Sewage is isotopically distinct from marine nitrogen, allowing its use as a tracer in this environment. Emphasis was placed on sampling modem coral tissues, as modern coral reefs are in a rapid state of decline, possibly as a result of sewage contamination. Samples were collected in Zanzibar for two separate studies. The first study involved sampling over a depth/light gradient on large coral heads. These data, when combined with data from Jamaica, show light is a controlling factor on the nitrogen isotopic composition of coral tissue. Regression of delta15N of coral tissue with depth/light attenuation explains 75-90% of the variance. Results indicate increased fractionation with depth, which is related to the symbiotic nature of corals. Light-sufficient, nitrogen-limited zooxanthellae ( in the coral tissue ) must diffusl! all available nitrogen, and there is little fractionation. At depth, light-limited, nitrogen-sufficient zooxanthellae fractionate nitrogen during assimilation processes. These results have important implications for the use of nitrogen isotopes as a sewage tracer on reefs. In general, increased nutrients to the reef environment result in decreased water clarity, or lowered available light to the coral. This could lower the zooxanthellae's nitrogen requirements and allow fractionation (isotopic depletion). Corals have been shown to become reliant on heterotrophy in non-limiting nutrient conditions, related to loss of control over their zooxanthellae. This suggests the delta15N of their tissues would reflect their diet (and therefore the source of contamination). The counteractive effects of these two factors suggests it may not be possible to resolve the source of eutrophication to corals using the isotopic signatures of their tissue. That is, if the contamination gradient is coincident with a gradient in the symbiotic relationship (i.e. from nutrient limited to nutrient non-limited) or trophic status, there is little possibility of resolution of sewage effects. Results from the second sample suite from Zanzibar and a sample suite from Jepara Bay, Indonesia confirm this hypothesis. Zanzibar samples were collected at a eutrophied and non-eutrophied reef, and show no significant difference between isotopic data. This may be a result of distance from source, or the counter-effects of light. At Jepara Bay, samples were collected along a contamination gradient, from 2 point source discharges. Isotopic data show significant change along the gradient, with the entire bay eutrophied. Without delta15N from all potential nitrogen sources it is impossible to adequately conclude whether sewage was the contaminant using isotopes. Other data collected from these reefs do support the interpretation of anthropogenic contamination. These data include decline in coral and fish communities (determined using biological assays, Zanzibar), and increased heavy metal and chlorophyll-a concentrations (Jepara). One control on nitrogen isotope composition of modern corals was identified, and others suggested. Results will remain enigmatic until sample suites including complete water chemistry, source chemistry, and light regime are interpreted. / Thesis / Master of Science (MSc)

Large wildfires in California cause significant socioecological impacts, and half of the federal funds for fire suppression are spent each year in California. Future fire activity is projected to increase with climate change, but predictions are uncertain because humans can modulate or even override climatic effects on fire activity. Here we test the hypothesis that changes in socioecological systems from the Native American to the current period drove shifts in fire activity and modulated fire-climate relationships in the Sierra Nevada. We developed a 415-y record (1600-2015 CE) of fire activity by merging a treering-based record of Sierra Nevada fire history with a 20th-century record based on annual area burned. Large shifts in the fire record corresponded with socioecological change, and not climate change, and socioecological conditions amplified and buffered fire response to climate. Fire activity was highest and fire-climate relationships were strongest after Native American depopulation-following mission establishment (ca. 1775 CE)-reduced the self-limiting effect of Native American burns on fire spread. With the Gold Rush and EuroAmerican settlement (ca. 1865 CE), fire activity declined, and the strong multidecadal relationship between temperature and fire decayed and then disappeared after implementation of fire suppression (ca. 1904 CE). The amplification and buffering of fire-climate relationships by humans underscores the need for parameterizing thresholds of human-vs. climate-driven fire activity to improve the skill and value of fire-climate models for addressing the increasing fire risk in California.

Anthropogenic noise may interfere with avian acoustic communication, however some species alter the structure of vocalizations, to improve transmission in noise. Here, I conducted playback experiments to determine whether compressor stations, generator or grid-powered screw pump oil wells, and overall ambient noise levels affected responses of Savannah sparrows (Passerculus sandwichensis) to conspecific alarm calls at their nests. I also measured the structure of alarm calls, to determine whether Savannah sparrows altered vocalizations in noise. On control sites, Savannah sparrows responded to alarm calls by delaying provisioning visits. At compressor station sites, the loudest infrastructure treatment, they showed less of a delay. Close to compressor stations, Savannah sparrows lowered the frequency and increased the bandwidth of alarm calls. These findings suggest the compressor stations may interfere with anti-predator communication, but that Savannah sparrows can alter the structure of alarm calls at these sites, perhaps mitigating some effects of noise. / October 2016

Managing anthropogenic emissions in urban areas is a major challenge in sustainable environmental development for cities, and future changes and increasing urbanisation may increase this challenge. Systems perspectives have become increasingly important in helping urban managers understand how different changes may alter future emissions and whether current management strategies can efficiently manage these emissions. This thesis provides some systems perspectives that have been lacking in previous studies on modelling and managing future anthropogenic emissions in urban areas. The city of Stockholm, Sweden, was selected as the study site and studies about nitrogen, phosphorus and carbon were chosen, given world-wide urban eutrophication and global concerns about climate change. A substance flow analysis (SFA) structured model, comprising a source model coupled with a watershed model in an SFA structure, was developed to investigate future nutrient loading scenarios under various urban changes in small urban lake catchments. The results demonstrated that climate change potentially posed a greater threat to future nutrient loads to a selected lake catchment in Stockholm than the other scenarios examined. Another SFA-based study on future phosphorus flows through the city of Stockholm indicated that the best management option may depend on the perspective applied when comparing future scenarios of phosphorus flows and that both upstream and downstream measures need to be considered in managing urban phosphorus flows. An evaluation approach for examining current management plans and low-carbon city initiatives using the Driving forces-Pressure-States-Impact-Response (DPSIR) framework, was formulated. With such an evaluation approach, investigation of how well selected plans cover different aspects of the DPSIR framework and whether root causes and systematic measures are highlighted is possible. The results revealed that the current low-carbon city initiative in Stockholm falls within pressure-based, driver-orientated plans and that technical, institutional and cognitional measures are generally well covered. / <p>QC 20160510</p>

Half of Earth's land surface has been altered by human activities, creating various consequences on the climate and weather systems at local to global scales, which in turn affect a myriad of land surface processes and the adaptation behaviors. This study reviews the status and major knowledge gaps in the interactions of land and atmospheric changes and present 11 grand challenge areas for the scientific research and adaptation community in the coming decade. These land-cover and land-use change (LCLUC)-related areas include 1) impacts on weather and climate, 2) carbon and other biogeochemical cycles, 3) biospheric emissions, 4) the water cycle, 5) agriculture, 6) urbanization, 7) acclimation of biogeochemical processes to climate change, 8) plant migration, 9) land-use projections, 10) model and data uncertainties, and, finally, 11) adaptation strategies. Numerous studies have demonstrated the effects of LCLUC on local to global climate and weather systems, but these putative effects vary greatly in magnitude and even sign across space, time, and scale and thus remain highly uncertain. At the same time, many challenges exist toward improved understanding of the consequences of atmospheric and climate change on land process dynamics and services. Future effort must improve the understanding of the scale-dependent, multifaceted perturbations and feedbacks between land and climate changes in both reality and models. To this end, one critical cross-disciplinary need is to systematically quantify and better understand measurement and model uncertainties. Finally, LCLUC mitigation and adaptation assessments must be strengthened to identify implementation barriers, evaluate and prioritize opportunities, and examine how decisionmaking processes work in specific contexts.

The New Madrid Seismic Zone is well known for its historical seismicity, most notably the 1811-12 New Madrid, MO earthquakes and to a lesser extent the 1895 Charlston, MO earthquake. It has been 124 years since an earthquake larger than M 5.1 occurred in the area. The debate of whether the New Madrid Seismic Zone is an active system or a system in decline has remained a contentious topic when interpreting the intricacies and challenges of an intraplate seismic system. This thesis focuses on an overlooked parameter in the already complex issue regarding the seismic hazard of the New Madrid Seismic Zone. In the early part of the 20th century the Little River Drainage District excavated 9.7 x 109 metric tons of overburden and drained approximately 5000 km2 from within the New Madrid Seismic Zone. Our model demonstrates that the Little River Drainage District resulted in a likely perturbation of the seismic system. The overburden removal, coupled with a reduction of the water column has moved the system away from failure when interpreted in the context of regional stress orientation in relation to the geographic orientation of the Little River Drainage District. This potentially explains the apparent lack of moderate to large events over the past century in the New Madrid Seismic Zone.

En Afrique Sub-Saharienne, les problématiques de contamination de la ressource en eau par les pesticides et les résidus pharmaceutiques commencent à être mises en évidence. La problématique de la thèse porte sur la caractérisation de l’impact des activités humaines sur la qualité de la ressource en eau, par l’étude de la contamination par les pesticides et les résidus pharmaceutiques. Le site d’étude choisi est le bassin versant de la Méfou, qui draine la capitale du Cameroun, Yaoundé. Dans un premier temps, le site est caractérisé par ses spécificités environnementales (relief, occupation des sols) et sociodémographiques afin d’identifier les pressions anthropiques. Les pratiques d’agriculture urbaine, et en particulier le maraîchage intensif dans les bas-fonds entraîneraient l’utilisation massive de pesticides. L’absence d’assainissement efficace et les multiples latrines, drains et fosses septiques constitunt autant de sources diffuses de contamination par les résidus de médicaments. En prenant le cas des pesticides, une méthode cartographique a permis de confirmer l’hypothèse selon laquelle les parcelles agricoles pourraient être identifiées comme des sources de pollution diffuses de pesticides via le ruissellement. La méthode multicritère SIRIS-Pesticides de l’INERIS (Institut National de l’Environnement Industriel et des Risques) appliquée sur deux scénarios de pratiques agricoles indique un potentiel transfert des pesticides ciblés vers les eaux de surface. Afin de conforter ces hypothèses, deux diagnostics de pollution ont été réalisés entre 2015 et 2018 en saisons pluvieuses, couplant des méthodes d’échantillonnages ponctuels et passifs. Une liste de 32 pesticides et de 24 résidus pharmaceutiques a été recherchée dans les eaux de surface et les eaux souterraines du bassin de la Méfou. Les résultats généraux indiquent (i) de fortes concentrations en herbicides et en anti-inflammatoires non stéroïdiens ainsi que la détection et la quantification d’une large gamme de composés recherchés, (ii) une contamination bien plus marquée en milieu urbain qu’en milieu péri-urbain, (iii) un risque environnemental à ces concentrations pour deux herbicides (diuron et atrazine) et (iv) la contamination de certains points d’eau souterraine (forages, puits, sources) par les résidus pharmaceutiques. Une enquête sociologique réalisée autour des points d’eau de prélèvement a permis d’identifier les enjeux liés à l’utilisation de cette ressource en eau. La contamination des eaux souterraines pourrait entraîner une exposition potentielle des populations aux résidus pharmaceutiques présents dans leur eau de boisson. Les résultats principaux constituent donc une base d’information sur les pressions anthropiques, les niveaux de contamination et les enjeux liés à l’eau à Yaoundé. Ils soulèvent des questionnements sur (i) les transferts des pesticides et des résidus médicamenteux dans l’hydrosystème de la Méfou, et (ii) à propos de l’exposition et des risques sanitaires potentiels posés par leur occurrence et leurs niveaux de contamination dans la ressource en eau. / Demographic growth and urbanization create pressure on water resources. Among urban contaminants, pesticides and pharmaceuticals can be discharged into the aquatic environment through agricultural activities and untreated waste waters. Their presence is also reported in global water bodies. Measured contamination levels can have ecotoxicological effects on aquatic organisms as well as on human populations. In Sub-Saharan Africa, these problems are beginning to be highlighted. Local agricultural practices and consumption of pharmaceuticals lead to specific concerns.The aim of this thesis is to identify and characterize the impacts of human activity on the quality of the water resource in urban Sub-Saharan Africa, by analyzing pesticide and pharmaceutical contamination. The study area was the Méfou watershed that drains the political capital of Cameroon, Yaoundé (Center Region).First, the study area was characterized by its environmental (reliefs, land use) and socio-demographic specificities to identify anthropogenic pressures. Urban agricultural practices and in particular the intensive market gardening in the humid lowlands involves the use of massive amounts of pesticides. The absence of a sewage system and the numerous pit-latrines, drains and septic tanks are the sources of diffuse pharmaceutical contamination.Using the example of pesticides, a contaminated runoff mapping method based on susceptibility maps (from the IRIP method) confirmed that some treated plots located in situations that favor runoff were sources of diffuse pesticide contamination. Several areas in the study basin can accumulate this polluted runoff. Next, the multi-criteria SIRIS-Pesticides method from INERIS was applied based on two agricultural scenarios constructed with data sources from the literature. Results pointed to the potential transfer of pesticides from crops to both surface and groundwater.To reinforce these hypotheses, two water quality surveys were conducted in the rainy season between 2015 and 2018, combining grab and passive sampling. Thirty-two pesticides and twenty-four pharmaceuticals were searched for in surface and groundwater in the Méfou watershed. The main results indicate that (i) high concentrations of herbicides and analgesics were detected and quantified in the water samples along with a wide range of targeted compounds; (ii) the contamination pattern showed that the urban area is more polluted than the peri-urban area of Yaoundé; (iii) the measured concentrations pose an environmental risk, in particular the herbicides atrazine and diuron; and (iv) some groundwater sampling points used for drinking water were contaminated by the targeted pharmaceuticals.A social survey conducted in March 2018 around the sampling points identified the risks related to water use. The lack of a sewage system and the discharge of untreated waste water into the immediate surroundings facilitate contamination of the sampling sites. As groundwater is used as an alternative to the tap water network in Yaoundé, the population is also exposed to the risk of pharmaceutically contaminated drinking water.The main results provide baseline information about anthropogenic pressures, contamination levels and related issues in Yaoundé. They raise questions about (i) the transfer of contaminants in the Méfou hydrosystem and (ii) population exposure and potential health risks due to their presence and to the levels of contamination of the water resources.

Anthropogenic contaminants in the marine environment often biodegrade slowly, bioaccumulate in organisms, and can cause reproductive, immune, and developmental effects on wildlife; however, their effects on cetacean health and behavior have not been extensively studied. This study aims to expand knowledge concerning concentrations and biological effects of endocrine disrupting contaminants and essential and non-essential inorganic elements in stranded cetaceans. We evaluated tissue samples and pathology data from 66 odontocetes that stranded in the southeastern United States during 2012– 2017. Using mass spectrometry blubber samples were analyzed for five endocrine disrupting contaminants (atrazine, bisphenol-A, diethyl phthalate, nonylphenol ethoxylate, triclosan), and liver samples were analyzed for 12 inorganic elements (As, Cd, Co, Cu, Mg, Mn, Fe, Pb, Hg, Se, Tl, Zn). Results from this study demonstrate that exposure to certain contaminants may be associated with subtle or sublethal cellular changes in free-ranging marine mammals that could contribute to health declines or stranding. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2019. / FAU Electronic Theses and Dissertations Collection

Non-Anglophone voices in literature can lead to a better understanding of the intricate relationships shown by Ashley Dawson tying capitalism, slow violence, and uneven development to climate change. There is skepticism that science fiction (sf) in particular can properly present climate issues in the anthropocentric era that we live in today, but scholars such as Shelley Streeby argue against such perceptions. Science fiction writers that use magical realism, such as Ngugi wa Thiong’o and Nalo Hopkinson, as ecological sf have already accomplished the task of creating speculative works that fit in perfectly under the umbrella of “serious fictions.” These writers work from a non-Anglophone perspective or from a minority group within a Western society, allowing for different modes of thinking to play a part in these bigger discourses. Writers, educators, and other scholars need to reestablish humanity’s kinship with nature. / Includes bibliography. / Thesis (M.A.)--Florida Atlantic University, 2019. / Florida Atlantic University Electronic Theses and Dissertations Collection