Scientific evidence shows that dietary intake of the omega-3 polyunsaturated fatty acids is beneficial to human health. Fish oil is a rich source of omega-3 fatty acids. However, fish oil with high levels of omega-3 PUFA is very susceptible to oxidative deterioration during storage. The objective of this study was to investigate the effect of xanthan gum (XG)-locust bean gum (LBG) mixtures on the physicochemical properties of whey protein isolate (WPI) stabilized oil-in-water (O/W) emulsions containing 20% v/v menhaden oil. The O/W emulsions containing XG/LBG mixtures were compared to emulsions with either XG or LBG alone. The emulsions were prepared using a sonicator by first mixing menhaden oil into the WPI solution and then either XG, LBG or XG/LBG mixtures were added. WPI solution (2 wt%) and gum solutions (0.0,0.05, 0.1, 0.15, 0.2 and 0.5 wt%) were prepared separately by dissolving measured quantities of WPI in distilled water. XG and LBG gums were blended in a synergistic ratios of 50:50 for the mixture. The emulsions were evaluated for apparent viscosity, microstructure, creaming stability and oxidative stability. Addition of 0.15, 0.2 and 0.5 wt% XG/LBG mixtures greatly decreased the creaming of the emulsion. The emulsion with 0.15, 0.2 and 0.5 wt% XG/LBG mixtures showed no visible serum separation during 15 d of storage. The apparent viscosity of the emulsions containing XG/LBG mixtures was significantly higher (p < 0.05) than the emulsions containing either XG or LBG alone. The viscosity was sharply enhanced at higher concentrations of XG/LBG mixtures. Microstructure images showed depletion flocculation for LBG (0.05-0.5 wt%), XG (0.05- 0.2 wt%) and XG/LBG mixtures (0.05 and 0.1 wt%) emulsions. Flocculation was decreased with the increased biopolymer concentration in the emulsion. The decrease in flocculation was much pronounced for the emulsion containing XG/LBG mixtures. The rate of lipid oxidation for 8 week storage was significantly (p < 0.05) lower in emulsions containing XG/LBG mixtures than in emulsions containing either of the biopolymer alone. The results suggested that the addition of XG/LBG mixtures greatly enhanced the creaming and oxidative stability of the WPI-stabilized menhaden O/W emulsion as compared to either XG or LBG alone.

Mechanistic studies of electrochemical proton coupled electron transfer (PCET) have attracted attention for many decades due to their importance in many fields ranging from electrocatalysis to biology. However, mechanistic research is confined to only a few groups, and challenges in this field can be found in both theory and experiment. The contributions to mechanistic studies of electrochemical PCET reaction in this thesis can be categorized under the following two headings: 1) mechanistic studies of an aminobenzoquinone modified monolayer system with multiple electron/proton transfer reaction; 2) studies that attempt to develop the relationship between thermochemical data and electrochemical PCET mechanism. An aminobenzoquinone modified monolayer showing nearly ideal electrochemical behavior and high stability was successfully prepared and used as a model system for the mechanistic study of electrochemical multiple electron/proton transfer. This model system has been proposed to undergo a 2e3H transfer at low pH electrolyte and a 2e2H transfer at high pH electrolyte. Two non-destructive electrochemical techniques (cyclic voltammetry and chronocoulmetry) have been applied for the measurement of apparent standard rate constant as a function of pH. Both pH dependent apparent formal potential and pH dependent apparent standard rate constant have been used to determine the charge transfer mechanism of this monolayer system. Under the assumption of an operative PCET mechanism (i.e. electron transfer step is the rate determining step), a theoretical description of this system has been developed based on the refinement and extension of previous models. By combining this extended theoretical model with pH dependent apparent formal potential and apparent standard rate constant, charge transfer pathways have been determined and shown to be consistent with the observed pH dependent electrochemical response, in addition, the determined pathways in this aminobenzoquinone modified monolayer are similar to previous reported pathways for benzoquinone freely dissolved in aqueous buffered electrolyte. A series of analytical expressions built in this thesis demonstrate that the parameters that differentiate stepwise mechanisms from concerted mechanisms can be classified into two aspects: thermodynamic parameters, namely acid dissociation constants, standard formal potentials; and kinetic parameters, namely standard rate constants, standard transfer coefficients. Although attempts to understand the relation between controlling parameters and electrochemical PCET mechanism (stepwise versus concerted) has been reported previously by some groups, there are still lots of unresolved aspects requiring further investigation. In this thesis, an important conclusion has been drawn which is that for the stepwise mechanism, an apparent experimentally observable kinetic isotope effect (KIE) can be induced by solvent isotope induced variation of acid dissociation constants, which contradicts previous understanding. Additionally, for the first time, values of apparent KIE, which were measured for the aminobenzoquinone modified monolayer system with stepwise PCET mechanism, were successfully explained by variation in acid dissociation constants, not by variation in standard rate constants. Based on theoretical prediction, a nitroxyl radical modified bilayer showing one electron one proton transfer reaction has been prepared in an effort to afford experimental verification. After applying similar analytical procedures as those for the aminobenzoquinone modified monolayer system, this bilayer system has been shown to follow the concerted 1e1H transfer pathway in high pH electrolytes. These latter contributions provide evidence that further development in this field will eventually lead to a comprehensive theory that can use known thermochemical variables to fully predict PCET mechanism.

Objectives were to characterize residual feed intake (RFI) and determine the phenotypic correlation between performance, feed efficiency, and other biological measurements in Brahman heifers, as well as the relationship between RFI determined in confinement and measurements of grazing activity on pasture. Three separate 70 d feeding trials were performed, and RFI was determined as the residual between actual and predicted dry matter intake (DMI) for a given level of production. Brahman heifers (n = 103; 5-to-9 mo of age) were individually limit-fed a pelleted 12% CP complete ration daily in Calan gates. Weekly body weight (BW) and DMI data were collected, and predicted DMI was determined by linear regression of actual DMI on mid-test metabolic BW. Ytterbium chloride was used to evaluate digestive kinetics, and fecal samples were collected to determine fecal volatile fatty acids (VFA) concentration and determine apparent dry matter digestibility (DMD) utilizing acid insoluble ash as an internal marker. Measurements of temperament were evaluated on all heifers at weaning. High (n = 6) and low (n = 6) RFI heifers (Exp. I) grazed fescue and ryegrass to determine variation in grazing behavior, DMI, and apparent DMD. Data from all three experiments were pooled, and RFI was not correlated with average daily gain (ADG), DMI, BW, partial efficiency of gain, feed conversion ration, fecal VFA concentration, or any measures of temperament. There were no significant differences in digestive kinetics between the RFI efficiency groups. Fecal samples taken for acid detergent insoluble ash (ADIA) determination were not collected at frequent enough intervals to account for weekly variation in fecal ADIA concentration. Pasture measurements were not different between the efficiency groups for heifers evaluated for grazing behavior, as well as estimated intake as a proportion of BW, or apparent DMD. Results of this study suggest that Bos indicus cattle appear to have similar efficiency traits as Bos taurus and Bos indicus influenced cattle, making this measure of efficiency equally as valid for use in both types of cattle. This indicates that selection based on RFI can be made to increase feed efficiency without affecting ADG or BW in Brahman cattle.

Objectives were to characterize residual feed intake (RFI) and determine the phenotypic correlation between performance, feed efficiency, and other biological measurements in Brahman heifers, as well as the relationship between RFI determined in confinement and measurements of grazing activity on pasture. Three separate 70 d feeding trials were performed, and RFI was determined as the residual between actual and predicted dry matter intake (DMI) for a given level of production. Brahman heifers (n = 103; 5-to-9 mo of age) were individually limit-fed a pelleted 12% CP complete ration daily in Calan gates. Weekly body weight (BW) and DMI data were collected, and predicted DMI was determined by linear regression of actual DMI on mid-test metabolic BW. Ytterbium chloride was used to evaluate digestive kinetics, and fecal samples were collected to determine fecal volatile fatty acids (VFA) concentration and determine apparent dry matter digestibility (DMD) utilizing acid insoluble ash as an internal marker. Measurements of temperament were evaluated on all heifers at weaning. High (n = 6) and low (n = 6) RFI heifers (Exp. I) grazed fescue and ryegrass to determine variation in grazing behavior, DMI, and apparent DMD. Data from all three experiments were pooled, and RFI was not correlated with average daily gain (ADG), DMI, BW, partial efficiency of gain, feed conversion ration, fecal VFA concentration, or any measures of temperament. There were no significant differences in digestive kinetics between the RFI efficiency groups. Fecal samples taken for acid detergent insoluble ash (ADIA) determination were not collected at frequent enough intervals to account for weekly variation in fecal ADIA concentration. Pasture measurements were not different between the efficiency groups for heifers evaluated for grazing behavior, as well as estimated intake as a proportion of BW, or apparent DMD. Results of this study suggest that Bos indicus cattle appear to have similar efficiency traits as Bos taurus and Bos indicus influenced cattle, making this measure of efficiency equally as valid for use in both types of cattle. This indicates that selection based on RFI can be made to increase feed efficiency without affecting ADG or BW in Brahman cattle.

ADHD is a highly prevalent disorder in both children and adults that involves significant impairment throughout the lifespan, and yet the core cognitive deficits of the disorder are not well understood. Accumulating evidence of dysfunctioning dopamine systems motivated the theory that delay-of-reinforcement gradients are altered in ADHD in such a way that reinforcers must arrive earlier in time following a response for an association between the two to be learned. The current work is motivated by the conjecture that dopamine dysfunction has consequences for the maximum timescales over which connections can be formed, not just in reinforcement learning, but also in the processes of temporal integration and scene formation that allow humans to understand and navigate their world. There is a maximum window of temporal separation over which discrete events can be integrated into a unified experience, and the current experiments indicate that this maximum window of integration is contracted in ADHD. The experiments included multiple tasks designed so that the participant response required implicit integration over temporal intervals, and the length of those intervals was varied as an independent variable. Adults with and without ADHD completed these tasks, and the strength of temporal integration was measured with respect to interval length and compared between the two groups. This methodology was applied in five types of tasks: rhythmic tapping, spatial cuing, irrelevant feature priming, and two apparent motion tasks. On the whole, this suite of studies was successful in demonstrating a contraction in the maximum interval over which temporal integration can occur in ADHD relative to controls. Two of the tasks, rhythmic tapping and spatial cuing, generated unexpected and interesting results, and several follow-up tasks were designed to further explore these findings. As a result, a somewhat improved tapping task was discovered. This tapping task, as well as the irrelevant feature priming task and one of the apparent motion tasks, demonstrated potential utility for the diagnosis of adults with ADHD. / text

Boosted black holes play an important role in General Relativity (GR), especially in relation to the binary black hole problem. Solving Einstein vacuum equations in the strong field regime had long been the holy grail of numerical relativity until the significant breakthroughs made in 2005 and 2006. Numerical relativity plays a crucial role in gravitational wave detection by providing numerically generated gravitational waveforms that help search for actual signatures of gravitational radiation exciting laser interferometric detectors such as LIGO, VIRGO and GEO600 here on Earth. Binary black holes orbit each other in an ever tightening adiabatic inspiral caused by energy loss due to gravitational radiation emission. As the orbits shrinks, the holes speed up and eventually move at relativistic speeds in the vicinity of each other (separated by ~ 10M or so where 2M is the Schwarzschild radius). As such, one must abandon the Newtonian notion of a point mass on a circular orbit with tangential velocity and replace it with the concept of black holes, cloaked behind spheroidal event horizons that become distorted due to strong gravity, and further appear distorted because of Lorentz effects from the high orbital velocity. Apparent horizons (AHs) are 2-dimensional boundaries that are trapped surfaces. Conceptually, one can think of them as 'quasi-local' definitions for a black hole horizon. This will be explained in more detail in chapter 2. Apparent horizons are especially important in numerical relativity as they provide a computationally efficient way of describing and locating a black hole horizon. For a stationary spacetime, apparent horizons are 2-dimensional cross-sections of the event horizon, which is itself a 3-dimensional null surface in spacetime. Because an AH is a 2-dimensional cross-section of an event horizon, its area remains invariant under distortions due to Lorentz boosts although its shape changes. This fascinating property of the AH can be attributed to the fact that it is a cross-section of a null surface, which, under the boost, still remains null and the total area does not change. Although this invariance of the area is conceptually easy to see it is less straightforward to derive this result. We present two different ways to show the area invariance. One is based on the spin-boost transformation of the null tetrad and the other a direct coordinate transformation of the boosted metric under the Lorentz boost. Despite yielding identical results the two methods differ significantly and we elaborate on this in much more detail. We furthermore show that the use of the spin-boost transformation is not well-suited for binary black hole spacetime and that the spin-boost is fundamentally different from a Lorentz boost although the transformation equations look very similar. We also provide a way to visualize the distorted horizons and look at the multi-pole moments of these surfaces under small boosts. We finish by summarizing our main results at the end and by commenting on the binding energy of the binary and how the apparent horizon is distorted due to presence of another black hole. / text

The study reviews and examines the definitions of reactive power, apparent power, and power factor. Among the different definitions of power factor in three-phase circuits under a non-sinusoidal condition, this study adopts the definition of the effective power factor, which is also advocated by IEEE Standard 1459-2010. The effective power factor is defined as the ratio of the real power consumed by the load over the effective apparent power. The effective apparent power is the maximum power transmitted to the load (or delivered by a source) while keeping the same line losses and the same load (or source) voltage and current. The effective power factor theory gives apparent power a definite physical significance and provides more insights than other definitions in unbalanced circuits. Another merit of the effective power factor definition is that it only involves measurements and computations in the time domain. This study implements the computation of the effective power factor in MATLAB for use in PSCAD/EMTDC. The latter simulates the power system and provides three-phase voltage and current measurements. MATLAB performs the effective power factor computation and sends the results back to PSCAD. A number of simulations are provided in this report to demonstrate the validity and the accuracy of this implementation. / text

Detailed soil and water data are essential to ensure the optimum long-term management of fields. The objective of this study was to estimate water table depths, spatially variable and layered soil properties using electromagnetic induction methods. Soil samples were collected and analyzed within two wild blueberry, a soybean-barley and a pasture fields. Observation wells were installed. The DualEM-2 was calibrated to predict the soil properties and groundwater depths. The apparent ground conductivity (ECa) and water table depths were measured simultaneously from each well, before and after every significant rainfall for three consecutive days. Comprehensive surveys were conducted in selected fields to measure ECa with DualEM-2. Survey data were imported in C++ program to estimate layered soil properties using mathematical models. Regression models were developed to predict soil properties and groundwater depths. The predicted soil properties and groundwater table maps were generated. This information can help to develop variable rate technologies.

The aim of this study was to investigate the effect the plant matrix and the structure of the flavonoid (i.e. whether aglycone or glycoside) may have on the gastrointestinal uptake and metabolism of luteolin derivatives from Artemisia afra traditional plant medicine. Specifically, how these two factors influenced the intestinal uptake and disposition of luteolin derivatives in pure and in Artemisia afra plant extract forms were to be assessed by investigating the uptake and metabolism of the luteolin derivatives in human intestinal epithelial Caco-2 cells and the perfused rat intestinal loop. To realize this aim, the following were determined: (1) identification and characterization of major luteolin derivatives found in Artemisia afra, (2) the effect of the plant matrix on the uptake of luteolin derivatives in Artemisia afra aqueous-extract forms across the Caco-2 cell monolayer, (3) the effect of the plant matrix on the absorption and metabolism of luteolin derivatives in Artemisia afra aqueous-extract forms in the perfused rat small intestine, (4) the effect of gut contents on the uptake and metabolism of luteolin derivatives in intestinal loop and (5) the metabolic profiles of luteolin derivatives obtained for the pure solutions versus plant aqueous extract solutions in Caco-2 cells and the rat intestine. / Philosophiae Doctor - PhD

Transportation costs represent a significant role in the economics of packaged hay and biomass crops. The material’s low bulk density limits transportation efficiency. Density is currently limited by the ability of the baling twine to withstand the expansion forces generated by the baled material shortly after it is ejected from the bale chamber. It was hypothesized that compromising the structure of the plant, particularly the plant nodes could reduce the amount of energy stored in the material as it is compressed and thereby reduce the material’s elastic response to compression. Literature pertinent to the biomass material’s behavior in compression was reviewed. Bulk samples of switchgrass and miscanthus were subject to uniaxial compression, and the required pressure needed to obtain a target density of 256 kg/m3 was compared on a wet and dry density basis. Both switchgrass and miscanthus showed a statistically significant decrease in the required compression pressure, and the interaction between the moisture level and required pressure was also significant. Existing models for the pressure density relationship of compressed bulk material were evaluated for suitability. Individual nodes and internode sections were subject to radial compression and the apparent modulus of elasticity and maximum contact stress were determined.