Este trabalho teve como objetivo avaliar o uso do método das médias móveis na atomização de cádmio, crômio e chumbo utilizando filamento de tungstênio de 150 W (OSRAM) como atomizador eletrotérmico. Realizou-se um estudo sistemático da influência da altura de observação, da temperatura e taxa de aquecimento na atomização dos analitos e a viabilidade do uso do método das médias móveis no tratamento dos sinais transientes gerados na atomização. O estudo da influência da altura de observação foi realizado posicionado-se o filamento no centro (0 mm), 1 e 2 mm abaixo do feixe de radiação. A influência da temperatura e da taxa de aquecimento foi estudada utilizando temperaturas na etapa de atomização entre 1890 e 2780 °C. O método das médias móveis foi aplicado aos sinais transientes gerados na atomização, com o filamento posicionado no centro (0 mm), 1 e 2 mm e com temperatura de atomização entre 2060 e 2780 °C, utilizando fatores 0, 3, 5, 7 e 9. No estudo da temperatura e da taxa de aquecimento foram aplicadas ddps no software de controle na etapa de atomização entre 4 e 12 V. As soluções usadas no desenvolvimento deste trabalho foram preparadas em meio 0,1 % v/v HNO3. Utilizou-se como gás de proteção a mistura de 90% Ar+10 % H2. Para o cádmio, recomenda-se a utilização da altura de observação de 1 mm, para o chumbo recomenda-se 0 mm e para o crômio a altura recomendada é a de 2 mm. Os estudos comprovaram a dependência dos sinais de absorção atômica em altura de pico com a temperatura e a taxa de aquecimento. O cádmio foi o analito em que a taxa de aquecimento foi a menos crítica para a atomização, enquanto que o crômio foi o mais afetado pela variação da taxa de aquecimento. Não foi observada diferença significativa entre os sinais de cádmio com alturas de observação de 0 e 1 mm. Para o chumbo, a diferença entre os sinais com altura de observação de 0 e 1 mm foi constante em todas as taxas de aquecimento estudadas. A 2 mm a diferença entre os sinais aumentou com o aumento da taxa de aquecimento. Para o crômio, não ocorreu uma diferença significativa entre os sinais nas alturas de 1 e 2 mm com atomização até 2180 °C. Nos três analitos a sensibilidade aumentou com o aumento da taxa de aquecimento. O método das médias móveis permitiu a diminuição da variação dos sinais transientes do branco e do ruído. Para o cádmio, não ocorreu uma melhora no limite de detecção do método com a aplicação das médias móveis em nenhuma condição. Para o chumbo e crômio, ocorreu uma melhora no limite de detecção do método nas alturas de observação de 0 e 1 mm. O limite de detecção instrumental apresentou uma melhora significativa para os três elementos em todas as condições estudadas. / The aim of this paper was to evaluate the use of moving averages of cadmium, chromium and lead transient atomic absorption signals generated by 150 W (OSRAM) tungsten coil electrothermal atomizer. A systematic study dealing with the influence of observation height, temperature and heating rate on atomization was carried through in order to demonstrate the viability of moving averages in the treatment of the transient signals during the atomization step. The influence of observation height was carried out with the tungsten coil in the center (0 mm), at 1 and 2 mm below the radiation beam. The influence of atomization temperature and heating rate were evaluated between 1890 °C (3.3 K.ms-1) and 2780 °C (9,3 K.ms-1). The transient moving averages were obtained by using factors 0, 3, 5, 7 and 9, with the tungsten coil in the center (0 mm), 1 and 2 mm and with atomization between 2060 and 2780 °C. For obtaining different temperatures and heating rates, an appropriate power supply was used by applying 4 to 12 V (40 to 120 W) to the atomizer during atomization and a mixture 90% Ar+10% H2 was used as purge/atomization gas. Blanks and reference solutions were prepared in 0,1% v/v HNO3. Best results for cadmium were obtained at 1 mm. For lead it is recommended 0 mm and for chromium 2 mm. The studies had proven the dependence of peak height absorbance signals with temperature and heating rate. Cadmium was the analyte where the heating rate was to less critical for the atomization, whereas chromium was affected by the variation of the heating rate. Significant differences were not observed between cadmium signals with observation heights of 0 and 1 mm. For lead, the difference between the absorbance signals with observation heights of 0 and 1 mm were constant in all tested heating rates. At 2 mm the difference between signals increased by increasing the heating rates. For chromium, a significant difference was not noticed between peak height absorbance signals at 1 and 2 mm with up to 2180 °C. As expected, sensitivity increased for all three analytes by increasing the heating rate. The moving average is a powerful mathematical treatment for minimizing unpredictable fluctuations of the base line during the chosen time interval for measuring the transient absorbance signals. With the exception of Cd, where no improvements on the method detection limit were noticed, the application of the moving average for the lead and chromium showed 3 to 4 fold improvement in the LDmet at 0 and 1 mm observation heights, respectively. The LDinstr presented a significant improvement (3 to 6 fold) for the three analytes in all studied conditions.

The purpose of this investigation is to analyze the flow pattern of cooling fluids in the 3D "twister-effect" mixing chamber and to approximate the free surface behaviors exiting the 2D spray nozzle. The cone angle and free surface height located at the end of the free surface are two significant factors to determine the spraying area on a heated plane. This process is a reasonable representation of many industrial cooling application. The whole system consists of 4 inlet tubes connected to the top of the mixing chamber, and the spray nozzle is located under the chamber. Four different refrigerants, like FC-72, FC-77, FC-87 and methanol were used for the turbulent flow simulations. According to different fluid properties, the cone angle, free surface, pressure drop and Reynolds number can be investigated at different flow rates. First, at a certain volumetric flow rates, the velocities in x, y, z directions were found on the positive x-axis (0 degree), y-axis (90 degrees), negative x-axis (180 degrees) and y-axis (270 degrees) at 8.0 x 10-4m below the top of chamber. After the transformations, the interpolated and averaged radial, circumferential and axial velocities were used in the 2D nozzle simulations. Finally, the cone angle, the radial locations of the free surface and the pressure drop were obtained in each scenario. As the results, higher volumetric flow rate produced higher free surface height and cone angle. Also, FC-87 created the highest free surface height and cone angle among all four working fluids in both volumetric flow rates. It means that FC-87 can produce the largest spraying area on the heated surface. Fluctuation, spinning and eddy circulation can be found in the velocity plot because of the turbulent flow syndromes. When comparing two different nozzle designs, it was found that the nozzle without mixing chamber gave a larger cone angle and free surface height. Alternatively, the design in this investigation produced a relatively narrow jet concentrated to the stagnation zone.

A conical nozzle with two separate inlets within its top plate is analyzed. One of the inlets is in the center of the top plate, which is free to rotate, whereas the other inlet is positioned away from the center. The fluid entering through the outer inlet slot causes the top plate of the nozzle to spin. Several fluids including FC-77, FC-72, FC-87, and Methanol running at different flow rates were investigated to observe the effect that their particular properties have on the geometry of the fluid's free surface exiting the nozzle. Another variation performed was the geometry of the nozzle. The outer inlet slot was positioned at various radial distances along the top plate. For this nozzle, the top plate remained stationary and swirling was introduced to the fluid at the inlets. It was observed that the faster flow rates caused an increase in the free surface height and cone angle. For the various radial locations of the outer inlet slot, it was noted that a position at approximately 75% of the nozzle radius produced the largest free surface height. The largest cone angle was produced when the outer inlet slot was positioned at the edge of the nozzle top plate. Another factor that increased the radial height and cone angle of the free surface was the working fluid used in the study. A larger Reynolds number produced a larger cone angle and larger free surface height (while a smaller Reynolds number produced a less significant cone angle and free surface height).

Title from PDF of title page. / Document formatted into pages; contains 230 pages. / Thesis (M.S.M.E.)--University of South Florida, 2003. / Includes bibliographical references. / Text (Electronic thesis) in PDF format. / ABSTRACT: A conical nozzle with two separate inlets within its top plate is analyzed. One of the inlets is in the center of the top plate, which is free to rotate, whereas the other inlet is positioned away from the center. The fluid entering through the outer inlet slot causes the top plate of the nozzle to spin. Several fluids including FC-77, FC-72, FC-87, and Methanol running at different flow rates were investigated to observe the effect that their particular properties have on the geometry of the fluid's free surface exiting the nozzle. Another variation performed was the geometry of the nozzle. The outer inlet slot was positioned at various radial distances along the top plate. For this nozzle, the top plate remained stationary and swirling was introduced to the fluid at the inlets. It was observed that the faster flow rates caused an increase in the free surface height and cone angle. / ABSTRACT: For the various radial locations of the outer inlet slot, it was noted that a position at approximately 75% of the nozzle radius produced the largest free surface height. The largest cone angle was produced when the outer inlet slot was positioned at the edge of the nozzle top plate. Another factor that increased the radial height and cone angle of the free surface was the working fluid used in the study. A larger Reynolds number produced a larger cone angle and larger free surface height (while a smaller Reynolds number produced a less significant cone angle and free surface height). / System requirements: World Wide Web browser and PDF reader. / Mode of access: World Wide Web.

Este trabalho teve como objetivo avaliar o uso do método das médias móveis na atomização de cádmio, crômio e chumbo utilizando filamento de tungstênio de 150 W (OSRAM) como atomizador eletrotérmico. Realizou-se um estudo sistemático da influência da altura de observação, da temperatura e taxa de aquecimento na atomização dos analitos e a viabilidade do uso do método das médias móveis no tratamento dos sinais transientes gerados na atomização. O estudo da influência da altura de observação foi realizado posicionado-se o filamento no centro (0 mm), 1 e 2 mm abaixo do feixe de radiação. A influência da temperatura e da taxa de aquecimento foi estudada utilizando temperaturas na etapa de atomização entre 1890 e 2780 °C. O método das médias móveis foi aplicado aos sinais transientes gerados na atomização, com o filamento posicionado no centro (0 mm), 1 e 2 mm e com temperatura de atomização entre 2060 e 2780 °C, utilizando fatores 0, 3, 5, 7 e 9. No estudo da temperatura e da taxa de aquecimento foram aplicadas ddps no software de controle na etapa de atomização entre 4 e 12 V. As soluções usadas no desenvolvimento deste trabalho foram preparadas em meio 0,1 % v/v HNO3. Utilizou-se como gás de proteção a mistura de 90% Ar+10 % H2. Para o cádmio, recomenda-se a utilização da altura de observação de 1 mm, para o chumbo recomenda-se 0 mm e para o crômio a altura recomendada é a de 2 mm. Os estudos comprovaram a dependência dos sinais de absorção atômica em altura de pico com a temperatura e a taxa de aquecimento. O cádmio foi o analito em que a taxa de aquecimento foi a menos crítica para a atomização, enquanto que o crômio foi o mais afetado pela variação da taxa de aquecimento. Não foi observada diferença significativa entre os sinais de cádmio com alturas de observação de 0 e 1 mm. Para o chumbo, a diferença entre os sinais com altura de observação de 0 e 1 mm foi constante em todas as taxas de aquecimento estudadas. A 2 mm a diferença entre os sinais aumentou com o aumento da taxa de aquecimento. Para o crômio, não ocorreu uma diferença significativa entre os sinais nas alturas de 1 e 2 mm com atomização até 2180 °C. Nos três analitos a sensibilidade aumentou com o aumento da taxa de aquecimento. O método das médias móveis permitiu a diminuição da variação dos sinais transientes do branco e do ruído. Para o cádmio, não ocorreu uma melhora no limite de detecção do método com a aplicação das médias móveis em nenhuma condição. Para o chumbo e crômio, ocorreu uma melhora no limite de detecção do método nas alturas de observação de 0 e 1 mm. O limite de detecção instrumental apresentou uma melhora significativa para os três elementos em todas as condições estudadas. / The aim of this paper was to evaluate the use of moving averages of cadmium, chromium and lead transient atomic absorption signals generated by 150 W (OSRAM) tungsten coil electrothermal atomizer. A systematic study dealing with the influence of observation height, temperature and heating rate on atomization was carried through in order to demonstrate the viability of moving averages in the treatment of the transient signals during the atomization step. The influence of observation height was carried out with the tungsten coil in the center (0 mm), at 1 and 2 mm below the radiation beam. The influence of atomization temperature and heating rate were evaluated between 1890 °C (3.3 K.ms-1) and 2780 °C (9,3 K.ms-1). The transient moving averages were obtained by using factors 0, 3, 5, 7 and 9, with the tungsten coil in the center (0 mm), 1 and 2 mm and with atomization between 2060 and 2780 °C. For obtaining different temperatures and heating rates, an appropriate power supply was used by applying 4 to 12 V (40 to 120 W) to the atomizer during atomization and a mixture 90% Ar+10% H2 was used as purge/atomization gas. Blanks and reference solutions were prepared in 0,1% v/v HNO3. Best results for cadmium were obtained at 1 mm. For lead it is recommended 0 mm and for chromium 2 mm. The studies had proven the dependence of peak height absorbance signals with temperature and heating rate. Cadmium was the analyte where the heating rate was to less critical for the atomization, whereas chromium was affected by the variation of the heating rate. Significant differences were not observed between cadmium signals with observation heights of 0 and 1 mm. For lead, the difference between the absorbance signals with observation heights of 0 and 1 mm were constant in all tested heating rates. At 2 mm the difference between signals increased by increasing the heating rates. For chromium, a significant difference was not noticed between peak height absorbance signals at 1 and 2 mm with up to 2180 °C. As expected, sensitivity increased for all three analytes by increasing the heating rate. The moving average is a powerful mathematical treatment for minimizing unpredictable fluctuations of the base line during the chosen time interval for measuring the transient absorbance signals. With the exception of Cd, where no improvements on the method detection limit were noticed, the application of the moving average for the lead and chromium showed 3 to 4 fold improvement in the LDmet at 0 and 1 mm observation heights, respectively. The LDinstr presented a significant improvement (3 to 6 fold) for the three analytes in all studied conditions.

Master thesis focused on the research of the effervescent atomizers. Effervescent atomizers belong to a group of two-phase atomizers, which are often used in combustion applications. Right there in combustion applications, the degree of the stability sprays has a significant impact on combustion efficiency and exhaust gas emissions. The main aim of this work was to asses the level of spray unsteadiness depending on the atomizer design and its operating mode. The effect of construction was studied on the diameter and length of mixing chamber, and then on the size, number and location of aeration holes. Seventeen specific variants of the atomizer were constructed by different combinations of these design parameters. Each of these variants was measured in three operating modes, which were represented by a liquid pressure at the inlet to the atomizer and gas-to-liquid mass flow ratio (GLR). To evaluate the level of spray unsteadiness was used a methodology, which compares the ideal element´s distribution into the interparticle time bin, defined for the ideal (stable) spray, with the experimentally observed distribution. The laser measurement system P/DPA (Phase Doppler Particle Analyzer) was used to determine the experimental interparticle distribution. The result of the comparison of the ideal and the experimental distribution was the parameter , which expresses the level of spray unsteadiness for a specific atomizer and operating mode. With that parameter it was possible to compare the individual atomizers and determinate to the benefit of various construction´s correction of the atomizer. The results showed the recommendation for the modifications of the atomizer, creating a spray with a minimum level of spray´s unsteadiness. For the surveyed atomizer and his individual costruction´s variations the drawing was made.

Interference effects of co-generated hydrides of arsenic, antimony, bismuth and selenium on trapping behavior of selenium or antimony hydrides (analytes) within iridium modified, transversely heated graphite tube atomizer (THGA) was investigated. A twin-channel hydride generation system was used for independent separate generation and introduction of analyte and interferent hydrides, i.e. in simultaneous and/or sequential analyte-interferent and interferent-analyte mode of operation. Influence of the analyte and modifier mass, interferent amount, trapping temperature and composition of the gaseous phase was studied. A simple approach for elimination of mutual interference effects by modification of the gaseous phase with oxygen in substoichiometric ratio to chemically generated hydrogen is proposed and suppression of these interference effects is demonstrated. A hypothesis on mechanism of trapping and mutual interference effects is drawn.

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