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This thesis is concerned with modelling rockfall parameters associated with cliff collapse debris and the resultant “ramp” that formed following the high peak ground acceleration (PGA) events of 22 February 2011 and 13 June 2011. The Christchurch suburb of Redcliffs, located at the base of the Port Hills on the northern side of Banks Peninsula, New Zealand, is comprised of Miocene-age volcanics with valley-floor infilling marine sediments. The area is dominated by basaltic lava flows of the Mt Pleasant Formation, which is a suite of rocks forming part of the Lyttelton Volcanic Group that were erupted 11.0-10.0Ma. Fresh exposure enabled the identification of a basaltic ignimbrite unit at the study site overlying an orange tuff unit that forms a marker horizon spanning the length of the field area. Prior to this thesis, basaltic ignimbrite on Banks Peninsula has not been recorded, so descriptions and interpretations of this unit are the first presented. Mapping of the cliff face by remote observation, and analysis of hand samples collected from the base of the debris slopes, has identified a very strong (>200MPa), columnar-jointed, welded unit, and a very weak (<5MPa), massive, so-called brecciated unit that together represent the end-member components of the basaltic ignimbrite. Geochemical analysis shows the welded unit is picrite basalt, and the brecciated unit is hawaiite, making both clearly distinguishable from the underlying trachyandesite tuff. RocFall™ 4.0 was used to model future rockfalls at Redcliffs. RocFall™ is a two-dimensional (2D), hybrid, probabilistic modelling programme for which topographical profile data is used to generate slope profiles. GNS Science collected the data used for slope profile input in March 2011. An initial sensitivity analysis proved the Terrestrial Laser Scan (TLS)-derived slope to be too detailed to show any results when the slope roughness parameter was tested. A simplified slope profile enabled slope roughness to be varied, however the resulting model did not correlate with field observations as well. By using slope profile data from March 2011, modelled rockfall behaviour has been calibrated with observed rockfall runout at Redcliffs in the 13 June 2011 event to create a more accurate rockfall model. The rockfall model was developed on a single slope profile (Section E), with the chosen model then applied to four other section lines (A-D) to test the accuracy of the model, and to assess future rockfall runout across a wider area. Results from Section Lines A, B, and E correlate very well with field observations, with <=5% runout exceeding the modelled slope, and maximum bounce height at the toe of the slope <=1m. This is considered to lie within observed limits given the expectation that talus slopes will act as a ramp on which modelled rocks travel further downslope. Section Lines C and D produced higher runout percentage values than the other three section lines (23% and 85% exceeding the base of the slope, respectively). Section D also has a much higher maximum bounce height at the toe of the slope (~8.0m above the slope compared to <=1.0m for the other four sections). Results from modelling of all sections shows the significance of the ratio between total cliff height (H) and horizontal slope distance (x), and of maximum drop height to the top of the talus (H*) and horizontal slope distance (x). H/x can be applied to the horizontal to vertical ratio (H:V) as used commonly to identify potential slope instability. Using the maximum value from modelling at Redcliffs, the future runout limit can be identified by applying a 1.4H:1V ratio to the remainder of the cliff face. Additionally, the H*/x parameter shows that when H*/x >=0.6, the percentage of rock runout passing the toe of the slope will exceed 5%. When H*/x >=0.75, the maximum bounce height at the toe of the slope can be far greater than when H*/x is below this threshold. Both of these parameters can be easily obtained, and can contribute valuable guideline data to inform future land-use planning decisions. This thesis project has demonstrated the applicability of a 2D probabilistic-based model (RocFall™ 4.0) to evaluate rockfall runout on the talus slope (or ramp) at the base of ~35-70m high cliff with a basaltic ignimbrite source. Limitations of the modelling programme have been identified, in particular difficulties with adjusting modelled roughness of the slope profile and the inability to consider fragmentation. The runout profile using RocFall™ has been successfully calibrated against actual profiles and some anomalous results have been identified.

Cassini spacecraft images of Io obtained during its flyby of Jupiter in late 2000 and early 2001 were used to determine the lava composition and eruption style of three faint hotspots, Pillan, Wayland, and Loki. We found a maximum color temperature of 1130+/-289 K for Pillan and maximum color temperatures of 1297+/-289 K and 1387+/-287 K for Wayland and Loki, respectively. These temperatures are suggestive of basaltic lava. The temperatures with the best signal-to-noise ratios also suggested basaltic lava and were found to be 780+/-189 K, 1116+/-250 K, and 1017+/-177 K for Pillan, Wayland, and Loki, respectively. Pillan showed increased activity on the third eclipse day after being fairly constant for the first two days, suggesting increased fountaining or lava flow activity on the third day. The data also suggest that Pillan is surrounded by topography that blocked emission on day000 and caused a much more dramatic decrease in emission. Wayland's intensity decreased over the three eclipses, consistent with a cooling lava flow or decreasing eruption. However, rapid decreases in intensity over periods of 26 to 48 minutes could have resulted from the eruption of highly exposed lava, perhaps an open channel or fountain. The data also suggest Wayland may be in a depression surrounded by ridges that blocked part of the emission. Intensities at Loki over the course of the observation varied in both directions, and were consistent with previous determinations of an often quiescent lava lake with periods of active overturning and fountains.

Mafic magma is the most common magma erupted at the surface of the earth. It is generated from partial melting of the mantle, which has been subdivided into end-members based on unique geochemical signatures. One reason these end members, or heterogeneities, exist is subduction of lithospheric plates back into the mantle. The amount of elements, such as Cl and K, removed during subduction and recycled into the deep mantle, is poorly constrained. Additionally, the amount of volatiles, such as Cl, that are recycled into the deep mantle will strongly affect the behavior of the system. I have looked at Cl and K in HIMU source melts to see how it varies. Cl/Nb and K/Nb suggest that elevated Cl/K ratios are the result of depletion of K rather than increased Cl recycled into the deep mantle. After the mantle has partially melted and mafic melt has migrated to the surface, it usually erupts effusively or with low explosivity because of its low viscosity, but it is possible for larger eruptions to occur. These larger, Plinian eruptions, are not well understood in mafic systems. It is generally thought that basalt has a viscosity that is too low to allow for such an eruption to occur. Plinian eruptions require fragmentation to occur, which means the melt must undergo brittle failure. This may occur if the melt ascends rapidly enough to allow pressure to build in bubbles without the bubbles expanding. To test this, I have done decompression experiments to try to bracket the ascent rate for two Plinian eruptions. One eruption has a fast ascent, faster than those seen in more silicic melts, whereas the other eruption is unable to be reproduced in the lab, however it began with a increased viscosity in the partly crystallized magma. After fragmentation and eruption, it is generally thought that tephra do not continue to crystallize. We have found that crystallinity increases from rim to core in two basaltic pumice. Textural data along with a cooling model has allowed us to estimate growth rates in a natural system, which are similar to experimental data. / text

A plethora of magmatic processing occurs in magma reservoirs, where melts are stored prior to eruption. Magma reservoirs are complex, open systems, and often multiple reservoirs are partially inter-connected from source to surface, giving rise to the term 'volcanic plumbing system'. Parental melts feeding these reservoirs can have diverse and distinct geochemical and petrological characteristics, and be variably evolved or enriched. These melts can also bring with them a crystal cargo that may remain in equilibrium in the magma reservoir, but may also be modified by reaction, resorption, crystallisation and diffusion. Melts and crystals can be transported between reservoirs, from the upper mantle and through the crust, leading to melt mixing, reactions and volatile exsolution. Basaltic volcanic systems are fed by primitive melts, and due to the rapid ascent of melts and short magma storage times, these volcanoes provide the best means of unravelling the mantle and crustal contribution to geochemical heterogeneity observed in erupted samples. Despite the potential chemical complexity of a magma reservoir, evidence for magma processing and reaction can be preserved in melt inclusion suites and the compositional structure of their host crystals. Magmatic processes during storage and transport at two basaltic volcanoes are investigated using two carefully selected eruptions: the 1669 eruption at Mt. Etna, and the 2007 Father's Day eruption at Kīlauea. A suite of diverse geochemical, petrological and petrographical observations, made at a range of length-scales, are combined and interpreted in tandem with geophysical monitoring data. The conclusions of these studies shed light on the architecture of each volcano's plumbing systems and basaltic plumbing systems in general. This thesis is divided into two parts. The first study unravels the crustal and mantle processes controlling melt geochemical heterogeneity at Mt. Etna, Sicily, during the 1669 eruption, the largest eruption in historical times. The 1669 melt inclusion suite arises from the mixing of two basaltic melts with similar major element compositions but very different trace and volatile element compositions. The melt geochemistry suggests that at least one end-member melt has been heavily influenced by assimilation of carbonate in the crust. The elevation in alkalis, caused by carbonate assimilation, enhances carbon and sulfur solubility in one end member. The melt inclusion suite indicates that mixing of these melts occurred in the shallow crust shortly before eruption and this mixing may be the cause of the enhanced $CO_{2}$ fluxes prior to eruptions at Mt. Etna. The second study is split into two parts. Each uses the eruptive products of the Father's Day eruption at Kīlauea and aims to unravel the connectivity of the plumbing system between the summit and East Rift Zone, with a focus on timescales of storage and transport. The first part investigates the melt geochemistry in terms of heterogeneity and volatile composition, and the second investigates the crystal cargo in terms of features of the macro-scale crystal cargo distribution and the micro-scale geochemical zoning of individual crystals. The integration of observations and models from these two studies constrains the pressure, temperature and composition of source magma feeding the Father's Day eruption. The eruption is investigated in the context of the "magma surge'' event that preceded the intrusion, as well as within the context of the longer-term trends in Kīlauea geochemistry at the summit and East Rift Zone. Melt inclusion and matrix glass volatile systematics provide insights into the degassing path of the magma and the duration of magma transport to the surface is constrained by diffusion modelling. Estimated timescales for ascent by diffusion modelling of macrocryst major element composition, melt inclusion water content and the melt Fe$^{3+}$/Fe$_{tot}$ ratio are in agreement with timescales observed from the geophysical data of $< $8 hours from reservoir depth to eruption. Both studies emphasise how petrological observations can supplement geophysical monitoring datasets collected at the surface to aid our interpretation of volcanic behaviour and eruption forecasting.

abstract: Olympus Mons is the largest volcano on Mars. Previous studies have focused on large scale features on Olympus Mons, such as the basal escarpment, summit caldera complex and aureole deposits. My objective was to identify and characterize previously unrecognized and unmapped small scale features to understand the volcanotectonic evolution of this enormous volcano. For this study I investigated flank vents and arcuate graben. Flank vents are a common feature on composite volcanoes on Earth. They provide information on the volatile content of magmas, the propagation of magma in the subsurface and the tectonic stresses acting on the volcano. Graben are found at a variety of scales in close proximity to Martian volcanoes. They can indicate flexure of the lithosphere in response to the load of the volcano or gravitation spreading of the edifice. Using Context Camera (CTX), High Resolution Imaging Science Experiment (HiRISE), Thermal Emission Imaging System (THEMIS), High Resolution Stereo Camera Digital Terrain Model (HRSC DTM) and Mars Orbiter Laser Altimeter (MOLA) data, I have identified and characterized the morphology and distribution of 60 flank vents and 84 arcuate graben on Olympus Mons. Based on the observed vent morphologies, I conclude that effusive eruptions have dominated on Olympus Mons in the Late Amazonian, with flank vents playing a limited role. The spatial distribution of flank vents suggests shallow source depths and radial dike propagation. Arcuate graben, not previously observed in lower resolution datasets, occur on the lower flanks of Olympus Mons and indicate a recent extensional state of stress. Based on spatial and superposition relationships, I have constructed a developmental sequence for the construction of Olympus Mons: 1) Construction of the shield via effusive lava flows.; 2) Formation of the near summit thrust faults (flank terraces); 3) Flank failure leading to scarp formation and aureole deposition; 4) Late Amazonian effusive resurfacing and formation of flank vents; 5) Subsidence of the caldera, waning volcanism and graben formation. This volcanotectonic evolution closely resembles that proposed on Ascraeus Mons. Extensional tectonism may continue to affect the lower flanks of Olympus Mons today. / Dissertation/Thesis / Masters Thesis Geological Sciences 2015

Postglacial activity on the Askja volcanic system, north Iceland, has been dominated by basaltic volcanism. Over 80% of Askja's postglacial basalts fall within a relatively narrow compositional range containing between 4 and 8 wt.% MgO. The 'main series' is further divided into two groups separated by a distinct compositional gap evident in major and trace element concentrations. The most evolved basalts formed by fractional crystallisation within shallow magma reservoirs, followed by the extraction of residual liquid from a semi-rigid, interconnected crystal network. This process is analogous to the formation of melt segregations within single lava flows, and was responsible for generating several small-volume, aphyric basaltic lavas erupted along caldera ring fractures surrounding the Oskjuvatn (Askja lake) caldera in the early 20th century. Further examples of evolved basalt are found throughout Askja's postglacial volcanic record. However, Askja's early postglacial output is dominated by more primitive compositions. Some of the most primitive basalts erupted within the Askja caldera are found in phreatomagmatic tuff cone sequences which crop out in the walls of Oskjuvatn caldera. one such tuff sequence has been dated at between 2.9 and 3.6 ka. This tuff cone shares geochemical source characteristics, such as Nb/La and Nb/Zr, with basaltic tephras erupted during precursory activity to the Plinian-phreatoplinian eruption of 28th-29th March 1875. It may therefore be considered to be compositionally representative of the primitive basaltic magmas supplied to Askja during the postglacial period. The predominance of relatively primitive basalt (6.8 wt.% MgO) within Askia's postglacial lava succession suggests that it did not have a permanent shallow magma chamber during the postglacial period. It is envisaged that the postglacial Askja magmas evolved by a process of polybaric factionation in transient, sill-like magma storage zones located at various levels in the crust. The most primitive magmas erupted directly from deeper reservoirs, while the more evolved magmas experienced longer crustal residence times. The buoyant rise of volatile-enriched melt from these sill-like bodies, without mobilising phenocryst phases, explains the observation that almost all lavas on Askja's eastern and southern lava aprons are essentially aphyric. The 28th-29th March 1975 eruption marked the climax of a volcanotectonic episode on the Askja volanic system lasting from late 1874 to early 1876. Fissure eruptions also occurred at the Sveinagja graben, 45-65 km north of Askja, between February and October 1875, producing the Nyjahraun lava. A strong similarity exists between whole-rock major element concentrations from Myjahraun and the Askja 20th century basalts. This has led to the suggestion that these basalts originated from a common shallow magma reservoir beneath Askja central volcano, with the Nyjahraun eruptions being fed by a lateral dyke extending northwards from Askja. This theory also offers an explanation for the observation that the volume of phyolitic ejecta from 28th-29th March 1875 is significantly less than the volume of Oskjuvatn caldera, which was formed as a result of this eruption. New major and trace element data from whole-rock and glass samples indicated that Nyjahraun and the Askja 20th century basalts did not share a common parental magma. A detailed investigation of historical accounts from explorers and scientists who visited Askja between 1875 and 1932 reveals that Oskjuvatn caldera took over 40 years to reach its current form, and that its size in 1876 was equal to the volume erupted on 28th-29th March 1875. Small injections of magma into an igneous intrusion complex beneath Askja, coupled with background deflation, are sufficient to provide the required accommodation space for continued caldera collapse after 1876. Lateral flow is therefore not required to explain the volume of Oskjuvatn caldera, nor the eruption of evolved basaltic magma on the Askja volcanic system in 1875. It has been conjectured that the Holuhraun lava, located at the southern tip of the Askja volcanic system, was also connected with the 1874-76 Askja volcanotectonic episode. However, major and trace element data from whole-rock samples, glass and melt inclusions receal the Holuhraun is geochemically more similar to basalts erupted on the Bardarbunga-Veidivotn volcanic system than to postglacial basalts from Askja. The division between the 'Askja' and 'Veidivotn' geochemical signatures appears to be linked to east-west-striking lineations in the region south of Askja. This indicates that a particular geochemical signature is not necessarily confined to the tectonic expression of a single volcanic system, and has important implications for the identification and delineation of individual volcanic systems beneath the northwest sector of Vatnajokull.

Chlorite and corrensite are very common secondary minerals in very low-grade metamorphic or hydrothermally altered mafic rocks. Corrensite, although defined as a 1:1 regularly mixed-layered chlorite/smectite or chlorite/vermiculite, has been considered as a unique mineral phase and might thus be a potential index mineral for evaluating very low metamorphic grade. Many lenticular basaltic rocks, which are intercalated with unmetamorphosed to low-grade metamorphosed Tertiary sedimentary rocks, occur sporadically in the Western foothills and the Central Range in Taiwan. The lenticular basaltic rocks in the Western foothills (diagenetic zone) and the western flank of the Central Range (anchizone to epizone) were subjected to different degrees of hydrothermal alteration and/or metamorphism. However, only few occurrences of corrensite in these basaltic rocks were reported. In the present study, the occurrences and mixed-layering features of corrensite and coexisting chloritic minerals in the basaltic rocks were characterized by utilizing optical microscopy, X-ray diffraction, scanning electron microscopy with energy dispersive spectrometry, and transmission electron microscopy (TEM). The results showed that most of these basaltic rocks contain abundant chloritic minerals occurring as replacements of mafic minerals or interstitial glass, or as vein- or vesicle-filling materials. The chloritic minerals include smectite, corrensite, chlorite, mixed-layered chlorite/smectite, or mixed-layered chlorite/corrensite. The compositions of chlorite, corrensite, and smectite are distinctive in terms of their Si/Al ratios, interlayer cations, and total cation numbers. Corrensite, chlorite, and mixed-layered chlorite/corrensite are common secondary mineral assemblages in the anchizone basaltic rocks, whereas only discrete chlorite occur in the epizone. The basaltic rocks in the diagenetic zone contain different assemblages, such as smectite only, chlorite + smectite + mixed-layered chlorite/smectite + mixed-layered chlorite/corrensite, or chlorite + corrensite + mixed-layered chlorite/corrensite. These different assemblages of chloritic minerals and other secondary mineral assemblages might reflect different stages of hydrothermal alteration. Corrensite was positively identified with TEM lattice-fringe imaging in the diagenetic rocks collected from Nangang, Poneikeng, Shanzijiao, Nanshihjiao, Hsiungkong, Shihsiouping, Fusing, and Northern Shihmen Reservoir areas, and in the studied anchizone rocks from Junghua, Kaopo and Baolai areas. The disappearance of corrensite clearly marks the boundary between the anchizone and epizone basaltic rocks. Corrensite, as a chemically and structurally unique mineral phase, is therefore a potential index mineral in very low-grade metamorphic rocks.