Coatings are frequently applied on gas turbine components inorder to restrict surface degradation such as corrosion andoxidation of the structural material or to thermally insulatethe structural material against the hot environment, therebyincreasing the efficiency of the turbine. However, in order toobtain accurate lifetime expectancies and performance of thecoatings system it is necessary to have a reliableunderstanding of the mechanical properties and failuremechanisms of the coatings. In this thesis, mechanical and fracture behaviour have beenstudied for a NiAl coating applied by a pack cementationprocess, an air-plasma sprayed NiCoCrAlY bondcoat, a vacuumplasma-sprayed NiCrAlY bondcoat and an air plasma-sprayed ZrO2+ 6-8 % Y2O3topcoat. The mechanical tests were carried out ata temperature interval between room temperature and 860oC.Small punch tests and spherical indentation were the testmethods applied for this purpose, in which existing bending andindentation theory were adopted for interpretation of the testresults. Efforts were made to validate the test methods toensure their relevance for coating property measurements. Itwas found that the combination of these two methods givescapability to predict the temperature dependence of severalrelevant mechanical properties of gas turbine coatings, forexample the hardness, elastic modulus, yield strength, fracturestrength, flow stress-strain behaviour and ductility.Furthermore, the plasma-sprayed coatings were tested in bothas-coated and heat-treated condition, which revealedsignificant difference in properties. Microstructuralexamination of the bondcoats showed that oxidation with loss ofaluminium plays an important role in the coating degradationand for the property changes in the coatings. Keywords:small punch test, miniaturised disc bendingtests, spherical indentation, coatings, NiAl, APS-NiCoCrAlY,VPS-NiCrAlY, mechanical properties

<p>Coatings are frequently applied on gas turbine components inorder to restrict surface degradation such as corrosion andoxidation of the structural material or to thermally insulatethe structural material against the hot environment, therebyincreasing the efficiency of the turbine. However, in order toobtain accurate lifetime expectancies and performance of thecoatings system it is necessary to have a reliableunderstanding of the mechanical properties and failuremechanisms of the coatings.</p><p>In this thesis, mechanical and fracture behaviour have beenstudied for a NiAl coating applied by a pack cementationprocess, an air-plasma sprayed NiCoCrAlY bondcoat, a vacuumplasma-sprayed NiCrAlY bondcoat and an air plasma-sprayed ZrO₂+ 6-8 % Y₂O₃topcoat. The mechanical tests were carried out ata temperature interval between room temperature and 860oC.Small punch tests and spherical indentation were the testmethods applied for this purpose, in which existing bending andindentation theory were adopted for interpretation of the testresults. Efforts were made to validate the test methods toensure their relevance for coating property measurements. Itwas found that the combination of these two methods givescapability to predict the temperature dependence of severalrelevant mechanical properties of gas turbine coatings, forexample the hardness, elastic modulus, yield strength, fracturestrength, flow stress-strain behaviour and ductility.Furthermore, the plasma-sprayed coatings were tested in bothas-coated and heat-treated condition, which revealedsignificant difference in properties. Microstructuralexamination of the bondcoats showed that oxidation with loss ofaluminium plays an important role in the coating degradationand for the property changes in the coatings.</p><p><b>Keywords:</b>small punch test, miniaturised disc bendingtests, spherical indentation, coatings, NiAl, APS-NiCoCrAlY,VPS-NiCrAlY, mechanical properties</p>

The self-compacting concrete (SCC) has been characterized as a great evolution in the concrete technology, being able to fill all empty spaces of the formwork and selfcompacting only by action of its own weight. If steel fibers are added to SCC, without prejudice its properties in the fresh state, new advantages and possibilities of applications will provide concretes more efficient. In this context, a SCC with addition of industrial waste is used, and steel fibers with l/d ratio equal to 50 are incorporated, in a volume fraction of 1%, in order to assess the behavior of reinforced self-compacting concrete beams, with and without the addition of steel fibers, subject to normal and tangential stresses, and compare them with the behavior of conventional reinforced concrete beams. For that, were made reinforced concrete beams of dimensions (12,5 x 23,5 x 132) cm, which were tested by four-point bending, to the 28 days of age. To compare the results, were produced conventional concretes of different compositions, with and without steel fibers. The tests results in the fresh state shown that was possible the obtaining of concrete with self-compacting properties, even with the addition of steel fibers, from a mix already existent of SCC. The addition of the steel fibers to the SCC promoted slight gain in the load capacity of the beam, with lower displacements in the middle span, lower deformations in the reinforcement bars and improved cracking control, compared to the others beams produced with concrete compacted by vibration, with and without steel fibers. / O concreto auto-adensável (CAA) vem se caracterizando como uma grande evolução na tecnologia do concreto, sendo capaz de preencher todos os espaços vazios da fôrma e adensar-se apenas pela ação de seu peso próprio. Se ao CAA adicionam-se fibras de aço, sem prejuízo de suas propriedades no estado fresco, novas vantagens e possibilidades de aplicação proporcionarão concretos mais eficientes. Dentro desse contexto, um CAA com adição de resíduo industrial é usado, e fibras de aço com relação l/d = 50 são incorporadas, em uma fração volumétrica de 1%, com intuito de avaliar o comportamento de vigas de concreto auto-adensável armado, com e sem o reforço de fibras de aço, submetidas às solicitações normais e tangenciais, e compará-las com o comportamento de vigas de concreto armado convencional. Para isso, foram confeccionadas vigas de concreto armado de dimensões (12,5 x 23,5 x 132) cm, as quais foram ensaiadas por flexão a quatro pontos, aos 28 dias de idade. Para comparação dos resultados, foram produzidos concretos convencionais de diferentes composições, com e sem a adição das fibras de aço. Os resultados dos ensaios no estado fresco mostraram que foi possível a obtenção de concreto com propriedades auto-adensáveis, mesmo com adição de fibras de aço, a partir de uma dosagem de CAA já existente. A adição das fibras de aço ao CAA promoveu sensível ganho na capacidade resistente da viga, com menores flechas, menores deformações das armaduras, longitudinal e transversal, e melhorado controle da fissuração, em comparação às demais vigas produzidas com concretos adensados por vibração, com e sem fibras de aço.

Vários estudos têm avaliado os efeitos do ultra-som e da radiação laser de baixa intensidade separadamente no reparo ósseo. No entanto, são escassas as comparações entre estas duas modalidades terapêuticas. Este estudo teve por objetivo avaliar e comparar, através de análise histomorfométrica e ensaio mecânico de flexão em três pontos, as conseqüências que estes agentes físicos podem trazer ao reparo do tecido ósseo em osteotomias transversais experimentais em tíbias de ratos. Foram utilizados 48 ratos com fratura cirúrgica unilateral parcial do terço superior de tíbia. Os animais foram divididos em três grupos de 16 animais. Em um grupo, o membro fraturado foi tratado com ultra-som pulsado de baixa intensidade (freqüência de 1,5 MHz, ciclo de trabalho 1:4, intensidade SATA 30 mW/centímetro quadrado) em sessões de 20 minutos, 5 vezes por semana, em 12 dias de tratamento. Em um segundo grupo, o membro fraturado foi tratado com laser As-Ga-Al (112,5 J/centímetro quadrado, 780 nm, 30 mW) em sessões de 2,5 minutos, 5 vezes por semana, em 12 dias de tratamento. O terceiro grupo serviu de controle, sendo submetido à mesma cirurgia na tíbia direita mas não recebeu qualquer tratamento. No ensaio mecânico, a carga no limite máximo suportada pelo grupo tratado com laser foi significantemente maior (p < 0,05) que os grupos tratado com ultra-som e controle. Na análise histomorfométrica, o grupo tratado com laser apresentou significância estatística quanto ao número e superfície de osteoblastos e volume e superfície de osteóide e o grupo ultra-som obteve significância para as superfícies de reabsorção e de osteoclastos. Pode-se concluir que o ultra-som acelerou o reparo ósseo (em relação ao grupo controle) por viabilizar mais rapidamente a fase de reabsorção, enquanto que a terapia laser foi capaz de acelerar ainda mais este processo por já promover predomínio de formação óssea no décimo nono dia pós-cirúrgico no modelo experimental utilizado neste estudo / Many studies have assessed the effects of ultra-sound and low intensity laser therapy separatedly in bone repair. However, the comparison between these two therapeutic modalities is rare. The objective of this study was to verify and compare, through histomorphometrical analysis and a three-point bending test, the consequences of these physical agents on bone healing in animals. 48 male Wistar rats were used with tibial bone partial osteotomy, divided into 3 groups of 16. In one group, rats had their fractured limb treated with GaAIAs laser (780 nm, 30 mW, 112,5 J/square contimeter) in 12 five times-a-week sections. In another group, rats were treated with low intensity pulsed ultra-sound (1,5 MHz, 30 mW/square centimeter) in 12 five times-a-week sections too. In a third group, animals were taken as control, being submitted to the same osteotomy but receiving no treatment. After 19 days the tibias were extracted and half of them were submitted to a three-point bending test and the other half to histomorphometric analysis. During the bending test, the maximum load at failure of the tibia in the laser group was significantly higher (p<0.05). Histomorphometry showed statistical significance in osteoblasts number and surface and osteoid volume and surface for the laser group, and eroded and osteoclasts surfaces for the ultra-sound group. Ultra-sound was able to enhance bone healing (compared to control group) by speeding up the reabsorption phase, while low intensity laser therapy could accelerate this process even more by promoting mostly new bone formation 19 days after osteotomy in this experimental model

Um grande número de rochas de granulação grosseira tem valor agregado muito alto quando usadas como materiais de construção, as chamadas rochas exóticas. No entanto, existem problemas com a utilização desses materiais dado a sua fragilidade, que está relacionada com a sua textura muito heterogênea. No Brasil é empregado empiricamente um reforço (compósito) que utiliza resina epóxi e fibra de vidro para melhorar o desempenho mecânico de tais rochas quando empregadas como materiais de construção. Os objetivos da presente pesquisa foram estudar o reforço tradicional brasileiro (telagem) para determinar sua eficiência e, ao mesmo tempo, propor outras soluções de reforço alternativas e mais eficientes, e avaliá-las através da caracterização mecânica experimental. Foi proposto um critério denominado Declive Global para avaliar as tensões de serviço dos materiais pegmatíticos estudados, quando os reforços propostos foram aplicados. Para validar esse critério foi utilizado um sistema de correlação digital de imagem (CDI) para observar e medir o comportamento de deformação e fratura durante a realização de testes de flexão em 4 pontos. Tanto o critério proposto como a CDI mostraram que a propagação de fissuras ocorre muito antes do material atingir a carga máxima. O reforço alternativo proposto, que emprega resina epóxi e uma fibra de vidro 600 g/m² apresentou o melhor desempenho mecânico, elevando a carga de ruptura até 6x em comparação com as amostras onde nenhum reforço foi aplicado. Os resultados demonstrados pelos reforços propostos são promissores e aumentam a possibilidade de aplicar rochas exóticas frágeis como materiais de construção, além do critério proposto fornecer uma ferramenta importante para a compreensão mecânica prévia de produtos de rocha que utilizam reforços compósitos. / A great number of coarse-grained natural stones have very high added-value when used as building materials, the so called exotic stones. However, problems using these materials arise from its brittleness behavior, which are related to its very heterogeneous texture. Glass fiber-reinforced epoxy composite (GFRC) is being used to improve mechanical performance of such stones when employed as building materials. The objectives of this present investigation it were studying the Brazilian traditional reinforcement to determinate its efficiency and, at the same time, a number of alternative solutions were proposed and evaluated through experimental mechanical characterization. It was proposed a slope-based criterion to evaluate the useful service loads of pegmatitic materials when glass fiber-reinforcement is applied. To validate the proposed criterion, a digital image correlation (DIC) system was employed to observe and measure strain and fracture behavior during the realization of 4-point bending tests. Both proposed criterion and DIC show that crack propagation occurs long before the material reaches maximum load. GFRC acts as a crack inhibitor, raising the breaking load up to 6x in comparison with the specimens where no reinforcement was applied. The results from this study enhance the capability to apply such materials as building materials and provide an important tool to perform prior mechanical understanding of stone products using GFRC.

Os materiais cerâmicos são utilizados pelo homem há milhares de anos e podem ser considerados os primeiros materiais utilizados na fabricação de ferramentas. Argamassas são materiais cerâmicos formados pela mistura de cimento, areia e água, são fluidos nas primeiras horas e endurecem com o tempo, ganhando resistência mecânica, já os refratários são materiais constituídos basicamente por duas partes, uma de granulometria fina denominada matriz e a outra de granulometria grosseira, chamada agregado, trabalham em altas temperaturas e muitas vezes sofrem choques térmicos. Devido a sua fragilidade, são susceptíveis a fratura catastrófica, por isso o conhecimento de seu comportamento mecânico é tão importante. Uma importante propriedade dos materiais cerâmicos é a energia de fratura e o método mais conhecido para a sua determinação é o da barra entalhada flexionada em três ou quatro pontos, porém o grande problema deste método é a relação de tamanho de agregado/área de fratura, pois como a barra apresenta, em geral, pequenas dimensões, o material pode apresentar um agregado de dimensões próximas à dimensão da área de fraturada e o resultado final pode ser fortemente afetado. Então, em 1986, Tschegg patenteou o método da cunha (wedge splitting test) que minimiza este efeito, devido à utilização de amostras com grande área de fratura. Desde então, este método vem sendo utilizado com freqüência por diversos pesquisadores no mundo. Porém não há estudos publicados que definam a posição ideal dos roletes do dispositivo de teste, levando ao uso de diferentes posições, sem que se saiba como isso pode influenciar o ensaio. Além de não existir uma definição de, a partir de que tamanho de agregado o método da barra entalhada passa a ser desaconselhável sendo necessário o uso do método da cunha. Neste trabalho analisou-se a influência da posição dos roletes e do tamanho de agregados nas medidas de energia de fratura e na carga máxima atingida no ensaio. / The ceramic materials are used by humans for thousands of years and can be considerate the first materials used in the manufacture of tools. Mortar are ceramic materials made by the mixture of cement, sand and water, it is fluid in the first hours and stiffen over time, gaining mechanical strength, the refractories in turn are made basically of two phases, one of fine granulometry called matrix and another of coarse called aggregate. It works over high temperature and many times suffer thermal shock. Due to its fragility, it is susceptible to catastrophic fracture; therefore the knowledge of its mechanical behavior is so important. One of the mainly properties of ceramic materials is the fracture energy and o most knew method for its determination is of three-point bending test on notched beams, but the biggest problem of this method is the relation between aggregate size and fracture area, because as the beam has small dimensions the aggregate can have a dimension so closed of the fracture area dimension and the final result can be tightly affect. Then in 1986, Tschegg patented the wedge splitting test, which minimizes this effect, because of the use of samples with a big fracture area. Since then, this method has been used for scientists around the world. But there are no studies that define the roll position of the test device, leading to the use of different positions, without know how it can influence the test. Besides not having a definition of from what aggregate size the wedge splitting test is advisable in despite of the bending test on notched beams. In this work was analyzed the influence of the rolls positions in the wedge splitting test and of the aggregate size in the measures of fracture energy and maximum load of test.

Malgré le cumul de connaissances sur le sujet du flambage des coques minces, des questions essentielles demeurent. En effet, malgré les avancées et une meilleure compréhension de l’effet des défauts, le dimensionnement continue de recourir aux anciennes règles qui découlent d’une démarche empirique et qui s’avèrent souvent trop conservatives comme c’est le cas par exemple pour la NASA SP8007 (1968). Cette règle est utilisée notamment pour le dimensionnement du lanceur Ariane 5. L’Etage Principal Cryogénique est en effet constitué de coques cylindriques minces, qui sont soumises à une combinaison de chargements et donc sujettes au déclenchement d’instabilités pouvant être catastrophiques. Il est ainsi nécessaire d’avoir une meilleure compréhension du phénomène pour pouvoir améliorer ces méthodes de dimensionnement dans le cas de coques moyennement longues (1 < L/R < 3) et minces (250 < R/t <1500). Nous employons pour cela une approche à la fois numérique et expérimentale. L’outil numérique est utilisé, via une modélisation pertinente, afin de construire une nouvelle règle de dimensionnement et d’étudier l’influence des différents paramètres (géométriques, matériau). L’aspect expérimental a pris une place prépondérante, une large campagne nous permettant de valider les résultats simulations pour différentes configurations, mais également d’avoir une bonne compréhension du phénomène. Ces deux aspects de notre recherche nous ont également permis de mieux déterminer l’interaction entre les différents chargements (pression interne, compression, flexion, cisaillement), plus ou moins comprise selon les cas. / The stability of thin cylindrical shells has been studied for decades, but despite the accumulated knowledge on the subject, important questions remain, in particular regarding the design of such structures. The effect of geometrical imperfections is now well understood, but old design recommandations resulting from purely empirical approaches, are still used. The NASA SP8007 recommendation (1968) is one them, and leads to conservative designs. This rule is used in particular for the design of the Ariane 5 launcher. Indeed, the Principal Cryogenic Stage is made of thin cylindrical shells, subjected throughout the structure’s life cycle to a combination of loadings, and hence prone to possibly disastrous structural instabilities. It is is then necessary to better understand those phenomena in order to improve the design methods for relatively long (1 < L/R < 3) and thin (250 < R/t < 1500) shells. Our work is based on both numerical and experimental approaches. Numerical tools are used, through a relevant choice of the critical imperfections, to build a new design recommendation and study the influence of different parameters (geometrical or material). Experiments took an important place in our research, and the large experimental campaign allowed us to validate the numerical results for different configurations, and to better understand the physics of the problem as well. These two aspects of our study also enabled us to clarify the interaction between different loadings (internal pressure, compression, bending and transverse shear), which is today more or less understood, according to the case.

Abstract The effects of restoration and certain elements, nitrogen, sulphur, calcium and Misch metal, on the hot ductility of austenitic, high-alloyed austenitic and duplex stainless steels have been investigated by means of hot rolling, hot tensile, hot bending and stress relaxation tests. The results of these different testing methods indicated that hot rolling experiments using stepped specimens is the most effective way to investigate the relationship between the softening and cracking phenomena under hot rolling conditions. For as-cast, high-alloyed and duplex stainless steels with a low impurity level, the cracking tendency was observed to increase with increasing pass strain and temperature, being minimal for the small strain of 0.1. No cracking occurred in these steels when rolled in the wrought condition. It could be concluded that the cracking problems are only exhibited by the cast structure with the hot ductility of even partially recrystallised steel being perfectly adequate. However, the recrystallisation kinetics of the high-alloyed austenitic stainless steels, determined by stress relaxation and double-pass rolling tests, were found to be so slow that only partial softening can be expected to occur between roughing passes under normal rolling conditions. In the duplex steel, the restoration is fairly fast so that complete softening can occur within typical interpass times in hot rolling, while certain changes in the phase structure take place as well. Sulphur was found to be an extremely harmful element in duplex stainless steel with regard to their hot ductility so that severe cracking can take place with sulphur content above 30 ppm. However, the effect of sulphur can be eliminated by reducing its content and by calcium or Misch metal treatments that significantly increase the number and decrease the average size of the inclusions. It seems that the desulphurisation capacity of an element is the most important property for assessing its usefulness in reducing the detrimental influence of sulphur. The hot ductility of type 316L stainless steel determined by tensile tests was found to be better for nitrogen content of 0.05 wt-% than 0.02%, while in double-hit tensile tests the hot ductility values were identical. The mechanism whereby nitrogen affects hot ductility remains unclear but a retarding effect on static recrystallisation was observed.

The level of residual stresses in welded components is known to have a significant influence on their failure behaviour. It is, therefore, necessary to understand the combined effect of mechanical loading and residual stresses on the ductile fracture behaviour of these structures in order to provide the accurate structural safety assessment. Recently, STYLE (Structural integrity for lifetime management-non-RPV component) performed a large scale bending test on a welded steel pipe containing a circumferential through-thickness crack (the MU2 test). The purpose of this test is to study the impact of high magnitude weld residual stresses on the initiation and growth of cracks in austenitic stainless steels. This research presents the simulation part of the STYLE project which aims to develop the finite element model of MU2 test in ABAQUS to enhance the understanding and ability to predict the combined influence of mechanical loading and residual stresses on the ductile fracture behaviour of nuclear pressure vessel steels. This research employs both fracture mechanics principles (global approach) and Rousselier damage model (local approach) to study this behaviour including crack initiation and growth. In this research, the Rousselier model was implemented into ABAQUS via the user defined subroutines for ABAQUS/Standard and ABAQUS/Explicit modules, i.e. UMAT and VUMAT. The subroutines were developed based on the integration algorithm proposed by Aravas and Zhang. The validation of these subroutines was checked by comparing the FE results obtained from the implementation of these subroutines with the analytical and other benchmark solutions. This process showed that UMAT and VUMAT provide accurate results. However, the UMAT developed in this work shows convergence problems when the elements start to fail. Hence, only VUMAT was used in the construction of the finite element model of the MU2 test. As mentioned above, the results obtained from both fracture mechanics approach and Rousselier model are compared with the experimental data to validate the accuracy of the model. The results shows that both fracture mechanics approach and the Rousselier model predict similar final crack shapes which correspond closely to the test results in south direction. The other conclusions about the influence of residual stress on ductile fracture obtained from this work are also summarized in this thesis.

This thesis provides an approach to incorporate natural composites like Flax Fiber using a resin with 30% bio-content to enhance the packaging boxes made of corrugated cardboard. The objective of introducing natural composite skins is to reduce/eliminate the compressive loading subjected to the boxes while stacking in warehouses.