Cette étude repose sur l’observation de la mise en oeuvre, sous l’égide du Centre social de l’AMA (Association Montargoise d’Animation), d’un projet participatif dans une zone urbaine sensible.Après avoir rappelé les origines de la politique de la ville en France, et décrit les différents dispositifs qui la constituent, l’auteure analyse le déroulement de ce projet, dans lequel elle a joué un rôle de conseillère méthodologique. Elle montre comment les personnes qui ont choisi d’y participer sont parvenues à former un groupe de recherche en vue de réaliser une enquête sur la réussite scolaire, et comment elles ont su tirer partie des données recueillies pour aboutir à la rédaction d’un livret de 82 pages dans lequel elles exposent leurs conclusions.L’auteure montre enfin que la mise à distance de la réalité sociale qu’implique une démarche d’enquête a permis à ces personnes de surmonter les effets de la stigmatisation sociale dont elles se sentent les victimes pour assumer pleinement leur statut de citoyen.Loin de résulter de la transmission d’un savoir, ce changement d’attitude a été la conséquence du nouveau rôle qu’elles ont ainsi été amenées à jouer. En ce sens, une telle expérience relève de l’éducation populaire, c’est-à-dire d’un modèle d’éducation dans lequel l’enseignant accepte de partir, non pas de son propre savoir, mais de celui des « apprenants ». / This study is based on the observation of a citizen project that was implemented in an underprivileged area of Montargis, under the aegis of a « Social center » called AMA (Association Montargoise d’Animation).First, the author traces the origins of French urban policy, and describes its various administrative and operative levels. Then, she relates how some of the underprivileged citizens of this area joined the particular AMA project she has studied and in which she acted as a methodological consultant. She goes on describing how, together, they decided to conduct a survey with the aim of identifying factors which determine successful results at school, and how they wrote and published an 82 pages booklet in which they develop their findings. She makes it clear that she just recommended some research methods, without directly interfering in the survey itself.Finally, she shows that through the research they themselves conducted, the people involved in the project learned to take a step back from immediate social reality. This allowed them to overcome the effects of social stigmatization and to fully assume their citizen status. Far from submitting to transmitted knowledge, that change of attitude is an outcome of the new part they were induced to play in society. In that sense, such an experiment becomes an experience which belongs in the domain of people’s education (éducation populaire), that is to say a bottom-up education process in which teaching relies on learners’ knowledge instead of relying exclusively on teachers’ knowledge.

L’approche « bottum-up » via l’auto-assemblage moléculaire est considéré comme une voie prometteuse pour contrôler la fabrication de nouveaux matériaux et leur intégration dans des dispositifs hybrides présentant de propriétés nouvelles. Dans ce travail, nous avons synthétisé plusieurs hybrides à base de molécules organiques (fullerène, porphyrines, phtalocyanine), d’oligonucléotides ou de nanotubes de carbone.Dans un premier temps, nous nous sommes intéressés à la synthèse d’une nouvelle famille de produits constituée d’une unité C60 lié à deux chromophores positionnés face à face et permettant la formation de complexes hôte-invités. Nous avons montré que ces composés s’assemblent pour donner des structures supramoléculaires en solution et sur surface. Les interactions électroniques et la compléxation entre le fullerène et les deux chromophores (porphyrines et phtalocyanines) ont été étudiées par spectroscopie optique et RMN ainsi que par voltammétrie cyclique.Parmi les outils de l’approche « bottom-up », l’ADN a montré son extraordinaire potentiel pour la fabrication d’assemblages bio-dirigés. En effet, la synthèse de matériaux hybrides à base d’ADN permet un contrôle précis (théoriquement à l’échelle d’une base, ~3,4Å) du positionnement des groupements fonctionnels dans un matériau. Dans le but de former des réseaux bi- et tridimensionnels à base d’ADN permettant le positionnement de nano-objets, nous avons synthétisé des hybrides à base d’oligonucléotides et de porphyrines (molécule 2D) ou d’adamantane (molécule 3D). Des édifices supramoléculaires simples ont été réalisés et le travail se poursuit en vue de la réalisation de réseaux fonctionnels.Enfin, dans une dernière partie, nous nous sommes intéressés à la fonctionnalisation des nanotubes de carbone monoparoi (SWNT) avec des chromophores de type porphyrines et phtalocyanines. Alors que les porphyrines présentent une absorption intense presque exclusivement dans le bleu, les phtalocyanines absorbent principalement dans le rouge. Combiner ces deux chromophores à la surface des nanotubes de carbone présente donc un intérêt particulier pour la collecte de lumière car les deux composés absorbent des régions complémentaires du spectre visible. Ce travail ouvre la voie vers l'étude des propriétés optoélectroniques des hybrides à base de nanotubes et en particulier leur utilisation pour la conversion d’énergie lumineuse en énergie électrique (application photovoltaïque). / An Approach "bottum-up" via molecular self-assembly is considered as a promising way to control the manufacture of new materials and their integration into hybrid devices with novel properties. In this work, we have synthesized several hybrids based on organic molecules (fullerene, porphyrin, phthalocyanine), oligonucleotides or carbon nanotubes.At first, we were interested in the synthesis of a new family of products consisting of a unit C60 linked to two chromophores positioned face to face and allowing the formation of host-guest complexes. We have shown that these compounds are combined to give supramolecular structures in solution and on the surface. Electronic interactions and complexation between fullerene and the two chromophores (porphyrins and phthalocyanines) were studied by NMR and optical spectroscopy as well as cyclic voltammetry.Among the tools of the "bottom-up", DNA showed its tremendous potential for the production of bio-directed assembly. Indeed, the synthesis of hybrid materials based DNA allows precise control (theoretically on the scale of a base, ~ 3.4 Å) of the positioning of the functional groups in a material. In order to form networks and bi-dimensional DNA-based for positioning nano-objects, we have synthesized hybrid oligonucleotide-based and porphyrin molecule (2D) or adamantane molecule (3D). Supramolecular structures have been made and this work is ongoing to achieve functional networks.Finally, in a last part, we are interested in the functionalization of single-walled carbon nanotubes (SWNTs) with chromophores like porphyrins and phthalocyanines. While porphyrins exhibit almost exclusively an intense absorption in the blue (around 420-440 nm), phtalocyanines absorb mainly in the red spectral region. Taken together these two chromophores have interesting light harvesting, photophysical and redox properties; the two components will participate independently to increase the overall absorption in the visible range of the solar spectrum. This work opens the route to study the optoelectronic properties of hybrid nanotube and in particular their use for the conversion of light energy into electrical energy (photovoltaic application).

The visual sense has outstanding importance for humans’ interaction with the environment and visual attention is the key mechanism that bundles our limited cognitive resources in order to enhance the perceptual processing of the most relevant environmental features at a certain point in time. Eye-Tracking technology enables us to accurately observe peoples’ eye movement behavior i.e. overt attention. In the last decade, overt attention on real-world scenes gained increasing popularity in vision research. The higher ecological validity of such scenes in combination with a free-viewing task allows us to investigate human viewing behavior under natural conditions. In this context, the majority of previous studies focused on the impact of basal image properties, such as color and luminance differences, to quantify the extent to which our fixation behavior is guided by these so-called low-level image properties. However, in most experimental studies complex images are observed only one time, whereas we are continually confronted with repeated visual impressions in everyday life. Therefore, I introduce a repeated-presentation-design that allows scrutinizing the impact of low-level image properties and the power of scene types over time. Besides these low-level factors, I also address inter-individual differences in motivation as well as emotional components as so-called high-level factors in overt attention. Previous research on visual attention has widely neglected these factors, especially in the context of real-world images. On the basis of novel study designs and by means of various analysis techniques, I show how several low- and high-level factors influence overt attention on complex scenes, how they interact, and how eye movement parameters are interrelated. In addition to that, I provide a comprehensive review of the previous literature on emotions’ and personality traits’ impacts on visual attention. On the basis of the inconsistent understanding of core concepts in the literature, I describe how behaviorally oriented studies investigate these high-level factors in visual attention, how the interplay between emotion and attention is conceptualized from a neuroscientific perspective, and I derive several conceptual and practical recommendations for future research. Finally, I outline some new ideas and venues for future research in the general discussion of the present work, for example how eye-tracking might overcome some fundamental problems of classical testing in psychological diagnostics, or how the view of embodied cognition can help us to get a better understanding of high- and low-level factors in visual attention.