Esse trabalho discute a viabilidade de utilização de impressoras domésticas a jato de tinta líquida por sistema termoelétrico para a inserção de microcápsulas em papel. O procedimento experimental, em etapas, consistiu inicialmente da desmontagem do cartucho termoelétrico e da análise por microscopia óptica e estéreo microscopia. A síntese das microcápsulas poliméricas e cerâmicas ocorreu via polimerização por miniemulsão e sol-gel, respectivamente. A caracterização das partículas foi realizada via microscopia eletrônica de varredura - MEV, espectroscopia por energia dispersiva - EDS, granulometria e espectroscopia de infravermelho por transformada de Fourier - FT-IR. As microcápsulas misturadas em tinta, água deionizada e etanol 99,8% através de agitador magnético e sonda ultrassônica foram analisadas por MEV. As tintas puras e as diferentes misturas, com quantidades específicas de tinta e cápsulas, foram submetidas a testes de densidade relativa, viscosidade, granulometria e FT-IR. Já a caracterização dos papéis deu-se por MEV e EDS. Finalizando o procedimento, a impressão da tinta contendo microcápsulas foi avaliada por MEV e FT-IR. Os resultados demonstraram que as dimensões das partículas estão diretamente relacionadas com o desempenho da impressão. O uso de partículas menores, com tamanho médio de 250 nm, mostrou-se eficiente, posto que a dimensão dos pigmentos em tintas a jato está entre 100 e 200 nm e os orifícios no cabeçote dos cartuchos termoelétricos testados possuem aproximadamente 13,5 μm. Dessa forma, o design de produto pode se beneficiar da aplicação de microcápsulas, com dimensões controladas, pelo processo de impressão termoelétrico em materiais fibrosos, porosos ou ocos. / This research discusses the use viability of domestic inkjet liquid printers for thermoelectric system to insert microcapsules in paper. The experimental procedure, in stages, consisted firstly at the disassembly of the thermoelectric cartridge and analysis by optical and stereo microscopy. The polymeric and ceramic microcapsules synthesis occurred by miniemulsion polymerization and sol-gel reaction, respectively. The characterization of the particles was performed by scanning electron microscopy - SEM, energy dispersive system - EDS, granulometry and Fourier transform infrared spectroscopy - FT-IR. The microcapsules blended into paint, deionized water and 99.8% ethanol by ultrasonic probe and magnetic stirrer were analyzed by SEM. The pure inks and the different mixtures with specific amounts of ink and capsules were subjected to relative density, viscosity, granulometry and FT-IR tests. Concomitant, the characterization of the papers was performed by SEM and EDS. As a last stage of the experimental procedure, the impression with ink containing microcapsules was assessed by SEM and FT-IR. The results showed that the particle sizes are directly related to the printing performance. The use of smaller particles with an average size of 250 nm was efficient, since the size of the pigments in ink-jet is between 100 and 200 nm and the holes in the head of the thermoelectric cartridges. The holes are 13.5 μm. Therefore, the product design can take advantage of the application of microcapsules, with controlled dimensions, by thermoelectric printing process, in fibrous, porous or hollow materials.

Master of Science / Food Science Institute / J. Scott Smith / Food irradiation is one of the most important food processing methods utilized to reduce microbial load and extend shelf life. In 1995 the World Health Organization (WHO) declared irradiated foods to be safe from a nutritional and toxicological point of view. Various methods have been applied to detect irradiated foods. Detection of 2-alkylcyclobutanones has been found to be a useful method in identifying irradiated foods. The solvent extraction method utilizes a Soxhlet apparatus for lipid extraction followed by clean up with Florisil. However, this method is very time consuming. The other methods available to detect 2-alkylcyclobutanone include supercritical fluid extraction (SFE), and accelerated solvent extraction method using a Dionex ASE 200 instrument. The SFE is a fast method to detected 2-alkylcyclobutanone. All the above mentioned methods involve costly equipment. The aim of this study was to eliminate the requirement of costly extraction equipment for lipid extraction before clean up or direct isolation of 2-alkylcyclobutanone as in case of SFE instrument using Florisil cartridges. In this study, the manual solvent extraction method was applied to isolate alkylcylcobutanone followed by clean up with 2 g silica cartridge. The clean up extract was injected to gas chromatography-flame ionization detector (GC-FID) for detection of 2-dodecylcyclobutanone (2-DCB). Gas chromatography-mass spectrometry (GC-MS) was used to confirm that the compound detected was 2-dodecylcyclobutanone. The ions m/z 98 and 112 were selected for 2-DCB for monitoring in selected ion monitoring (SIM) mode of GC-MS. The results showed that this method was able to detect 2-DCB from irradiated ground beef. The manual method does not require costly equipment such as supercritical fluid extractor, Dionex, or Soxlet apparatus for extraction process.

Esse trabalho discute a viabilidade de utilização de impressoras domésticas a jato de tinta líquida por sistema termoelétrico para a inserção de microcápsulas em papel. O procedimento experimental, em etapas, consistiu inicialmente da desmontagem do cartucho termoelétrico e da análise por microscopia óptica e estéreo microscopia. A síntese das microcápsulas poliméricas e cerâmicas ocorreu via polimerização por miniemulsão e sol-gel, respectivamente. A caracterização das partículas foi realizada via microscopia eletrônica de varredura - MEV, espectroscopia por energia dispersiva - EDS, granulometria e espectroscopia de infravermelho por transformada de Fourier - FT-IR. As microcápsulas misturadas em tinta, água deionizada e etanol 99,8% através de agitador magnético e sonda ultrassônica foram analisadas por MEV. As tintas puras e as diferentes misturas, com quantidades específicas de tinta e cápsulas, foram submetidas a testes de densidade relativa, viscosidade, granulometria e FT-IR. Já a caracterização dos papéis deu-se por MEV e EDS. Finalizando o procedimento, a impressão da tinta contendo microcápsulas foi avaliada por MEV e FT-IR. Os resultados demonstraram que as dimensões das partículas estão diretamente relacionadas com o desempenho da impressão. O uso de partículas menores, com tamanho médio de 250 nm, mostrou-se eficiente, posto que a dimensão dos pigmentos em tintas a jato está entre 100 e 200 nm e os orifícios no cabeçote dos cartuchos termoelétricos testados possuem aproximadamente 13,5 μm. Dessa forma, o design de produto pode se beneficiar da aplicação de microcápsulas, com dimensões controladas, pelo processo de impressão termoelétrico em materiais fibrosos, porosos ou ocos. / This research discusses the use viability of domestic inkjet liquid printers for thermoelectric system to insert microcapsules in paper. The experimental procedure, in stages, consisted firstly at the disassembly of the thermoelectric cartridge and analysis by optical and stereo microscopy. The polymeric and ceramic microcapsules synthesis occurred by miniemulsion polymerization and sol-gel reaction, respectively. The characterization of the particles was performed by scanning electron microscopy - SEM, energy dispersive system - EDS, granulometry and Fourier transform infrared spectroscopy - FT-IR. The microcapsules blended into paint, deionized water and 99.8% ethanol by ultrasonic probe and magnetic stirrer were analyzed by SEM. The pure inks and the different mixtures with specific amounts of ink and capsules were subjected to relative density, viscosity, granulometry and FT-IR tests. Concomitant, the characterization of the papers was performed by SEM and EDS. As a last stage of the experimental procedure, the impression with ink containing microcapsules was assessed by SEM and FT-IR. The results showed that the particle sizes are directly related to the printing performance. The use of smaller particles with an average size of 250 nm was efficient, since the size of the pigments in ink-jet is between 100 and 200 nm and the holes in the head of the thermoelectric cartridges. The holes are 13.5 μm. Therefore, the product design can take advantage of the application of microcapsules, with controlled dimensions, by thermoelectric printing process, in fibrous, porous or hollow materials.

The purpose of this work is to look into the fundamental issues regarding spring design and develop a new, easy to use software program that would allow for optimal, flexible spring designs. Most commercial programs that address this function are basic and do not allow the designer much control over the variables hindering design. This is so because most programs start from the premise that the spring is a general purpose part of the system or that other design parameters can be altered to accommodate the chosen spring. In cases where this is not so, such as in hydraulic cartridge valves, where the geometric constraints are severe, spring design may be a cumbersome process. This is particularly true when fatigue life is taken into account. The solution chosen here is to tailor the software application to these particular design constraints, incorporating some ideas about spring optimization. In addition to this, a concerted effort was made to make the subject more accessible to the engineers using the program by automating the more technical aspects of the process allowing the designers to make intelligent decisions based on how the variables would affect design. To this end currently existing software was evaluated to determine where it was lacking and a new program was written and painstakingly tested. Finally, it was used to correct flaws identified in existing springs.

To ensure that manufactured cartridges is safe to use, a tensile test is performed. The frictional force between the bullet and the case is required according to Normas standard to be between 15 – 75 Kg. Variations of the frictional force, with values outside of the standard had been noted by Norma Precision without understanding the cause. The aim of this report was to investigate and evaluate possible causes of the variations measured by tensile tests, difference between extreme values and to find a solution to what can be done to prevent the variations. Two different cases and three different bullets were used by request from Norma in the scope of this report. Different combinations of the bullets and cases was tested by alternating process parameter, surfaces and loading procedures. The loaded cartridges went through tensile tests to investigate differences. Bullets and cases with extreme values from the measured frictional force were chosen for further investigation in SEM and profilometer. To be able to draw further conclusions four different simulation models was created in Abaqus and different parameters was calculated. The dimensions and shape of the bullet resulted as the cause of changes of the tensile test curves. The smallest frictional force was found to differ from the largest by a change in wear mechanism from mainly abrasive ploughing to cutting and adhesion that caused transfer of material from the bullet to the case. The change in wear mechanism was found to be caused by an increased bullet diameter. The loading procedure was found to cause variations in plastic deformation on the neck of the case and damage the bottom of the bullet. The loading procedure was assumed to have the largest impact on the variations in frictional force. To minimize the variations the central axis of the case was suggested to be in line with the central axis of the bullet.

GSR ou Gunshot Residues são partículas microscópicas de resíduos provenientes da descarga de uma arma de fogo e que, em geral, ficam depositadas pelo corpo do atirador e aos arredores da cena do crime. Este trabalho tem como objetivo empregar as técnicas de PIXE (Particle-Induced X-ray Emission) convencional e -PIXE na análise da munição e GSR gerados por disparo de arma de fogo, utilizando munição de fabricação brasileira. O estudo foi dividido em duas etapas, sendo que na primeira etapa foi utilizada a técnica PIXE no estudo da composição elementar de todos os componentes (estojo, espoleta, pólvora, projétil e camisa) de dois cartuchos distintos virgens, ou seja, antes do disparo com a arma de fogo. Na segunda etapa foram efetuados os ensaios de disparo com arma de fogo, utilizando os mesmos tipos de cartuchos analisados na primeira etapa. As partículas foram coletadas e analisadas por μ-PIXE. As amostras foram irradiadas com feixes de prótons, empregando diferentes parâmetros (energia e corrente), o que depende das amostras em estudo e da técnica utilizada. Para tal fim, foi utilizado o acelerador Tandetron (modelo TN-4130-HC) disponível no Laboratório de Implantação Iônica (IF-UFRGS). Dois diferentes tipos de munição foram analisadas: CHOG e EXPO +P+. Os elementos presentes nas amostras de espoleta de ambos os tipos de munição são o alumínio, antimônio, bário e chumbo, e em menores quantidades cobre, zinco e ferro (invólucro), além de níquel no caso da munição EXPO +P+. Ambos os estojos são constituídos por cobre e zinco, apresentando adicionalmente uma grande quantidade de níquel e um pouco de ferro na munição EXPO +P+. No projétil da munição CHOG os elementos predominantes são chumbo e antimônio, além de apresentar alumínio e ferro em menores quantidades. Na munição EXPO +P+ o projétil também é constituído por chumbo, antimônio e alumínio, mas o ferro é substituído pelo cobre. As amostras de pólvora de ambos os tipos são compostas por alumínio, silício, enxofre, potássio, cálcio, titânio, cromo, níquel, ferro, cobre e zinco, e essas quantidades foram diferentes para cada tipo de munição. A pólvora CHOG apresentou bário e chumbo adicionalmente. Por último, a camisa do projétil da munição EXPO +P+ apresentou cobre, zinco, níquel, chumbo e ferro. Estes resultados são em maioria condizentes com as especificações do fabricante, a Companhia Brasileira de Cartuchos – CBC. Para a coleta das amostras de GSR, foram efetuados disparos em um anteparo de papel, onde foi fixada uma fita microporosa da marca Missner. Neste estudo, foram utilizados os dois tipos de munição analisados por PIXE. Nos dois tipos de partículas coletadas, foi possível correlacionar a presença de Ba, Pb e Sb na mesma partícula, sendo inequivocamente caracterizadas como partículas de GSR. No entanto, os resíduos apresentaram diferentes características e particularidades. Em partículas do tipo CHOG as principais características observadas foram a diferença de tamanhos, homogeneidade (exceto em alguns pontos) e ausência de formato característico. Nas partículas do tipo EXPO +P+ as características se repetem, exceto no formato que, em geral, se apresentou esférico. Comparando os resultados de PIXE e μ-PIXE, observou-se que há relação entre a munição utilizada e os resíduos de disparo produzidos, mas, no entanto as quantidades dos elementos na munição antes e depois do disparo não possuem correlação, o que pode ser explicado pela distância entre o atirador e o anteparo. Os elementos bário, chumbo e antimônio precisam de altas temperaturas para vaporizar, e não alcançariam efetivamente o anteparo a uma distância de um metro, causando grande variabilidade de concentrações entre as partículas. / GSR stands for Gunshot Residues wich are microscopic particles stemming from the discharge of a firearm. These particles are deposited on the body of the shooter and on the vicinity of the crime scene. The aim of this work is to characterize two Brazilian ammunitions and their respective GSRs using PIXE (Particle-Induced X-ray Emission) and -PIXE. Initially, the components (case, primer, gunpowder, projectile and jacket) of two pristine cartridges were analyzed by PIXE technique. Then, shooting sessions were carried out with the same cartridges. In this case, the GSR were collected for -PIXE analysis. The samples were irradiated with protons with different energies and beam currents depending on the sample under study and the technique used for analysis. To that end, a Tandetron accelerator (model TN-4130-HC) from the Ion Implantation Laboratory (IF-UFRGS) was used. The elements present in the primer for both ammunitions were aluminum, antimony, barium and lead. Other trace elements like copper, zinc and iron were present as well. Nickel was also detected in EXPO +P+ samples. The cases were made of copper and zinc. For the EXPO +P+, other elements like nickel and, to a lesser degree, iron were present as well. The bullet from CHOG ammunition was mainly composed by lead and antimony with traces of iron and aluminum. On the other hand, bullets from EXPO +P+ were characterized by lead, antimony and aluminum while iron is replaced by copper. The gunpowder from both ammunitions were characterized by aluminum, silicon, sulfur, potassium, calcium, titanium, chromium, nickel, iron, copper and zinc, and their amounts were different for each type of ammunition. In addition, the CHOG type gunpowder presented barium and lead. Finally, the jacket of the EXPO +P+ bullet has considerable amounts of copper, zinc, nickel, lead and iron. These results are compatible with the datasheet provided by the Companhia Brasileira de Cartuchos. For the study of the GSR, shootings were performed using the afore mentioned ammunitions on a paper screen with Missner tape for the collection of the ejected particles. Elements like Ba, Pb and Sb were found in the particles, thus characterizing the GSR. The CHOG particles were characterized by a large distribution of sizes and distinct shapes. On the other hand, EXPO +P+ particles were distinct due to its round shape. Comparing the results of PIXE and μ-PIXE, it was observed that there is a correlation between ammunition used and the GSR produced, but nevertheless the amounts of the elements before and after the ammunition shot does not have correlation, which can be explained the distance between the shooter and the target. The elements barium, lead and antimony require high temperatures to vaporize and not effectively reach the target at a distance of one meter, causing large variability in concentrations between particles.

The aim of this diploma thesis was to describe consumers{\crq} behaviour in the market with regards to print cartridges and to recommend the most suitable products to them on the basis of the established preferences and attributes. I used a questionnaire survey and a calculation of print cartridges parameter weights using the method of multi-criteria decision making. I found from the survey that the respondents mostly own ink multifunction equipment. Among the most commonly used printer makes are Hewlett Packard, Cannon and Epson. However, the proportion of less significant makes has dropped in the last three years. The respondents mostly buy original cartridges in shops and they buy black cartridges more often than colour cartridges. The main criteria for choosing a certain cartridge are price, quality and availability. The obtained information helped me select suitable cartridges for consumers. I found that cartridges are more readily available on the market in comparison to toners. When evaluating measurable attributes (price, quality and environmental friendliness) I calculated that in most cases it pays to buy renovated cartridges, especially for the evaluated cartridge from the makes HP and Canon and for toner makes HP and Epson. Epson cartridges contain a chip which prevents their renovation which is why I would recommend the purchase of a compatible cartridge. For the Canon toner I would recommend the purchase of a compatible cartridge too. In summary of my recommendations I would advise consumers to look closely at the price, volume, quality, producer and possibility to renovate when purchasing cartridges. I would further recommend buying ink printers as it is difficult to get cartridges for laser printers. I would point out that in most cases a rule applies: the cheaper the printer the more expensive the cartridge.

GSR ou Gunshot Residues são partículas microscópicas de resíduos provenientes da descarga de uma arma de fogo e que, em geral, ficam depositadas pelo corpo do atirador e aos arredores da cena do crime. Este trabalho tem como objetivo empregar as técnicas de PIXE (Particle-Induced X-ray Emission) convencional e -PIXE na análise da munição e GSR gerados por disparo de arma de fogo, utilizando munição de fabricação brasileira. O estudo foi dividido em duas etapas, sendo que na primeira etapa foi utilizada a técnica PIXE no estudo da composição elementar de todos os componentes (estojo, espoleta, pólvora, projétil e camisa) de dois cartuchos distintos virgens, ou seja, antes do disparo com a arma de fogo. Na segunda etapa foram efetuados os ensaios de disparo com arma de fogo, utilizando os mesmos tipos de cartuchos analisados na primeira etapa. As partículas foram coletadas e analisadas por μ-PIXE. As amostras foram irradiadas com feixes de prótons, empregando diferentes parâmetros (energia e corrente), o que depende das amostras em estudo e da técnica utilizada. Para tal fim, foi utilizado o acelerador Tandetron (modelo TN-4130-HC) disponível no Laboratório de Implantação Iônica (IF-UFRGS). Dois diferentes tipos de munição foram analisadas: CHOG e EXPO +P+. Os elementos presentes nas amostras de espoleta de ambos os tipos de munição são o alumínio, antimônio, bário e chumbo, e em menores quantidades cobre, zinco e ferro (invólucro), além de níquel no caso da munição EXPO +P+. Ambos os estojos são constituídos por cobre e zinco, apresentando adicionalmente uma grande quantidade de níquel e um pouco de ferro na munição EXPO +P+. No projétil da munição CHOG os elementos predominantes são chumbo e antimônio, além de apresentar alumínio e ferro em menores quantidades. Na munição EXPO +P+ o projétil também é constituído por chumbo, antimônio e alumínio, mas o ferro é substituído pelo cobre. As amostras de pólvora de ambos os tipos são compostas por alumínio, silício, enxofre, potássio, cálcio, titânio, cromo, níquel, ferro, cobre e zinco, e essas quantidades foram diferentes para cada tipo de munição. A pólvora CHOG apresentou bário e chumbo adicionalmente. Por último, a camisa do projétil da munição EXPO +P+ apresentou cobre, zinco, níquel, chumbo e ferro. Estes resultados são em maioria condizentes com as especificações do fabricante, a Companhia Brasileira de Cartuchos – CBC. Para a coleta das amostras de GSR, foram efetuados disparos em um anteparo de papel, onde foi fixada uma fita microporosa da marca Missner. Neste estudo, foram utilizados os dois tipos de munição analisados por PIXE. Nos dois tipos de partículas coletadas, foi possível correlacionar a presença de Ba, Pb e Sb na mesma partícula, sendo inequivocamente caracterizadas como partículas de GSR. No entanto, os resíduos apresentaram diferentes características e particularidades. Em partículas do tipo CHOG as principais características observadas foram a diferença de tamanhos, homogeneidade (exceto em alguns pontos) e ausência de formato característico. Nas partículas do tipo EXPO +P+ as características se repetem, exceto no formato que, em geral, se apresentou esférico. Comparando os resultados de PIXE e μ-PIXE, observou-se que há relação entre a munição utilizada e os resíduos de disparo produzidos, mas, no entanto as quantidades dos elementos na munição antes e depois do disparo não possuem correlação, o que pode ser explicado pela distância entre o atirador e o anteparo. Os elementos bário, chumbo e antimônio precisam de altas temperaturas para vaporizar, e não alcançariam efetivamente o anteparo a uma distância de um metro, causando grande variabilidade de concentrações entre as partículas. / GSR stands for Gunshot Residues wich are microscopic particles stemming from the discharge of a firearm. These particles are deposited on the body of the shooter and on the vicinity of the crime scene. The aim of this work is to characterize two Brazilian ammunitions and their respective GSRs using PIXE (Particle-Induced X-ray Emission) and -PIXE. Initially, the components (case, primer, gunpowder, projectile and jacket) of two pristine cartridges were analyzed by PIXE technique. Then, shooting sessions were carried out with the same cartridges. In this case, the GSR were collected for -PIXE analysis. The samples were irradiated with protons with different energies and beam currents depending on the sample under study and the technique used for analysis. To that end, a Tandetron accelerator (model TN-4130-HC) from the Ion Implantation Laboratory (IF-UFRGS) was used. The elements present in the primer for both ammunitions were aluminum, antimony, barium and lead. Other trace elements like copper, zinc and iron were present as well. Nickel was also detected in EXPO +P+ samples. The cases were made of copper and zinc. For the EXPO +P+, other elements like nickel and, to a lesser degree, iron were present as well. The bullet from CHOG ammunition was mainly composed by lead and antimony with traces of iron and aluminum. On the other hand, bullets from EXPO +P+ were characterized by lead, antimony and aluminum while iron is replaced by copper. The gunpowder from both ammunitions were characterized by aluminum, silicon, sulfur, potassium, calcium, titanium, chromium, nickel, iron, copper and zinc, and their amounts were different for each type of ammunition. In addition, the CHOG type gunpowder presented barium and lead. Finally, the jacket of the EXPO +P+ bullet has considerable amounts of copper, zinc, nickel, lead and iron. These results are compatible with the datasheet provided by the Companhia Brasileira de Cartuchos. For the study of the GSR, shootings were performed using the afore mentioned ammunitions on a paper screen with Missner tape for the collection of the ejected particles. Elements like Ba, Pb and Sb were found in the particles, thus characterizing the GSR. The CHOG particles were characterized by a large distribution of sizes and distinct shapes. On the other hand, EXPO +P+ particles were distinct due to its round shape. Comparing the results of PIXE and μ-PIXE, it was observed that there is a correlation between ammunition used and the GSR produced, but nevertheless the amounts of the elements before and after the ammunition shot does not have correlation, which can be explained the distance between the shooter and the target. The elements barium, lead and antimony require high temperatures to vaporize and not effectively reach the target at a distance of one meter, causing large variability in concentrations between particles.

GSR ou Gunshot Residues são partículas microscópicas de resíduos provenientes da descarga de uma arma de fogo e que, em geral, ficam depositadas pelo corpo do atirador e aos arredores da cena do crime. Este trabalho tem como objetivo empregar as técnicas de PIXE (Particle-Induced X-ray Emission) convencional e -PIXE na análise da munição e GSR gerados por disparo de arma de fogo, utilizando munição de fabricação brasileira. O estudo foi dividido em duas etapas, sendo que na primeira etapa foi utilizada a técnica PIXE no estudo da composição elementar de todos os componentes (estojo, espoleta, pólvora, projétil e camisa) de dois cartuchos distintos virgens, ou seja, antes do disparo com a arma de fogo. Na segunda etapa foram efetuados os ensaios de disparo com arma de fogo, utilizando os mesmos tipos de cartuchos analisados na primeira etapa. As partículas foram coletadas e analisadas por μ-PIXE. As amostras foram irradiadas com feixes de prótons, empregando diferentes parâmetros (energia e corrente), o que depende das amostras em estudo e da técnica utilizada. Para tal fim, foi utilizado o acelerador Tandetron (modelo TN-4130-HC) disponível no Laboratório de Implantação Iônica (IF-UFRGS). Dois diferentes tipos de munição foram analisadas: CHOG e EXPO +P+. Os elementos presentes nas amostras de espoleta de ambos os tipos de munição são o alumínio, antimônio, bário e chumbo, e em menores quantidades cobre, zinco e ferro (invólucro), além de níquel no caso da munição EXPO +P+. Ambos os estojos são constituídos por cobre e zinco, apresentando adicionalmente uma grande quantidade de níquel e um pouco de ferro na munição EXPO +P+. No projétil da munição CHOG os elementos predominantes são chumbo e antimônio, além de apresentar alumínio e ferro em menores quantidades. Na munição EXPO +P+ o projétil também é constituído por chumbo, antimônio e alumínio, mas o ferro é substituído pelo cobre. As amostras de pólvora de ambos os tipos são compostas por alumínio, silício, enxofre, potássio, cálcio, titânio, cromo, níquel, ferro, cobre e zinco, e essas quantidades foram diferentes para cada tipo de munição. A pólvora CHOG apresentou bário e chumbo adicionalmente. Por último, a camisa do projétil da munição EXPO +P+ apresentou cobre, zinco, níquel, chumbo e ferro. Estes resultados são em maioria condizentes com as especificações do fabricante, a Companhia Brasileira de Cartuchos – CBC. Para a coleta das amostras de GSR, foram efetuados disparos em um anteparo de papel, onde foi fixada uma fita microporosa da marca Missner. Neste estudo, foram utilizados os dois tipos de munição analisados por PIXE. Nos dois tipos de partículas coletadas, foi possível correlacionar a presença de Ba, Pb e Sb na mesma partícula, sendo inequivocamente caracterizadas como partículas de GSR. No entanto, os resíduos apresentaram diferentes características e particularidades. Em partículas do tipo CHOG as principais características observadas foram a diferença de tamanhos, homogeneidade (exceto em alguns pontos) e ausência de formato característico. Nas partículas do tipo EXPO +P+ as características se repetem, exceto no formato que, em geral, se apresentou esférico. Comparando os resultados de PIXE e μ-PIXE, observou-se que há relação entre a munição utilizada e os resíduos de disparo produzidos, mas, no entanto as quantidades dos elementos na munição antes e depois do disparo não possuem correlação, o que pode ser explicado pela distância entre o atirador e o anteparo. Os elementos bário, chumbo e antimônio precisam de altas temperaturas para vaporizar, e não alcançariam efetivamente o anteparo a uma distância de um metro, causando grande variabilidade de concentrações entre as partículas. / GSR stands for Gunshot Residues wich are microscopic particles stemming from the discharge of a firearm. These particles are deposited on the body of the shooter and on the vicinity of the crime scene. The aim of this work is to characterize two Brazilian ammunitions and their respective GSRs using PIXE (Particle-Induced X-ray Emission) and -PIXE. Initially, the components (case, primer, gunpowder, projectile and jacket) of two pristine cartridges were analyzed by PIXE technique. Then, shooting sessions were carried out with the same cartridges. In this case, the GSR were collected for -PIXE analysis. The samples were irradiated with protons with different energies and beam currents depending on the sample under study and the technique used for analysis. To that end, a Tandetron accelerator (model TN-4130-HC) from the Ion Implantation Laboratory (IF-UFRGS) was used. The elements present in the primer for both ammunitions were aluminum, antimony, barium and lead. Other trace elements like copper, zinc and iron were present as well. Nickel was also detected in EXPO +P+ samples. The cases were made of copper and zinc. For the EXPO +P+, other elements like nickel and, to a lesser degree, iron were present as well. The bullet from CHOG ammunition was mainly composed by lead and antimony with traces of iron and aluminum. On the other hand, bullets from EXPO +P+ were characterized by lead, antimony and aluminum while iron is replaced by copper. The gunpowder from both ammunitions were characterized by aluminum, silicon, sulfur, potassium, calcium, titanium, chromium, nickel, iron, copper and zinc, and their amounts were different for each type of ammunition. In addition, the CHOG type gunpowder presented barium and lead. Finally, the jacket of the EXPO +P+ bullet has considerable amounts of copper, zinc, nickel, lead and iron. These results are compatible with the datasheet provided by the Companhia Brasileira de Cartuchos. For the study of the GSR, shootings were performed using the afore mentioned ammunitions on a paper screen with Missner tape for the collection of the ejected particles. Elements like Ba, Pb and Sb were found in the particles, thus characterizing the GSR. The CHOG particles were characterized by a large distribution of sizes and distinct shapes. On the other hand, EXPO +P+ particles were distinct due to its round shape. Comparing the results of PIXE and μ-PIXE, it was observed that there is a correlation between ammunition used and the GSR produced, but nevertheless the amounts of the elements before and after the ammunition shot does not have correlation, which can be explained the distance between the shooter and the target. The elements barium, lead and antimony require high temperatures to vaporize and not effectively reach the target at a distance of one meter, causing large variability in concentrations between particles.

This thesis deals with a concept and physical prototype of an intelligent, electronically programmable stamp, based on inkjet print. The stamp is basically a small inkjet printer. The stamp can print a simple custom text and is meant to replace regular office stamps. The benefit of the proposed stamp should include cost reduction and need for multiple stamps. The theoretical concept is followed by a prototype, which is an essential part of this work.