O Tiro com Arco é uma modalidade olímpica na qual os atletas exibem diversas estratégias de coordenação muscular na preparação do disparo da flecha, principalmente no período da liberação do clicker, tornando dificultosa a interpretação da coordenação de arqueiros no que tange à sua pontuação. Deste modo, algumas técnicas, como a Análise de Vetor Codificado e co-ativação/inibição recíproca, provenientes de abordagens de Controle Motor, podem ajudar-nos a desvendar quais parâmetros em comum que estes arqueiros utilizam quando atiram e sua relação com seu desempenho obtido durante o disparo sequencial de flechas. O objetivo do trabalho foi o de avaliar a coordenação muscular utilizada por arqueiros da seleção brasileira durante uma simulação qualificatória olímpica, através da técnica eletromiográfica. Participaram 11 arqueiros da seleção brasileira; idade: 25,2±4,9 anos, altura: 1,72±0,12m, peso: 68,6±11,8 kg, FITA score: 1258±43 pontos, Qualificação: 632±20 pontos, Flecha média: 8,7±0,3 pontos. A análise EMG foi dividida em 0,5s antes e 0,15s após a liberação do clicker. Foi utilizado o valor RMS deste sinal de doze músculos: no lado que traciona a corda (dominante) - FSD (Flexor Superficial dos dedos); ED (Extensor dos dedos); BBL (Bíceps Braquial); TBL (Tríceps Braquial Cabeça longa); GD (Grande Dorsal) PMC (Peitoral Maior Clavicular); TS (Trapézio Superior); SAD (Serrátil Anterior); RA (Reto Abdominal) e ML (Multífido Lombar). Lado não dominante (nD) DPnD (Deltóide Posterior); SAnD (Serrátil Anterior), no qual foram criados em 14 pares de análise (agonista-antagonista: FSD-ED; BBL-TBL; GD-PMC; TS-SAD; RA-ML; distal-proximal: FSD-BBL; FSD-TBL; ED-BBL; ED-TBL; e mistos: PMC-SAD; GD-TS; SAD-SAnD; SAnD-DPnD; GD-DPnD), para a análise dentro das técnicas de Co-ativação/Inibição Reciproca e Análise de Vetor Codificado. Nos resultados; oito pares (FSD-ED; BBL-TBL; TS-SAD; FSD-BBL; FSD-TBL; ED-TBL; SAD-SAnD; SAnD-DPnD) co-ativaram diferentemente na transição de blocos (p<0.05); e 12 (FSD-ED; BBL-TBL; GD-PMC; TS-SAD; FSD-BBL; FSD-TBL; ED-BBL; ED-TBL; PMC-SAD; SAD-SAnD; SAnD-DPnD; GD-DPnD) co-ativaram diferentemente na comparação do escore obtido (p<0.05). Em nove pares, os arqueiros, evidenciaram diferentes estratégias de inibição recíproca na transição de blocos (FSD-ED; BBL-TBL; TS-SAD; FSD-BBL; FSD-TBL; ED-BBL; ED-TBL; SAD-SAnD; SAnD-DPnD) (p<0.05); um (TS-SAD) na análise de flechas (p<0.05); e nove (FSD-ED; BBL-TBL; FSD-BBL; FSD-TBL; ED-BBL; ED-TBL; SAD-SAnD; SAnD-DPnD; GD-DPnD) na análise do escore. A análise de Vetor Codificado apresentou que, no total de flechas disparadas nove pares (FSD-ED; GD-PMC; FSD-BBL; FSD-TBL; ED-BBL; ED-TBL; PMC-SAD; SAD-SAnD; SAnD-DPnD) mudaram a moda de fase de coordenação na transição de ajustes posturais, enquanto no desempenho 11 pares (FSD-ED; BBL-TBL; GD-PMC; TS-SAD; FSD-BBL; FSD-TBL; ED-BBL; ED-TBL; PMC-SAD; SAD-SAnD; SAnD-DPnD) evidenciaram tais mudanças. As técnicas apresentadas no presente estudo revelaram parâmetros em comum associados com as sequências temporais de disparo de flechas e com os escores obtidos por arqueiros de elite, isto corrobora com a complexidade da análise do desempenho em atletas de alto rendimento, contudo também colocam a disposição técnicas que ajudam na filtragem e verificação desses parâmetros outrora divergentes / Archery is an Olympic sport in which the athletes exhibit several muscular coordination patterns in the arrow shooting, mainly in the clicker falls tempo, making difficult the interpretation of the coordination of archers in what concerns to their score. Thus, some techniques, such as Vector Coding and co-activation/reciprocal inhibition, from Motor Control approaches, can help us to discover what common patterns these archers use when firing and their relation to their obtained performance during the sequential firing of arrows. Aim: evaluate the muscular coordination used by archers of the Brazilian team during an Olympic qualifying simulation, using the electromyographic technique. Eleven archers of the Brazilian team participated; age: 25.2 ± 4.9 years, height: 1.72 ± 0.12m, weight: 68.6 ± 11.8 kg, FITA score: 1258 ± 43 points, Qualification: 632 ± 20 points, Mean arrow: 8.7 ± 0.3 points. The EMG analysis was divided in 0.5s before and 0.15s after the release of the clicker. The RMS value of this twelve-muscle signal was used: drawning arm (dominant side) - FDS (Flexor Digitorum Superficilis); ED (Extensor Digitorum); BB (Biceps Brachii); TBL (Triceps Brachii - Long Head); LD (Latissimus Dorsi) PMC (Pectoralis Major Clavicular Head); UT (Upper Trapezius); ASD (Anterior Serratus); RA (Rectus Abdominis) and LM (Lumbar Multifidus). Non-dominant side (nD) DPnD (Posterior deltoid) and ASnD (Anterior Serratus non-dominant side); pairs created (Agonist-Antagonist: FDS-ED, BBL-TBL, LD-PMC, UT-ASD, RA-LM; Distal-Proximal: FDS-BBL, FDS-TBL, ED-BBL, ED-TBL and the pairs glenohumeral-scapular: PMC-SAD, GD-TS, SAD-SAnD, SAnD-DPnD, GD-DPnD) for analysis of co-activation/reciprocal inhibition and Vector Coding. Results; eight pairs (FDS-ED, BB-TBL, UT-ASD, FDS-BB, FDS-TBL, ED-TBL, ASD-ASnD, ASnD-DPnD) coactivated differently in blocks transition (p<0.05); and 12 (FDS-ED, BB-TBL, LD-PMC, UT-ASD, FDS-BB, FDS-TBL, ED-BB, ED-TBL, PMC-ASD, ASD-ASnD, ASnD-DPnD, LD-DPnD) co-activated differently in the score comparison (p<0.05). Also, the archers displayed different strategies of reciprocal inhibition in the blocks transition (FDS-ED, BB-TBL, UT-ASD, FDS-BB, FDS-TBL, ED-BBL, ED-TBL, ASD-ASnD; ASnD-DPnD) (p<0.05); one (UT-ASD) in the arrow analysis (p<0.05); and nine (FDS-ED, BB-TBL, FDS-BBL, FDS-TBL, ED-BBL, ED-TBL, ASD-ASnD, ASnD-DPnD, LD-DPnD) in the score analysis. Nine Vector Coding pairs (FDS-BB, FDS-TBL, ED-BB, ED-TBL, PMC-ASD, ASD-ASnD, ASnD- DPnD) changed the coordination phase mode in postural adjustments transition, while 11 pairs (FDS-ED; BB-TBL; LD-PMC; UT-ASD; FDS-BB; FDS-TBL; ED-BB; ED-TBL, PMC-ASD, ASD-ASnD, ASnD-DPnD) showed such changes in score analysis. The techniques presented in the present study revealed common parameters associated with temporal shoot-out and scores obtained by elite archers, dispite the complexity of performance analysis in high-performance athletes

Abstract The subject of the thesis was to analyze by an engineering approach the global CO₂ balance and CO₂ utilisation. The aim was to apply methods and knowledge used in engineering sciences to describe the global CO₂ balance and the role of CO₂ in anthropogenic utilisation applications. Moreover barriers restricting commercialisation of new applications are discussed. These subjects were studied by literature reviews and calculations based on thermodynamics models. Engineering methods have shown to be applicable to describe the global balance of CO₂ and to define by a numerical way the Earth’s system carrying capacity. Direct and indirect actions, which mitigate the overload situation, were derived from the results. To screen out the attractive CO₂ properties in utilisation applications a mapping analysis was carried out. Properties, which enhance mass and heat transfer, are one of the most meaningful characteristics from the chemical engineering point of view. Attractive properties are often achieved at the supercritical state. Engineering thermodynamic methods were used in fluid phase determination of the case studies. Even simple methods are sufficient to advice experimental research work. The thermodynamic knowledge is the basement in creation of industrial scale chemical processes. If detailed information on system properties is needed, a model development due to the special requirements of high pressure systems and CO₂ features is required. This knowledge covers property information from all the components involved in chemical reactions. In addition to engineering knowledge successful technology transfer requires positive social structure as well. Finally, if the humankind is willing to mimic Nature and use light of the Sun as an energy source in engineering systems, development of thermodynamic methods is required also in this area. Especially the work terms, originally defined in classical mechanical thermodynamics and afterwards formulised also in other parts of the engineering fields, play a key role. If this development work is successful, we may see the shift from thermodynamics approach to ‘photodynamics’. Mitigation of global warming is a problem, which needs several kinds of activities. As a result of this study, there are listed a few engineering actions, which have a possibility to contribute to the work towards the carbon neutral society. / Tiivistelmä Väitöskirjatyössä sovelletaan insinööritieteissä käytettyjä metodeja ja tietämystä määriteltäessä ilmakehän CO₂-tase sekä antropogeenisten hyötykäyttökohteiden merkitys teollisissa prosesseissa ja globaaleissa CO₂-virroissa. Lisäksi pohditaan uusien CO₂-hyötykäyttösovellusten kaupallistamiseen liittyviä rajoitteita. Näitä aiheita on tutkittu käymällä läpi tieteellistä kirjallisuutta ja tekemällä laskelmia. Insinööritieteistä tutun taselaskennan avulla tarkastellaan ilmakehän CO₂-virtoja. Sen pohjalta määritetään numeerisesti maapallon CO₂-kantokyky. Tuloksista johdetaan suoria ja epäsuoria toimenpide-ehdotuksia, joiden avulla voidaan lieventää ilmakehän CO₂-ylikuormaa. Kartoitusmenetelmän avulla selvitetään hyötykäytön kannalta edulliset CO₂:n aineominaisuudet. Kemiantekniikan näkökulmasta ominaisuudet, jotka parantavat aineen- ja lämmönsiirtoa, ovat kiinnostavimpia. Nämä ominaisuudet tulevat esille silloin, kun fluidi on ylikriittisessä olomuodossa. Termodynaamisia laskentamenetelmiä sovelletaan esimerkkiseosten olomuodon eli faasin määrityksessä. Tulokset osoittavat, että jopa verraten yksinkertaiset menetelmät antavat tietoja, jotka auttavat ymmärtämään laboratoriokokeiden faasikäyttäytymistä. Teollisen mittakaavan kemiallisten prosessien kehityksessä ja suunnittelussa termodynamiikan hallitseminen on keskeinen edellytys. Jos CO₂:n kiinnostavia ominaisuuksia toivotaan hyödynnettävän teollisesti, korkeapaineisten systeemien termodynaamisen teorian hallinta sekä aineominaisuuksien määrittäminen kaikille systeemiin osallistuville komponenteille ja niiden seoksille nousee merkittävään asemaan. Läpikotainen teorian ja teknisten perusteiden hallitseminen ei vielä takaa menestyksellistä teknologiansiirtoa pienestä suureen mittakaavaan. Lisäksi tarvitaan myönteinen ja kannustava yhteiskuntajärjestelmä. Mikäli tavoitellaan vielä rohkeampaa kehitysnäkymää, tilannetta, jossa luonnon tavoin CO₂-prosessien energianlähteenä käytettäisiin auringonvaloa, havaitaan, että tämäkin askel edellyttäisi termodynaamista menetelmäkehitystä. Keskeinen termodynaaminen konsepti on työ. Työ siirtää energiaa ympäristön ja systeemin välillä. Tämä on määritelty jo klassisessa mekaniikassa; kappaleen siirto tietystä paikasta toiseen. Kemiantekniikassa työlle on kehitetty käyttökelpoisia kaavoja paine–tilavuus–lämpötila-systeemeihin. Mikäli työn elementit kyettäisiin määrittelemään auringonvalon fotoenergialle, avaisi se uusia näkymiä reaktiokemiaan. Silloin termodynamiikan sijaan voitaisiin ehkä mieluummin puhua 'photodynamiikasta'. Ilmaston lämpeneminen on ongelma, jonka lieventämiseen tarvitaan useanlaisia toimia. Etsittäessä tietä kohti hiilineutraalia yhteiskuntaa, insinöörit voivat avustaa suunnan löytämisessä hyödyntämällä tieteenalallaan käytettyjä metodeja ja teorioita sekä tarpeen vaatiessa kehittää niitä edelleen uusille alueille.