Switchable adhesives using stimuli-responsive systems have many applications, including transfer printing, climbing robots, and gripping in pick and place processes. Among these adhesives, electroadhesive surface can spontaneously adjust their adhesion in response to an external electric field. However, electroadhesives usually need high voltage (e.g. kV) and the adhesion disappears upon turning off the signal. These limitations make them complicated and costly. In this research, we demonstrated a gold-coated silica microsphere (GCSM) with highly switchable and memorable adhesion triggered by a relatively small voltage (<30 V). In the experiment, a silica microsphere with a diameter of 15 μm was glued to a tipless atomic force microscope (AFM) cantilever. The nanoscale thick gold coating was sprayed on the surface of the microsphere by a sputter coater. AFM was used to explore the tunable adhesion with an external voltage at different relative humidity (RH). The results revealed that when applying a positive electrical bias at high RH, the adhesive force increased dramatically while it decreased to almost zero after applying a negative potential. Even if the bias was turned off, the adhesive force state could still be kept and erased on demand by simply applying a negative voltage. The adhesive force can be altered repeatedly by an alternative electrical bias. This adhesion modulated by the external electrical signals is attributed to the electrochemical effect of the nanoscale-thick gold coating, where an oxide layer can be formed and thus becomes positively charged when applying a positive voltage, and counter electric field cancel out the applied negative voltage to decrease the adhesion force.

<p> Polyurea microcapsules are micron-scale, hollow polymer spheres commonly used in agriculture to encapsulate pesticides for controlled diffusive release onto target crops. Diffusion of these active materials through a protective polymer wall offers a safer and more effective method of delivery compared to the direct spraying of crops with toxicants. The approach we are taking to control the release rate is to coat pre-formed porous polyurea capsules with a separate release-controlling outer layer. This allows us to separately optimize the load-bearing capsule wall and the release control layer, an approach commonly used in other membrane diffusion systems.</p> <p> Montmorillonite clay incorporation into polymer matrices can reduce membrane permeability by forcing diffusants to take a tortuous path around the stacked silicate sheets. Effective formation of clay-polyurea composites requires the delamination of clay particles into thin sheets with high aspect ratios, and their incorporation into polyurea microcapsules either during interfacial polymerization, or post-polymerization. The net negative surface charge of the silicate sheets should facilitate their initial binding to the cationic polyurea surfaces, as well as subsequent binding of polycations to the clay-coated polyurea capsules to create layer-by-layer (LbL) capsule assemblies with decreasing release rates of internal materials.</p> <p> The main focus of this project is to gain a fundamental understanding of montmorillonite clay and polyurea microcapsules, and the development of a model polyurea composite capsule for release rate analysis. Emphasis will be placed on the reduced permeability of microcapsules coated with clay by LbL assembly post-polymerization, followed by an exploration of further layering with polycations.</p> / Thesis / Master of Science (MSc)

The corrosion protection performance of epoxy-coated reinforcing steel (ECR) was evaluated in 18 concrete bridge decks in Virginia in 1997. The decks were 2 to 20 years old at the time of the investigation. The concrete bridge deck inspections included crack survey and cover depth determination in the right traffic lane. Maximum of 12 cores with the top reinforcement randomly located in the lowest 12th percentile cover depth and 3 cores with the truss bars were drilled from each bridge deck. The concrete core evaluation included visual examination and determination of carbonation depth, moisture content, absorption, percent saturation and chloride content at 13 mm depth. Rapid chloride permeability test was also performed for the surface and base concrete on samples obtained from cores containing truss bars. The ECR inspection consisted of visual examination and damage evaluation, coating thickness and adhesion determination. The condition of the steel underneath the epoxy coating was also evaluated. Adhesion loss of the epoxy coating to the steel surface was detected for 4 years old bridge decks. The epoxy coating had debonded from the reinforcing bar before the chloride arrival. Visible signs of a possibility of a corrosion process underneath the coating suggest that ECR will not provide any or little additional service life for concrete bridge decks in comparison to black steel. Other systems, which will provide longer protection with a higher degree of reliability against chloride induced corrosion of steel in concrete, should be considered. / Ph. D.

Soluble manganese (Mn) is a common water contaminant which can cause discoloration of water and staining if not treated properly in a water treatment plant. The "natural greensand effect" is one of the proven methods for efficient removal of Mn from water. Therefore, research is ongoing to develop different ways to effectively create the natural greensand effect in a post-filtration sorptive contactor for application at water treatment facilities. The research reported by Zuravnsky (2007) focused on the use of oxide-coated media in a post-filtration contactor and served as a starting point for the research reported in this thesis. As a part of the work conducted by Zuravnsky (2007), a preliminary model was formulated to predict soluble Mn removal via adsorption and oxidation onto large-size MnOx(s)-coated media. A major part of the current research was to calibrate the proposed model in predicting the soluble Mn removal performance by incorporating a statistical non-linear regression method to estimate a best-fit value for the fitting parameter kr, the rate constant associated with Mn oxidation by free chlorine. The research work included an 18-week pilot-plant study conducted at a water treatment facility in Newport News, VA. A contactor column loaded with 27â of pyrolucite media was operated at varying applied water conditions. Hydraulic loading rate (HLR), temperature, pH and influent free chlorine concentration were the operational parameters that were varied and their effect on the Mn removal performance evaluated. The resulting data were then used in the model to aid in its calibration and to obtain the best-fit kr values corresponding to effective Mn removal for the various operating conditions. Soluble Mn removal in the contactor column was directly dependent on solution pH and initial free chlorine concentration. The applied water temperature and HLR also had a small impact on the Mn removal profiles observed. On analyzing the results obtained from the model, it was noted that the best-fit kr values for the pilot plant data increased with increasing solution pH (When temperature = 200C and the initial Cl levels were below 1.5mg/L). Also, the Mn uptake capacity of the pyrolucite media increased with both an increase in initial Mn concentration and solution temperature. Long-term operation of the contactor also resulted in significant head loss accumulation in the upper portion of the contactor column, most probably due to MnOx(s) deposition on the media and partial blockage of contactor void spaces. Media fluidization was necessary to address this operational issue. / Master of Science

It is known that subsidence cracking may cause premature deterioration of concrete slab structures in salt laden environments. Chlorides from either deicing salts or marine environments may cause chloride-induced corrosion of the reinforcing steel resulting in spalling of the cover concrete. Concrete specimens with 16 mm (# 5) diameter bars were cast with various cover depths, bar spacing and two concrete mixture types to determine the influence that epoxy coated reinforcement, cement type and bar spacing may have on the probability of subsidence cracking in bridge deck slabs. It was determined that there is not a significant difference in the probability of cracking of concrete between concrete cast with epoxy coated reinforcing steel and bare reinforcing steel. Concrete subsidence cracking was found to be dependent upon the clear cover depth and cement type. / Master of Science

No / Polymeric materials are described which have a bioflavonoid coating, the bioflavonoid content of the coating comprising at least naringin and neohesperidin. The use of such coated polymeric materials is also described as well as the process for making the coated polymeric materials.

No description available.

Nanomaterials such as carbon nanotubes, gold nanorods, magnetic nanocrystals, and binary nanocrystal superlattices have exciting potential applications. However, before these ideas can be applied, it is imperative to fully understand the materials synthesis. Multiwall carbon nanotubes were synthesized in supercritical toluene using cobaltocene, nickelocene, ferrocene, or metal nanocrystals as catalysts. Toluene served as both the solvent and carbon source for nanotube growth. The reaction was optimized by introducing supplemental carbon sources; either hexane or ethanol increased the yield relative to pure toluene and catalytic amounts of water minimized carbon filament and amorphous carbon formation. Gold nanorods were synthesized by the colloidal seed-mediated, surfactantassisted approach using cetyltrimethylammonium bromide (CTAB) obtained from ten different suppliers. The gold nanorod yield depended strongly on the CTAB used: with the same recipe, three of the CTABs produced only spherical particles, whereas the other CTABs produced nanorods with nearly 100% yield. Inductively coupled plasma mass spectrometry revealed a trace iodide impurity in the CTABs that did not yield nanorods. Further experiments introducing potassium iodide to the nanorod synthesis verified the detrimental effect of iodide on nanorod formation. Multifunctional colloidal core-shell nanoparticles of magnetic nanocrystals or gold nanorods coated with a fluorescent dye (Tris(2,2 -bipyridyl)dichlororuthenium(II) hexahydrate) doped silica shells were also synthesized. The as-prepared magnetic nanocrystals were initially hydrophobic and silica coated using a microemulsion approach, while the gold nanorods were hydrophilic and silica coated using a Stöber process. These colloidal heterostructures have the potential to be used as dual-purpose tags, exhibiting a fluorescent signal that could be combined with either dark-field optical contrast or enhanced contrast in magnetic resonance imaging. Binary superlattices (BSLs) of large iron oxide and small gold nanocrystals were assembled by slow evaporation of colloidal dispersions on tilted substrates. SEM and grazing incidence small angle X-ray scattering (GISAXS) confirmed the BSLs were simple hexagonal AB2 superlattices with long range order. GISAXS also revealed that the superlattice was slightly contracted perpendicular to the substrate as a result of solvent drying during the deposition process. Additionally, in some BSLs nearly periodic superlattice dislocations consisting of inserted half-planes of gold nanocrystals were observed. / text

In this thesis work, a systematic quantitative study has been undertaken, on the performance of etched fiber Bragg Grating (FBG) sensors in the investigation of surface molecular adsorption in real-time; it is shown that the limit of detection (LOD) of FBGs etched below 2 microns diameter, is better compared to prominent optical label-free molecular sensing techniques such as Surface Plasmon Resonance (SPR). Novel fiber optic sensors based on FBG and etched FBG with various nano materials (polyelectrolytes, carbon nanotubes, hydrogel, metals and chalcogenides) coated on the surface of the core or cladding, have been proposed for sensing multi parameters such as pH, protein, humidity, gas, strain, temperature, and light etc. Besides being reproducible and repeatable, the proposed methods are fast, compact, and highly sensitive. A novel optical instrument has also been developed to measure angular deviation, binocular deviation and refractive index of glass slabs, and liquids, based on a shadow casting technique. This method uses the deviation in the geometrical shadow cast by a periodic dot pattern trans-illuminated by a distorted light beam from the transparent test specimen relative to a reference pattern.

The service life and electrocatalytic activity of tantalum oxide/iridium oxide coated titanium plate and mesh anodes used in the electrolytic production of chromic acid were investigated by performing accelerated life tests, voltammetric and chronoamperometric measurements in chrome (VI) solutions. Experimental results showed that the service life for the coated mesh anode was 1059 hours, compared to 828 hours for the plate anode at a current density of 1.2 A cm-2. In addition, the coating failed earlier in higher chromic acid concentration. Physical analysis by SEM and EDS before and after accelerated life test confirmed that the deactivation was a result of corrosion of IrO2 followed by titanium substrate passivation. A simple and rapid method for assessing the electrocatalytic activity of iridium–tantalum oxide coating based on a chronoamperometric technique was developed.