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Under 2011 började MacBat AB ta fram ett elenergilager kallat Macbat Energy Storage System (MESS), vilket är uppbyggt av 360 stycken tvåvolts bly-syrabatterier inhysta i ett 20 fots container. Då bly-syrabatterier är känsliga för värme är den här studien inriktad på att utreda hur stort kylbehovet blir under olika förutsättningar där kyldistribution, drifttemperatur på batterierna, klimat, isolering och termiska tröghet är varierande parameterar. Det ska även avgöras vilken konfiguration av kyldistribution och isolering som ger lägst kylbehov för de studerade klimaten, vilka är av varmtempererad, arid och tropisk karaktär. För att besvara studiens två mål togs fyra matematiska modeller fram i SIMULINK. Två luftkylda och två vattenkylda där en av varje var isolerad med 100 mm mineralull medan den andra var oisolerad. För samtliga modeller varierades drifttemperaturen mellan 25 – 35 °C och de studerade klimaten utgjordes av Phnom Phen, Kambodja, Djibouti, Djibouti, Bagdad, Irak samt London, England. För de vattenkylda modellerna varierades även MESS termiska tröghet i spannet 1,8058 – 9,0288 MJ/K genom att öka mängden kylvatten i systemet som användes för att kyla batterierna. Batteriernas drifttemperatur visade sig vara den parameter som i högst grad avgör kylbehovets storlek. Isoleringen gav en reducerande effekt på kylbehovet i de fall då omgivningstemperaturen under längre perioder överstiger batteriernas drifttemperatur. Varierande termisk tröghet, i de vattenkylda modellerna, hade liten eller ingen inverkan på kylbehovet. Det beror förmodligen på att den termiska massa som konstant finns i batterierna i form av elektrolyt var betydligt större. I fråga om vilken konfiguration av distributionssystem och isolering som ska användas för att erhålla ett lågt kylbehov visade sig detta bero på klimatet och drifttemperaturen på batterierna. Varmtemperade klimat som London behöver dock inget kylsystem överhuvudtaget. / In 2011 MacBat AB began to develop a electrical energy storage system called Macbat Energy Storage System (MESS), which is made up of 360 two volt lead acid batteries housed in a 20 foot container. However, while lead acid batteries are sensitive to heat this study is focused on investigating how great a cooling demand will be required under different conditions in which chilled distribution, operating temperature of the batteries, climate, insulation and thermal inertia are varied parameters. The study will also determine the configuration of chilled distribution and isolation that gives minimum cooling requirements for the studied climates, which is warm temperate, arid and tropical nature To answer the study's two goals four mathematical models were developed in SIMULINK. Two air-cooled and two water-cooled where one of each was insulated with 100 mm mineral wool while the other was bare. For all models the operating temperature varied between 25 - 35 ° C and the studied climates consisted of Phnom Penh, Cambodia, Djibouti, Djibouti, Baghdad, Iraq, and London, England. For the water cooled models thermal inertia was also varied in the range of 1.8058 to 9.0288 MJ/ K by increasing the amount of cooling water in the system used to cool the batteries. The battery operating temperature was proven to have the most significant impact on the cooling load. The isolation yielded a reducing effect on the cooling load in the case where the ambient temperature surpassed the battery operating temperature during longer periods. Varying thermal inertia of the water cooled models had little or no impact on the cooling load. It is probably due to the electrolyte in the batteries. It is a considerably larger source of thermal mass and is constant in all the models. Which configuration, regarding the distribution system and insulation, that obtains a low cooling requirement was found to depend on the ambient climate and the battery operating temperature. However, warm temperate climates such as London requires no cooling system at all.

Submitted by Cláudia Bueno (claudiamoura18@gmail.com) on 2015-11-30T13:23:21Z No. of bitstreams: 2 Dissertação - Flávia Carneiro Gonçalves - 2015.pdf: 3718226 bytes, checksum: 3024f921d7aec7030599eee358d0593f (MD5) license_rdf: 23148 bytes, checksum: 9da0b6dfac957114c6a7714714b86306 (MD5) / Approved for entry into archive by Luciana Ferreira (lucgeral@gmail.com) on 2015-12-01T06:45:31Z (GMT) No. of bitstreams: 2 Dissertação - Flávia Carneiro Gonçalves - 2015.pdf: 3718226 bytes, checksum: 3024f921d7aec7030599eee358d0593f (MD5) license_rdf: 23148 bytes, checksum: 9da0b6dfac957114c6a7714714b86306 (MD5) / Made available in DSpace on 2015-12-01T06:45:31Z (GMT). No. of bitstreams: 2 Dissertação - Flávia Carneiro Gonçalves - 2015.pdf: 3718226 bytes, checksum: 3024f921d7aec7030599eee358d0593f (MD5) license_rdf: 23148 bytes, checksum: 9da0b6dfac957114c6a7714714b86306 (MD5) Previous issue date: 2015-07-30 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPES / This study objectives to evaluate the effect of an inappropriate night cooling condition, it is practiced by some shops with processed mozzarella cheese and conventional mozzarella chemical profiles, using nuclear magnetic resonance technique (NMR). The simulation of inappropriate cooling was performed using a Styrofoam box with ice, not covered, and leaving the system to reach thermal equilibrium with the ambient temperature during the night. To make studies with processed mozzarella cheese was acquired two packages of the same batch, at local shops. Subjecting the spectral data, coming from the analysis made with HR-MAS, in the chemometric treatment was observed a tendency of discrimination in the samples exposed to different cooling conditions, and signals concerning lactose and some of fatty acids had greater influence in the observed separation. For the mozzarella cheese, in addition to NMR studies, it was also performed physical and chemical characteristics studies. For these studies, it has been acquired twenty-two trays containing sliced cheese, in the local market, which were divided into two sets with eleven trays each. Samples were analyzed in nature, using HR-MAS probe, and the crude extract using TBI probe. The identification of metabolites was done from the HSQC experiments, J-resolved and NMR ¹H, the last one being also used in the relative quantification of twelve metabolites. For the mozzarella cheese maintained under improper cooling conditions, there was a reduction in the galactose content and an increasing of amino acids and organic acids contents. The physicochemical analysis of pH, saturated fat and protein showed no significant differences that could be correlated with the different conditions of sample cooling. Finally, it has been concluded that NMR technique and chemometric tools are promising in identify the cheese samples submitted to different cooling conditions that has been studied, which could not be done using the physical and chemical parameters commonly used in cheese quality analysis. / Neste estudo vislumbrou-se avaliar a o efeito da condição de refrigeração noturna inadequada, praticada por alguns estabelecimentos comerciais, no perfil químico dos queijos tipo processados sabor mozarela e tipo mozarela convencional, fazendo uso da técnica de Ressonância Magnética Nuclear (RMN). A simulação da refrigeração inadequada foi realizada utilizando-se uma caixa de isopor contendo gelo, sem tampa, deixando o sistema atingir o equilíbrio térmico com o ambiente no decorrer da noite. Para os estudos com o queijo tipo mozarela processado adquiriu-se dois pacotes, pertencentes a um mesmo lote, no comércio local. Submetendo-se os dados espectrais, advindos das análises fazendo uso da sonda HR-MAS, ao tratamento quimiométrico, observa-se uma tendência de discriminação das amostras submetidas a diferentes condições de refrigeração, sendo que os sinais referentes a lactose e de alguns ácidos graxos tiveram maior influencia na separação observada. Já para o queijo tipo mozarela convencional, além dos estudos de RMN, realizou-se também estudos de características físico-químicas. Para isso, foram adquiridas no comércio local vinte e duas bandejas contendo queijo fatiado, as quais foram divididas em dois conjuntos com onze bandejas cada. Foram realizadas análises da amostra in natura, fazendo uso da sonda HR-MAS, e do extrato bruto, fazendo uso da sonda TBI. A identificação de metabólitos foi feita a partir dos experimentos HSQC, J-resolved e RMN de ¹H, sendo este último utilizado também na quantificação relativa de doze metabólitos. Para o queijo tipo mozarela mantido sob condições inadequadas de refrigeração observou-se uma redução no teor de galactose e aumento no teor de aminoácidos e ácidos orgânicos. As análises físicoquímicas de pH, gordura total e proteína total não mostraram diferenças significativas que pudessem ser correlacionadas com as diferentes condições de refrigeração das amostras. Nesse sentido, conclui-se que a técnica de RMN e ferramentas quimiométricas mostraram-se promissoras na identificação das amostras de queijo submetidas às diferentes condições de refrigeração estudadas, o que não pôde ser feito utilizando-se os parâmetros físico-químicos rotineiramente empregados em análises da qualidade de queijos.

This master thesis deals with the phenomenon of non-human narrator in the literary fiction. The theoretical part of the thesis provides a conceptual framework. The framework is based on the so-called unnatural narratology. Firstly, the thesis discusses non-human narrators that are conventionally accepted. Secondly, the thesis provides a case study of non-human narrators that are perceived as unnatural. The case study includes examples from both canonical works and contemporary works. The research focuses on two main levels related to the usage of the phenomenon of non-human narration as used in the narratives: the level of "meaning" and the level of "form and effect".