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Magnetic properties of three families of metal-organic coordinated networks which have the general form of M(II)A(4,4'-bipyridine), where M=Fe, Ni, Co, and Cu and A=Cl2, (ox) and (N3)2, are studied in this dissertation. Novel Ni(N3)2(4,4'-bipyridine), Co(N3)2(4,4'-bipyridine) and Cu(N3)2(4,4'-bipyridine) have been synthesized. We applied different synthesis procedures and produced Ni, Co, and Cu azide compounds for the first time, thus leaving the hydrothermal route procedure. Powder x-ray diffraction at room temperature was done in order to establish the crystal structure of the members of these three families. It was found that all of them crystallize in orthorhombic structure, where transitional metals have an octahedral coordination. Since all three families have identical crystal structure we got opportunity to examine how ligands facilitate magnetic interaction between metallic centers and also to test existing magnetic theoretical models. Since 4,4'-bipyridine is much longer than other ligands, our systems can be considered as 1-D magnetic systems. Their interchain magnetic interactions are very weak, and they order magnetically at very low temperatures of the order of few K. Measurements of M(H) at temperatures T=1.9K and T=2K and χ(T) in different external magnetic fields in zero field and field cooled modes have been made. In the case of MCl2(4,4'-bipyridine) family of compounds, we observed ferromagnetic interactions between metal ions within the chains and antiferromagnetic interactions between adjacent chains. M(ox)(4,4'-bipyridine) family of metal-organic compounds has antiferromagnetic interactions between the transitional metal ions within the chain, while weak ferromagnetic interaction exists between the chains. All members in the M(N3)2(4,4'-bipyridine) family except in the case of the copper compound were found to have ferromagnetic interactions between metal ions within the chains and then antiferromagnetic interactions between adjacent chains. The copper compound does not show magnetic ordering in the temperature range we considered. All the metal ions in these compounds were detected in high spin states. The magnetic susceptibility data was fit to appropriate 1-D models, which in the case of MCl2(4,4'-bipyridine) and M(N3)2(4,4'-bipyridine) were the Classical Spin Fisher model, and the Bonner Fisher model in the case M(ox)(4,4'-bipyridine). The experimental results and fitting to the appropriate model with the accuracy of 0.995 suggests that shorter Cl-M-Cl distances facilitate ferromagnetic interactions, which are more sensitive to the total spin value then to the sole distance between metal ions. The magnetic behavior of M(N3)2(4,4'-bipyridine) family of coordinated metal-organic compounds is very interesting because family members exhibit both ferromagnetic and antiferromagnetic behavior. The ferromagnetic characteristics decrease with decreasing spin. Fitting the results for all compounds of the M(ox)(4,4'-bipyridine) family have shown that strong anisotropy exists in all of them, being highest in Ni(ox)(4,'4-bipyridine) and lowest in Co(ox)(4,4'-bipyridine). Specific heat measurements were performed in the case of cobalt and copper azide compounds and then compared with previously obtained results for the iron coordinated network of the same family. Although none of these compounds show the characteristic λ shaped transition indicating magnetic ordering, all of them have unusually large values of the constant γ, which indicates significant magnetic contribution to the observed specific heat, since the free electron contribution in these observed families is negligible. We have concluded that total spin of the transitional metal plays a more important role than the distance between ions within the chain in determining magnitude of interaction, and that (N3)2 is a better facilitator of ferromagnetic interaction between ions than Cl2. / Physics

Aerobiological sampling using unmanned aerial vehicles (UAVs) is an exciting research field blending various scientific and engineering disciplines. The biological data collected using UAVs helps to better understand the atmospheric transport of microorganisms. Autopilot-equipped UAVs can accurately sample along pre-defined flight plans and precisely regulated altitudes. They can provide even greater utility when they are networked together in coordinated sampling missions: such measurements can yield further information about the aerial transport process. In this work flight vehicle path planning, control and coordination strategies are considered for unmanned autonomous aerial vehicles. A time-optimal path planning algorithm, that is simple enough to be solved in real time, is derived based on geometric concepts. The method yields closed-form solution for an important subset of candidate extremal paths; the rest of the paths are found using a simple numerical root-finding algorithm. A multi-UAV coordination framework is applied to a specific control-volume sampling problem that supports aerobiological data-collection efforts conducted in the lower atmosphere. The work is part of a larger effort that focuses on the validation of atmospheric dispersion models developed to predict the spread of plant diseases in the lower atmosphere. The developed concepts and methods are demonstrated by field experiments focusing on the spread of the plant pathogen <i>Phytophthora infestans</i>. / Ph. D.

Spacecraft formations offer more powerful and robust space system architectures than single spacecraft systems. Investigations into the dynamics and control of spacecraft formations are vital for the development and design of future successful space missions. The problem of controlling the attitude of a formation of spacecraft is investigated. The spacecraft formation is modelled as a distributed system, where the individual spacecraft's attitude control systems are the local control agents. A decentralized attitude controller utilizing behavior-based control is developed. The global stability of the controller is proven using Lyaponuv stability theory. Convergence of the attitude controller is proven through the use of an invariance argument. The attitude controller's stability and convergence characteristics are investigated further through numeric simulation of the attitude dynamics of the spacecraft formation. / Master of Science

Terrestrial mobile peer-to-peer millimeter wave networks will likely use beamforming arrays with narrow beams. Aligning narrow beams is difficult. One consideration for aligning narrow beams is co-channel interference. Beams can be aligned either on a per-link basis where co-channel interference is ignored, or on a global basis where co-channel interference is considered. One way to align beams on a global basis is coordinated beamforming. Coordinated beamforming can be defined as alignment of beams on a global basis, so as to jointly optimize the signal-to-interference-plus-noise ratio (SINR) of all links operating in a network. In this work, we explore coordinated beamforming in peer-to-peer networks and demonstrate its efficacy. Networks with varying numbers of links are simulated in scenarios with and without obstructions. The coordinated beamforming schemes presented in this work significantly improve link SINR statistics in these scenarios. Greater improvement was found in networks with higher numbers of links and in networks in terrain with obstructions. / Master of Science / Wireless communication links can interfere with each other. Interference can be mitigated by adjusting the antennas with which the links are formed. One method of mitigating interference is coordinated beamforming. Coordinated beamforming can be defined as a method of adjusting antennas to jointly optimize the strength of the links operating in a network. In this work, we explore coordinated beamforming in terrestrial mobile peer-to-peer communication networks and demonstrate its efficacy. Networks with varying numbers of links are simulated in scenarios with and without obstructions. The coordinated beamforming schemes presented in this work significantly improve link strength statistics in these scenarios. Greater improvement was found in networks with higher numbers of links and in networks in terrain with obstructions.

The next generation wireless networks i.e. 5G aim to provide multi-Gbps data traffic, in order to satisfy the increasing demand for high-definition video, among other high data rate services, as well as the exponential growth in mobile subscribers. To achieve this dramatic increase in data rates, current research is focused on improving the capacity of current 4G network standards, based on Long Term Evolution (LTE), before radical changes are exploited which could include acquiring additional/new spectrum. The LTE network has a reuse factor of one; hence neighbouring cells/sectors use the same spectrum, therefore making the cell edge users vulnerable to inter-cell interference. In addition, wireless transmission is commonly hindered by fading and pathloss. In this direction, this thesis focuses on improving the performance of cell edge users in LTE and LTE-Advanced (LTE-A) networks by initially implementing a new Coordinated Multi-Point (CoMP) algorithm to mitigate cell edge user interference. Subsequently Device-to-Device (D2D) communication is investigated as the enabling technology for maximising Resource Block (RB) utilisation in current 4G and emerging 5G networks. It is demonstrated that the application, as an extension to the above, of novel power control algorithms, to reduce the required D2D TX power, and multihop transmission for relaying D2D traffic, can further enhance network performance. To be able to develop the aforementioned technologies and evaluate the performance of new algorithms in emerging network scenarios, a beyond-the-state-of-the-art LTE system-level simulator (SLS) was implemented. The new simulator includes Multiple-Input Multiple-Output (MIMO) antenna functionalities, comprehensive channel models (such as Wireless World initiative New Radio II i.e. WINNER II) and adaptive modulation and coding schemes to accurately emulate the LTE and LTE-A network standards. Additionally, a novel interference modelling scheme using the 'wrap around' technique was proposed and implemented that maintained the topology of flat surfaced maps, allowing for use with cell planning tools while obtaining accurate and timely results in the SLS compared to the few existing platforms. For the proposed CoMP algorithm, the adaptive beamforming technique was employed to reduce interference on the cell edge UEs by applying Coordinated Scheduling (CoSH) between cooperating cells. Simulation results show up to 2-fold improvement in terms of throughput, and also shows SINR gain for the cell edge UEs in the cooperating cells. Furthermore, D2D communication underlaying the LTE network (and future generation of wireless networks) was investigated. The technology exploits the proximity of users in a network to achieve higher data rates with maximum RB utilisation (as the technology reuses the cellular RB simultaneously), while taking some load off the Evolved Node B (eNB) i.e. by direct communication between User Equipment (UE). Simulation results show that the proximity and transmission power of D2D transmission yields high performance gains for a D2D receiver, which was demonstrated to be better than that of cellular UEs with better channel conditions or in close proximity to the eNB in the network. The impact of interference from the simultaneous transmission however impedes the achievable data rates of cellular UEs in the network, especially at the cell edge. Thus, a power control algorithm was proposed to mitigate the impact of interference in the hybrid network (network consisting of both cellular and D2D UEs). It was implemented by setting a minimum SINR threshold so that the cellular UEs achieve a minimum performance, and equally a maximum SINR threshold to establish fairness for the D2D transmission as well. Simulation results show an increase in the cell edge throughput and notable improvement in the overall SINR distribution of UEs in the hybrid network. Additionally, multihop transmission for D2D UEs was investigated in the hybrid network: traditionally, the scheme is implemented to relay cellular traffic in a homogenous network. Contrary to most current studies where D2D UEs are employed to relay cellular traffic, the use of idle nodes to relay D2D traffic was implemented uniquely in this thesis. Simulation results show improvement in D2D receiver throughput with multihop transmission, which was significantly better than that of the same UEs performance with equivalent distance between the D2D pair when using single hop transmission.