The Gulf of Mexico (GOM) represents a challenge for exploration and production. Most of the sediments coming from North America has bypassed the shelf margin into Deep Water. In an Attempt to attack this challenge this thesis pretends to break the GOM's false bottom, mainly comprised by diverse salt structures and growth fault families. In this attempt, geological and geophysical data are integrated to find clues to potential hydrocarbons indicator (PHI) that could be of Reservoir Quality (RQ). 3D Pre stack depth migrated data comprised of Mississippi Canyon blocks, were interpreted: Top and base of salt, leading to the identification of a PHI represented by a consistent Amplitude Anomaly (AA) below and towards a salt structure. This AA may be of RQ and feasibility evaluation for further decisions may be taken. Following the structural sequences that Govern central GOM during Oligocene through out Miocene was important to support the results.

This study investigates Mio-Pliocene mass-transport deposits (MTDs) in an understudied, hydrocarbon-rich region of the northeastern Gulf of Mexico. The research utilizes a high-quality 3D seismic dataset with an area of 635 km2, along with wireline logs and biostratigraphic data. With the help of quantitative seismic geomorphology techniques, detailed mapping of MTDs suggests a complex erosional and depositional history. Deposition of a MTD unit resulted in a 180 m topographic high that substantially influenced the distribution and morphology of subsequent MTDs, specifically the bifurcation of later mass-transport flows. This bifurcation contributed to the generation of a non-shielded erosional remnant with an area of 65 km2. Depositional elements of the remnant strata are interpreted to be sediment waves. Instantaneous frequency attribute maps of the erosional remnant suggest a different lithology than the surrounding muddy MTDs; and, thus, the remnant unit is interpreted to be sandy. For the first time in literature, this research documented intra-MTD channel and lobe features. The development of a sinuous channel system encased within MTD gives new insights into mass-transport processes. This provides evidence for considering MTD as amalgamation deposits of multiple and different-type of flow events (e.g., turbidity currents and debris flows), rather than a singular event-deposit. The channel, lobe, and erosional remnant features examined in this research demonstrate reservoir-prone facies encased within MTD units, forming stratigraphic traps directly associated with mass-transport phenomena. This research contributes to the understanding of seal vs. reservoir rock development and distribution in the study area, as well as presents new developments into mass-transport deposit flow processes and their resulting morphologies.

This thesis addresses the utility of deep-water coral geochemistry and its potential to reconstruct oceanographic conditions in the Straits of Florida. Through stable isotope and elemental analyses of the carbonate skeletons and use of available geochemical proxy calibration equations, present and past environmental parameters were determined. Over the last several years, scientific expeditions to the bottom of the Straits of Florida have revealed hundreds of deep-water coral mounds and led to the collection of extensive oceanographic data, sediment samples, and deep-water coral specimens. In 2005-2006, an Autonomous Underwater Vehicle (AUV) was used to map the coral mound fields at five sites with the use of geophysical imaging technology, and the manned Johnson-Sea-Link II submersible was deployed for further exploration and sample collection. The AUV and the submersible CTD also measured numerous environmental parameters, including temperature and salinity. With the goal of reconstructing environmental parameters across the Straits of Florida, Scleractinian and gorgonian deep-water coral specimens were selected from three sites spanning the Straits. Each coral was sampled at the highest resolution possible and analyzed for stable isotopes and elemental concentrations. Resulting geochemical data, specifically d18O, d13C, Sr/Ca, and Mg/Ca, was then used with previously published and newly developed calibration equations to calculate temperature, salinity, and seawater density. Kinetic and vital effects were also examined and taken into account while reconstructing environmental parameters using the coral geochemistry. Additional reconstructions using stable isotopic values from benthic foraminifera corroborated the geochemical reconstructions, and analyses of pteropods and surface sediment samples provided further insight into the oceanographic conditions at the bottom of the Straits of Florida. Results from geochemical reconstructions agreed with in situ data, indicating that slightly warmer bottom temperatures exist on the eastern side of the Straits and salinity variability among the three sites is minimal. This suggests that the deep-water coral skeletons are sensitive recorders of the environmental conditions in which they lived. Ultimately, in situ measurements and reconstructed parameters showed that there is little variability across the bottom of the Straits and that Antarctic Intermediate Water (AAIW) is the only apparent water mass in the area at that depth. Moreover, comparison of the coral habitat from this study with others from around the world demonstrated that certain conditions are required for deep-water coral growth, and that these same parameters are common to deep-water reef systems throughout the globe. Further sampling and geochemical analyses of deep-water corals in the region may be used to gain additional insight into the oceanographic conditions surrounding the coral mounds both presently and in the past. As with other previously studied deep-water coral systems, this highlights the potential for the reconstruction of paleo environmental records from deep-water corals in the Straits of Florida.

Abstract Slope to Basin-floor Evolution of Channels to Lobes, Jurassic Los Molles Formation, Neuquén Basin, Argentina Nataleigh Kristine Vann, MS Geo Sci The University of Texas at Austin, 2013 Supervisor: Ronald J. Steel and Cornel Olariu The relatively steep and short-headed Neuquén Basin margin provides an excellent laboratory for demonstrating down slope changes in sediment gravity flow bed thickness, grain size and facies, as well as channel to lobe transitions. Approximately 400m high clinoformal, shelf-slope-basin-floor deposits of Jurassic Los Molles Formation outcrops are evaluated for reservoir scale definition of facies and architectures in the La Jardinera field area, Neuquén Basin. Slope deposits represent the accretionary front of the prograding shelf margin that were fed by a coarse grained shelf (Lajas Formation). Mapping of a high-resolution satellite images draped on digital elevation model resolved a sub-meter stratigraphic framework. Thirty-three measured sections from outcrops exposed along a 5km transect characterize the evolution of sand body architectures from the shelf edge to the basin floor. The Neuquén Basin margin is typified by four main depositional environments that transition from shelf edge incisions filled with conglomerates, to confined channels in upper- to middle-slope reaches, to weakly confined channels on the lower slope to sheet-like lobes and distributary channel complexes that drape onto both the lower slope and basin floor. Along the slope to basin floor profile the depositional architecture changes by overall decrease in grain size, amalgamation of beds and degree of erosion. Confined slope channels are up to 25m deep, isolated within muddy slope deposits and have complex multistory fills marked by basal and internal erosive contacts lined with mud-clast and/or pebble conglomerates. Channel axes contain amalgamated, medium to coarse sandstones that thin and fine towards channel margins over 100m. Down dip, lower slope channels are up to 400m wide and less than 10m thick. A marked reduction in mud clasts and conglomeratic material at basal erosional surfaces in weakly confined channels represent a downslope decrease in flow energy. However, distinct meter scale erosion surfaces continue to be recognizable where thin ripple laminated sands are truncated on channel margins by amalgamated structureless sands. Erosional surfaces are absent in laterally extensive (>5km), sheet-like lobes of basin-floor fans that are generally finer grained than lower or upper slope channel fills. There are lenticular debrites and thin micro-conglomerates associated with basin-floor fans. / text

A presente dissertação aborda a modelagem física de sistemas marinho profundo em escala reduzida, uma metodologia que vem contribuindo no entendimento dos processos sedimentares atuantes neste ambiente, principalmente as correntes de turbidez, fluxo gravitacional subaquoso responsável pela formação dos turbiditos, importantes reservatórios de hidrocarbonetos da costa brasileira. A modelagem física 3D empregada neste trabalho aborda a influência da autogênese no comportamento espacial e evolutivo de depósitos análogos gerados por simulações de correntes de turbidez em duas séries de 10 experimentos com parâmetros de controle constantes (vazão, concentração volumétrica de sedimentos, tipo e granulometria das partículas sedimentares), onde em cada série foi utilizada uma concentração de sedimentos diferente: uma com maior concentração – HDTC (high-density turbidity currents) e outra com menor concentração – LDTC (low-density turbidity currents) onde se buscou observar o efeito desta propriedade na construção dos depósitos. Para caracterizar o comportamento geométrico dos depósitos, uma nova abordagem estatística é utilizada a partir de uma análise de variância. Os resultados obtidos apontam que processos autogênicos locais puderam alterar a configuração global dos depósitos. A concentração de sedimentos teve influência direta nas características morfológicas e evolutivas dos depósitos, sendo os experimentos de HDTC os que apresentam uma evolução mais complexa, onde ocorreu um processo de auto-confinamento das correntes, gerando uma morfologia mais diversa. / Autogenic / allogenic controls have been discussed widely because they represent an important parameter in the constructive and evolutionary process of a sedimentary system. To evaluate these controls in submarine fans and analyse its capacity of selforganizing and creating depositional patterns, this work performed fully controlled 3D physical simulations of turbidity currents under ideal autogenic controls (no external influence) with detailed data for the generated deposits. Two series of 10 experiments of high-density turbidity currents (HDTC) and low-density turbidity currents (LDTC) were run, keeping all other input parameters (discharge, volumetric concentration, type and grain size) constant. From statistical and qualitative approach were characterised the geometric elements and morphodynamic behaviour of the deposits (centroid, Length/Width ratio, morphodynamic evolution). The results indicate local autogenic processes change the global setting of the flow evolution and deposits of submarine fans. A morphodynamic evolution generated by HDTC showed complex stages of filling and stacking caused by two types of flow self-channelling. Type I is characterised by flow channelling due to the elevation of levees without lateral avulsion and more efficient sediment transport (longer deposits, with terminal lobes well developed), and Type II is characterised by flow channelling but allows lateral avulsions and involves less efficient sediment transport (shorter deposits with terminal lobes undeveloped). The HDTC deposits showed random behaviour for the length/width ratio and for the centroid of sedimentary bodies and distinct morphological elements (elongated central deposit, fringes and distal lobes). By contrast, the LDTC morphodynamics were simplified without any self-confining process or distinct morphological elements. Finally, the statistical approach showed that the HDTC deposits had a greater variance of geometrical elements in relation to LDTC deposits. The experiments provided evidence that high rates of sediment supply decisively influenced the geometry and morphodynamic of the deposits, as well as they self-organizing capacity.

This thesis investigates the utility of sequence stratigraphy on a regional scale and the control of eustacy on basin infill in unprecedented detail. To achieve this, the thesis utilises a wealth of data, including a continuous 3D seismic MegaSurvey dataset covering 55,000 sq. km, combined with state of the art seismic interpretation software to interpret the basin infill of the Late Cenozoic southern North Sea. The prograding shelf-prism clinoforms of the Late Cenozoic are calibrated to high density borehole penetrations, high resolution chronostratigraphy and climate proxies. The chronostratigraphic control enables a correlation of geomorphology, seismic architectures and seismic facies with full 3D control to the global sea level curve, which enables an evaluation of the impact of eustatic change on sequence development. The control of eustacy and the limitations of sequence stratigraphy are highlighted by: 1) Investigating the regional expression of chronostratigraphically calibrated seismic units, which are linked to the global sea level curve. This was carried out by mapping across the region, the dominance of oblique or sigmoidal clinoform types and seismic features such as iceberg scours, terrestrial channels and submarine fans in order to evaluate the lateral variation of depositional systems and accommodation. 2) Investigating sediment partitioning basinwards of the shelf edge and how deposition basinwards can be predicted via observations of seismic facies and architecture. This was achieved by focusing on specific seismic architectures of forced regressive slope clinoforms and deep water sedimentary systems and the link updip to the shelf within the highly constrained chronostratigraphic framework. The thesis results suggest that sequence stratigraphic models do not represent lateral variation well or integrate other allocyclic forcings on sequence development. A holistic and observation based approach to understanding basin infill and recognising the importance of sediment supply, pre-existing geomorphology, process type of the feeder system, differential subsidence, as well as eustacy, is imperative.

A presente dissertação aborda a modelagem física de sistemas marinho profundo em escala reduzida, uma metodologia que vem contribuindo no entendimento dos processos sedimentares atuantes neste ambiente, principalmente as correntes de turbidez, fluxo gravitacional subaquoso responsável pela formação dos turbiditos, importantes reservatórios de hidrocarbonetos da costa brasileira. A modelagem física 3D empregada neste trabalho aborda a influência da autogênese no comportamento espacial e evolutivo de depósitos análogos gerados por simulações de correntes de turbidez em duas séries de 10 experimentos com parâmetros de controle constantes (vazão, concentração volumétrica de sedimentos, tipo e granulometria das partículas sedimentares), onde em cada série foi utilizada uma concentração de sedimentos diferente: uma com maior concentração – HDTC (high-density turbidity currents) e outra com menor concentração – LDTC (low-density turbidity currents) onde se buscou observar o efeito desta propriedade na construção dos depósitos. Para caracterizar o comportamento geométrico dos depósitos, uma nova abordagem estatística é utilizada a partir de uma análise de variância. Os resultados obtidos apontam que processos autogênicos locais puderam alterar a configuração global dos depósitos. A concentração de sedimentos teve influência direta nas características morfológicas e evolutivas dos depósitos, sendo os experimentos de HDTC os que apresentam uma evolução mais complexa, onde ocorreu um processo de auto-confinamento das correntes, gerando uma morfologia mais diversa. / Autogenic / allogenic controls have been discussed widely because they represent an important parameter in the constructive and evolutionary process of a sedimentary system. To evaluate these controls in submarine fans and analyse its capacity of selforganizing and creating depositional patterns, this work performed fully controlled 3D physical simulations of turbidity currents under ideal autogenic controls (no external influence) with detailed data for the generated deposits. Two series of 10 experiments of high-density turbidity currents (HDTC) and low-density turbidity currents (LDTC) were run, keeping all other input parameters (discharge, volumetric concentration, type and grain size) constant. From statistical and qualitative approach were characterised the geometric elements and morphodynamic behaviour of the deposits (centroid, Length/Width ratio, morphodynamic evolution). The results indicate local autogenic processes change the global setting of the flow evolution and deposits of submarine fans. A morphodynamic evolution generated by HDTC showed complex stages of filling and stacking caused by two types of flow self-channelling. Type I is characterised by flow channelling due to the elevation of levees without lateral avulsion and more efficient sediment transport (longer deposits, with terminal lobes well developed), and Type II is characterised by flow channelling but allows lateral avulsions and involves less efficient sediment transport (shorter deposits with terminal lobes undeveloped). The HDTC deposits showed random behaviour for the length/width ratio and for the centroid of sedimentary bodies and distinct morphological elements (elongated central deposit, fringes and distal lobes). By contrast, the LDTC morphodynamics were simplified without any self-confining process or distinct morphological elements. Finally, the statistical approach showed that the HDTC deposits had a greater variance of geometrical elements in relation to LDTC deposits. The experiments provided evidence that high rates of sediment supply decisively influenced the geometry and morphodynamic of the deposits, as well as they self-organizing capacity.

A presente dissertação aborda a modelagem física de sistemas marinho profundo em escala reduzida, uma metodologia que vem contribuindo no entendimento dos processos sedimentares atuantes neste ambiente, principalmente as correntes de turbidez, fluxo gravitacional subaquoso responsável pela formação dos turbiditos, importantes reservatórios de hidrocarbonetos da costa brasileira. A modelagem física 3D empregada neste trabalho aborda a influência da autogênese no comportamento espacial e evolutivo de depósitos análogos gerados por simulações de correntes de turbidez em duas séries de 10 experimentos com parâmetros de controle constantes (vazão, concentração volumétrica de sedimentos, tipo e granulometria das partículas sedimentares), onde em cada série foi utilizada uma concentração de sedimentos diferente: uma com maior concentração – HDTC (high-density turbidity currents) e outra com menor concentração – LDTC (low-density turbidity currents) onde se buscou observar o efeito desta propriedade na construção dos depósitos. Para caracterizar o comportamento geométrico dos depósitos, uma nova abordagem estatística é utilizada a partir de uma análise de variância. Os resultados obtidos apontam que processos autogênicos locais puderam alterar a configuração global dos depósitos. A concentração de sedimentos teve influência direta nas características morfológicas e evolutivas dos depósitos, sendo os experimentos de HDTC os que apresentam uma evolução mais complexa, onde ocorreu um processo de auto-confinamento das correntes, gerando uma morfologia mais diversa. / Autogenic / allogenic controls have been discussed widely because they represent an important parameter in the constructive and evolutionary process of a sedimentary system. To evaluate these controls in submarine fans and analyse its capacity of selforganizing and creating depositional patterns, this work performed fully controlled 3D physical simulations of turbidity currents under ideal autogenic controls (no external influence) with detailed data for the generated deposits. Two series of 10 experiments of high-density turbidity currents (HDTC) and low-density turbidity currents (LDTC) were run, keeping all other input parameters (discharge, volumetric concentration, type and grain size) constant. From statistical and qualitative approach were characterised the geometric elements and morphodynamic behaviour of the deposits (centroid, Length/Width ratio, morphodynamic evolution). The results indicate local autogenic processes change the global setting of the flow evolution and deposits of submarine fans. A morphodynamic evolution generated by HDTC showed complex stages of filling and stacking caused by two types of flow self-channelling. Type I is characterised by flow channelling due to the elevation of levees without lateral avulsion and more efficient sediment transport (longer deposits, with terminal lobes well developed), and Type II is characterised by flow channelling but allows lateral avulsions and involves less efficient sediment transport (shorter deposits with terminal lobes undeveloped). The HDTC deposits showed random behaviour for the length/width ratio and for the centroid of sedimentary bodies and distinct morphological elements (elongated central deposit, fringes and distal lobes). By contrast, the LDTC morphodynamics were simplified without any self-confining process or distinct morphological elements. Finally, the statistical approach showed that the HDTC deposits had a greater variance of geometrical elements in relation to LDTC deposits. The experiments provided evidence that high rates of sediment supply decisively influenced the geometry and morphodynamic of the deposits, as well as they self-organizing capacity.

The naturally occurring isotopes 231Pa and 230Th are used as tracers of marine biogeochemical processes. They are both produced from the radioactive decay of their uniformly distributed uranium parents (235U and 234U) in seawater. After production, 231Pa and 230Th are removed by adsorption onto settling particles (scavenging) and subsequently buried in marine sediments. 230Th is more particle reactive compared to 231Pa. Consequently, 230Th will be removed from the open ocean by adsorption onto settling particles, while 231Pa tend to be laterally transported by currents and removed by scavenging in areas of high particle flux (e.g. ocean margins). The primordial 232Th indicates lithogenic supply via rivers and resuspension of sediments, which provides additional information about processes involved in the cycling of particle reactive elements in the ocean. The preferential deposition of particle reactive elements at ocean margins (boundary scavenging) has important implications for our understanding of the distribution and dispersion of micronutrients (e.g. iron) and pollutants in the ocean. It is therefore valuable to understand the nature of boundary scavenging processes in order to evaluate the relative contribution of circulation and scavenging behaviors.The major characteristics of thermohaline circulation in the Mediterranean are well known and have been studied for decades. This sea is an almost land-locked area, where limited water-exchange with the Atlantic Ocean only occurs through the Strait of Gibraltar. Therefore, this marginal sea is often referred to as a “miniature ocean” suitable as a “laboratory” for marine environmental research. In this licentiate thesis, distributions of 231Pa, 230Th and 232Th in seawater and marine particles collected during the GEOTRACES MedSeA-GA04-S cruise in 2013 are presented. Observed nuclide distributions indicate the impact of deep water formation processes, where observed differences can be linked to the type of deep water formation process that occurs in respective basin. Essentially all in-situ produced 230Th is buried in Mediterranean Sea sediments. Despite lower affinity of 231Pa for marine particles, most 231Pa is also scavenged and deposited in Mediterranean Sea sediments. The efficient scavenging of 231Pa produces a relatively low fractionation between 231Pa and 230Th in terms of the fractionation factor FTh/Pa. This licentiate thesis presents a summary of the methods used for the analysis of 231Pa and Th-isotopes with details on the exchange chromatography method and the treatment of mass spectrometric data. The study of 231Pa, 230Th and 232Th in the Mediterranean Sea has important implications for our understanding of processes that control their water column distributions and how their behavior can be utilized to trace chemical flux in modern and past ocean environments. / GEOTRACES / MeDSeA

Made available in DSpace on 2014-12-17T14:09:10Z (GMT). No. of bitstreams: 1 ClovisDF_TESE_partes_autorizadas.pdf: 2764652 bytes, checksum: e400922c312c00169022c2f987a6d8b7 (MD5) Previous issue date: 2010-08-13 / The development of oil wells drilling requires additional cares mainly if the drilling is in offshore ultra deep water with low overburden pressure gradients which cause low fracture gradients and, consequently, difficult the well drilling by the reduction of the operational window. To minimize, in the well planning phases, the difficulties faced by the drilling in those sceneries, indirect models are used to estimate fracture gradient that foresees approximate values for leakoff tests. These models generate curves of geopressures that allow detailed analysis of the pressure behavior for the whole well. Most of these models are based on the Terzaghi equation, just differentiating in the determination of the values of rock tension coefficient. This work proposes an alternative method for prediction of fracture pressure gradient based on a geometric correlation that relates the pressure gradients proportionally for a given depth and extrapolates it for the whole well depth, meaning that theses parameters vary in a fixed proportion. The model is based on the application of analytical proportion segments corresponding to the differential pressure related to the rock tension. The study shows that the proposed analytical proportion segments reaches values of fracture gradient with good agreement with those available for leakoff tests in the field area. The obtained results were compared with twelve different indirect models for fracture pressure gradient prediction based on the compacting effect. For this, a software was developed using Matlab language. The comparison was also made varying the water depth from zero (onshore wellbores) to 1500 meters. The leakoff tests are also used to compare the different methods including the one proposed in this work. The presented work gives good results for error analysis compared to other methods and, due to its simplicity, justify its possible application / O desenvolvimento da perfura??o de po?os de petr?leo requer cuidados adicionais principalmente se a perfura??o for mar?tima em l?mina d ?gua ultraprofunda, o que levam a baixos gradientes de sobrecarga, ocasionando baixos gradientes de fratura e, conseq?entemente, dificultando as opera??es de perfura??o pela redu??o da janela operacional. Para minimizar as dificuldades enfrentadas pela perfura??o nesses cen?rios, na fase de planejamento, s?o utilizados modelos indiretos para estimativa do gradiente de fratura, que podem prev? valores aproximados dos testes de absor??o. Esses modelos geram perfis de geopress?o que permitem a an?lise detalhada do comportamento das press?es em todo o intervalo do po?o. A maioria dos modelos tem como base a equa??o de Terzaghi, diferenciando apenas na determina??o dos valores do coeficiente de tens?o da matriz da rocha. Este trabalho prop?e uma forma alternativa diferente, para se estimar o gradiente de fratura, por meio de uma correla??o geom?trica que relaciona proporcionalmente os gradientes de press?o para cada profundidade em todo o intervalo do po?o. As grandezas envolvidas variam em uma mesma propor??o em todo intervalo do po?o. O modelo baseia-se na aplica??o da propor??o ?urea do segmento sobre o diferencial de press?o correspondente ? tens?o da matriz. O estudo mostra que a propor??o ?urea encontra valores de gradiente de fratura com grande aproxima??o dos valores de testes de absor??o dispon?veis da ?rea. Os resultados obtidos foram comparados com doze modelos indiretos distintos que estimam gradiente de fratura baseados no efeito da compacta??o. Para isto, um programa em linguagem Matlab foi desenvolvido. A compara??o tamb?m foi feita com a varia??o de l?minas d ?gua variando de zero (para po?os terrestres, por exemplo) a 1500 m. A medida da precis?o para avalia??o de cada m?todo toma como referencial os valores de testes de absor??o e ? feita atrav?s do erro relativo percentual. A precis?o mostrada nos valores apresentados na an?lise de erro e a forma bastante simples do modelo proposto mostram que ? justific?vel a sua aplica??o