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Using the Dusty Gas Model to investigate reaction-induced multicomponent gas and solute transport in the vadose zoneMolins Rafa, Sergi 05 1900 (has links)
Biogeochemical reactions and vadose zone transport, in particular gas phase transport, are inherently coupled processes. To explore feedback mechanisms between these processes in a quantitative manner, multicomponent gas diffusion and advection are implemented into an existing reactive transport model that includes a full suite of geochemical reactions. Multicomponent gas diffusion is described based on the Dusty Gas Model, which provides the most generally applicable description for gas diffusion. Gas advection is described by Darcy's Law, which in the current formulation, is directly substituted into the transport equations.
The model is used to investigate the interactions between geochemical reactions and transport processes with an emphasis to quantify reaction-induced gas migration in the vadose zone. Simulations of pyrite oxidation in mine tailings, gas attenuation in partially saturated landfill soil covers, and methane production and oxidation in aquifers contaminated by organic compounds demonstrate how biogeochemical reactions drive diffusive and advective transport of reactive and non-reactive gases. Pyrite oxidation in mine tailings causes a pressure reduction in the reaction zone and drives advective gas flow into the sediment column, enhancing the oxidation process. Release of carbon dioxide by carbonate mineral dissolution partly offsets pressure reduction, and illustrates the role of water-rock interaction on gas transport. Microbially mediated methane oxidation in landfill covers reduces the existing upward pressure gradient, thereby decreasing the contribution of advective methane emissions to the atmosphere and enhancing the net flux of atmospheric oxygen into the soil column. At an oil spill site, both generation of CH4 in the methanogenic zone and oxidation of CH4 in the methanotrophic zone contribute to drive advective and diffusive fluxes. The model confirmed that non-reactive gases tend to accumulate in zones of gas consumption and become depleted in zones of gas production.
In most cases, the model was able to quantify existing conceptual models, but also proved useful to identify data gaps, sensitivity, and inconsistencies in conceptual models. The formulation of the model is general and can be applied to other vadose zone systems in which reaction-induced gas transport is of importance.
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Nitrogen in SL/RN direct reduced iron : origin and effect on the electric steelmaking processErwee, M.W. (Markus Wouter) January 2013 (has links)
Direct Reduced Iron (DRI) is used as an alternative feedstock in electric arc furnaces,
making up 50% or more of the total iron charge. DRI produced with coal based
reductants (for example in rotary kilns) make up roughly 25% of DRI produced in
the world. It was found that SL/RN DRI samples from a kiln cooler had high
nitrogen contents (50-250ppm, depending on particle size), higher than DRI from
gas-based reduction. The higher nitrogen content of SL/RN DRI would increase the
levels of nitrogen of liquid steel produced in the EAFs. The problem is exacerbated
by the fact that the SL/RN DRI contains virtually no carbon (which would aid in
preventing nitrogen pickup). The proposed mechanism of nitrogen pick-up by the
SL/RN DRI is one where nitrogen present within the atmosphere of the rotary cooler
(where hot DRI, discharged at 1000°C from the rotary kiln, is cooled to
approximately 100 °C in ca. two hours) penetrates the solids bed and nitrides DRI
particles. Possible rate-determining steps for nitriding in the cooler have been
evaluated. Nitriding of DRI particles is predicted to be rapid: the most plausible
location for rapid nitrogen pickup is the first 5 meters of the rotary cooler, where the
high temperature, nitrogen-rich gas atmosphere and rapid solids bed mixing are
conducive to nitriding; solid-state and pore diffusion of nitrogen into DRI particles
are predicted to be rapid too. The most plausible rate determining step for nitriding
of DRI particles is that of nitrogen dissociation on the DRI surface, which can be
further retarded by the presence of sulphur. A strong correlation was found between
the amount of “melt-in” carbon in the liquid steel and the final tap nitrogen content,
with 0.3% C resulting in nitrogen levels as low as 50 ppm (80 ppm or less is desired
on the plant in question) at tap, even with DRI material that is high in nitrogen and
contains virtually no carbon. Proposals to increase the melt-in carbon are included. / Dissertation (MEng)--University of Pretoria, 2013. / gm2014 / Materials Science and Metallurgical Engineering / unrestricted
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Expérimentation et Modélisation du Transfert d'hydrogène à travers des argiles de centre de stockage de déchets radioactifsBoulin, Pierre 02 October 2008 (has links) (PDF)
Des gaz vont être générés par corrosion des conteneurs de déchets radioactifs au niveau d'un stockage en couche géologique profonde. Une bulle de gaz se crée et monte en pression. Si le gaz pénètre difficilement la formation géologique, l'augmentation de pression pourra la fissurer et créer des chemins préférentiels à la migration de radionucléides. Les argilites du Callovo-Oxfordien sont ici caractérisées. Un dispositif permettant de mesurer de très faibles perméabilités à l'hydrogène/hélium a été utilisé couplé au Dusty Gas Model. Les argilites proches de la saturation ont une porosité accessible au gaz inférieure à 1% voire 0,1% de la porosité totale. A partir de l'étude de l'effet Knudsen cette porosité pourrait être due à des pores de 50 à 200 nm de diamètre mis en évidence lors de la caractérisation des réseaux. En intégrant ces résultats dans un modèle opérationnel de l'ANDRA, la pression maximale atteinte au sein d'une alvéole de stockage serait de 83 bar.
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Nonlinear reactive processes in constrained mediaBullara, Domenico 27 March 2015 (has links)
In this thesis we show how reactive processes can be affected by the presence of different types of spatial constraints, so much so that their nonlinear dynamics can be qualitatively altered or that new and unexpected behaviors can be produced. To understand how this interplay can occur in general terms, we theoretically investigate four very different examples of this situation. <p><p>The first system we study is a reversible trimolecular chemical reaction which is taking place in closed one-dimensional lattices. We show that the low dimensionality may or may not prevent the reaction from reaching its equilibrium state, depending on the microscopic properties of the molecular reactive mechanism. <p><p>The second reactive process we consider is a network of biological interactions between pigment cells on the skin of zebrafish. We show that the combination of short-range and long-range contact-mediated feedbacks can promote a Turing instability which gives rise to stationary patterns in space with intrinsic wavelength, without the need of any kind of motion.<p><p>Then we investigate the behavior of a typical chemical oscillator (the Brusselator) when it is constrained in a finite space. We show that molecular crowding can in such cases promote new nonlinear dynamical behaviors, affect the usual ones or even destroy them. <p><p>Finally we look at the situation where the constraint is given by the presence of a solid porous matrix that can react with a perfect gas in an exothermic way. We show on one hand that the interplay between reaction, heat flux and mass transport can give rise to the propagation of adsorption waves, and on the other hand that the coupling between the chemical reaction and the changes in the structural properties of the matrix can produce sustained chemomechanical oscillations. <p><p>These results show that spatial constraints can affect the kinetics of reactions, and are able to produce otherwise absent nonlinear dynamical behaviors. As a consequence of this, the usual understanding of the nonlinear dynamics of reactive systems can be put into question or even disproved. In order to have a better understanding of these systems we must acknowledge that mechanical and structural feedbacks can be important components of many reactive systems, and that they can be the very source of complex and fascinating phenomena.<p> / Doctorat en Sciences / info:eu-repo/semantics/nonPublished
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