Tungsten doped tantalum oxide films on titanium substrates were investigated for use as anodes in the electrochemical disinfection of wastewater (measured through e. coli inactivation). A sol-gel method for fabricating these films was developed that allowed for control of both the doping concentration (through volumes of tantalum and tungsten ethoxide added to the solutions), and the thickness (through the number of layers applied). The morphology and composition of these films were investigated using SEM and EDX mapping; the morphology was found to be connected to the fabrication heating procedure. Three different doping concentrations (0%, 8% and 14% tungsten by volume of added metals) were investigated for: 1) electrochemical activity; 2) long-term stability; and 3) disinfection capabilities. The 14% samples demonstrated the highest conductivity (0.06μS/cm), good long-term stability (verified using ICPMS, SEM and EDX analysis) and the best electrochemical activity for removal of e. coli (based on wastewater tests).

Tungsten doped tantalum oxide films on titanium substrates were investigated for use as anodes in the electrochemical disinfection of wastewater (measured through e. coli inactivation). A sol-gel method for fabricating these films was developed that allowed for control of both the doping concentration (through volumes of tantalum and tungsten ethoxide added to the solutions), and the thickness (through the number of layers applied). The morphology and composition of these films were investigated using SEM and EDX mapping; the morphology was found to be connected to the fabrication heating procedure. Three different doping concentrations (0%, 8% and 14% tungsten by volume of added metals) were investigated for: 1) electrochemical activity; 2) long-term stability; and 3) disinfection capabilities. The 14% samples demonstrated the highest conductivity (0.06μS/cm), good long-term stability (verified using ICPMS, SEM and EDX analysis) and the best electrochemical activity for removal of e. coli (based on wastewater tests).

This research focused on chlorine-free disinfection of wastewater by complying with today's regulations. The equipment used was a continuous flow electrochemical reactor connected to an alternating current (AC) power supply. The electrodes used were made out of titanium coated with iridium oxide. To determine the inactivation of Escherichia Coli, a bacterial count method based on the USEPA method 1603 was used. After several experiments it was determined that electrochemical disinfection using AC was not efficient and economic enough to be classified as a viable alternative to chlorine disinfection. It was demonstrated that chlorine can be produced by electrolysis using AC and that no hydrogen could be noticed as a byproduct of the electrolysis of wastewater. When the results from this investigation were compared to the ones obtained using DC in Acosta (2014), it was determined that the belief that AC and DC are equally efficient at disinfecting wastewater is wrong.

According to estimates of the United Nations Environment Programme (UNEP), more than 1.8 billion people will be living in countries or regions with absolute water scarcity by 2025. The pressure on water resources is increased not only in arid and semiarid regions, but also in fast growing megacities around the world as a result of, amongst other factors, the changing nutritional and consumer behavior (rising living standards). Over 90 % of the annual water consumption of the newly industrializing and developing countries in the arid and semiarid climate zone is used for agricultural irrigation to ensure the nutrition of the population. Thus, since the beginning of the 20th century, the planned/controlled reuse of wastewater has developed into a central task of the sustainable water resources management. Wastewater represents a valuable resource in view of its composition (e. g. nutrients P, N for soil fertilizing) and its reliable, weather-independent availability in every household. The establishment of a closed-loop water management can enhance the efficiency of water usage. Therefore, activities in research and development are currently focused on decentralized and semi-centralized concepts, since their structures offer better conditions for the establishment of closed-loop systems and innovations in wastewater technology can be implemented more easily. In general, the hygienic quality requirements for wastewater reuse are predominantly oriented towards the planned usage. These are, in turn, regulated by thresholds and guidance values, e. g. for faecal indicator bacteria (e. g. faecal coliforms: E. coli), in widely differing norms and legal provisions specific to the respective countries. In Germany since 2005, small wastewater treatment plants can obtain the discharge class +H by the German Institute for Civil Engineering (DIBt: Deutsches Institut für Bautechnik) if secondary effluents contain less than 100 faecal coliforms (E. coli) per 100 mL. This ensures a safe effluent seepage in karst and water protection areas. Due to the infectious risk caused by a multitude of pathogens (bacteria, viruses, worm eggs, protozoa) which are still contained in wastewater after mechanical-biological treatment, specific disinfection methods are indispensable for their satisfactory reduction. Demands on disinfection methods for wastewater reclamation are quite complex. They should be characterized by a high and constant disinfection efficiency at low or moderate formation of disinfection by-products. The reclaimed wastewater should be able to be stored safely. Moreover, the disinfection method should be technically simple, scaleable, space-saving, subjected to low maintenance and realized at moderate investment and operating costs without applying external toxic chemicals. Established methods in decentralized wastewater disinfection are mainly based on membrane and UV technologies. However, these methods are currently working under high operating costs (high maintenance and cleaning efforts). Furthermore, the high investment costs of the membrane filtration are disadvantageous. In addition, both methods do not provide a disinfection residual. Thus, further research is required for the development and testing of alternative disinfection technologies. Against this background, the applicability of the electrolysis and UV/electrolysis hybrid technology for the decentralized wastewater reclamation was investigated and assessed in this dissertation. Results have shown that the electrochemical disinfection of biologically treated wastewater represents an efficient method at temperatures of > 6 °C, pH values of < 8.5 and DOC con-centrations of < 22 mg L-1. Under these conditions, an E. coli reduction of four log levels was achieved at a concentration of free chlorine ranging from 0.4 mg L-1 to 0.6 mg L-1 and at an after-reaction time of 15...20 min. However, it becomes simultaneously apparent that low temperatures, high pH values and high DOC concentrations are limiting parameters for this disinfection method to reclaim biologically treated wastewater. A high energy consumption of the electrolysis cell equipped with boron-doped diamond (BDD) electrodes (2...2.6 kWh m-3) represents a further unfavourable effect. Moreover, the undesired formation of chlorate (c = 1.3 mg L-1) and perchlorate (c = 18 mg L-1) at BDD electrodes can be considered as critical, since these disinfection by-products are, amongst others, human-toxicologically relevant. The concentration of adsorbable organically bound halogens (AOX) and trihalomethanes (THMs) proved to be marginal to moderate. Due to the synergistic effect of the combined application of UV irradiation (primary disinfection method) and electrolysis, the disadvantages of the single methods can be compensated. Decisive drawbacks of UV irradiation are photo and dark repair mechanisms of reversibly damaged bacteria. It was observed that the reactivation of reversibly UV-damaged E. coli even occurs at low temperatures (T = 10 °C) and strongly differing pH values (pH = 5.7...8.1) as well as at low light intensities and in darkness to an extent excluding a safe usage and storage of the reclaimed wastewater. The reactivation processes might be lowered by increased UV fluences. However, this is limited by high concentrations of total suspended solids (TSS). In spite of high UV fluences of > 400 J m-1, no complete removal of E. coli bacteria can be achieved at TSS concentrations of > 17 mg L-1. Therefore, it is indispensable to prevent bacterial reactivation caused by photo and dark repair processes. This topic was studied in the current work by electrochemically produced oxidants using an electrolysis cell positioned downstream of the UV unit. Results have shown that photo and dark reactivation were completely prevented by oxidants in a total concentration of 0.5...0.6 mg L-1 at a TSS concentration of 8...11 mg L-1, at pH values ranging from 5.7 to 8.1 and at temperatures ranging from 10 °C to 30 °C (t = 24....72 h). Even at a high TSS concentration of 75 mg L-1, the reactivation of E. coli (ctotal oxidants = 1.8 mg L-1) and, up to a TSS concentration of 32 mg L-1, the reactivation of total coliforms (except E. coli, ctotal oxidants = 1.0 mg L-1) can be prevented at a high initial germ concentration of 2…3 105 per 100 mL. The lowest energy consumption could be observed when mixed oxide electrodes (MOX electrodes) were applied. This result and the fact that no chlorate and perchlorate were observed at MOX electrodes argue for the application of these electrodes in practice. All in all, the UV/electrolysis hybrid technology represents an energy-efficient method for reclamation of biologically treated wastewater with TSS concentrations ranging from < 11 to 32 mg L-1 (E = 0.17…0.24 kWh m-3, MOX electrodes). Thereby, the reclaimed wastewater meet the hygienic quality requirements for a multitude of reuse categories starting from agricultural irrigation to urban and recreational reuse. Moreover, the requirements of the discharge class +H (100 faecal coliforms (E. coli) per 100 mL) are complied with reliably. The operational stability of the UV/electrolysis hybrid technology should also be ensured within the required maintenance intervals (t > 6 months). The undesired formation of coverings caused by biofouling processes on quartz glass surfaces could be prevented by electrochemically produced oxidants in a total concentration of 1 mg L-1 within an experimental duration of 5.5 months. However, the application of the UV/electrolysis hybrid technology is limited by increased particle concentrations and faecal loadings (initial E. coli concentration). The resulting enhanced demand of electrochemically produced oxidants for the prevention of bacterial reactivation results in a considerable increase of the electric charge input and energy consumption.

According to estimates of the United Nations Environment Programme (UNEP), more than 1.8 billion people will be living in countries or regions with absolute water scarcity by 2025. The pressure on water resources is increased not only in arid and semiarid regions, but also in fast growing megacities around the world as a result of, amongst other factors, the changing nutritional and consumer behavior (rising living standards). Over 90 % of the annual water consumption of the newly industrializing and developing countries in the arid and semiarid climate zone is used for agricultural irrigation to ensure the nutrition of the population. Thus, since the beginning of the 20th century, the planned/controlled reuse of wastewater has developed into a central task of the sustainable water resources management. Wastewater represents a valuable resource in view of its composition (e. g. nutrients P, N for soil fertilizing) and its reliable, weather-independent availability in every household. The establishment of a closed-loop water management can enhance the efficiency of water usage. Therefore, activities in research and development are currently focused on decentralized and semi-centralized concepts, since their structures offer better conditions for the establishment of closed-loop systems and innovations in wastewater technology can be implemented more easily. In general, the hygienic quality requirements for wastewater reuse are predominantly oriented towards the planned usage. These are, in turn, regulated by thresholds and guidance values, e. g. for faecal indicator bacteria (e. g. faecal coliforms: E. coli), in widely differing norms and legal provisions specific to the respective countries. In Germany since 2005, small wastewater treatment plants can obtain the discharge class +H by the German Institute for Civil Engineering (DIBt: Deutsches Institut für Bautechnik) if secondary effluents contain less than 100 faecal coliforms (E. coli) per 100 mL. This ensures a safe effluent seepage in karst and water protection areas. Due to the infectious risk caused by a multitude of pathogens (bacteria, viruses, worm eggs, protozoa) which are still contained in wastewater after mechanical-biological treatment, specific disinfection methods are indispensable for their satisfactory reduction. Demands on disinfection methods for wastewater reclamation are quite complex. They should be characterized by a high and constant disinfection efficiency at low or moderate formation of disinfection by-products. The reclaimed wastewater should be able to be stored safely. Moreover, the disinfection method should be technically simple, scaleable, space-saving, subjected to low maintenance and realized at moderate investment and operating costs without applying external toxic chemicals. Established methods in decentralized wastewater disinfection are mainly based on membrane and UV technologies. However, these methods are currently working under high operating costs (high maintenance and cleaning efforts). Furthermore, the high investment costs of the membrane filtration are disadvantageous. In addition, both methods do not provide a disinfection residual. Thus, further research is required for the development and testing of alternative disinfection technologies. Against this background, the applicability of the electrolysis and UV/electrolysis hybrid technology for the decentralized wastewater reclamation was investigated and assessed in this dissertation. Results have shown that the electrochemical disinfection of biologically treated wastewater represents an efficient method at temperatures of > 6 °C, pH values of < 8.5 and DOC con-centrations of < 22 mg L-1. Under these conditions, an E. coli reduction of four log levels was achieved at a concentration of free chlorine ranging from 0.4 mg L-1 to 0.6 mg L-1 and at an after-reaction time of 15...20 min. However, it becomes simultaneously apparent that low temperatures, high pH values and high DOC concentrations are limiting parameters for this disinfection method to reclaim biologically treated wastewater. A high energy consumption of the electrolysis cell equipped with boron-doped diamond (BDD) electrodes (2...2.6 kWh m-3) represents a further unfavourable effect. Moreover, the undesired formation of chlorate (c = 1.3 mg L-1) and perchlorate (c = 18 mg L-1) at BDD electrodes can be considered as critical, since these disinfection by-products are, amongst others, human-toxicologically relevant. The concentration of adsorbable organically bound halogens (AOX) and trihalomethanes (THMs) proved to be marginal to moderate. Due to the synergistic effect of the combined application of UV irradiation (primary disinfection method) and electrolysis, the disadvantages of the single methods can be compensated. Decisive drawbacks of UV irradiation are photo and dark repair mechanisms of reversibly damaged bacteria. It was observed that the reactivation of reversibly UV-damaged E. coli even occurs at low temperatures (T = 10 °C) and strongly differing pH values (pH = 5.7...8.1) as well as at low light intensities and in darkness to an extent excluding a safe usage and storage of the reclaimed wastewater. The reactivation processes might be lowered by increased UV fluences. However, this is limited by high concentrations of total suspended solids (TSS). In spite of high UV fluences of > 400 J m-1, no complete removal of E. coli bacteria can be achieved at TSS concentrations of > 17 mg L-1. Therefore, it is indispensable to prevent bacterial reactivation caused by photo and dark repair processes. This topic was studied in the current work by electrochemically produced oxidants using an electrolysis cell positioned downstream of the UV unit. Results have shown that photo and dark reactivation were completely prevented by oxidants in a total concentration of 0.5...0.6 mg L-1 at a TSS concentration of 8...11 mg L-1, at pH values ranging from 5.7 to 8.1 and at temperatures ranging from 10 °C to 30 °C (t = 24....72 h). Even at a high TSS concentration of 75 mg L-1, the reactivation of E. coli (ctotal oxidants = 1.8 mg L-1) and, up to a TSS concentration of 32 mg L-1, the reactivation of total coliforms (except E. coli, ctotal oxidants = 1.0 mg L-1) can be prevented at a high initial germ concentration of 2…3 105 per 100 mL. The lowest energy consumption could be observed when mixed oxide electrodes (MOX electrodes) were applied. This result and the fact that no chlorate and perchlorate were observed at MOX electrodes argue for the application of these electrodes in practice. All in all, the UV/electrolysis hybrid technology represents an energy-efficient method for reclamation of biologically treated wastewater with TSS concentrations ranging from < 11 to 32 mg L-1 (E = 0.17…0.24 kWh m-3, MOX electrodes). Thereby, the reclaimed wastewater meet the hygienic quality requirements for a multitude of reuse categories starting from agricultural irrigation to urban and recreational reuse. Moreover, the requirements of the discharge class +H (100 faecal coliforms (E. coli) per 100 mL) are complied with reliably. The operational stability of the UV/electrolysis hybrid technology should also be ensured within the required maintenance intervals (t > 6 months). The undesired formation of coverings caused by biofouling processes on quartz glass surfaces could be prevented by electrochemically produced oxidants in a total concentration of 1 mg L-1 within an experimental duration of 5.5 months. However, the application of the UV/electrolysis hybrid technology is limited by increased particle concentrations and faecal loadings (initial E. coli concentration). The resulting enhanced demand of electrochemically produced oxidants for the prevention of bacterial reactivation results in a considerable increase of the electric charge input and energy consumption.