<div> Porous lithium ion battery (LIB) electrodes are comprised of electrochemically active material particles that store lithium and a surrounding conductive binder, liquid electrolyte, carbon black mixture that facilitates ionic and electronic transport. Typically, lithium diffusivity is several orders of magnitude smaller in the active material as compared to the surrounding electrolyte, making the electrode microstructure a governing factor in determining the balance between its lithium storage capacity and transport rate. Here, the effects of microstructure on the performance of LIBs are systematically analyzed at three length scales - the single particle length scale, the spatially resolved multiple particle length scale, and the porous electrode layer (homogenized) length scale. At the single particle length scale, a thermodynamically consistent variational framework is presented to examine the effects of crystallographic anisotropy, crystallographic texture, grain size, and grain morphology on the LiNi_1/3Mn_1/3Co_1/3O₂ (NMC111) chemistry. The theory was extended to the spatially resolved multiple particle length scale and the porous electrode layer length scale to explain the microstructural origin of experimentally observed instances of apparent phase separation in NMC111. At the electrode length scale, a data driven framework is presented to evaluate the electrochemical performance of a wide range of particle morphologies and battery architectures. Specifically, microstructural characteristics of 53 356 microstructures are assessed, and strategies to optimize electrode design parameters such as active particle morphology, spatial orientation, electrode porosity, and cell thickness are presented.</div><p></p>

<div>Many important measurements of low-amplitude instabilities related to hypersonic laminar-turbulent boundary-layer transition have been successfully performed with 1-MHz PCB132 pressure sensors. However, there is large uncertainty in measurements made with PCB132 sensors due to their poorly understood response at high frequency. The current work continues efforts to better characterize the PCB132 sensor with a low-pressure shock tube, using the pressure change across the incident shock as an approximate step input. </div><div> </div><div> New vacuum-control valves provide precise control of pre-run pressures in the shock tube, generally to within 1\% of the desired pressure. Measurements of the static-pressure step across the shock made with Kulite sensors showed high consistency for similar pre-run pressures. Skewing of the incident shock was measured by PCB132 sensors, and was found to be negligible across a range of pressure ratios and static-pressure steps. Incident-shock speed decreases along the shock tube, as expected. Vibrational effects on the PCB132 sensor response are significantly lower in the final section of the driven tube.</div><div> </div><div> Approximate frequency responses were computed from pitot-mode responses. The frequency-response amplitude varied by a factor of 5 between 200--1000 kHz due to significant resonance peaks. Measurements with blinded PCB132 sensors indicate that the resonances in the frequency response are not due to vibration. </div><div> </div><div> Using the approximate frequency response measured with the shock tube to correct the spectra of wind-tunnel data produced inconclusive results. Correcting pitot-mode PCB132 wind-tunnel data removed a possible resonance peak near 700 kHz, but did not agree with the spectrum of a reference sensor in the range of 11--100 kHz. </div>

The purpose of this qualitative case study is to explore the literacy practices of marginalized adolescent youth in India and the relationship of these practices to imagination and identity construction. More than just tools for communication, language and literacy practices allow individuals to express their selves and identities as they voice their thoughts, negotiate meaning (Dyson & Genishi, 2005; Gee, 2003), and enact themselves within society (Janks, 2010; New London Group, 1996). This qualitative case study took place in Lucknow, India; the subjects were a group of adolescent girls at a nonprofit all-girls school in a seventh-grade classroom. Using discourse analysis, the data revealed the ways in which the girls used literacy to agentively position themselves as actual selves in their societies, as imagined social selves and others, in relationship to social others, and in imagined events.

Electroactive polymers are a class of materials capable of reallocating their shape in response to an electric field while also having the ability to harvest electrical energy when the materials are mechanically deformed. Electroactive polymers can therefore be used as sensors, actuators, and energy harvesters. The parameters for manufacturing flexible electroactive polymers are complex and rate limiting due to number of steps, their necessity, and time intensity of each step. Successful additive manufacturing processes for electroactive polymers will allow for scalability and flexibility beyond current limitations, advancing the field, opening additional manufacturing possibilities, and increasing output. The goal for this research was to use additive manufacturing techniques to print conductive and dielectric substrates for building flexible circuits and sensors. Printing flexible conductive layers and substrates together allows for added creativity in design and application.

<div>Modeling methodologies based on state-of-the-art and classic theories of acoustics have been developed to provide a comprehensive toolbox, which can be used to model multilayer systems that involve acoustical and/or damping treatments, and to optimize these treatments' performance by designing their geometrical structures. The objective of this work was to understand, predict and optimize conventional sound absorbing porous media's near-field damping performance, so that automotive and aerospace industries can take full advantage of layered porous treatments' lightness and multi-functionality: i.e., absorption of airborne sound and reduction of structure-borne vibration, for noise control applications. First, acoustical models that include the Transfer Matrix Method and the Arbitrary Coefficient Method were developed to build connections between the bulk properties and acoustical properties of porous media when coupled into layered systems. Given a specified layered system consisting of a vibrating panel and a porous damping treatment, the acoustics models were then incorporated into the Near-field Damping model to predict the acoustical near-field and spatial response of the panel, based on which the near-field damping performance can be evaluated for a limp or an elastic porous layer when applied on different structures including an infinitely-extended panel, a partially-constrained panel, an aircraft fuselage-like structure and a vehicle floor pan-like structure. Furthermore, the relations between the material's microstructural details and bulk properties were established via an Air-Flow Resistivity model for porous media that are made of fibers, and the optimal fiber size that provides the largest damping for certain vibrating structures was identified. Relatively large fibers were found to be better at reducing lower frequency vibrations; fibers made of polymer were found to have manufacturing benefits over fibers made of glass to achieve equivalent optimal damping performance; and elastic fibers were found to have both manufacturing and damping advantages over limp fibers.</div>

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