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Glass and Jute fibers modified with CNT-based functional coatings for high performance compositesTzounis, Lazaros 02 July 2014 (has links) (PDF)
Carbon nanotubes are known as one of the strongest materials in nature and since their discovery; they have triggered the scientific interest for fabricating multi-functional polymer composites. However, a well-known problem associated to the incorporation of nanoparticulate materials in polymer matrices is their tendency to agglomerate in order to reduce their surface energy, and the extreme increase of the polymer viscosities (i.e melts, solutions, etc), which makes it very difficult to process them. Polymers can be efficiently reinforced by fibers for applications where high strength and stiffness are required. Micro-scale short fiber reinforced polymer composites have been an alternative way to obtain fiber reinforced composites since the long fiber incorporation is a painful job and not always feasible and easy to produce composites in big scale.
Therefore, use of long glass fibers as the support for depositing CNTs as well as CNTs+other kind of nanoparticles was made, and the resulting interfaces were investigated in detail by single fiber model composites. This approach can bring the CNT functionality, fiber strength and toughness to the final composite, and simultaneously alleviate the manufacturing process from increase of the polymer high viscosities. Finally, very logically the question of whether to improve or destroy the interface integrity comes before implementing the hybrid hierarchical reinforcements in bigger scales, and an output out of this work will be given. Furthermore, several information and functionalities arising from the CNTs at the interphase region will be elucidated like cure monitoring of the epoxy resin matrix, UV-sensing ability, and thermoelectric energy harvesting, giving rise to multi-functional structural composites. CNT-modified natural fibers also have been utillised to fabricate short fiber reinforced composites, and have shown a promising reinforcement effect due to the CNT nanostructured interfaces.
The ‘interface’ in fiber reinforced polymer composites (FRPCs) is known as a very crucial parameter that has to be considered in the design of a composite with desired properties. Interfaces are often considered as surfaces however, they are in fact zones or areas with compositional, structural, and property gradients, typically varying from that of the fiber and the matrix material. Characterization of the mechanical properties of interfaces is necessary for understanding the mechanical behavior of scaled-up composites. In fact, the mechanical characteristics of a fiber/resin composite depend mainly on i) the mechanical properties of the component materials, ii) the surface of the fiber, and iii) the nature of the fiber/resin bonding as well as the mode of stress transfer at the interface. Among the many factors that govern the characteristics of composites involving a glass, carbon, natural or ceramic fiber, and a macromolecular matrix, the adhesion between fiber and matrix plays a predominant role. In specific, the stress transfer at the interface requires an efficient coupling between fiber and matrix. Therefore, it is important to optimize the interfacial bonding since a direct linkage between fiber and matrix gives rise to a rigid, low impact resistance composite material.
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Comparative evaluation of in vivo biocompatibility and biodegradability of regenerated silk scaffolds reinforced with/without natural silk fibersMobini, Sahba, Taghizadeh-Jahed, Masoud, Khanmohammadi, Manijeh, Moshiri, Ali, Naderi, Mohammad-Mehdi, Heidari-Vala, Hamed, Ashrafi Helan, Javad, Khanjani, Sayeh, Springer, Armin, Akhondi, Mohammad-Mehdi, Kazemnejad, Somaieh 11 October 2019 (has links)
Nowadays, exceptional advantages of silk fibroin over synthetic and natural polymers have impelled the scientists to application of this biomaterial for tissue engineering purposes. Recently, we showed that embedding natural degummed silk fibers in regenerated Bombyx mori silk-based scaffold significantly increases the mechanical stiffness, while the porosity of the scaffolds remains the same. In the present study, we evaluated degradation rate, biocompatibility and regenerative properties of the regenerated 2% and 4% wt silk-based composite scaffolds with or without embedded natural degummed silk fibers within 90 days in both athymic nude and wild-type C57BL/6 mice through subcutaneous implantation. In all scaffolds, a suitable interconnected porous structure for cell penetration was seen under scanning electron microscopy. Compressive tests revealed a functional relationship between fiber reinforcement and compressive modulus. In addition, the fiber/fibroin composite scaffolds support cell attachment and proliferation. On days 30 to 90 after subcutaneous implantation, the retrieved tissues were examined via gross morphology, histopathology, immunofluorescence staining and reverse transcription-polymerase chain reaction as shown in Figure 1. Results showed that embedding the silk fibers within the matrix enhances the biodegradability of the matrix resulting in replacement of the composite scaffolds with the fresh connective tissue. Fortification of the composites with degummed fibers not only regulates the degradation profile but also increases the mechanical performance of the scaffolds. This report also confirmed that pore size and structure play an important role in the degradation rate. In conclusion, the findings of the present study narrate key role of additional surface area in improving in vitro and in vivo biological properties of the scaffolds and suggest the potential ability of these fabricated composite scaffolds for connective tissue regeneration.
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Glass and Jute fibers modified with CNT-based functional coatings for high performance compositesTzounis, Lazaros 16 May 2014 (has links)
Carbon nanotubes are known as one of the strongest materials in nature and since their discovery; they have triggered the scientific interest for fabricating multi-functional polymer composites. However, a well-known problem associated to the incorporation of nanoparticulate materials in polymer matrices is their tendency to agglomerate in order to reduce their surface energy, and the extreme increase of the polymer viscosities (i.e melts, solutions, etc), which makes it very difficult to process them. Polymers can be efficiently reinforced by fibers for applications where high strength and stiffness are required. Micro-scale short fiber reinforced polymer composites have been an alternative way to obtain fiber reinforced composites since the long fiber incorporation is a painful job and not always feasible and easy to produce composites in big scale.
Therefore, use of long glass fibers as the support for depositing CNTs as well as CNTs+other kind of nanoparticles was made, and the resulting interfaces were investigated in detail by single fiber model composites. This approach can bring the CNT functionality, fiber strength and toughness to the final composite, and simultaneously alleviate the manufacturing process from increase of the polymer high viscosities. Finally, very logically the question of whether to improve or destroy the interface integrity comes before implementing the hybrid hierarchical reinforcements in bigger scales, and an output out of this work will be given. Furthermore, several information and functionalities arising from the CNTs at the interphase region will be elucidated like cure monitoring of the epoxy resin matrix, UV-sensing ability, and thermoelectric energy harvesting, giving rise to multi-functional structural composites. CNT-modified natural fibers also have been utillised to fabricate short fiber reinforced composites, and have shown a promising reinforcement effect due to the CNT nanostructured interfaces.
The ‘interface’ in fiber reinforced polymer composites (FRPCs) is known as a very crucial parameter that has to be considered in the design of a composite with desired properties. Interfaces are often considered as surfaces however, they are in fact zones or areas with compositional, structural, and property gradients, typically varying from that of the fiber and the matrix material. Characterization of the mechanical properties of interfaces is necessary for understanding the mechanical behavior of scaled-up composites. In fact, the mechanical characteristics of a fiber/resin composite depend mainly on i) the mechanical properties of the component materials, ii) the surface of the fiber, and iii) the nature of the fiber/resin bonding as well as the mode of stress transfer at the interface. Among the many factors that govern the characteristics of composites involving a glass, carbon, natural or ceramic fiber, and a macromolecular matrix, the adhesion between fiber and matrix plays a predominant role. In specific, the stress transfer at the interface requires an efficient coupling between fiber and matrix. Therefore, it is important to optimize the interfacial bonding since a direct linkage between fiber and matrix gives rise to a rigid, low impact resistance composite material.
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Funktionsintegrative Leichtbaustrukturen für Tragwerke im Bauwesen / Function-integrated lightweight structures in architectureGelbrich, Sandra 17 January 2018 (has links) (PDF)
In den letzten Jahren gewinnt der Leichtbau im Bauwesen im Zuge der Ressourceneinsparung wieder stärker an Bedeutung, denn ohne eine deutliche Steigerung der Effizienz ist zukunfts-fähiges Bauen und Wohnen nur schwer zu bewerkstelligen. Optimiertes Bauen, im Sinne der Errichtung und Unterhaltung von Bauwerken mit geringem Einsatz an Material, Energie und Fläche über den gesamten Lebenszyklus eines Gebäudes hinweg, bedarf des Leichtbaus in punkto Material, Struktur und Technologie.
In der vorliegenden Arbeit wird ein wissenschaftlicher Überblick zum aktuellen Stand der eigenen Forschungen in Bezug auf funktionsintegrativen Leichtbau im Bauwesen gegeben sowie erweiterte Methoden und Ansätze abgeleitet, die eine Konzeption, Bemessung und Erprobung von neuartigen Hochleistungs-Tragstrukturen in Leichtbauweise gestatten. Dabei steht die Entwicklung leistungs-starker und zugleich multifunktionaler Werkstoffkombinatio-nen und belastungsgerecht dimensionierter Strukturkomponenten unter dem Aspekt der Gewichtsminimalität in Material und Konstruktion im Fokus. Ein breit gefächertes Eigen-schaftsprofil für \"maßgeschneiderte\" Leichtbauanwendungen besitzen textilverstärkte Ver-bundbauteile, denn sowohl die Fadenarchitektur als auch die Matrix können in weiten Berei-chen variiert und an die im Bauwesen vorliegenden komplexen Anforderungen angepasst werden. In der vorliegenden Arbeit werden hierzu vor allem Methoden und Lösungen anhand von Beispielen zu: multifunktionalen Faser-Kunststoff-Verbunden (FKV), funktionsintegrier-ten faserverstärkten mineralischen Tragelemente und Verbundstrukturen in textilbewehrter Beton-GFK-Hybridbauweise betrachtet. Von zentraler Bedeutung ist dabei die Schaffung von materialtechnischen, konstruktiven und technologischen Grundlagen entlang der gesamten Wertschöpfungskette – von der Leichtbauidee über Demonstrator und Referenzobjekt bis hin zur technologischen Umsetzung zur Überführung der Forschungsergebnisse in die Praxis. / In the last few years, lightweight construction in the building sector has gained more and more importance in the course of resource saving. Without a significant increase in efficiency, future-oriented construction and resource-conserving living is difficult to achieve. Optimized building, in the sense of the erection and maintenance of buildings with little use of material, energy and surface over the entire life time cycle of a building, requires lightweight design in terms of material, structure and technology.
In this thesis, a scientific overview of the current state of research on function-integrative light-weight construction in architecture is presented. Furthermore, advanced methods and research approaches were developed and applied, that allows the design, dimensioning and testing of novel high-performance supporting structures in lightweight design. The focus is on the development of high-performance, multi-functional material combinations and load-adapted structural elements, under the aspect of weight minimization in material and construction. Textile-reinforced composites have a broad range of material properties for optimized \"tailor-made\" lightweight design applications, since the thread architecture as well as the matrix can be varied within wide ranges and can adapted to the complex requirements in the building industry.
Within the scope of this thesis, methods and solutions are examined in the field of: multifunc-tional fiber-reinforced plastics (FRP), function-integrated fiber-reinforced composites with mineral matrix (TRC) and textile-reinforced hybrid composites (BetoTexG: combination of TRC and FRP). In this connection the creation of material, structural and technological foundations along the entire value chain is of central importance: From the lightweight design idea to the demonstrator and reference object, to the technological implementation for the transfer of the research results into practice.
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Funktionsintegrative Leichtbaustrukturen für Tragwerke im BauwesenGelbrich, Sandra 10 November 2016 (has links)
In den letzten Jahren gewinnt der Leichtbau im Bauwesen im Zuge der Ressourceneinsparung wieder stärker an Bedeutung, denn ohne eine deutliche Steigerung der Effizienz ist zukunfts-fähiges Bauen und Wohnen nur schwer zu bewerkstelligen. Optimiertes Bauen, im Sinne der Errichtung und Unterhaltung von Bauwerken mit geringem Einsatz an Material, Energie und Fläche über den gesamten Lebenszyklus eines Gebäudes hinweg, bedarf des Leichtbaus in punkto Material, Struktur und Technologie.
In der vorliegenden Arbeit wird ein wissenschaftlicher Überblick zum aktuellen Stand der eigenen Forschungen in Bezug auf funktionsintegrativen Leichtbau im Bauwesen gegeben sowie erweiterte Methoden und Ansätze abgeleitet, die eine Konzeption, Bemessung und Erprobung von neuartigen Hochleistungs-Tragstrukturen in Leichtbauweise gestatten. Dabei steht die Entwicklung leistungs-starker und zugleich multifunktionaler Werkstoffkombinatio-nen und belastungsgerecht dimensionierter Strukturkomponenten unter dem Aspekt der Gewichtsminimalität in Material und Konstruktion im Fokus. Ein breit gefächertes Eigen-schaftsprofil für \"maßgeschneiderte\" Leichtbauanwendungen besitzen textilverstärkte Ver-bundbauteile, denn sowohl die Fadenarchitektur als auch die Matrix können in weiten Berei-chen variiert und an die im Bauwesen vorliegenden komplexen Anforderungen angepasst werden. In der vorliegenden Arbeit werden hierzu vor allem Methoden und Lösungen anhand von Beispielen zu: multifunktionalen Faser-Kunststoff-Verbunden (FKV), funktionsintegrier-ten faserverstärkten mineralischen Tragelemente und Verbundstrukturen in textilbewehrter Beton-GFK-Hybridbauweise betrachtet. Von zentraler Bedeutung ist dabei die Schaffung von materialtechnischen, konstruktiven und technologischen Grundlagen entlang der gesamten Wertschöpfungskette – von der Leichtbauidee über Demonstrator und Referenzobjekt bis hin zur technologischen Umsetzung zur Überführung der Forschungsergebnisse in die Praxis. / In the last few years, lightweight construction in the building sector has gained more and more importance in the course of resource saving. Without a significant increase in efficiency, future-oriented construction and resource-conserving living is difficult to achieve. Optimized building, in the sense of the erection and maintenance of buildings with little use of material, energy and surface over the entire life time cycle of a building, requires lightweight design in terms of material, structure and technology.
In this thesis, a scientific overview of the current state of research on function-integrative light-weight construction in architecture is presented. Furthermore, advanced methods and research approaches were developed and applied, that allows the design, dimensioning and testing of novel high-performance supporting structures in lightweight design. The focus is on the development of high-performance, multi-functional material combinations and load-adapted structural elements, under the aspect of weight minimization in material and construction. Textile-reinforced composites have a broad range of material properties for optimized \"tailor-made\" lightweight design applications, since the thread architecture as well as the matrix can be varied within wide ranges and can adapted to the complex requirements in the building industry.
Within the scope of this thesis, methods and solutions are examined in the field of: multifunc-tional fiber-reinforced plastics (FRP), function-integrated fiber-reinforced composites with mineral matrix (TRC) and textile-reinforced hybrid composites (BetoTexG: combination of TRC and FRP). In this connection the creation of material, structural and technological foundations along the entire value chain is of central importance: From the lightweight design idea to the demonstrator and reference object, to the technological implementation for the transfer of the research results into practice.
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