This dissertation explores the reflexive and performative practices found in Mocha Jean Herrup's documentary work, POM, LESBIANFILM, and A FEW GOOD DYKES. By exploiting realism's failure to ever fully represent, reflexive and performative techniques enable a queer discourse. These techniques create 1) a parodic premise that calls attention to the disjunction between documentary's legitimizing conventions and queer as a viable subject, 2) a subjectification of the insider-outsider that troubles distinctions between the audience and the subject and the filmmaker and the subject, and 3) enables the embodied knowledge of queer subjectivity to emerge. / text

This thesis is devoted to the calculation of thermal contact resistance in various molecular systems based on carbon nanotubes (CNTs) and few layer graphene (FLG). This work has been performed through equilibrium molecular dynamics (EMD) simulations. We adopted the temperature difference fluctuations method in our EMD calculations. This method only needs the input of the temperatures of the subsystems whereas the heat flux, which is involved in all the other approaches, remains more difficult to compute in terms of simulation time and algorithm. Firstly, three cases were studied to validate this method, namely: (i) Si/Ge superlattices; (ii) diameter modulated SiC nanowires; and (iii) few-layer graphenes. The validity of the temperature difference fluctuations method is proved by equilibrium and non-equilibrium MD simulations. Then, by using this method, we show that an azide-functionalized polymer (HLK5) has a lower contact resistance with CNT than the one between CNT and PEMA, because HLK5 could form covalent bonds (C-N bonds) with CNT through its tail group azide, while only weak Van der Waals interactions exist in the case of CNT-PEMA contact. The data from our EMD simulations match with the results from experiments in a reasonable range. We then report the thermal contact resistance between FLG and a SiO2 substrate, which could be tuned with the layer number. Taking advantage of the resistive interface, we show that a SiO2 /FLG superlattices have a thermal conductivity as low as 0.30 W/mK, exhibiting a promising prospect in nano-scale thermal insulation. In the last part, we investigated the layer number dependence of the cross-plane thermal resistances of suspended and supported FLGs. We show that the existence of a silicon dioxide substrate can significantly decrease the cross-plane resistances of FLGs with low layer numbers, and the effective thermal conductivities were increased accordingly. The Frenkel-Kontorova model was introduced to explain the substrate-induced band gaps in FLG dispersion relations and the corresponding thermal energy transfer. The enhanced thermal conduction in the cross-plane direction is ascribed to the phonon radiation that occurs at the FLG-substrate interface, which re-distributes the FLG in-plane propagating energy to the cross-plane direction and to the substrate.

The work in this thesis is motivated by the problem of localization of interacting particles. The qualitative investigation of Thouless-type arguments in Chap.~\ref{ch:interacting-particles} lead us to consider the question of competition between alternative propagation channels, a question which we studied in great detail in the form of a single particle problem with two parallel, coupled channels. The theory also naturally applies for the Anderson localization of hybrid particles such as polaritons. These systems have a common feature: Two or more propagating channels with parametrically different transport properties are coupled and compete with each other. The principal question is: What happens to the localization properties when a less localized lattice is coupled to a more localized one? Will the less localized lattice dominate the localization of the system or the more localized? The qualitative answer to this question depends on the dimensionality of the system. Correspondingly, we exactly solved the Anderson models on a two-leg ladder ($D=1$) and on a two-layer Bethe lattice (formally $D=\infty$). In one dimension, weak disorder has a strong localization effect. In the \emph{weak disorder limit} we have found that under \emph{resonance} conditions the localization lengths of two coupled chains are of the order of the localization length of the more localized, uncoupled leg. We may interpret this phenomenon as a manifestation of the fact that in one dimension the mean free path is the relevant length scale that sets the localization length. It is not surprising that the backscattering rate, and thus the ''worst'' leg of the chains determines the localization properties of a coupled system. If away from resonance the two legs are hardly affected by each other. However, the close relation (proportionality) between mean free path and localization length is special for one-dimensional systems. On coupled Bethe lattices, weak disorder is irrelevant to localization. The localization effect is significant only if the disorder is intermediate or strong. Therefore, resonance conditions, which require weak disorder as compared to the hopping, can not be achieved. In general, we found that the less disordered lattice is not affected much by the more disordered lattice in the presence of coupling, except in the case where the less disordered (delocalized) lattice is very close to the transition and the more disordered lattice is strongly localized, in which case the more disordered lattice can push the less disordered lattice to a localized phase. We believe that these trends persist in high dimensions ($D>2$) where the metal-insulator transition takes places at strong disorder. In two dimensions, the localization length becomes parametrically larger than the mean free path at weak disorder. However, since the proliferation of weak-localization and backscattering leads to complete localization (in the absence of special symmetries), we expect that a well propagating channel becomes more strongly localized upon resonant coupling to a more disordered channel, similarly as in one dimension. It might be interesting to investigate this numerically. Investigating the localization properties of few- or many-particle systems is more complicated. First, we should map an interacting Hamiltonian to the Anderson model in the few- many-particle Fock space [cf. Eq.~\ref{ipfham}]. Thereby, the interaction provides effective hopping among the Fock states. This hopping in Fock space can be organized into channels with rather different propagation characteristics [e.g. Fig.~\ref{four-par} for four particles], namely, faster channels and slower channels. According to our analysis, the slow channel dominates only if it is \emph{resonantly} coupled to the fast channel. If the two channels are away from resonance, the fast channel essentially dominates the localization properties. For the few-particle problems discussed in Chap.~\ref{ch:interacting-particles} we expect that the fast channel, that is, the hierarchical structure we predicted, dominates the delocalization of the interacting particles, since the resonance between the fast and slow channels should be an exception rather than a rule. At this stage, this remains a conjecture which needs to be tested further.

This thesis addresses the problem of representing few group, homogenised neutron cross sections as a function of state parameters (e.g. burn-up, fuel and moderator temperature, etc.) that describe the conditions in the reactor. The problem is multi-dimensional and the cross section samples, required for building the representation, are the result of expensive transport calculations. At the same time, practical applications require high accuracy. The representation method must therefore be efficient in terms of the number of samples needed for constructing the representation, storage requirements and cross section reconstruction time. Sparse grid methods are proposed for constructing such an efficient representation. Approximation through quasi-regression as well as polynomial interpolation, both based on sparse grids, were investigated. These methods have built-in error estimation capabilities and methods for optimising the representation, and scale well with the number of state parameters. An anisotropic sparse grid integrator based on Clenshaw-Curtis quadrature was implemented, verified and coupled to a pre-existing cross section representation system. Some ways to improve the integrator’s performance were also explored. The sparse grid methods were used to construct cross section representations for various Light Water Reactor fuel assemblies. These reactors have different operating conditions, enrichments and state parameters and therefore pose different challenges to a representation method. Additionally, an example where the cross sections have a different group structure, and were calculated using a different transport code, was used to test the representation method. The built-in error measures were tested on independent, uniformly distributed, quasi-random sample points. In all the cases studied, interpolation proved to be more accurate than approximation for the same number of samples. The primary source of error was found to be the Xenon transient at the beginning of an element’s life (BOL). To address this, the domain was split along the burn-up dimension into “start-up” and “operating” representations. As an alternative, the Xenon concentration was set to its equilibrium value for the whole burn-up range. The representations were also improved by applying anisotropic sampling. It was concluded that interpolation on a sparse grid shows promise as a method for building a cross section representation of sufficient accuracy to be used for practical reactor calculations with a reasonable number of samples. / Thesis (MSc Engineering Sciences (Nuclear Engineering))--North-West University, Potchefstroom Campus, 2013.

This thesis addresses the problem of representing few group, homogenised neutron cross sections as a function of state parameters (e.g. burn-up, fuel and moderator temperature, etc.) that describe the conditions in the reactor. The problem is multi-dimensional and the cross section samples, required for building the representation, are the result of expensive transport calculations. At the same time, practical applications require high accuracy. The representation method must therefore be efficient in terms of the number of samples needed for constructing the representation, storage requirements and cross section reconstruction time. Sparse grid methods are proposed for constructing such an efficient representation. Approximation through quasi-regression as well as polynomial interpolation, both based on sparse grids, were investigated. These methods have built-in error estimation capabilities and methods for optimising the representation, and scale well with the number of state parameters. An anisotropic sparse grid integrator based on Clenshaw-Curtis quadrature was implemented, verified and coupled to a pre-existing cross section representation system. Some ways to improve the integrator’s performance were also explored. The sparse grid methods were used to construct cross section representations for various Light Water Reactor fuel assemblies. These reactors have different operating conditions, enrichments and state parameters and therefore pose different challenges to a representation method. Additionally, an example where the cross sections have a different group structure, and were calculated using a different transport code, was used to test the representation method. The built-in error measures were tested on independent, uniformly distributed, quasi-random sample points. In all the cases studied, interpolation proved to be more accurate than approximation for the same number of samples. The primary source of error was found to be the Xenon transient at the beginning of an element’s life (BOL). To address this, the domain was split along the burn-up dimension into “start-up” and “operating” representations. As an alternative, the Xenon concentration was set to its equilibrium value for the whole burn-up range. The representations were also improved by applying anisotropic sampling. It was concluded that interpolation on a sparse grid shows promise as a method for building a cross section representation of sufficient accuracy to be used for practical reactor calculations with a reasonable number of samples. / Thesis (MSc Engineering Sciences (Nuclear Engineering))--North-West University, Potchefstroom Campus, 2013.

The last works of Jane Austen and Barbara Pym, written while each was knowingly dying, both continue and transform a discourse of illness and cure traceable through their canon. Illness figures both literally and metaphorically in their narratives; in Austen as failures in wholeness and in Pym as failures in love. After undergoing the metaphorically medical treatments of purging and vivifying in Austen and inoculating in Pym, their female protagonists achieve conditions of health and wholeness by closure of the narrative. In the dying works, individual metaphorical illnesses become a general societal condition of fragmentation, and cure becomes more elusive. The shared use of a village undergoing profound change reflects each writer's own bodily transformation as certain death approaches, and the restoration of health to the village-as-body becomes one of achieving balance or homeostasis. This is effected in the narrative by the hinted-at curative powers of nature in Sanditon and of restored faith in A Few Green Leaves. On a theoretical level, both texts reflect their narratives of dis-ease and cure. Pym's last text remained unpublished before her death and therefore "ill" because not functioning, but second opinions and faith in her reputation confirmed its public health. Austen's Sanditon as a fragment embodies its own discourse of dis-ease, or failure of wholeness, and requires a curative act on the part of the reader to restore it to some sense of ideal wholeness or health.

Thesis (Ph. D.)--Missouri University of Science and Technology, 2010. / Vita. The entire thesis text is included in file. Title from title screen of thesis/dissertation PDF file (viewed April 21, 2010) Includes bibliographical references (p. 82-87).

Submitted by JOHN HADDER SANDOVAL QUESADA null (jsandoval@ift.unesp.br) on 2016-03-21T13:14:37Z No. of bitstreams: 1 Thesis.pdf: 687348 bytes, checksum: 6368301fa02619d10860d9db3bec7418 (MD5) / Approved for entry into archive by Juliano Benedito Ferreira (julianoferreira@reitoria.unesp.br) on 2016-03-22T14:28:16Z (GMT) No. of bitstreams: 1 quesada_jhs_me_ift.pdf: 687348 bytes, checksum: 6368301fa02619d10860d9db3bec7418 (MD5) / Made available in DSpace on 2016-03-22T14:28:16Z (GMT). No. of bitstreams: 1 quesada_jhs_me_ift.pdf: 687348 bytes, checksum: 6368301fa02619d10860d9db3bec7418 (MD5) Previous issue date: 2016-01-28 / Outra / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / Este trabalho foca no estudo de sistemas de poucos corpos em duas dimensões no regime universal, onde as propriedades do sistema quântico independem dos detalhes da interação de curto alcance entre as partículas (o comprimento de espalhamento de dois corpos é muito maior que o alcance do potencial). Nós utilizamos a decomposição de Faddeev para escrever as equações para os estados ligados. Através da solução numérica dessas equações nós calculamos as energias de ligação e os raios quadráticos médios de um sistema composto por dois bósons (A) e uma partícula diferente (B). Para uma razão de massas mB/mA = 0.01 o sistema apresenta oito estados ligados de três corpos, os quais desaparecem um por um conforme aumentamos a razão de massas restando somente os estados fundamental e primeiro excitado. Os comportamentos das energias e dos raios para razões de massa pequenas podem ser entendidos através de um potencial do tipo Coulomb a curtas distâncias (onde o estado fundamental está localizado) que aparece quando utilizamos uma aproximação de Born-Oppenheimer. Para grandes razões de massa os dois estados ligados restantes são consistentes com uma estrutura de três corpos mais simétrica. Nós encontramos que no limiar da razão de massas em que os estados desaparecem os raios divergem linearmente com as energias de três corpos escritas em relação ao limiar de dois corpos. / This work is focused in the study of two dimensional few-body physics in the universal regime, where the properties of the quantum system are independent on the details of the short-range interaction between particles (the two-body scatter- ing length is much larger than the range of the potential). We used the Faddeev decomposition to write the bound-state equations and we calculated the three-body binding energies and root-mean-square (rms) radii for a three-body system in two dimensions compounded by two identical bosons (A) and a different particle (B). For mass ratio mB/mA = 0.01 the system displays eight three-body bound states, which disappear one by one as the mass ratio is increased leaving only the ground and the first excited states. Energies and radii of the states for small mass ratios can be understood quantitatively through the Coulomb-like Born-Oppenheimer potential at small distances where the lowest-lying of these states are located. For large mass ratio the radii of the two remaining bound states are consistent with a more sym- metric three-body structure. We found that the radii diverge linearly at the mass ratio threshold where the three-body excited states disappear. The divergences are linear in the inverse energy deviations from the corresponding two-body thresholds. / MEC: 243164-72 / MEC: 243745-72

Cette thèse se concentre sur le calcul des résistances thermique de contact dans plusieurs systèmes moléculaires à base de nanotubes de carbone (NTCs) et de quelques couches de graphène (QCG). Ce travail a été réalisé en utilisant la méthode de simulation par dynamique moléculaire à l’équilibre (DME). Nous avons utilisé la méthode basée sur les fluctuations de la différence de température dans nos simulations de DME. Cette méthode ne nécessite que l’entrée des températures des sous-systèmes quand le flux thermique, qui intervient dans toutes les autres approches, reste plus difficile à calculer en terme de durée de simulation et d’algorithme. Premièrement, trois cas ont été étudiés pour valider cette méthode : (i) des super-réseaux Si/Ge ; (ii) des nanofils de SiC de plusieurs diamètres ; et (iii) QCGs. La validité de la méthode par fluctuation de la différence de température est démontrée par des simulations de dynamique moléculaire à l’équilibre et hors-équilibre. Ensuite, avec cette méthode, nous montrons qu’un polymère fonctionnalisé azoture (HLK5) a une plus faible résistance de contact avec un NTC que la résistance entre un NTC et un PEMA, car HLK5 forme des liaisons covalentes (C-N bonds) avec un NTC par le groupement azoture de sa queue, quand seul de faibles interactions de van der Waals existent dans le cas d’un contact NTC-PEMA. Les données de nos simulations de DME concordent raisonnablement avec les résultats expérimentaux. Nous rapportons ensuite la résistance thermique de contact entre QCG et un substrat de SiO2, qui peut être contrôlée par le nombre de couches de graphène. Avec l’avantage d’une interface résistante, nous montrons que des super-réseaux SiO2/QCG ont une conductivité thermique descendant sous 0.30 W/mK, ce qui est une perspective prometteuse pour l’isolation thermique à l’échelle du nanomètre. Dans la dernière partie, nous recherchons la dépendance de la résistance thermique inter-plan avec le nombre de couches de graphène pour des QCG suspendus ou supportés. Nous montrons que la présence d’un substrat de dioxyde de silicium peut significativement réduire les résistances inter-plan de QCG possédant peu de couches de graphène, et la conductivité thermique effective est augmentée en accord. Le modèle de Frenkel-Kontorova a été introduit pour expliquer les bandes interdites induites par le substrat dans la relation de dispersion de QCG et le transfert d’énergie thermique correspondant. L’augmentation de la conduction thermique inter-plan est attribuée au rayonnement de phonons à l’interface QCG-substrat, qui redistribue l’énergie se propageant dans le plan du QCG en énergie dans la direction inter-plan et dans le substrat. / This thesis is devoted to the calculation of thermal contact resistance in various molecular systems based on carbon nanotubes (CNTs) and few layer graphene (FLG). This work has been performed through equilibrium molecular dynamics (EMD) simulations. We adopted the temperature difference fluctuations method in our EMD calculations. This method only needs the input of the temperatures of the subsystems whereas the heat flux, which is involved in all the other approaches, remains more difficult to compute in terms of simulation time and algorithm. Firstly, three cases were studied to validate this method, namely: (i) Si/Ge superlattices; (ii) diameter modulated SiC nanowires; and (iii) few-layer graphenes. The validity of the temperature difference fluctuations method is proved by equilibrium and non-equilibrium MD simulations. Then, by using this method, we show that an azide-functionalized polymer (HLK5) has a lower contact resistance with CNT than the one between CNT and PEMA, because HLK5 could form covalent bonds (C-N bonds) with CNT through its tail group azide, while only weak Van der Waals interactions exist in the case of CNT-PEMA contact. The data from our EMD simulations match with the results from experiments in a reasonable range. We then report the thermal contact resistance between FLG and a SiO2 substrate, which could be tuned with the layer number. Taking advantage of the resistive interface, we show that a SiO2 /FLG superlattices have a thermal conductivity as low as 0.30 W/mK, exhibiting a promising prospect in nano-scale thermal insulation. In the last part, we investigated the layer number dependence of the cross-plane thermal resistances of suspended and supported FLGs. We show that the existence of a silicon dioxide substrate can significantly decrease the cross-plane resistances of FLGs with low layer numbers, and the effective thermal conductivities were increased accordingly. The Frenkel-Kontorova model was introduced to explain the substrate-induced band gaps in FLG dispersion relations and the corresponding thermal energy transfer. The enhanced thermal conduction in the cross-plane direction is ascribed to the phonon radiation that occurs at the FLG-substrate interface, which re-distributes the FLG in-plane propagating energy to the cross-plane direction and to the substrate.

Au delà du graphène, de nouveaux semiconducteurs 2D tels que MoS2, GaS, GaSe et InSe deviennent pertinents pour les applications et dispositifs émergents. Dans cette thèse, nous fabriquons des échantillons de quelques feuillets atomiques de ces matériaux pour des dispositifs de photo-détecteurs et les caractérisons par microscopie optique, AFM et TEM. L'interaction de la lumière avec le substrat et le dispositif ultra-mince étant critique pour son fonctionnement, nous calculons et mesurons le contraste et l'intensité de la lumière diffusée par le dispositif. Nous caractérisons également la réponse Raman et la photoluminescence en fonction du nombre de couches pour étudier les propriétés vibrationnelles et électroniques. Plusieurs dispositifs ont été fabriqués et analysés. Nous examinons d'abord les dispositifs homogènes basés sur MoS2, GaSe ou InSe, et trouvons une excellente photosensibilité pour notre photo-détecteur MoS2. Nous examinons ensuite plusieurs hétéro-structures pour combiner les propriétés de chaque matériau et atteindre de meilleures performances. Le premier exemple est un photo-détecteur graphène/InSe dont la photosensibilité augmente de quatre ordres de grandeur par rapport à un dispositif basés sur InSe seul. Nous montrons également que la couche supérieure de graphène prévient la dégradation de couches atomiques ultra-minces dans l'air. Des hétéro-structures plus complexes graphène/InSe/graphène et graphène/InSe/Au montrent un effet photovoltaïque. Enfin, nous combinons InSe avec MoS2 et obtenons un dispositifs avec photo-réponse rapide, un comportement de type photo-diode, une distribution de photo-courant uniforme et un fort effet photovoltaïque. / Novel two dimensional (2D) semiconductors beyond graphene such as MoS2, GaS, GaSe and InSe are increasingly relevant for emergent applications and devices. In this thesis, we fabricate these 2D samples for photo-detector applications and characterize them with optical microscopy, atomic force microscopy, Raman and photoluminescence (PL) spectroscopy and transmission electron microscopy. Since the interaction of light with the substrate and the ultra-thin photodetector device is critical for its functioning we calculate and measure optical contrast and intensity of light scattered from the device. We also characterize the Raman and PL response as a function of number of layers to study both vibrational properties and the band gap transition. For the device application, we first examine homogenous devices based on few-layer MoS2, GaSe and InSe respectively and find an excellent photoresponsivity in our few-layer MoS2 photo-detector. We then examine several geometries for heterostructure devices, which have the advantage of combining favorable properties of each material to reach better performances. The first example is a graphene/InSe photo-detector where the photoresponsivity increases by four orders of magnitude with respect to a few-layer InSe device while the top graphene layer is also shown to prevent degradation of ultra-thin atomic layers in air. Still more complex graphene/InSe/graphene and graphene/InSe/Au heterostructures show a photovoltaic effect. Finally for the first time, we combine InSe with MoS2 and obtain a high performance device with fast photo-response, photodiode like behavior, uniform photocurrent distribution and high photovoltaic effect.