A novel hierarchical flexing and stretching strategy for rigid semiconducting substrates was devised. Architectures for comprehensively compliant semiconductors were created as a result. Si and GaN-on-Si have been segmented into both highly flexible and rigid segments. An advanced controlled cleavage technique has been integrated into the manufacturing process. The bending radius of the substrate has been decoupled from the substrate thickness thus allowing for higher mechanical stability, while achieving bending radii below 250 .m. Novel fabrication workflows have been created, one of which is completely compatible with CMOS fabrication techniques, while still being cost effective. Each of the rigid segments have been designed to carry in excess of its own weight. The reliability of the interconnecting springs was examined by rugged cyclic bending and twisting tests. Finite element simulations in COMSOL exhibited no stress for the rigid segments. For the first time a flexible and/or stretchable Si substrate has been integrated with pick and place tool technology. Additionally the platform serves as a More-than-Moore technology, by folding the monocrystalline substrate on top of itself, while routing power through the flexible segments. This More-than-Moore (MtM) technology has the advantages of System-in-Package (SiP) but does not have the additional costs. From this compliant approach a qubic 4D electronic platform was created. An aerially deployable electronic system was achieved by incorporating thermal paste into the qubic platform. Energy storage, sensing, and actuating were successfully tested on the system. Buried cavities for microfluidics were developed for on-chip chemical and biological processes. A platform was developed for µTF-SOFCs deposition. Cavities were interconnected subterraneously and columnar anodes were developed to enhance the fuel flow in the fuel cell electrode. The triple phase boundary (TPB) was enhanced by over an order of magnitude in comparison to standard processing techniques. A subsequent, microfluidic platform was developed for biological applications. The wettability of the platform gave good results for water, as well as for neurobasal media buffer. Tests indicate that neurons can grow directly on the platform.

No description available.

Wide bandgap semiconductor visible light-emitting diodes (LED) development has spawned the prestigious Nobel Prize in Physics in 2014. Building upon this success, the scope of research has expanded to ultrawide bandgap semiconductors, which possess immense potential in the realm of deep ultraviolet (DUV) photonics. These materials have gained attention for their applicability in various areas, including public sterilization, solar-blind DUV communication, and real-time monitoring. Leveraging on the unique ultrawide tunable bandgap property, highly crystalline capability, and robust behavior, group III-Oxide and III-Nitride semiconductors were employed for sensitive DUV photodetector (PD) and efficient DUV emission, respectively. The primary research are as follows: • III-Oxide heteroepitaxial growth optimization: The influences of substrate temperature, laser energy, and oxygen pressure for the Ga2O3 growth are systematically investigated. Furthermore, the doping capability, multi-phase availability, and bandgap tunability are demonstrated. • Flexible Ga2O3 film growth and electronic devices: Flexible Mica substrate is employed to epitaxially grow κ-phase Ga2O3 thin film. The fabricated flexible PD has an Iphoton/Idark ratio of over 107 under DUV luminescence. The fatigue test performed with 1-3 cm bending radii and 10,000 bending cycles exhibits the robust flexibility of the demonstrated DUV PD. • Transferable Ga2O3 membrane for vertical electronics: Mica as a Ga2O3 growth platform enables the large-scale transfer of ultra-thin Ga2O3 membrane from mica to arbitrary tape due to the weak interfacial bond energy. A vertical and self-powered PD is demonstrated with a responsivity of 17 mA/W under DUV illumination and 0 V bias. • Interfacial mismatch engineering for freestanding Ga2O3 membrane: Looking beyond the hetero-mismatch and engineering the interfacial thermal strain between Si-doped Ga2O3 and AlN could result in the exfoliation of freestanding ultrathin Ga2O3 membrane, allowing vertical device configuration and preferable thermal management. The exfoliation mechanism has been clarified and vertical DUV PD with high on/off ratio is demonstrated. • Efficient III-Nitride LEDs: Buried polarization-induced tunneling junction is employed to suppress electron overflow and simultaneously enhance hole injection. Furthermore, monolithic integration of DUV and visible LEDs is proposed and demonstrated by deliberately cascading DUV and visible active regions, which could replace the current integration technique in the sterilization system.

Electronic platforms that are able to re-shape and assume different geometries are attractive for the advancing biomedical technologies, where the re-shaping feature increases the adaptability and compliance of the electronic platform to the human body. In this thesis, we present a serpentine-honeycomb reconfigurable electronic platform that has the ability to reconfigure into five different geometries: quatrefoil, ellipse, diamond, star and one irregular geometry. We show the fabrication processes of the serpentine-honeycomb reconfigurable platform in a micro-scale, using amorphous silicon, and in a macro-scale using polydimethylsiloxane (PDMS). The chosen materials are biocompatible, where the silicon was selected due to its superior electrical properties while the PDMS was selected due to its unique mechanical properties. We study the tensile strain for both fabricated-versions of the design and we demonstrate their reconfiguring capabilities. The resulting reconfiguring capabilities of the serpentine-honeycomb reconfigurable platform broaden the innovation opportunity for wearable electronics, implantable electronics and soft robotics.

<p></p><p>Flexible electronics involve electronic circuits fabricated on flexible substrates. They have promising applications in wearable devices and flexible sensors etc. and have thus attracted much research interest in recent years. The working environment of flexible electronic devices may require them to go through repeating deformations, during which cracks may generate and grow in the metallic components of the devices, reducing service life of these devices. To address such challenges, it is desirable to investigate methods to improve the reliability of flexible electronics in these working conditions. </p> <p>This research reported here will focus on topics related to laser-based fabrication of carbon nanotube-metal composites on flexible substrates: </p> <p>Experimental studies were carried out to investigate the structures and properties of carbon nanotube – metal composites produced by a laser-based fabrication process on flexible substrates. Extensive characterizations and testes were carried out, including measurements of electrical resistivity of laser-sintered material, characterizations with SEM, TEM, EDS and XPS, and mechanical performance tests (bending fatigue test, static tensile test and adhesion test). The experimental study suggests that the laser-fabricated metal composites have promising potentials to help enhancing reliability and durability of metal components in flexible electronic devices. </p> <p>A molecular dynamics model was also developed to study the coalescence of metal nanoparticles (gold NPs in this study) around the end of a multi-walled carbon nanotube (MWCNT) and their interaction with the CNT at elevated temperatures. The MD model was first tested by comparing the MD-predicted NP melting points with experiment-deduced results from the literature. Then the coalescence of five 3-nm Au NPs around the end of a MWCNT and their interactions with the CNT were studied with MD simulations. The molecular system was studied under different elevated temperatures and for different carbon nanotube diameters, and the simulation results were analyzed and discussed. </p><br><p></p>

Le travail de thèse a été réalisée dans le cadre du projet ANR «Stick’It» visant à développer de nouvelles technologies peu coûteuses et innovantes dédiées à la conception de composants radiofréquences (RF) 2D, 2,5D et 3D, notamment des antennes imprimées sur des matériaux conformes. Les applications ciblées sont principalement des appareils de réseaux domestique, tels que les décodeurs, dont les formes et les dimensions sont très variées. Par conséquent, il est nécessaire de concevoir des antennes sur des substrats souples.Selon nos besoins pour un matériau de substrat flexible, peu coûteux, avec de bonnes propriétés RF, la capacité de recyclage et en particulier la capacité à fabriquer des structures 3D, après avoir étudié différents matériaux diélectriques pour l’électronique flexible, le papier s'est trouvé le plus adapté.Les travaux de cette thèse se sont déroulés en trois phases.Dans la première phase, c'était l'étude des méthodes de caractérisation des matériaux pour obtenir leurs propriétés électromagnétiques. Après l'analyse, la méthode de perturbation utilisant une cavité cylindrique a été choisie pour la caractérisation du papier. Les premiers résultats de ce processus ont été vérifiés en réalisant et en testant des antennes simples telles que des monopoles alimentés par CPW sur du papier et du PET. Ensuite, la mesure du papier E4D a été effectuée avec 50 échantillons découpés dans différentes feuilles de papier E4D de trois épaisseurs différentes, 104 m, 210 m et 387 m. Les résultats ont été analysés statistiquement et ont donné r = 3.184, tan = 0.092. Les dispersions des résultats mesurés à 2,5 GHz sont 0.25% pour r et 0.26% pour tan. Ces résultats ont été utilisés pour la phase suivante.Au cours de la deuxième phase, les antennes différentes ont été conçues sur le papier E4D d'épaisseur 0,104 mm et 0,21 mm, notamment des IFA, des antennes SIW et des antennes monopoles alimentées par une ligne microruban. Les prototypes ont été réalisés à l'aide d'une technique de sérigraphie et testés pour déterminer les propriétés de l'adaptation et les diagrammes de rayonnement.Dans la troisième phase, les antennes proposées ont été étudiées dans des conditions d'emballage réalistes, où un boîtier décodeur était en plastique ABS avec différentes dimensions. Le premier cas concernait deux antennes MIMO placées orthogonalement dans des boîtiers ABS différents, avec un espace suffisant pour que les deux puissent rester plats. Le second cas était une boîte à hauteur limitée, de sorte qu’au moins une des antennes doit être pliée.Ainsi, une étude de l'effet de flexion a été réalisée, tout d'abord avec un simple dipôle droit et un monopole droit sur le papier E4D, puis avec une antenne à large bande proposée dans la seconde phase. L’étude a montré que la flexion n’affecte pas beaucoup l’adaptation de l’antenne sur une large bande de fréquences. Cependant, ses diagrammes de rayonnement tournent dans le plan E avec un angle de rotation dépendant de la position de pliage et de l'angle de flexion.Ensuite, le système MIMO de deux antennes placé orthogonalement dans un boîtier ABS de hauteur limitée, de sorte qu’une antenne doit être pliée et une autre reste plate. Dans tous les cas de système d'antenne MIMO, nous avons obtenu une bonne isolation (> 20 dB) et un coefficient de corrélation (ECC) inférieur à 0,05. / The thesis was carried out within the ANR project « Stick’It » that aimed at developing new, low-cost and innovative technologies devoted to the design of 2D, 2,5D and 3D radiofrequency (RF) components including antennas printed on conformable materials. The targeted applications are primarily home-networking devices such as set-top boxes where their forms and dimensions are widely varied. Therefore, it is necessary to design antennas on flexible substrates.According to our needs for a substrate material that is flexible, low cost, with good RF properties, recycling ability, and especially ability to make 3D structures, after considering various dielectric materials for flexible electronics, paper substrate appeared to be the most suitable for our purpose.The work of this thesis conducted in three phases.In the first phase, it was the study of methods for characterization of materials to obtain their electromagnetic properties. After analysis, the method of perturbation using a cylindrical cavity was chosen for characterization of paper. The first results of this process were verified by realization and testing of simple antennas such as CPW-fed monopoles on paper and PET. Then, the measurement of E4D paper substrate was performed with 50 samples cut from various E4D paper sheets of three different thicknesses, 104 m, 210 m and 387 m. The results were analyzed statistically and gave r = 3.184, tan = 0.092.The dispersions of the results measured at 2.5 GHz are 0.25% for r and 0.26% for tan. These results were used for the next phase.In the second phase, different antennas were designed on 0.104-mm and 0.21-mm thick E4D paper including IFAs, SIW cavity-back antenna and microstrip-fed wideband monopole antennas. The prototypes were realized using screen printing technique and tested for matching property and radiation patterns.In the third phase the proposed antennas were studied in realistic package conditions, where a set-top box was made of ABS plastic with different dimensions. The first case was with two MIMO antennas orthogonally located in different ABS boxes with sufficient space, so that both of them can remain flat. The second case was a box with a restricted height, so that at least one of the antennas needs to be bent.Thus, a study of bending effect was carried out, first of all, with a simple straight dipole and a straight monopole on E4D paper, then with a wideband antenna proposed in the second phase. The study showed, that bending does not much affect the matching of the antenna over a wide frequency band. However, its radiation patterns rotate in the E-plane with a rotation angle depending on the bending location and bending angle.Then, the MIMO system of two antennas placed orthogonally in an ABS box with restricted height so that one antenna needed to be bent and another remained flat. In all cases of MIMO antenna system, we obtained good isolation (>20 dB) and Envelope Correlation Coefficient (ECC) less than 0.05.

This thesis reports the discovery of a wide negative di↵erential resistance (NDR) region in a graphite-silicone composite that was utilized to create a strain-tuned flexible oscillator. Encoding the strain into frequency mimics the behavior of mechanoreceptor neurons in the skin and demonstrates a flexible and electronically active material suitable for state of the art bio-electronic applications. The NDR was investigated over a range of composite filling fractions and temperatures; alongside theoretical modelling to calculate the tunneling current through a graphite-silicone barrier. This led to the understanding that the NDR is the result of a semi-metal to insulator transition of embedded graphene bilayers within the graphite nanoparticles. The transition, brought about by a transverse bias across specifically orientated particles, opens a partial band-gap at the Fermi level of the bilayer. NDR in a flexible material has not been observed before and has potential for creating a flexible active device. The electromechanical properties of the composite were considered through a bend induced bilayer strain. The piezoresistance was found to be dominated by transient resistance spiking from the breaking of conduction lines, which then reform according to the viscoelasticity of the polymer matrix. The resistance spiking was embraced as a novel method for sensitive di↵erential pressure detection, used in the development of two applications. Firstly, it was employed for the detection of ultrasound waves and found to have an acoustic pressure detection threshold as low as 48 Pa. A commensurability was observed between the composite width and ultrasound wavelength which was shown to be consistent with the formation of standing waves, described by Bragg’s law. Secondly, a differential pressure array of 64 composite pixels was fabricated and demonstrated to image pressures under 3.8 kPa at a resolution of 10 dpi. The NDR active region was incorporated into an LC circuit where it was demonstrated to sustain oscillations of up to 12.5 kHz. The composite was then strained and an intrinsic frequency was observed which had a linear dependence on the strain with a frequency shift of 84 Hz / % strain. Lastly the composite was used in a strain-tuned amplifier circuit and shown to provide a gain of up to 4.5. This thesis provided the groundwork for a completely flexible electronically active device for futuristic bio-electronic skins with resolutions and sensitivities rivalling those of human tactile sensing.

Symmetric and fast (∼5 ms) on-to-off and off-to-on drain current switching characteristics have been obtained in screen printed organic electrochemical transistors (OECTs) including PEDOT:PSS (poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonic acid)) as the active transistor channel material. Improvement of the drain current switching characteristics is made possible by including a carbon conductor layer on top of PEDOT:PSS at the drain electrode that is in direct contact with both the channel and the electrolyte of the OECT. This carbon conductor layer suppresses the effects from a reduction front that is generated in these PEDOT:PSS-based OECTs. In the off-state of these devices this reduction front slowly migrate laterally into the PEDOT:PSS drain electrode, which make off-to-on switching slow. The OECT including carbon electrodes was manufactured using only standard printing process steps and may pave the way for fully integrated organic electronic systems that operate at low voltages for applications such as logic circuits, sensors and active matrix addressed displays. / <p>Funding Agencies|Lintec Corporation||</p>

We proposed a flexible electronics with functional poly (arylene ether)s and discotic liquid crystal. Firstly, we provided a series of the PAE polymer with remarkable thermal stability and high optical transmittance. The PAEs were synthesized via nucleophilic displacement as polymerization on a 2-trifluoromethyl-activated bisfluoro monomer, which reacted with bisphenols. Thermal analysis indicated the PAEs possessed a high glass transition point of ~300¢J and the decomposition temperature Td=500¢J at a weight loss of 5%. Additionally, high transmittance of 85%, low dielectric constant of ~2.0, and well mechanical property of the PAE films were experimentally verified, as a high potential substrate for flexible electronics. Two kind of device structure has been prepared, were organic thin film solar cell and Dye sensitized solar cell. Furthermore, we provided the self-assembled triphenylene-based liquid crystal and its polymer derivative to apply for photovoltics. The 2, 3, 6, 7-tetra-6-octyloxydibenzo[a,c]phenazine-11-carboxylic group and the polymer of merging with disc-unit and polyacrylamide. Both show a highly isotropic phase transition point of ~270¢J and the decomposition temperature Td~450¢J at a weight loss of 5%. The specific absorption in visible light region was at 200 - 450 nm. A distinct self-arrangement of columnar array was investigated by optical textures. The self-arranged pathway enhanced carrier mobility due to £k-£k conjugation in hexagonal column stacking. Finally, the PAEs and DLC materials applied to thin film solar cell (ITO/PEDOT:PSS/DLC-PAM/P3HT:PCBM/Al) as hole transporting layer. The photo-conversion efficiency was strong depending on organic compounds, such as molecular structure, photo-physic and chemical properties. On the basis of integrated characteristics, it suggested a high potential as flexible electronics for photovoltics.

In this research that we design in the polymer structure containing the core monomer into benzene ring structure for appied on the flexible substrate and the optoelectronic components .Three novel bisphenol monomers have been synthesised successfully and converted to a series of poly(arylene ether)s by nucleophilic displacement reaction with Bis(4-fluorophenyl) sulfone, then we called them:P1, P2 and P3.We can see from the material structure that the steric hindrance of the group connected to the side of the main chain (M2) is larger than the group in the main chain(M1,M3),and the steric hindrance of the longer length of main chain (M3) is smaller than the shorter one(M1) in the polymerization Thermal analysis physics studies with these polymers confirmed by Thermogravimetric analyzer(TGA) and differential scanning calorimetry (DSC).It is indicated that Td5% of these polymers were 476¢XC~577¢XC in TGA and Tg of these polymers were 264¢XC~290¢XC in DSC. Besides, these polymers were not observed apparent crystallizing point, so we consider that they are not crystallized easily. The transmission spectra of thin film in the visible light region were up to 87%~93%. In drop shape analysis system, the contact angles of them are 85¢X~87¢X, show that they have good hyrophobicity.By above material properties of these polymers, they have high thermal stabilities, high optical transparency and good hydrophobicity.