M. S.

No description available.

Surface tension is an essential force for the functioning of the world and life. Centuries of study, and still, new applications and limits of surface tension are being explored. Water has always drawn attention for its high surface tension value, 72mN/m compared to ethanol's 20mN/m. The high surface tension allows for numerous applications, superhydrophobic surfaces being one that takes heavy advantage of that value. Superhydrophobicsurfaceshave a high surface energy cost with water, resulting in small contact areas with high advancing and receding contact angles and low contact angle hysteresis. This results in very low adhesion on the surfaces. Here we study the ability of superhydrophobic surfaces with their low adhesion to shed meltwater from frost, showing a decrease in frost thickness to below 3mm for the meltwater to shed. We then take another approach to removing water from a surface, rather than increasing the surface energy cost, we introduce a difference in surface energy cost. Introducing a porous surface across from a solid one, droplets transfer from the solid to the porous, removing over 90% of the volume of the droplet from the solid surface. We thoroughly examine and model the hydrodynamics of the transfer process, varying the solid surface, the donor surface, and the liquid. This bridging between surfaces is then applied to fog harps, examining the efficiencies of large-form fog harps. Fog harps have shown a 3 to 5 times increase in water collection compared to the industry-standard mesh collector. However, droplets from fog collected on the wires eventually grow large enough to touch neighboring wires. Tominimizetheirsurfaceenergy, they begin pulling wires together, "tangling" them. This can potentially reduce efficiency, but has not been applied to large-scale harps until here. Another application of surface tension is then examined, using lower surface tension oils, but trapping them in microstructures to make slippery liquid-infused porous surfaces (SLIPS). The oil coats the microstructure, due to its lower surface tension. This creates a lubricating layer on the surface, along with potential air pockets reducing friction further. These surfaces have been studied extensively with liquids being placed on them, but here we begin to examine them when solids are used instead, showing some interesting cases where increasing the viscosity of the oil actually decreases the friction force. / Doctor of Philosophy / Sponges are something everyone has used, and most people can tell you that they work using surface tension. And for most people, that's enough. It's actually more useful to know to squeeze your sponge dry when you're done to prevent mold than it is to know that it holds onto liquids because of surface tension. But the point here was to take the study of sponges and surface tension to the extreme. To the point that some knowledge is going to be gained solely for the sake of gaining knowledge. Not all knowledge will have immediate uses, but this doesn't take value away from the knowledge, or any eventual uses it might have. So we start this by looking at the building of scientific knowledge and noticing that a brick is missing. Superhydrophobic surfaces, surfaces that water doesn't want to touch, have been studied very extensively and their properties have been thoroughly explored. However, a direct comparison of the defrosting behaviors, the process of frost melting on a surface, between superhydrophobic and hydrophobic surfaces had not been done. Water does prefer to be on a hydrophobic surface compared to a superhydrophobic one, but it's still uncomfortable. A plate was treated so that half was hydrophobic and the other half was superhydrophobic. Frost was grown across the surface and then melted simultaneously, allowing us to characterize the differences in the behaviors, highlighting the ability of the superhydrophobic surface to shed water droplets at smaller sizes than other surfaces. Next is a pure fluid mechanics work supporting a heat transfer application. Evaporation, for enhanced heat transfer, and a hydrophilic wick, essentially a sponge, are paired to create a plate with one-way heat transfer. Heating side A can heat side B, but heating side B can't heat side A. Water in the wick gets heated, evaporates from side A and then condenses on side B, carrying heat with it. The condensation grows until it touches the wick, which then pulls it in, allowing it to be evaporated again and cycling more heat. When side B, the smooth surface, is heated, the water can evaporate off it and condense in the wick, but then it has no way to return, preventing further heat transfer. The process of droplets being pulled from side B to the wick in side A is key to the process. It's a sponge pulling water in using surface tension. However, all the smaller pieces have been taken for granted. The second piece is a systematic study of this capture mechanism, exploring the effects of changing liquids, donor surfaces, and receiving porous wicks. The third is a continuation of the lab's previous work on Fog Harps, arrays of vertical fibers held in place to let fog run into them. The droplets grow until they slide down and can be collected. The wires of the harp are close enough that the water can actually start to tangle them together. This tangling can increase the water needed for sliding and collection to begin. Tensioning the wires can help mitigate the tangling. Here we show harps on around 1,$text{m}^2$, using optimal wire size and spacing that is possible for mass manufacturing. The harps were tested in the lab using humidifiers to generate fog for the harps to collect. Finally, an initial study of solid objects being pulled across oil-infused microstructured surfaces. The microstructure helps keep the oil on the surface thanks to the surface energy of the oil. These oil-infused surfaces have been studied extensively when liquids are placed on them, but not with solid objects. Solid objects can exert significantly more pressure than liquids, which naturally want to spread when they reach a certain thickness. Experiments were performed with a variety of oil viscosities, microstructures, and oil excess thicknesses. This work is not entirely complete but a significant portion of it is presented here.

Bud dormancy is an essential characteristic of deciduous woody perennials, including apple, to cope with the low temperatures during winter. The release from dormancy and subsequent budburst in apple can only occur after fulfillment of chilling and heat requirements. In the Mid-Atlantic region, dormancy release and bud break of apple often coincide with late-spring freezes that cause severe damages to flowers, and small fruitlets. Therefore, the present study aimed to better understand mechanisms underlying bud dormancy in apple, with an ultimate goal of exploring chemical and/or genetic approaches for bloom-time modulation to avoid spring frost. Using two apple cultivars, 'Cripps Pink' and 'Honeycrisp,' representing early- and late-blooming cultivars, respectively, the present study specifically investigated the accumulation kinetics of plant hormones, carbohydrates, and reactive oxygen species (ROS) throughout the dormancy-regrowth cycle. Our results indicated that both cultivars required 1000 chilling hours for endodormancy release, but 'Honeycrisp' required 1000 growing degree hours (GDHs) more than 'Cripps Pink' for ecodormancy release and budburst. Among plant hormones, abscisic acid (ABA) showed remarkably elevated levels in the dormant buds of both cultivars during endodormancy, but its levels were significantly higher in 'Honeycrisp'. The decline of the ABA level at bud burst was combined with increased levels of cytokinin (CK). The ABA accumulation pattern during dormancy paralleled with an upregulation and downregulation of ABA biosynthetic and catabolic genes, respectively. On the other hand, the levels of hydrogen peroxide (H2O2) and superoxide (O2.-) were significantly higher in 'Cripps Pink' than 'Honeycrisp', particularly by the time of endodormancy and ecodormancy release, respectively. Our findings also showed a gradual decline in starch levels with the dormancy progression and increased levels of total soluble sugars (TSS) that were generally higher in the early-blooming cultivars. Transcriptomic profiling and module-trait relationship identified two modules that contrast between two cultivars mainly during eco-dormancy. Gene ontology (GO) analysis indicated that these DEGs were mostly involved in pathways related to hormones and signaling and co-expressed with H2O2 whereas, during ecodormancy pathways related to glutathione metabolism, auxin biosynthesis, carbohydrate metabolism and reproductive development were co-expressed with O2.-. Together, our results suggest that the contrasting bloom dates between 'Cripps Pink' and 'Honeycrisp' can be explained, at least partially, by the differential accumulation levels of ABA, ROS, antioxidants, and their associated genes in the buds of these cultivars throughout the dormancy cycle. / Doctor of Philosophy / Spring frosts represent a significant threat to apple production in many fruit-producing states of the United States including Virginia. The risk of frost damage is rising due to global climate change, and there is a high demand for effective measures to reduce frost damage. Exogenous applications of plant growth regulators (PGRs) to delay bloom has been suggested as an effective frost avoidance strategy, but with limited success. Therefore, the present study aimed to investigate molecular and biochemical pathways regulating bud dormancy and bloom time in apple, which can ultimate lead to novel approaches for bloom delay and frost mitigation. To this end, the accumulation patterns of major plant hormones (e.g. abscisic acid, ABA, cytokinin, CK and jasmonic acid, JA), reactive oxygen species (ROS) and carbohydrates (e.g. starch, sucrose, glucose and fructose) were thoroughly monitored throughout the dormancy-regrowth cycle in two apple cultivars, 'Cripps Pink' and 'Honeycrisp,' representing early- and late-blooming cultivars, respectively. Both these cultivars had similar chilling requirements (1000 chilling hours) but differed in their heat requirements; with 'Honeycrisp' requiring 1000 growing degree hours more than 'Cripps Pink'. Among plant hormones, ABA increased with the progression of dormancy and decreased with dormancy release in both cultivars. However, ABA levels were significantly higher in 'Honeycrisp' compared to 'Cripps Pink'. On the contrary, during dormancy release, the growth-promoting hormone, CK, increased earlier in 'Cripps Pink'. The levels of ROS, e.g., hydrogen peroxide (H2O2), and superoxide (O2.-), were also higher in 'Cripps Pink' than 'Honeycrisp', particularly by the time of endodormancy and ecodormancy release, respectively. Our data showed that starch levels generally declined during dormancy, whereas soluble sugars increased. However, there was no significant alternations in the carbohydrate accumulation profiles between the two cultivars that could account for the differences in their bloom dates. These results were verified further at the transcriptomic level. Using the RNA-sequencing technology, identified two modules that contrast between two cultivars mainly during eco-dormancy. Gene ontology (GO) analysis indicated that these genes were mostly involved in pathways related to hormones and signaling and co-expressed with H2O2 whereas during ecodormancy pathways related to glutathione metabolism, auxin biosynthesis, carbohydrate metabolism and reproductive development were co-expressed with O2.-. Overall, our results suggest that ABA, cytokinin, H2O2, and O2.- may, at least partially, explain the differences in the bloom time between the two apple cultivars. Further analysis of these molecules and their associated genes in other apple cultivars with contrasting bloom dates is necessary for better understanding of bloom time regulation in apple and developing strategies against frost damage.

The most ubiquitous mode of frost formation on substrates is condensation frosting, where dew drops condense on a supercooled surface and subsequently freeze, and has been known since the time of Aristotle. The physics of frost incipience at a microscopic scale has, nevertheless, eluded researchers because of an unjustified ansatz regarding the primary mechanism of condensation frosting. It was widely assumed that during condensation frosting each supercooled droplet in the condensate population freezes in isolation by heterogeneous nucleation at the solid-liquid interface, quite analogous to the mechanism of icing. This assumption has very recently been invalidated with strong experimental evidence which shows that only a single droplet has to freeze by heterogeneous nucleation (typically by edge effects) in order to initiate condensation frosting in a supercooled condensate population. Once a droplet has frozen, it subsequently grows an ice bridge towards its nearest neighboring liquid droplet, freezing it in the process. Thus ensues a chain reaction of ice bridging where the newly frozen droplets grow ice bridges toward their nearest neighbor liquid droplets forming a percolating network of interconnected frozen droplets. Not always are these ice bridges successful in connecting to their adjacent liquid droplets. Sometimes the liquid droplet can completely evaporate before the ice bridges can connect, thus forming a local dry region in the vicinity of the ice bridge. In this work, we first formulate a thermodynamic framework in order to understand the localized vapor pressure gradients that emerge in mixed-mode phase-change systems and govern condensation and frost phenomena. Following this, we study droplet pair interactions between a frozen droplet and a liquid droplet to understand the physics behind the local ice bridge connections. We discuss the emergent scaling laws in ice bridging dynamics, their relative size dependencies, and growth rates. Thereafter, we show how with spatial control of interdroplet distances in a supercooled condensate and temporal control of the first freezing event, we can tune global frost propagation on a substrate and even cause a global failure of all ice bridges to create a dry zone. Subsequently, we perform a systematic study of dry zones and derive a scaling law for dry zones that collapses all of our experimental data spanning a wide parameter space. We then show that almost always the underlying mechanism behind the formation of dry zones around any hygroscopic droplet is inhibition of growth and not inhibition of nucleation. We end with a discussion and preliminary results of our proposed anti-frosting surface that uses ice itself to prevent frost. / Master of Science / In the movie Iron Man, during the very final battle sequence between our eponymous hero and Iron Monger, there is a moment when Tony Stark realizes that Iron Monger can fly. Immediately Iron Man shoots up into the sky. He tries to reach as high as he can. Iron Monger chases after him. Eventually, high up in the sky amidst the clouds, Iron Monger catches up. He grabs Iron Man in his enormous grip and punches him. It seems like there is no escape for Iron Man. But right then, writhing in Iron Monger’s grip, Tony Stark asks Iron Monger, ‘How’d you solve the icing problem?’ It is then revealed that Iron Monger’s suit has completely frozen over, whereas Iron Man’s suit has no ice whatsoever. Iron Monger shuts down and starts falling from the sky. The icing problem, which Tony Stark mentions, occurs when supercooled liquid water droplets impact on a chilled substrate and subsequently freeze. Another way of accretion of ice constitutes the frosting problem. The most common mode of frost formation on a surface is called condensation frosting, where the ambient water vapor first condenses on the chilled surface as dew drops, and these liquid droplets subsequently freeze. Until very recently, it was widely assumed that during condensation frosting all the dew droplets freeze in isolation at the solid-liquid interface, without interacting with each other. This assumption, however, is not true. It has recently been shown that in order to initiate condensate frosting, only a single droplet has to freeze by itself, at the solid-liquid interface. Thereafter, frost propagates by the formation of an inter-droplet ice bridge network, where the frozen droplets grow ice bridges toward their nearest neighbor liquid droplets. Interestingly, these ice bridges are not always successful in connecting to their adjacent liquid droplets. If the inter-droplet distance is too large, the liquid droplet can completely evaporate before the ice bridges can connect, thus forming a local dry region in the vicinity of the ice bridge. In this work, we do extensive experiments to investigate the underlying physics of frost incipience on a microscopic scale. We then derive scaling laws for successful ice connections, their growth rates and for dry zone formations, and end by discussing possible anti-frosting strategies. It appears that Tony Stark in his universe has solved the icing problem, and most probably also the frosting problem. In reality, however, on earth, we have not. Though anti-icing has received a lot of attention, the same cannot be said about the frosting problem. This work tries to take the first steps towards that. Quite ironically, it looks like ice itself might be the solution to the frosting problem, because of its ability to create dry zones.

Mémoire numérisé par la Direction des bibliothèques de l'Université de Montréal.

On the basis of freezing and thawing tests of air-entrained concretes having poor quality cherts as course aggregates subjected to three different treatments for improving durability, the following conclusions have been derived: 1. Removal of cherts lighter than the BSSD specific gravity of 2.5 by heavy liquid definitely improved the durability of the concrete. 2. Combining 50 percent durable aggregate (1/2"-1/4" size) with 50 percent cherts (1"-1/2" size) did not show any significant improvement in durability over that containing 100 percent chert. 3. As much as 12 percent chert could be blended with durable aggregate without an appreciable reduction in durability. / Master of Science

Results indicate that the durability of the concrete mixes using poor aggregates can be improved to a considerable extent by moist-curing. / Master of Science

Frost heave is a primary mechanism of pavement distress in cold regions. The distress exhibited is dependent on the frost susceptibility of the soil within the depth of frost penetration, the availability of subsurface water, and the duration of freezing surface temperatures. Cement stabilization is one technique used to mitigate the effects of frost heave. The tube suction test (TST) is one possible method for determining the frost susceptibility of soils in the laboratory. The purpose of this research was to assess the utility of the TST for identifying non-frost-susceptible (NFS) materials stabilized with cement. This research investigated two aggregate base materials from Alaska that have exhibited negligible frost susceptibility in the field. The unconfined compressive strength (UCS), final dielectric value in the TST, and frost heave at three levels of cement treatment and in the untreated condition were evaluated for both materials. The data collected in this research indicate that, for the two known NFS materials included in this study, the TST is a good indicator of frost heave behavior. The total heave of the untreated materials was approximately 0.15 in. at the conclusion of the 10-day freezing period, which classifies these materials as NFS according to the U.S Army Corp of Engineers. Both materials had final dielectric values of less than 10 in the TST, indicating a superior moisture susceptibility rating. The results of this research suggest that the TST should be considered for identifying NFS materials, including those stabilized with cement. Additional testing should be performed on known NFS materials stabilized with cement and other additives to further assess the validity of using the TST to differentiate between frost-susceptible and NFS materials. Consistent with previous studies, this research indicates that, once a sufficient amount of cement has been added to significantly reduce frost heave, additional cement has only a marginal effect on further reduction. Therefore, to avoid unnecessary expense in construction, the minimum cement content required for preventing frost heave should be identified through laboratory testing and specified by the engineer. In this work, UCS values ranging between 200 psi and 400 psi after a 7-day cure were typically associated with this minimum cement content. Because the scope of this research is limited to two aggregate base materials, further testing is also necessary to validate this finding.

The objective of this research was to investigate emulsion-treated base (ETB) frost susceptibility in terms of both freeze-thaw cycling and frost heave. The research performed in this study involved laboratory testing of ETB materials sampled from both the Redwood Road and 7800 South reconstruction projects in northern Utah. The effects of freeze-thaw cycling were evaluated by comparing the stiffness and strength of tested specimens to the same properties of control specimens not subjected to freeze-thaw cycling. Frost heave testing enabled evaluation of the effects of emulsion content and degree of curing on the volumetric stability of ETB materials during sustained freezing. Since permeability affects the frost susceptibility of a material, samples were also prepared to specifically evaluate the effect of curing condition on the permeability of the two base materials when treated with emulsion. The results of freeze-thaw testing showed that both the Redwood Road and 7800 South specimens experienced decreases in modulus as a result of freeze-thaw damage. The results also showed that the Redwood Road specimens experienced substantial decreases in strength as a result of freeze-thaw damage. The specimens from 7800 South did not exhibit such strength loss; since those specimens initially had much lower modulus and unconfined compressive strength values than the Redwood Road specimens, they were less susceptible to stiffness and strength loss during the freeze-thaw test. Results for the frost heave tests showed that the untreated base materials were not susceptible to frost heave and that the addition of emulsion, with or without curing, did not change the frost heave behavior in a practically important way. While susceptibility to frost heave is not expected to be a problem with these base materials, the laboratory results revealed a significant increase in the permeability of the ETB specimens after curing, which could facilitate greater freeze-thaw damage. In consideration of these research results, engineers should ensure proper material sampling and laboratory testing to assess the efficacy of emulsion treatment for a given project. ETB to be constructed in cold regions should be subjected to freeze-thaw testing during the design phase, and designers should be aware that curing of the ETB may dramatically increase permeability and therefore increase frost susceptibility.