In co-operation with the Geological Survey of Norway, 395 samples of topsoil, 44 bedrock samples and 24 samples of sand from sandboxes at kindergartens taken in Oslo, the capital city of Norway, were analysed for a wide range of elements. To get a measure on the bio-availability of arsenic, a five stage sequential extraction procedure was accomplished on a subset of 98 topsoil samples and on all 24 samples of sand from sandboxes. These fractions (i.e. “Exchangeable”, “Carbonate”, “Reducible substrate”, “Organic” and “Residual”) were analysed for arsenic. Bulk concentrations in a representative subset of 10 bedrock samples were determined by XRF analysis. For the concentrations of the elements As, B, Ba, Cd, Cr, Cu, Hg, Mn, Mo, Ni, P, Pb and Zn in soil, geologic sources are important, but human activity has had a large effect on concentrations in topsoil, especially in the central districts. At least 81% of the samples contain more arsenic than the Norm value for polluted soil used by the Norwegian authorities. For chromium, zinc and lead, the percentages are 65, 74 and 25 respectively. In topsoil, up to 50% of the arsenic is extractable in the exchangeable, the carbonate and the reducible substrate fractions, but only 2% of the samples exceeded the Norm value after the three extraction stages. After four stages of extraction, 69% of the samples exceeded the Norm value. At 24 kindergartens in the central districts of Oslo, concentrations of As, Cd, Cr, Cu, Ni, Pb and Zn in topsoil samples are higher than in samples of sand from sandpits, but differences in arsenic are low. All topsoil samples and 63% of the sandbox samples exceed the arsenic Norm value for polluted soil used by the Norwegian authorities. Concentrations of at least one of the elements Cr, Cu, Ni, Pb and Zn exceed the Norm value in the topsoil. At two kindergartens all elements, except Cd, exceed the Norm value in the topsoil. In the samples from the sandboxes, arsenic concentrations in the exchangeable, the carbonate and the reducible substrate fractions, lie at a higher level than in topsoil samples. Leakage of arsenic compounds from impregnated and painted wood have probably caused elevated concentrations of this element in the sand. At two kindergartens the cumulative arsenic content in samples from the sandboxes exceeds the Norm value of 2 mg/kg As for polluted soil already after two fractions (i.e. the “Exchangeable” and the “Carbonate” fraction). After three fractions, the arsenic content in sand at 5 kindergartens exceeds this value. After four fractions this number was still 5. Regarding soil, no kindergartens had a cumulative arsenic content after three stages of the extraction procedure. After four stages 16 kindergartens contained more arsenic than the Norwegian Norm value of 2 mg/kg As. Bulk concentrations of metals, in the bedrock samples, are generally higher than the acid soluble concentrations. Differences are small for copper and zinc, somewhat higher for lead and nickel and considerably different for chromium. Acid soluble chromium concentrations in soil differ little when compared with acid soluble concentrations in bedrock, but are in general much lower than bulk concentrations in rock. Chromium is probably strongly incorporated in the mineral structure of rock samples and concentrated HNO3 cannot solubilize all chromium molecules. For copper, lead and zinc, the acid soluble concentrations in soil are higher than the bulk concentrations in bedrock. The parent rock material cannot be the only source for these elements in soils and various anthropogenic sources dispersed by air or water probably have major influence. The enrichment of nickel in topsoil near highways in Oslo might be due to the bitumen content of road dust. The enrichment of chromium and copper might be due to wear and tear of cars and engine parts. There is no enrichment of cadmium and zinc in topsoil near highways. Concentrations of zinc in topsoil in Oslo are generally high, most probably because of industry. The possible addition of zinc from traffic to the topsoil is not observed, in this study.

In this thesis, we assess various climatic impacts of stratospheric aerosol injection (SAI), a geoengineering proposal that aims to cool Earth by enhancing the sunlight-reflecting aerosol layer in the lower stratosphere. To this end, we employ simpleradiative transfer models, a detailed radiative transfer code (SOCRATES), and two Hadley Centre general circulation models (HadGEM2-CCS and HadGEM2-ES). We find that the use of a light-absorbing aerosol (black carbon) for SAI would result in significant stratospheric warming and an unprecedented weakening of the hydrological cycle. Conversely, we find that SAI with sulphate or titania aerosol could counteract many of the extreme climate changes exhibited by a business-as-usual scenario (RCP8.5) by the end of this century. In a separate investigation, we show that volcanic aerosol dispersion following low-altitude volcanic eruptions can exhibit high sensitivity to the ambient weather state. Volcanic aerosol may get 'trapped' in a single hemisphere or transported to the opposite hemisphere depending simply on the meteorological conditions on the day of the eruption. In a final study, we investigate the impacts of SAI on North Atlantic tropical storm frequency. We find that SAI exclusively promoted in the southern hemisphere would increase North Atlantic storm frequency, and vice versa for northern hemisphere SAI. The results of this thesis should promote further research into SAI, which could conceivably be deployed to maintain global-mean temperature below the COP21 target of +1.5 K above pre-industrial levels, whilst society transitions onto a sustainable energy pathway. Conversely, the possibility of SAI being weaponised, for instance, to specifically increase North Atlantic tropical storm frequency, should motivate policymakers to implement effective regulation and governance to deter unilateral SAI deployments.

<p>The purpose of this study was to build a database for point-bearing piles in dense noncohesive soil, predominantly moraine. Further, the database was analysed and areas with difficult geotechnical conditions was identified.</p><p>The database includes for point-bearing piles driven to refusal in moraine. Piles with mainly shaft friction have been excluded. Only concrete piles have been included. Geographically the database covers almost all geotechnical conditions of Sweden. The total amount of piling projects is 110 and the total amount of piles is 600.</p><p>For contractors, foundation work is usually connected with a lot of uncertainty and risk, concerning the estimating of time and cost. During the design stage of foundation construction the database can be a useful tool to estimate suitable loads on the piles.</p><p>The data was analysed further with different statistical method. Possible reasons for low bearing capacity, in some projects, have also been investigated.</p> / <p>Syftet med examensarbetet är att upprätta en databas över spetsburna pålar fastslagna i friktionsjord och morän. Vidare skall databasen analyseras för att hitta styrande parametrar samt även hitta områden med problematisk geoteknik.</p><p>Databasen omfattar spetsburna pålar som stoppslås i friktionsjord. Pålar som i huvudsak är mantelburna har uteslutits. Endast betongpålar har tagits med. Geografiskt omfattar databasen i stort sett hela Sverige. Totalt innehåller databasen 110 projekt med sammanlagt över 600 pålar.</p><p>För entreprenörer i byggbranschen är grundläggningsarbetet ofta förknippat med ekonomiska risker och osäkerhet gällande omfattning och tidsåtgång. Vid dimensionering av grundläggningsarbeten kan databasen vara till stor hjälp för att bestämma lämpliga lastnivåer. Mängden slagningsarbete och risken för bortslagna pålar kan lättare uppskattas.</p><p>Först analyserades olika påltyper utan ytterligare urvalskriterier. Vikten av att filtrera informationen blev då tydlig, eftersom resultatet blev svårtolkat och inga markanta samband kunde urskiljas. Med databasen som grund har materialet vidare analyserats med hjälp av statistiska metoder. Orsaken till låga bärförmågor vid ett urval av projekt har även kartlagts.</p>

<p>Outline of the thesis</p><p>This thesis is comprises three papers that are intended for journal publication. The version provided in the thesis is a bit longer than they will be at final publication. However it was the desire to include some additional documentation that may be omitted in the final versions. Each paper in the manuscript is written as an independent paper. Because all the papers are strongly tied together there is significant repetition partly because the documentation and interpretation of the results in on paper depends on the results documented in another paper. The essence of the three papers are summarised below:</p><p>Paper 1:</p><p>Sørensen, B.E. and Larsen R.B. 2007. “Fluid induced multistage recrystallisation microstructures in Quartzites and Quartz veins from the Bamble shear zone complex”</p><p>Paper 1 deduces basic principles of infiltration, physiochemical alteration processes and deformation mechanisms in quartzites and in quartz veins from the Froland area, the Bamble sector. SEM-CL is used to define generations of recrystallised quartz. A progressive quartz purification process ending with high purity quartz through recrystallisation is documented through LA-ICP-MS. The study demonstrates how fluids provokes recrystallisation and trace element mobilisation from the quartz lattice and at fluid-absent conditions, quartz is resistant to retrograde recrystallisation hence preserving its early high grade metamorphic trace element signature. Evidence of retrograde fluid flow is preserved in fluid channel textures intersecting quartz and documented by SEM-CL images as well as changes in the trace element distribution. Quartz recrystallisation is associated with metasomatic processes in the quartzites such as for example the replacement of ilmenite by rutile and replacement of biotite by muscovite. The strong focus of fluid flow along narrow pathways intersecting the quartzites generates mm-scale differences in the rheological properties of the quartz grains with increased ductility and recovery in recrystallised grains. Therefore, the study demonstrates a strong coupling between strain softening, fluid flow and mass transfer in shearzones in quartz rich rocks.</p><p>Paper 2:</p><p>Sørensen, B.E. and Larsen R.B. 2007. “The fluid evolution of the Froland area in the Bamble sector from peak P-T through cooling and uplift: implications for retrograde mineral paragenesis and PT evolution of the Bamble sector”</p><p>Paper 2 comprises a detailed characterisation of the fluid evolution during cooling and uplift through fluid inclusion studies compared with thermodynamic modelling of calc-silicate volatile dependant mineral equilibria. Fluids are documented to be brines throughout the cooling and uplift path. The paper also includes a detailed discussion of the chemical properties of the aggressive brines and their implications for mineral equilibria during cooling and exhumation. The study also document which fluids that were in equilibrium with quartz recrystallisation and purification. The study focussed on fluids that could be related to the quartz SEM-CL textures documented in Paper 1. Had the main purpose of this thesis been to understand calc-silicate equilibria in the Bamble sector fluid inclusions in the calc-silicates would have been in the focus.</p><p>Paper 3:</p><p>Sørensen, B.E, Larsen R.B. and Austrheim, H. 2007. “Metasomatic evolution of the Froland amphibolites during cooling and uplift – textural observations and geochemical evolution of hydrous minerals”</p><p>Paper 3 comprises a detailed study of alteration processes in amphibolites. The study focuses on the chemistry of amphiboles as a function P, T and the composition of the co-existing fluids. Amphibole and biotite undergo a co-genetic evolution both becoming more Mg-rich during cooling and exhumation. The chemical changes in biotite and amphibole reflects the interaction with the brines present throughout cooling and uplift. A relationship between element depletion in amphibolites and formation of Fe-Cu sulphides is observed.</p><p>As earlier stated the papers are strongly tied together. In conjunction with each other they deduce the metamorphic and metasomatic evolution of the area and put the observed quartz recrystallisation and purification into a physiochemical framework. The locality numbering varies between the papers because samples from different localities are included in each paper, accordingly a locality termed”1” in one of the papers may have a different number in the next paper. This was done because the papers are supposed to be independent research papers and the numbering logically relate to the context of the single papers and not the thesis as a whole.</p>

<p>Research interests in the studies of complex systems have been booming in many disciplines for the last decade. As the nature of geographic environment is a complex system, researches in this field are anticipated. In particular, the urban street networks in the Geographic Information System (GIS) as complex networks are brought forth for the thesis study. Meanwhile, identifying the scale-free property, which is represented as the power law distribution from a mathematical perspective, is a hot topic in the studies of complex systems. Many previous studies estimated the power law distributions with graphic method, which used linear regression method to identify the exponent value and estimate the quality that the power law fits to the empirical data. However, such strategy is considered to cause inaccurate results and lead to biased judgments. Whereas, the Maximum Likelihood Estimation (MLE) and the Goodness of fit test based on Kolmogorov-Smironv (KS) statistics will provide more solid and trustable results for the estimations. Therefore, this thesis addresses these updated methods exploring the topological patterns of urban street networks from an analytical perspective, which is estimating the power law distributions for the connectivity degree and length of the urban streets. Simultaneously, this thesis explores the street networks from a visual perspective as well. The visual perspective adopts the large network visualization tool (LaNet-vi), which is developed based on the k-core decomposition algorithm, to analyze the cores of the urban street networks. By retrieving the spatial information of the networks from GIS, it actually enables us to see how the urban street networks decomposed topologically and spatially. In particular, the 40 US urban street networks are reformed as natural street networks by using three "natural street" models.</p><p>The results from analytical perspective show that the 80/20 principle still exists for both the street connectivity degree and length qualitatively, which means around 20% natural streets in each network have a connectivity degree or length value above the average level, while the 80% ones are below the average. Moreover, the quantitative analysis revealed the fact that most of the distributions from the street connectivity degree or length of the 40 natural street networks follow a power law distribution with an exponential cut-off. Some of the rest cases are verified to have power law distributions and some extreme cases are still unclear for identifying which distribution form to fit. The comparisons are made to the power law statement from previous study which used the linear regression method. Moreover, the visual perspective not only provides us the chance to see the inner structures about the hierarchies and cores of the natural street networks topologically and spatially, but also serves as a reflection for the analytical perspective. Such relationships are discussed and the possibility of combining these two aspects are pointed out. In addition, the future work is also proposed for making better studies in this field.</p>

Outline of the thesis This thesis is comprises three papers that are intended for journal publication. The version provided in the thesis is a bit longer than they will be at final publication. However it was the desire to include some additional documentation that may be omitted in the final versions. Each paper in the manuscript is written as an independent paper. Because all the papers are strongly tied together there is significant repetition partly because the documentation and interpretation of the results in on paper depends on the results documented in another paper. The essence of the three papers are summarised below: Paper 1: Sørensen, B.E. and Larsen R.B. 2007. “Fluid induced multistage recrystallisation microstructures in Quartzites and Quartz veins from the Bamble shear zone complex” Paper 1 deduces basic principles of infiltration, physiochemical alteration processes and deformation mechanisms in quartzites and in quartz veins from the Froland area, the Bamble sector. SEM-CL is used to define generations of recrystallised quartz. A progressive quartz purification process ending with high purity quartz through recrystallisation is documented through LA-ICP-MS. The study demonstrates how fluids provokes recrystallisation and trace element mobilisation from the quartz lattice and at fluid-absent conditions, quartz is resistant to retrograde recrystallisation hence preserving its early high grade metamorphic trace element signature. Evidence of retrograde fluid flow is preserved in fluid channel textures intersecting quartz and documented by SEM-CL images as well as changes in the trace element distribution. Quartz recrystallisation is associated with metasomatic processes in the quartzites such as for example the replacement of ilmenite by rutile and replacement of biotite by muscovite. The strong focus of fluid flow along narrow pathways intersecting the quartzites generates mm-scale differences in the rheological properties of the quartz grains with increased ductility and recovery in recrystallised grains. Therefore, the study demonstrates a strong coupling between strain softening, fluid flow and mass transfer in shearzones in quartz rich rocks. Paper 2: Sørensen, B.E. and Larsen R.B. 2007. “The fluid evolution of the Froland area in the Bamble sector from peak P-T through cooling and uplift: implications for retrograde mineral paragenesis and PT evolution of the Bamble sector” Paper 2 comprises a detailed characterisation of the fluid evolution during cooling and uplift through fluid inclusion studies compared with thermodynamic modelling of calc-silicate volatile dependant mineral equilibria. Fluids are documented to be brines throughout the cooling and uplift path. The paper also includes a detailed discussion of the chemical properties of the aggressive brines and their implications for mineral equilibria during cooling and exhumation. The study also document which fluids that were in equilibrium with quartz recrystallisation and purification. The study focussed on fluids that could be related to the quartz SEM-CL textures documented in Paper 1. Had the main purpose of this thesis been to understand calc-silicate equilibria in the Bamble sector fluid inclusions in the calc-silicates would have been in the focus. Paper 3: Sørensen, B.E, Larsen R.B. and Austrheim, H. 2007. “Metasomatic evolution of the Froland amphibolites during cooling and uplift – textural observations and geochemical evolution of hydrous minerals” Paper 3 comprises a detailed study of alteration processes in amphibolites. The study focuses on the chemistry of amphiboles as a function P, T and the composition of the co-existing fluids. Amphibole and biotite undergo a co-genetic evolution both becoming more Mg-rich during cooling and exhumation. The chemical changes in biotite and amphibole reflects the interaction with the brines present throughout cooling and uplift. A relationship between element depletion in amphibolites and formation of Fe-Cu sulphides is observed. As earlier stated the papers are strongly tied together. In conjunction with each other they deduce the metamorphic and metasomatic evolution of the area and put the observed quartz recrystallisation and purification into a physiochemical framework. The locality numbering varies between the papers because samples from different localities are included in each paper, accordingly a locality termed”1” in one of the papers may have a different number in the next paper. This was done because the papers are supposed to be independent research papers and the numbering logically relate to the context of the single papers and not the thesis as a whole.

The purpose of this study was to build a database for point-bearing piles in dense noncohesive soil, predominantly moraine. Further, the database was analysed and areas with difficult geotechnical conditions was identified. The database includes for point-bearing piles driven to refusal in moraine. Piles with mainly shaft friction have been excluded. Only concrete piles have been included. Geographically the database covers almost all geotechnical conditions of Sweden. The total amount of piling projects is 110 and the total amount of piles is 600. For contractors, foundation work is usually connected with a lot of uncertainty and risk, concerning the estimating of time and cost. During the design stage of foundation construction the database can be a useful tool to estimate suitable loads on the piles. The data was analysed further with different statistical method. Possible reasons for low bearing capacity, in some projects, have also been investigated. / Syftet med examensarbetet är att upprätta en databas över spetsburna pålar fastslagna i friktionsjord och morän. Vidare skall databasen analyseras för att hitta styrande parametrar samt även hitta områden med problematisk geoteknik. Databasen omfattar spetsburna pålar som stoppslås i friktionsjord. Pålar som i huvudsak är mantelburna har uteslutits. Endast betongpålar har tagits med. Geografiskt omfattar databasen i stort sett hela Sverige. Totalt innehåller databasen 110 projekt med sammanlagt över 600 pålar. För entreprenörer i byggbranschen är grundläggningsarbetet ofta förknippat med ekonomiska risker och osäkerhet gällande omfattning och tidsåtgång. Vid dimensionering av grundläggningsarbeten kan databasen vara till stor hjälp för att bestämma lämpliga lastnivåer. Mängden slagningsarbete och risken för bortslagna pålar kan lättare uppskattas. Först analyserades olika påltyper utan ytterligare urvalskriterier. Vikten av att filtrera informationen blev då tydlig, eftersom resultatet blev svårtolkat och inga markanta samband kunde urskiljas. Med databasen som grund har materialet vidare analyserats med hjälp av statistiska metoder. Orsaken till låga bärförmågor vid ett urval av projekt har även kartlagts.

Research interests in the studies of complex systems have been booming in many disciplines for the last decade. As the nature of geographic environment is a complex system, researches in this field are anticipated. In particular, the urban street networks in the Geographic Information System (GIS) as complex networks are brought forth for the thesis study. Meanwhile, identifying the scale-free property, which is represented as the power law distribution from a mathematical perspective, is a hot topic in the studies of complex systems. Many previous studies estimated the power law distributions with graphic method, which used linear regression method to identify the exponent value and estimate the quality that the power law fits to the empirical data. However, such strategy is considered to cause inaccurate results and lead to biased judgments. Whereas, the Maximum Likelihood Estimation (MLE) and the Goodness of fit test based on Kolmogorov-Smironv (KS) statistics will provide more solid and trustable results for the estimations. Therefore, this thesis addresses these updated methods exploring the topological patterns of urban street networks from an analytical perspective, which is estimating the power law distributions for the connectivity degree and length of the urban streets. Simultaneously, this thesis explores the street networks from a visual perspective as well. The visual perspective adopts the large network visualization tool (LaNet-vi), which is developed based on the k-core decomposition algorithm, to analyze the cores of the urban street networks. By retrieving the spatial information of the networks from GIS, it actually enables us to see how the urban street networks decomposed topologically and spatially. In particular, the 40 US urban street networks are reformed as natural street networks by using three "natural street" models. The results from analytical perspective show that the 80/20 principle still exists for both the street connectivity degree and length qualitatively, which means around 20% natural streets in each network have a connectivity degree or length value above the average level, while the 80% ones are below the average. Moreover, the quantitative analysis revealed the fact that most of the distributions from the street connectivity degree or length of the 40 natural street networks follow a power law distribution with an exponential cut-off. Some of the rest cases are verified to have power law distributions and some extreme cases are still unclear for identifying which distribution form to fit. The comparisons are made to the power law statement from previous study which used the linear regression method. Moreover, the visual perspective not only provides us the chance to see the inner structures about the hierarchies and cores of the natural street networks topologically and spatially, but also serves as a reflection for the analytical perspective. Such relationships are discussed and the possibility of combining these two aspects are pointed out. In addition, the future work is also proposed for making better studies in this field.

We have analyzed the application of decision analysis and risk management tools to solve practical problems associated with Climate Change and Risk Detection in the financial services industry. Geoengineering, which is described as an intentional modification of earth’s environment to mitigate the harmful effects of climate change, is evaluated as a policy alternative using the aforementioned tools. We compared the performance of geoengineering with optimal emission controls and a business as usual strategy under various scenarios and found that geoengineering passes the cost benefit test for a majority of the scenarios. We modified the DICE model (Nordhaus, 2008) and used it to evaluate the performance of different environmental policies. Our results show geoengineering as a potential alternative to solve climate change problems. Through this application, and by comparing our findings against Goes et al. (2011), we showed that how framing of the decision problem can lead to completely different results. We also analyzed the application of risk management in the financial services industry. The industry faces three main types of risk: Market risk, Credit risk and Operational risk. Market risk is managed using a diversified portfolio, derivatives, insurance and contracts. More challenging is the task of preventing credit and fraud risk. Statistical models used by the industry to detect and prevent these types of risk are explained in the thesis. / text

Pores provide important hotspots for chemical and biological processes in soils. Earthworm burrows affect the macropore structure and their actions may create new preferential pathways for water and gas flow within soils. This, in turn, indirectly affect plants, nutrient cycling, hydraulic conductivity, gas exchange, and soil organisms. While the effects of invasive earthworms on soil properties has been well-documented in temperate and boreal ecosystems, we know little how these organism may affect tundra soils. In this study, I assessed how the three-dimensional network of soil-macropores are affected by earthworm species (Aporrectodea sp. and Lumbricus sp). I hypothesized: i) that earthworms increase the frequency of macropores with a likely biological origin (biopores); ii) effects of biopores are dependent on tundra vegetation type (meadow or heath); and iii) the macropore network properties are altered by earthworms.  The hypotheses were tested using a common garden experiment with 48 mesocosms. The pore structure of each mesocosm was analyzed using X-ray CT tomography. I found that biopores increased in the tundra from on 0.05 ±0.01 % (mean ± standard deviation) in the control to about 0.59 ± 0.07 % in the earthworm treatments. However, in contrast to my second hypothesis, I found no vegetation dependent effect. Interestingly, I found that earthworms decreased the complexity and directionality of macropores. My findings strongly indicate that burrowing can severely impact the pore properties of previously uninhabited subarctic soils.