The coarse-grained configurational-bias Monte Carlo (CG-CBMC) simulation was employed to study the structural behaviors of methyl methacrylate (MMA) oligomers adsorbed on grooved substrate due to molecular dynamics (MD) simulation is probably trapped at some local energy minima and difficult to carry out over a long enough time to allow relaxation of chain motion for an enormous polymeric system. Therefore, the CG-CBMC simulation was adopted in the present study. In this study, three types of chains are classified according to their positions relative to the groove. Type 1, Type 2, and Type 3 represent the entire MMA-oligomer within the groove, the MMA-oligomer partially within the groove, and the oligomer outside the groove, respectively. The orientational order parameters of Type 1 and Type 2 oligomers decrease with the increase of groove width, but the orientational order parameter of Type 3 oligomers is approximately equal to 0.1. In addition, observation of the orientational order parameters of Type 1 oligomers interacting with the grooved substrate at different interaction strengths decrease with increasing the groove width. Furthermore, the orientational order parameters of Type 1 oligomers within the narrowest (20 Å) and the widest (35 Å) groove with different depths were determined. For the narrowest groove, the arrangement of Type 1 oligomers will be influenced by the groove width. However, in the case of the widest groove, the orientational order parameter of Type 1 oligomers is approximately equal to 0.2. This study can help engineers clarify the characteristics and phenomena of physical adsorption of the molecules, as well as contributing to the application of recent technology.

Les cellules LGBC (Laser Grooves Buried Contact) ont été inventées et développées par M. GRENN au sein de l'UNSW. Elles présentent des contacts métal/silicium enterrés permettant d'optimiser le contact métal/silicium sans augmenter le taux d'ombrage de la cellule. Dans ce manuscrit nous étudierons toutes les étapes clefs nécessaires à la réalisation de ce type de cellules de façon à les rendre industrialisables. Dans un premier temps nous étudierons la réalisation de tranchées dans le silicium via deux lasers (vert & IR). Les paramètres de ces tranchées seront comparées pour sélectionner les plus adaptées à notre technologie en nous assurant qu'il est possible de réaliser une diffusion thermique dans ces tranchées. Nous développerons ensuite deux techniques pour réaliser des émetteurs sélectifs, par double diffusion et par diffusion à travers une couche de nitrure de silicium. Enfin nous étudierons deux méthodes de dépôt de nickel par voie chimique une électrolytique et un electroless. / LGBC (Laser Grooved Buried Contact) solar cells was invented and developed by M.GREEN at UNSW. Grooved contact allow to reach a good serial resistivity without incresing the shadowing of the solar cell. In this report we will study the different step necessarry to build this kind of photovoltaic cells. Fisrt we will see the impact of laser effects on silicon and the different parameters to adapte red and green laser for grooved contct. The we will study to way to create selective emitter, on by two diffusion and the second one by diffusion throught a silicon nitride layer. Then we will develope two nickel metallisation one electrolytique and one electroless.

SKLENÁŘ Luděk: Bulk forming technology of grooved charge. The project prepared as part of the Master-degree studies in the Manufacturing Technology and Management in Industry, concerns the technology design for manufacturing a grooved charge by cold bulk forming. Grade 12 040.3 (CSN) steel was used as the initial material. For the batch of 50,000 pieces per year are proposed three alternatives. The chosen option No. 1 is made of technology and tensile strength calculations for metal forming operations: upsetting, backwards extrusion, forward extrusion and calibrating. The grooved charge production is designed for two forming processes that will be realised at the Colombo press Agostino, which is part of the machinery park company Metaldyne Oslavany. The extruding dies for the manufacture are made of tool steel 19 655 and tool steel 19 830 is designed for extruding punches.

Transferring a unimanual motor skill to the untrained hand, a phenomenon known as cross-limb transfer, was shown to deteriorate as a function of age. While transcranial direct current stimulation (tDCS) ipsilateral to the trained hand facilitated cross-limb transfer in older adults, little is known about the contribution of the contralateral hemisphere to cross-limb transfer. In the present study, we investigated whether tDCS facilitates cross-limb transfer in older adults when applied over the motor cortex (M1) contralateral to the trained hand. Furthermore, the study aimed at investigating short-term recovery of tDCS-associated cross-limb transfer. In a randomized, doubleblinded, sham-controlled setting, 30 older adults (67.0 4.6 years, 15 female) performed a short grooved-pegboard training using their left hand, while anodal (a-tDCS) or sham-tDCS (s-tDCS) was applied over right M1 for 20 min. Left (LHtrained) - and right-hand (RHuntrained) performance was tested before and after training and in three recovery measures 15, 30 and 45 min after training. LHtrained performance improved during both a-tDCS and s-tDCS and improvements persisted during recovery measures for at least 45 min. RHuntrained performance improved only following a-tDCS but not after s-tDCS and outlasted the stimulation period for at least 45 min. Together, these data indicate that tDCS over the M1 contralateral to the trained limb is capable of enhancing cross-limb transfer in older adults, thus showing that cross-limb transfer is mediated not only by increased bi-hemispheric activation.

No / Gas chromatography (GC), GC-mass spectrometry (GC-MS) and GC-combustion-isotope ratio MS (GC-C-IRMS) analyses of absorbed and surface lipid residues preserved in potsherds were used to explore the extent of pig product processing exploitation in the later British Neolithic Grooved Ware tradition. Assessments were made regarding whether porcine lipids were associated with specific Grooved Ware traits, i.e. decoration, substyle, geographical area and type of site. Two hundred and twenty-two Grooved Ware potsherds were analysed, 70% of which contained lipid concentrations considered significant (>5 μg g−1). All the lipid residues were dominated by animal fats, although plant and beeswax were also detected in a small number of extracts. δ13C values of the major fatty acid components of degraded animal fats (C16:0 and C18:0) were determined for 126 extracts and used to assign ruminant or porcine origins to the residues; 16% of these were found to have a predominantly porcine isotope signature. Statistical associations with pig exploitation were shown to exist with substyle, geographical area and site type, whereas, no relationship was seen between decoration and the type of commodity processed. Intact triacylglycerols were preserved in 19% of the sherds; half of these had distributions consistent with the identifications based on δ13C values, the remainder differed either due to the presence of mixed commodities or because lower molecular weight homologues had been lost due to degradation. In addition to the detection of pig exploitation, results from lipid residue analysis showed a good correlation with faunal assemblages, suggesting that stable isotope analysis may be used as a proxy for animal exploitation at sites where bones have not survived.

Capillary pumped loop (CPL) and loop heat pipe (LHP), are two-phase heat transport devices which rely on surface tension induced by a fine pore wick to drive a working fluid in a loop. These are based on a working principle similar to that of heat pipes -closed evaporation and condensation cycle being maintained by capillary pumping. CPLs and LHPs are gaining importance as a part of the thermal control system of modern high power spacecraft, electronic thermal management, cryogenics, etc. A mathematical model to simulate the thermo-hydraulic performance of CPLs and LHPs is developed to aid in the design of such a spacecraft thermal control system. In this study a unified mathematical model to estimate thermal and hydraulic performance of a CPL and an LHP -with a two-phase or a hard-filled reservoir is presented. The steady state model is based on conservation of energy and mass in the system. Heat exchanges between the loop and the surroundings and pressure drops in the loop are calculated. The constant conductance regime in a CPL or an LHP occurs when the reservoir is hard-filled. It also occurs in an LHP if the condenser is fully utilised. The heat leak across the wick becomes significant in a hard-filled LHP since the core is no longer saturated and hence the mass flow rate must be calculated using an energy balance on the outer surface of the wick. Theoretical studies indicate that the core of a hard-filled CPL and LHP is always sub-cooled. Hard-filled LHPs (with a bayonet) cannot be operated under all conditions. If the heat exchange between the compensation chamber (of an LHP with bayonet) and the ambient is small then such an LHP will not deprime if the hard-filling occurs before the condenser opens. Deprime due to hard-filling is not expected if it occurs after the condenser opens. A laboratory model is built to demonstrate the operation of these two devices and to correlate the theoretical predictions with the experimental observations. The CPL/LHP laboratory model is fabricated and designed so that different evaporator and reservoir designs can be integrated into the test-rig and tested with different working fluids. Experiments are conducted on a three-port CPL with a tubular axially grooved (TAG) evaporator. This CPL is operated with three different fluids -namely -Ammonia, Acetone and R134a. The CPL is operated for heat loads in the range of 75W to 400W with sink temperatures of -10◦C and 0◦C. The influence of reservoir temperature (35◦C and 43◦C) is also studied. The TAG evaporator is modified to operate in an LHP mode with R134a as the working fluid with heat loads in the range of 75W to 150W. This LHP does not exhibit typical “√” shaped operating characteristic due to large liquid inventory in the compensation chamber (CC). The R134a based LHP results suggest that large liquid inventory (in the CC) and absence of secondary wick significantly influence the thermal coupling between the core and the compensation chamber. Experiments are also conducted with a flat plate (FP) evaporator, in LHP operating mode, with Ammonia as the working fluid. This LHP can transport heat loads from 25W to 300W with a sink temperature at -15◦C. The experimental results indicate that ammonia is the best working fluid (moderate temperature regime) among all the working fluids tested, and that evaporation heat transfer coefficients in sintered Ni-wick are better. The correlation of the predicted temperatures on the transport lines and the saturation temperature (in LHPs) with the observations is good. Some of the salient conclusions from these experiments are that mass of charge can significantly influence the operating characteristics of a TAG LHP, even though the fluid in the CC is in two-phase condition. Theoretical predictions can be significantly affected when thermal and hydraulic development lengths in the condenser are comparable with the length of the sub-cooling section.

In this research, Fresnel zone plates were studied using an accurate, full-electromagnetic simulator based on the body-of-revolution finite-difference time-domain (BOR-FDTD) method. This tool was used to investigate zone plates for two different applications: zone plates used as antennas in communication systems and zone plates used as focusing elements in free-space, focused-beam measurement systems. Through detailed studies of zone plates for these applications, a number of general characteristics of the zone plate were given a more in-depth look than they have been given in the past. For the first application, parametric studies were performed for Soret, folded, and grooved-dielectric, phase-correcting zone plates for antenna applications. These studies were used to generate new design graphs, from which general observations are made about the effect of varying different parameters on the focusing ability of a zone plate. For the grooved-dielectric, phase-correcting zone plate, these studies show that a number of factors influence the focusing ability in ways that are unexpected, based on many of the simple techniques typically used to analyze zone plates. Each of these factors is evaluated individually. For the second application, a zone plate was designed to be used as a focusing element in a free-space, focused-beam measurement system. To determine the suitability of zone plates for this application, simulations and measurements of the electric field were used to compare this zone plate to a doubly-hyperbolic lens. A complete focused-beam system, using two zone plates as focusing elements, was used to measure the permittivity of different dielectric materials. These measurements are compared to results for a system that uses doubly-hyperbolic lenses and to published values. A technique for increasing the usable bandwidth of a zone plate in a focused-beam system was proposed and tested. Finally, as a topic for future research, the question is posed: Using the BOR-FDTD method, can a similar volume of material be shaped in a way that results in improved focusing performance compared to a traditional zone plate? Some insight into this open-ended question can be gained by examining preliminary results of the optimization of zone plates using of a genetic algorithm.

Le projet e-MECA : electro-Mécanique Embarquée à Compacité Améliorée, dont l’objectif est de concevoir une machine ultra compacte et ultra rapide à une puissance utile de 12Kw, trouve son application dans les véhicules mild et full hybrides. Ce type de machine présente en effet un fort potentiel de déploiement industriel en très grandes séries à des prix abordables. Pour ces machines, les pertes de charge liées aux écoulements dans le jeu constituent des enjeux essentiels pour les constructeurs. La présente étude porte sur le moyen d’identifier de ces pertes des machines électriques ultra-compactes et ultra-rapides (50 000 rpm).Cette thèse a pour objet l’étude des pertes aérauliques dans l’espace entre le rotor et le stator d’une machine électrique ultra-rapide (≈ 250 m/s) et ultra-compacte (0,5mm - 2mm d’entrefer), en cherchant à répondre aux spécifications élaborées par nos partenaires dans le cadre du projet e-MECA. / The project e-MECA: electromechanical engineering Embarked in Improved Compactness, the objective of which is to design a machine with a small gap and high speed rotor with a useful power of 12Kw, finds its application in mild and hybrid vehicle. This type of machine indeed presents a high potential in the industrial deployment in very big series to affordable prices. The losses in these machines are linked to the flow in the gap has a significant importance for the manufacturers. This study aims to identify these losses for the ultra-compact and ultrafast electric machines (50 000 rpm).This thesis is a study of the air losses in the space between the rotor and the stator of an ultra-fast electric machine (≈ 250 m/s) and ultra-compact (0,5mm - 2mm of air-gap). This study was done to meet the specifications that had been elaborated by our partners in the e-MECA project.

An approach to hybrid cooling technique is proposed using air jets which impinge on a triangular grooved surface with dry grooves and grooves containing water. One major application is for condensers of thermoelectric power plants. The heat and mass transfer analogy were successfully used to evaluate the simultaneous heat and mass transfer. Results showed that hybrid jet impingement produced high heat flux levels at low jet velocities and flow rates. Experimental results were used to characterize the resulting heat transfer under different conditions such as flow open area percentage, array orifices diameter and array to surface stand-off distance. The results have shown that jet impingement is capable of delivering high transfer rates with lower cooling cost rates compared to current industry conventional techniques. Water is efficiently used in hybrid jet impingement because evaporative energy is absorbed directly from the surface instead of cooling air to near wet-bulb temperature. / Master of Science / Array jet impingement cooling experiments were conducted on a triangular grooved surface with the surface at a constant temperature. Results showed that jet impingement can provide high transfer rates with lower rates of cooling cost in comparison to contemporary conventional techniques in the industry. Experiments on the triangular grooved surfaces were performed at dry and wet surface conditions. Under the dry conditions, the objective is to characterize the resulting heat transfer under varying operational conditions such as jet speed, array orifice diameter, array to surface stand-off distance, and flow open area percentage. Results from the triangular surface when dry showed less improvement in heat transfer than the rectangular grooved surface. A hybrid cooling technique approach was proposed and developed by using air jets impinging on a triangular grooved surface with the grooves containing water. The approach is being suggested and experimentally tested for its viability as an alternative to thermoelectric power plant cooling towers. Convection heat and mass transfer coefficients were experimentally measured for different wet coverage of the surface. Results showed that the hybrid jet impingement produced high heat flux levels at low jet velocities and flow rates. The highest heat transfer was consistently found with a 50% coverage of the surface. Hybrid jet impingement showed an improvement up to 500% in heat transfer as compared to jet impingement on a dry grooved surface.

Array jet impingement cooling experiments were performed on flat and grooved surfaces with the surface at a constant temperature. For the flat surface, power and temperature measurements were performed to obtain convection coefficients under a wide range of operating conditions such as jet speed, orifice to surface stand-of distance, and open area percentage. Cooling performance (CP) was calculated as the ratio between heat transfer and fan power. An empirical model was developed to predict jet impingement heat transfer taking into account the entrainment effects. Experimental results showed that jet impingement can provide high transfer rates with lower rates of cooling cost in comparison to contemporary conventional techniques in the industry. CP values over 279 were measured which are significantly higher than the standard values of 70 to 95 in current technology. The model enhanced prediction accuracy by taking into account the entrainment effects; an effect that is rarely considered in the literature. Experiments on the grooved surfaces were performed at dry and wet surface conditions. Under dry conditions, results showed 10%~55% improvement in heat transfer when compared to the flat surface. Improvement percentage tends to be higher at wider gaps between the array of orifices and the grooved surface. An improvement of 30%~40% was observed when increasing Re either by increasing orifice diameter or jet speed. Similar improvement was observed at higher flow open area percentages. No significant improvement in heat transfer resulted from decreasing the size of the grooves from 3.56mm to 2.54mm. Similarly, no noticeable change in heat transfer resulted from changing the relative position of the jets striking the surface at the top of the grooves to the bottom of the grooves. Deeper grooves with twice the depth gave statistically similar average heat transfer coefficients as shallower grooves. Under wet conditions, a hybrid cooling technique approach was proposed by using air jets impinging on a grooved surface with the grooves containing water. The approached is proposed and evaluated experimentally for its feasibility as an alternative for cooling towers of thermoelectric power plants. Convection heat and mass transfer coefficients were measured experimentally using the heat mass transfer analogy. Results showed that hybrid jet impingement provided high magnitudes of heat flux at low jet speeds and flow rates. High coefficients of performance CP > 3000, and heat fluxes > 8,000W/m2 were observed. Hybrid jet impingement showed 500% improvement as compared to jet impingement on a dry flat surface. CP values of hybrid jet impingement is 600% to 1,500% more as compared to performance of air-cooled condensers and wet cooling towers. Water use for hybrid jet impingement cooling is efficient since evaporation energy is absorbed from the surface directly instead of cooling air to near wet-bulb temperature. / PHD / This thesis explored the possibility of using air jets on the outside surface of a device that is used to condense steam. An experiment apparatus was used to imitate the conditions of steam condensation in the lab. A flat metallic surface was heated by placing an electric heater beneath it. The metallic surface was cooled using air jets coming out of orifices situated above the hot metallic surface. A fan, connected to an electric motor, was used to create the air jets. The amount of heat transfer was measured by measuring the electric power the heater consumed. This measured power was compared to the power needed to run the fan. The ratio of heat transfer to fan power is called the coefficient of performance CP. The CP values of more than 200 were obtained when air jets were used meaning that we need one kilowatt of mechanical power to remove 200 kilowatts of heat. This CP value is 300% more than the current technology used in the industry where CP ranges from 70 to 90. This means that we can build very efficient steam condensers for power plants. This type of condensers that uses air jets allows the power plant to be efficient and to be able to increase the amount of power generated without extra cost. Further enhancement of the CP can be achieved by making the hot surface grooved instead of flat with the grooves containing water. Air jets, coming out of orifices situated above the grooved surface, were used for cooling. The CP values of more than 3,000 were obtained when air jets were used with wet grooved surface. This CP values is 1,500% more than the current technology used in the industry. This type of condensers that uses air jets on wet grooves allows the power plant to be efficient and to be able to tremendously increase the amount of power generated without extra power and water costs.